The purpose of this study is to investigate the catalytic effects of alkali and alkaline earth metallic species （AAEM） on char conversion during the gasification in steam and the changes in ex-situ char reactivity i...The purpose of this study is to investigate the catalytic effects of alkali and alkaline earth metallic species （AAEM） on char conversion during the gasification in steam and the changes in ex-situ char reactivity in oxygen after the gasification in steam using different forms （i.e. H-form, Na-form） of Shengli brown coal. The surface area, AAEM concentration and carbon crystallite of chars were obtained to understand the change in char reactivity. It was found that not only Na concentration and carbon structure were the main factors governing the char reactivity in the atmosphere of steam and oxygen, but also they interacted each other. The presence of Na could facilitate the formation of disordering carbon structure in char, and the amorphous carbon structure would in turn affect the distribution of Na and thus its catalytic performance. The surface area and pore volume had very little relationship with the char＇s reactivity. Addi- tionally, the morphology of chars from different forms of coals were observed using scanning electron microscope （SEM）.展开更多
Boiler fan is the main power consumption device in thermal power units and the induced draft fan accounted for the largest proportion. Reducing the energy consumption rate of induced draft fan is the main path to redu...Boiler fan is the main power consumption device in thermal power units and the induced draft fan accounted for the largest proportion. Reducing the energy consumption rate of induced draft fan is the main path to reduce the power consumption rate of thermal power units. The induce fan driven by small turbine is greatly effective for reducing the power consumption rate and the supply coal consumption rate in large thermal power plant. Take 1000 MW power units for example, the selection of steam source for steam turbine were discussed and economic performance of the unit under different steam source was compared in this paper. The result shows that compared with the motor driven method, there is about 1.6 g/kWh decrease in supply coal consumption rate driven by the fourth stage extraction steam;whereas there is about 2.5 g/kWh decrease in supply coal consumption rate driven by the fifth stage extraction steam.展开更多
The effects of reactant composition and steam on propane combustion over Pd/LaFe_ 0.8Co_ 0.2O_3 catalyst were investigated. Propane conversion and the oxidation state of palladium were strongly affected by the redox...The effects of reactant composition and steam on propane combustion over Pd/LaFe_ 0.8Co_ 0.2O_3 catalyst were investigated. Propane conversion and the oxidation state of palladium were strongly affected by the redox ratio of reactants. Higher propane conversion could be obtained under rich conditions and explained as a complex balance between oxidation and steam reforming. Water produced in the oxidation could promote the propane conversion by steam reforming. However, the presence of excess steam would bring about inhibition.展开更多
Internal reformation of low steam methane fuel is highly beneficial for improving the energy efficiency and reducing the system complexity and cost of solid oxide fuel cells(SOFCs).However,anode coking for the Ni-base...Internal reformation of low steam methane fuel is highly beneficial for improving the energy efficiency and reducing the system complexity and cost of solid oxide fuel cells(SOFCs).However,anode coking for the Ni-based anode should be prevented before the technology becomes a reality.A multi-physics fully coupled model is employed to simulate the operations of SOFCs fueled by low steam methane.The multi-physics model produces I-V relations that are in excellent agreement with the experimental results.The multi-physics model and the experimental non-coking current density deduced kinetic carbon activity criterion are used to examine the effect of operating parameters and the anode diffusion barrier layer on the propensity of carbon deposition.The interplays among the fuel utilization ratio,current generation,thickness of the barrier layer and the cell operating voltage are revealed.It is demonstrated that a barrier layer of 400μm thickness is an optimal and safe anode design to achieve high power density and non-coking operations.The anode structure design can be very useful for the development of high efficiency and low cost SOFC technology.展开更多
文摘The purpose of this study is to investigate the catalytic effects of alkali and alkaline earth metallic species （AAEM） on char conversion during the gasification in steam and the changes in ex-situ char reactivity in oxygen after the gasification in steam using different forms （i.e. H-form, Na-form） of Shengli brown coal. The surface area, AAEM concentration and carbon crystallite of chars were obtained to understand the change in char reactivity. It was found that not only Na concentration and carbon structure were the main factors governing the char reactivity in the atmosphere of steam and oxygen, but also they interacted each other. The presence of Na could facilitate the formation of disordering carbon structure in char, and the amorphous carbon structure would in turn affect the distribution of Na and thus its catalytic performance. The surface area and pore volume had very little relationship with the char＇s reactivity. Addi- tionally, the morphology of chars from different forms of coals were observed using scanning electron microscope （SEM）.
文摘Boiler fan is the main power consumption device in thermal power units and the induced draft fan accounted for the largest proportion. Reducing the energy consumption rate of induced draft fan is the main path to reduce the power consumption rate of thermal power units. The induce fan driven by small turbine is greatly effective for reducing the power consumption rate and the supply coal consumption rate in large thermal power plant. Take 1000 MW power units for example, the selection of steam source for steam turbine were discussed and economic performance of the unit under different steam source was compared in this paper. The result shows that compared with the motor driven method, there is about 1.6 g/kWh decrease in supply coal consumption rate driven by the fourth stage extraction steam;whereas there is about 2.5 g/kWh decrease in supply coal consumption rate driven by the fifth stage extraction steam.
文摘The effects of reactant composition and steam on propane combustion over Pd/LaFe_ 0.8Co_ 0.2O_3 catalyst were investigated. Propane conversion and the oxidation state of palladium were strongly affected by the redox ratio of reactants. Higher propane conversion could be obtained under rich conditions and explained as a complex balance between oxidation and steam reforming. Water produced in the oxidation could promote the propane conversion by steam reforming. However, the presence of excess steam would bring about inhibition.
基金supported by the National Natural Science Foundation of China (No.11574284 abd No.11774324)the National Basic Research Program of China (No.2012CB215405)Collaborative Innovation Center of Suzhou Nano Science and Technology
文摘Internal reformation of low steam methane fuel is highly beneficial for improving the energy efficiency and reducing the system complexity and cost of solid oxide fuel cells(SOFCs).However,anode coking for the Ni-based anode should be prevented before the technology becomes a reality.A multi-physics fully coupled model is employed to simulate the operations of SOFCs fueled by low steam methane.The multi-physics model produces I-V relations that are in excellent agreement with the experimental results.The multi-physics model and the experimental non-coking current density deduced kinetic carbon activity criterion are used to examine the effect of operating parameters and the anode diffusion barrier layer on the propensity of carbon deposition.The interplays among the fuel utilization ratio,current generation,thickness of the barrier layer and the cell operating voltage are revealed.It is demonstrated that a barrier layer of 400μm thickness is an optimal and safe anode design to achieve high power density and non-coking operations.The anode structure design can be very useful for the development of high efficiency and low cost SOFC technology.
