为判别炉管的损伤程度和运行安全性,本文对运行了约46 000 h的苯乙烯生产加热炉炉管,在大修期间进行了宏观检查、氧化物的XRD(X-ray d iffraction)分析、管径测量、超声波测厚、硬度试验、金相组织分析及炉管的危险点计算分析等。实验...为判别炉管的损伤程度和运行安全性,本文对运行了约46 000 h的苯乙烯生产加热炉炉管,在大修期间进行了宏观检查、氧化物的XRD(X-ray d iffraction)分析、管径测量、超声波测厚、硬度试验、金相组织分析及炉管的危险点计算分析等。实验结果表明:炉管表面发生了高温氧化以及碳化腐蚀,炉管壁厚明显减薄。与新管相比硬度也明显下降,显微组织明显退化,骨架状共晶碳化物形态消失,一次碳化物和从奥氏体晶内析出的二次碳化物明显粗化,且析出少量块状σ相。并在此基础上对炉管的剩余使用寿命作了估算。展开更多
To alleviate catalytic coking on the inner surface of radiant tube for ethylene production in petrochemical plants,SiO2/S coatings were deposited on HP40 alloy specimens using dimethyldisulfide （DMDS） and tetraethox...To alleviate catalytic coking on the inner surface of radiant tube for ethylene production in petrochemical plants,SiO2/S coatings were deposited on HP40 alloy specimens using dimethyldisulfide （DMDS） and tetraethoxysilane （TEOS） by atmospheric pressure chemical vapor deposition （APCVD）. A two-dimension mathematical model was made to predict the growth rate of SiO2/S coating and to study the effects of deposition parameters on the deposition rate. The results show that the predicted deposition rate is in good agreement with the experimental one. The deposition rate mainly depends on the concentrations of precursors in the total gas flow, concentrations of intermediates on the deposition surface, total gas flow rate and deposition temperature. The weight of SiO2/S coating linearly increases with the deposition time. When the gas flow rate is below 0.3 m/s, the rate-limiting step of SiO2/S coating deposition is the diffusions of intermediates.However, the surface reactions of intermediates will be the rate-limiting step after the gas flow rate is above 0.3 m/s. When the deposition temperature is below 780℃, the rate-limiting step of SiO2/S coating deposition mainly depends on the surface reactions of intermediates. When the deposition temperature is above 780℃,the rate-limiting step depends on the diffusions of intermediates. The deposition rate increases with increasing the concentrations of the intermediates. However, when the partial pressures of the intermediates reach 8 Pa,the deposition rate keeps constant.展开更多
文摘为判别炉管的损伤程度和运行安全性,本文对运行了约46 000 h的苯乙烯生产加热炉炉管,在大修期间进行了宏观检查、氧化物的XRD(X-ray d iffraction)分析、管径测量、超声波测厚、硬度试验、金相组织分析及炉管的危险点计算分析等。实验结果表明:炉管表面发生了高温氧化以及碳化腐蚀,炉管壁厚明显减薄。与新管相比硬度也明显下降,显微组织明显退化,骨架状共晶碳化物形态消失,一次碳化物和从奥氏体晶内析出的二次碳化物明显粗化,且析出少量块状σ相。并在此基础上对炉管的剩余使用寿命作了估算。
文摘To alleviate catalytic coking on the inner surface of radiant tube for ethylene production in petrochemical plants,SiO2/S coatings were deposited on HP40 alloy specimens using dimethyldisulfide （DMDS） and tetraethoxysilane （TEOS） by atmospheric pressure chemical vapor deposition （APCVD）. A two-dimension mathematical model was made to predict the growth rate of SiO2/S coating and to study the effects of deposition parameters on the deposition rate. The results show that the predicted deposition rate is in good agreement with the experimental one. The deposition rate mainly depends on the concentrations of precursors in the total gas flow, concentrations of intermediates on the deposition surface, total gas flow rate and deposition temperature. The weight of SiO2/S coating linearly increases with the deposition time. When the gas flow rate is below 0.3 m/s, the rate-limiting step of SiO2/S coating deposition is the diffusions of intermediates.However, the surface reactions of intermediates will be the rate-limiting step after the gas flow rate is above 0.3 m/s. When the deposition temperature is below 780℃, the rate-limiting step of SiO2/S coating deposition mainly depends on the surface reactions of intermediates. When the deposition temperature is above 780℃,the rate-limiting step depends on the diffusions of intermediates. The deposition rate increases with increasing the concentrations of the intermediates. However, when the partial pressures of the intermediates reach 8 Pa,the deposition rate keeps constant.
