Temperature and stress fields in electron beam welded Ti-15-3 alloy to 304 stainless steel joint with copper interlayer sheet

Electron beam welding of Ti-15-3 alloy to 304 stainless steel （STS） using a copper filler metal was carried out. The temperature fields and stress distributions in the Ti/Fe and Ti/Cu/Fe joint during the welding process were numerically simulated and experimentally measured. The results show that the rotated parabola body heat source is fit for the simulation of the electron beam welding. The temperature distribution is asymmetric along the weld center and the temperature in the titanium alloy plate is higher than that in the 304 STS plate. The thermal stress also appears to be in asymmetric distribution. The residual tensile stress mainly exists in the weld at the 304 STS side. The copper filler metal decreases the peak temperature and temperature grade in the joint as well as the residual stress. The longitudinal and lateral residual tensile strengths reduce by 66 MPa and 31 MPa, respectively. From the temperature and residual stress, it is concluded that copper is a good filler metal candidate for the electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel.

Effect of Aging Temperature on Erosion-Corrosion Behavior of 17-4PH Stainless Steels in Dilute Sulphuric Acid Slurry

The effect of aging temperature on erosion corrosion （E-C） behavior of 17-4PH stainless steels in dilute sulphuric acid slurry containing solid particles was studied by using self-made rotating E-C apparatus. The effect of impact velocity on EC behavior of 17 4PH steels at different aging temperatures was analyzed. Surface micrographs of the specimens after E C test were observed by using scanning electron microscope （SEM）. The results showed that under the condition of the same solution heat treatment, when aging temperature ranged from 400 ℃ to 610℃, the hardness reached the highest value near the temperature 460℃. The characteristics of E-C for 17-4PH stainless steels at different aging temperatures were as follows： pure erosion （wear） was dominant, corrosion was subordinate and at the same time corrosion promoted erosion. The effect of aging temperature on E-C rate of 17-4PH steels was not significant at low impact velocity, but it was found that E-C resistance of 17-4PH steels aged near 460℃ was the most excellent due to the best precipitation strengthening effect of fine and dispersed e-Cu phase. With a prerequisite of appropriate corrosion resistance, the precipitation hardening could significantly improve the E-C resistance of the materials.

Deformation behaviors of 21-6-9 stainless steel tube numerical control bending under different friction conditions

For contact dominated numerical control(NC) bending process of tube, the effect of friction on bending deformation behaviors should be focused on to achieve precision bending forming. A three dimensional(3D) elastic-plastic finite element(FE) model of NC bending process was established under ABAQUS/Explicit platform, and its reliability was validated by the experiment. Then, numerical study on bending deformation behaviors under different frictions between tube and various dies was explored from multiple aspects such as wrinkling, wall thickness change and cross section deformation. The results show that the large friction of wiper die-tube reduces the wrinkling wave ratio η and cross section deformation degree ΔD and increases the wall thinning degree Δt. The large friction of mandrel-tube causes large η, Δt and ΔD, and the onset of wrinkling near clamp die. The large friction of pressure die-tube reduces Δt and ΔD, and the friction on this interface has little effect on η. The large friction of bending die-tube reduces η and ΔD, and the friction on this interface has little effect on Δt. The reasonable friction coefficients on wiper die-tube, mandrel-tube, pressure die-tube and bending die-tube of 21-6-9(0Cr21Ni6Mn9N) stainless steel tube in NC bending are 0.05-0.15, 0.05-0.15, 0.25-0.35 and 0.25-0.35, respectively. The results can provide a guideline for applying the friction conditions to establish the robust bending environment for stable and precise bending deformation of tube bending.

Effect of rare earths on mechanical properties of plasma nitrocarburized surface layer of 17-4PH steel

The aim of this investigation is to reveal the influence of rare earths(RE) addition on mechanical properties of plasma nitrocarburized 17-4PH steel.The nitrocarburized layers were characterized by optical microscope,scanning electron microscope equipped with energy dispersive X-ray analyzer,X-ray diffractometer,microhardness tester and pin-on-disc tribometer.The results showed that RE atoms could diffuse into the surface layer of 17-4PH steel plasma nitrocarburized at 500 °C for 4 h and did not change the ...

Relationship of microstructure transformation and hardening behavior of type 17-4 PH stainless steel

The relationship between the microstructure transformation of type 17-4 PH stainless steel and the aging hardening behavior was investigated. The results showed that, when 17-4 PH stainless steel aging at 595℃, the bulk hardness of samples attains its peak value （42.5 HRC） for about 20 min, and then decreases at all time. TEM revealed the microstructure corresponding with peak hardness is that the fine spheroid-shape copper with the fcc crystal structure and the fiber-shape secondary carbide M23C6 precipitated from the lath martensite matrix. Both precipitations of copper and M23C6 are the reasons for strengthening of the alloy at this temperature. With the extension of holding time at this temperature, the copper and secondary carbide grow and lose the coherent relationship with the matrix, so the bulk hardness of samples decreases.

Electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel with copper interlayer sheet

Electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel with a copper sheet as interlayer was carried out.Microstructures of the joint were studied by optical microscopy(OM),scanning electron microscopy(SEM) and X-ray diffractometry(XRD).In addition,the mechanical properties of the joint were evaluated by tensile test and the microhardness was measured.These two alloys were successfully welded by adding copper transition layer into the weld.Solid solution with a certain thickness was located at the interfaces between weld and base metal in both sides.Regions inside the weld and near the stainless steel were characterized by solid solution of copper with TiFe2 intermetallics dispersedly distributed in it.While weld near titanium alloy contained Ti-Cu and Ti-Fe-Cu intermetallics layer,in which the hardness of weld came to the highest value.Brittle fracture occurred in the intermetallics layer when the joint was stretched.

A two-parameter model to predict fatigue life of high-strength steels in a very high cycle fatigue regime

In this paper, ultrasonic （20 kHz） fatigue tests were performed on specimens of a high-strength steel in very high cycle fatigue （VHCF） regime. Experimental results showed that for most tested specimens failed in a VHCF regime, a fatigue crack originated from the interior of specimen with a fish-eye pattern, which contained a fine granular area （FGA） centered by an inclusion as the crack origin. Then, a two-parameter model is proposed to predict the fatigue life of high-strength steels with fish-eye mode failure in a VHCF regime, which takes into account the inclusion size and the FGA size. The model was verified by the data of present experiments and those in the literature. Furthermore, an analytic formula was obtained for estimating the equivalent crack growth rate within the FGA. The results also indicated that the stress intensity factor range at the front of the FGA varies within a small range, which is irrespective of stress amplitude and fatigue life.

Microstructure and mechanical properties of similar and dissimilar metal gas tungsten constricted arc welds:Maraging steel to 13-8 Mo stainless steel

Maraging steel (250) and 13-8 Mo stainless steel plates were joined by gas tungsten constricted arc welding(GTCAW) process in similar and dissimilar metal combinations using 13-8 Mo stainless steel filler wire. The similar and dissimilar metal welds made in solutionized condition were subjected to standard post weld hardening treatments direct ageing at 485 ℃, soaking for 31/2 hours followed by air cooling(ageing treatment of maraging steel) and direct ageing at 510 ℃, soaking for 4 h followed by air cooling(ageing treatment of 13-8 Mo stainless steel). The joint characterization studies include microstructure examination, microhardness survey across the weldments and transverse weld tensile test.Similar and dissimilar metal weldments responded to both the post weld ageing treatment. After post weld aging, increase in yield strength, UTS and slight reduction in % elongation of similar and dissimilar metal were observed. The observed tensile properties were correlated with microstructure and hardness distribution across the welds.

Process for improving the ladle free- opening rate for high aluminum steel in continuous casting

Steel 20Mn23AlV is a type of high aluminum steel with a very low ladle free-opening rate. The aluminum composition of 20Mn23AlV ranges from 1.6% to 2.45% ,which is significantly higher than other types of steel. According to the real condition of 40 t ladle in steel-making plant of Baosteel Special Steel Company, previous works show that the key factors affecting the ladle free-opening rate of high aluminum steel in continuous casting are：sand material, accessories baking, ladle nozzle cleaning, the process and amount of adding sand, and the rate of argon stirring during refining. Therefore, improving the ladle filler sand quality, baking all of the raw materials, controlling the addition of ladle filler sand, cleaning the ladle nozzle, and optimizing argon stirring during the refining process can resolve the problem of a low ladle free-opening rate of high aluminum steel caused by the long ladle time of liquid steel.

EFFECT OF DYNAMIC STRAIN AGING ON LOW CYCLE FATIGUE BEHAVIOUR OF 18-8 AUSTENITIC STAINLESS STEEL

Studies were made of the symmetric tensile-compressive low cycle fatigue behaviour and the influence of dynamic strain aging(DSA)pre-treatment of 18-8 austenitic stainless steel. Within the testing amplitude range of strain.±0.5 % to±1.5 %,the three processes of cyclic hardening,cyclic saturation and cyclic softening were observed.In the same amplitude of strain,the peak stress of the samples pre-treated by DSA is higher than that of solid-solu- tion and cold working pre-treatment,but no remarkable differences of the fatigue lives of them were found.TEM observation shows that the uniform and stable dislocation networks with high density form after DSA pre-treatment,which increases the cyclic peak stress.The cyclic softening results from the low dislocation density and elongated cell structure with low energy.

The EVA plastic film for V-process and steel castings by V-process in China

EVA plastic film is the key material for V-process. Through decades of research, special EVA film for V-process has been produced. The film has adequate elongation; its maximum is about 800% in longitudinal direction and 750% in transversal direction. The single width of the film is 2.8 m and the double width is 5.6 m, which is the widest sheet film for V-process in China. Sheets with different thickness ranging from the thickest 0.35 mm to the thinnest 0.08 mm can meet different demands in China. The film can be used not only for V-process of iron castings, but also for the manganese steel railway frog, steel rocking support and side frame castings for train and the steel bridge box for engine truck.

Analysis of microstructure and performance of temper bead welded joints for SA508-3 steel by Quenching and Tempering mode

The HAZ microstructure and performance of Quenching and Tempering mode temper bead welding and general welded joints which were made on SA508-3 steel of 60 mm thickness were compared in this article. The result shows that tempering sorbite which has excellent overall performance was obtained in both modes. The microstructure of Quenching and Tempering mode welded joints got more fine grain. Even though the hardness of tempering bead welded joints is higher than the general one,it still meets the standards which is lower than 350 HV. The impact absorbing energy of each district of tempering bead welded joints HAZ reached 170 J,which is equal to general one.

Corrosive-wear resistance of stainless steels for the impeller of slurry pump used in zinc hydrometallurgy process

This paper presents corrosive-wear (C-W) behaviors of three kinds of steels under the simulating condition oftraditional zinc hydrometallurgy process by using a self-made rotating disk apparatus. Result shows that pure wear lossrate is significantly larger than pure corrosion loss rate. Under this C-W condition, the ranking of C-W resistance is S2 >S3 > S1 (S1: austenite stainless steel; S2: CD-4MCu duplex stainless steel; S3 :17-4PH stainless steel). S2 has excellentC-W resistance due to strong surface deformation strengthening effect of high-density dislocations of the γ phase. S3 alsohas excellent C-W resistance owing to high hardness and strength. However, S1 does not show good C-W resistanceunder strong erosion of liquid-solid slurry because of its single-phase austenitic structure and very low hardness. As aresult, duplex stainless steels as well as 17-4 PH stainless steel can be used as impeller candidate materials in the zinchydrometallurgy process due to their excellent C-W resistance and lower cost.

MIXED MODE SCC OF 18-8 STAINLESS STEEL IN BOILING 42% MgCl_2 SOLUTION

A series of mixed mode tests were carried out on 18-8 stainless steel in boiling 42% MgCl_2 solution.The results show that for any K_Ⅱ/K_Ⅰ ratio,the SCC direction coin- cides well with the crack tip maximum normal stress plane,while the SCC resistance of the material reduces as the ratio of K_Ⅱ/K_Ⅰ increases.The experimental results were discussed in the light of anode dissolving mechanism and the effect of mixed mode loading on crack tip stress and strain.It is concluded that for fracture analysis if mixed mode cracks were simply taken into account as mode Ⅰ cracks,and only mode Ⅰ testing results as mode Ⅰ fracture criter- ion were employed,it may not be safe.

The Influence of Preheat Temperature of Steel Plate on Steel-mushy Cu-graphite Bonding

The pressing bonding of steel plate to QTi3.5-3.5 graphite slurry was conducted. Under the conditions of 530 ℃ for the preheat temperature of dies, 45% for the solid fraction of QTi3.5- 3.5 graphite slurry, 50 MPa for the pressure and 2 min for the pressing time, the relationship between the preheat temperature of steel plate and interfacial mechanical property of bonding plate was studied. The results show that when the preheat temperature of steel plate is lower titan 618 ℃ , the interfacial shear strength of bonding plate increases with the increasing of the preheat temperature of steel plate. When the preheat temperature of steel plate is higher than 618 ℃ , the interfacial shear strength decreases with the increasing of the preheat temperature of steel plate. When the preheat temperature of steel plate is 618 ℃ , the highest interfacial shear strength of bonding plate of 127.8 MPa can be got.

Phase and CCT Diagram of an N-Containing 8%Cr Roller Steel

The pseudo-equilibrium phase diagram and continuous cooling transformation diagram of an N-containing 8％ Cr roller steel were investigated by using thermodynamic calculation,differential scanning calorimetry,Ⅹ-ray diffraction,expansion method,and so on.Under equilibrium conditions,the main carbonitrides are MX,M7C3,and M23C6 types.The measured Ac1,Ac3,start temperature of martensitic transformation,and M7C3 transformation temperatures are 811,855,324,and 1100 ℃,respectively.Bainite appears at cooling rates ranging from 0.5 to 5 ℃/s and ferrite forms at grain boundaries at a cooling rate lower than 0.5 ℃/s.Finally,the effects of adding N and lowering the C content on workability and mechanical properties of common 8％Cr steel were discussed.

Effect of Heat Treatment on Mechanical Properties and Microstructure of NST 37-2 Steel

Engineering materials, mostly steel, are heat treated under controlled sequence of heating and cooling to alter their physical and mechanical properties to meet desired engineering applications. In this study, the effect of heat treatment (annealing, normalising, hardening, and tempering) on the microstructure and some selected mechanical properties of NST 37-2 steel were studied. Sample of steel was purchased from local market and the spectrometry analysis was carried out. The steel samples were heat treated in an electric furnace at different temperature levels and holding times;and then cooled in different media. The mechanical properties (tensile yield strength, ultimate tensile strength, Young’s modulus, percentage reduction, percentage elongation, toughness and hardness) of the treated and untreated samples were determined using standard methods and the microstructure of the samples was examined using metallographic microscope equipped with camera. Results showed that the mechanical properties of NST 37-2 steel can be changed and improved by various heat treatments for a particular application. It was also found that the annealed samples with mainly ferrite structure gave the lowest tensile strength and hardness value and highest ductility and toughness value while hardened sample which comprise martensite gave the highest tensile strength and hardness value and lowest ductility and toughness value.

Corrosion Resistance of Heat-Treated NST 37-2 Steel in Hydrochloric Acid Solution

Corrosion of metal components constitutes a major challenge in many engineering systems, with appropriate design, proper material selection, and heat treatment as commonly used control strategies. In this study, the corrosion behaviour of heat-treated (annealed, normalised, hardened, and tempered) NST 37-2 steel in three concentrations (1.0, 1.5 and 2.0 M) of hydrochloric acid solution was investigated using weight loss and electrode-potential methods. Results showed that corrosion rate increased with increase in acid concentration. The decreasing order of corrosion resistance was Tempered > Annealed > Normalised > Hardened > Untreated. The surface pictures of the heat-treated and untreated samples showed uniform and pitting corrosion with the latter becoming more pronounced as concentration increased.

Adsorption properties of CFBC ash-cement pastes as compared with PCC fly ash-cement pastes

Circulating fluidized bed combustion （CFBC） ash can be potentially used as supplementary cementitious materials for concrete production due to its desirable pozzolanic activity. The adsorption properties of CFBC ash-cement pastes were studied, and ordinary pulverized coal combustion （PCC） fly ash-cement pastes were used as control. The water-adsorption and superplasticizer （SP）-adsorption properties of the pastes were evaluated by water demand and UV-visible absorption spectroscopy respectively. The results show that CFBC ash-cement system has greater compressive strength as compared with PCC fly ash-cement system at a given curing age, although the water demand of the former is significantly higher than that of the latter. CFBC ash-cement pastes possess higher adsorption ability of aliphatic SP than PCC fly ash-cement pastes and the adsorption amount increases with an increase in ash replacement ratio. CFBC ash- cement pastes exhibit lower workability with higher slump loss. It is concluded that CFBC ash can be potentially used as supplementary cementitious material in concrete production, but the mix design of CFBC ash concrete needs to be appropriately adjusted. It is suggested that CFBC ash is used for the production of the concrete needing low flowability.

Effect of nitrite intercalated Mg-Al layered double hydroxides on mortar durability under Cl−and SO_(4)^(2-) coexisting environment

The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.