In this work,the microstructure,hydrogen storage properties,anti-oxide ability and rate limiting step of Zr(Cr_(1−x)Co_(x))_(2)(x=0,0.2,0.4 and 0.6)alloys have been investigated.After studying the crystal structure,we...In this work,the microstructure,hydrogen storage properties,anti-oxide ability and rate limiting step of Zr(Cr_(1−x)Co_(x))_(2)(x=0,0.2,0.4 and 0.6)alloys have been investigated.After studying the crystal structure,we found that all alloy samples could show C14-type phase but the alloy sample x=0 could also show a small amount of Cr phase.Rietveld fitting showed that lattice parameter and unit cell volume of C14-type phase decreased with increasing x.After further research,it was clear that the first hydrogen absorption capacity decreased with increasing x.But introducing more Co content had a positive influence on the effective hydrogen storage capacity and cyclic hydrogen absorption and desorption properties of the alloy sample.We also found that adding Co to ZrCr_(2)alloy could improve its anti-oxide ability.In addition to this,the rate limiting step model was also studied.展开更多
The design of the active region structures,including the modifications of structures of the quantum barrier(QB)and electron blocking layer(EBL),in the deep ultraviolet(DUV)Al Ga N laser diode(LD)is investigated numeri...The design of the active region structures,including the modifications of structures of the quantum barrier(QB)and electron blocking layer(EBL),in the deep ultraviolet(DUV)Al Ga N laser diode(LD)is investigated numerically with the Crosslight software.The analyses focus on electron and hole injection efficiency,electron leakage,hole diffusion,and radiative recombination rate.Compared with the reference QB structure,the step-like QB structure provides high radiative recombination and maximum output power.Subsequently,a comparative study is conducted on the performance characteristics with four different EBLs.For the EBL with different Al mole fraction layers,the higher Al-content Al Ga N EBL layer is located closely to the active region,leading the electron current leakage to lower,the carrier injection efficiency to increase,and the radiative recombination rate to improve.展开更多
2195 aluminum-lithium alloy was widely applied in the aviation and aerospace industry, but it is highly susceptible to pitting and intergranular corrosion undergoing sever corrosive circumstance and moisture atmospher...2195 aluminum-lithium alloy was widely applied in the aviation and aerospace industry, but it is highly susceptible to pitting and intergranular corrosion undergoing sever corrosive circumstance and moisture atmosphere. To solve this problem and consequently to prolong its service life, a multi-step-heating-rate(MSRC) process was carried out. Investigations were carried out to find the effect of the MSRC process on the alloys corrosion resistance. It is found that the MSRC process is more favorable for the uniform phase precipitation by comparing the corrosion resistance of samples treated by traditional heat treatments. The potential difference between phases can be reduced and intergranular corrosion is able to be prohibited efficiently. Besides, the rare earth infiltration is beneficial to improving the corrosion resistance. As heating time increases, the corrosion resistance declines gradually, samples treated by artificial aging and solid solution also exhibit a better corrosion resistance.展开更多
In this research, a vermicular graphite cast iron brake drum was produced by cored wire injection in a one-step method. Silica sand and low-density alumina-silicate ceramic were used as molding materials in order to i...In this research, a vermicular graphite cast iron brake drum was produced by cored wire injection in a one-step method. Silica sand and low-density alumina-silicate ceramic were used as molding materials in order to investigate the effect of cooling rate on percentage of vermicular graphite and mechanical properties of the brake drum casting. Several thermocouples were inserted into the casting in the desired positions to measure the temperature change. By means of one-step cored wire injection, the two residual concentrations of Mg and RE were effectively controlled in the ranges of 0.013%-0.017% and 0.019%-0.025%, respectively, which are crucial for the production of vermicular graphite cast iron and the formation of vermicular graphite. In addition, the cooling rate had a significant effect on the vermicular graphite percentage. In the case of the silica mold brake drum casting, there was an obvious difference in the cooling rate with the wall change, leading to a change in vermicular graphite percentage from 70.8% to 90%. In the low-density alumina-silicate ceramic mold casting, no obvious change in temperature was detected by the thermocouples and the percentage of the vermicular graphite was stable at 85%. Therefore, the vermicular graphite cast iron brake drum with a better combination of mechanical properties could be obtained.展开更多
Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipat...Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipathic Ru(bda)-based catalysts(bda=2,2'-bipyrdine-6,6'-dicarbonoxyl acid)and aliphatic chain decorated electrode surfaces,forming lipid bilayer membrane(LBM)-like structures.The Ru(bda)catalysts on electrode-supported LBM films demonstrated remarkable water oxidation performance with different O-O formation mechanisms.However,compared to the slow charge transfer process,the O-O formation pathways did not determine the PEC water oxidation efficiency of the dyesensitized photoanodes,and the different reaction rates for similar catalysts with different catalytic paths did not determine the PEC performance of the DSPECs.Instead,charge transfer plays a decisive role in the PEC water oxidation rate.When an indolo[3,2-b]carbazole derivative was introduced between the Ru(bda)catalysts and aliphatic chain-modified photosensitizer in LBM films,serving as a charge transfer mediator for the tyrosine-histidine pair in PSⅡ,the PEC water oxidation performance of the corresponding photoanodes was dramatically enhanced.展开更多
实车动力电池的健康状态(state of health,SOH)评估存在数据质量差、工况不统一、数据利用率低等问题,本文面向阶梯倍率充电工况构建多源特征提取及SOH估计模型。首先,通过数据清洗、切割、填充,获取独立的充电片段;其次,基于不同电流...实车动力电池的健康状态(state of health,SOH)评估存在数据质量差、工况不统一、数据利用率低等问题,本文面向阶梯倍率充电工况构建多源特征提取及SOH估计模型。首先,通过数据清洗、切割、填充,获取独立的充电片段;其次,基于不同电流阶段计算容量,实现原始数据利用率达96.9%,并与单独限定SOC范围计算容量的方法相比,误差降低48.1%以上;然后,从当前工况、历史累积两个维度提取多个健康因子,对于当前工况特征值,通过灰色关联度及干扰性随机森林重要度分析双重筛选。对于历史累积特征值,利用Spearson相关性分析和核主成分分析方法(kernel principal component analysis,KPCA)降低信息冗余;最后,对门控循环单元网络模型(gated recurrent unit,GRU)引入注意力机制和龙格库塔优化算法(Runge Kutta optimizer,RUN),建立RUN-GRU-attention模型,基于实车运行数据集与现有5种模型进行对比,实验结果表明,无论是包含单阶段还是多阶段电流的测试样本,优化模型的估计精度更佳,误差不高于0.0086,并且随着充电循环次数增加表现出良好的误差收敛性,可有效预测SOH波动趋势。展开更多
针对经典盲均衡算法收敛速度较慢和稳态误差较大的问题,提出了一种基于变步长恒模算法(Constant Modulus Algorithm, CMA)和判决引导的最小均方(Decision Directed Least Mean Square, DD-LMS)算法的双模式切换盲均衡算法。在算法收敛...针对经典盲均衡算法收敛速度较慢和稳态误差较大的问题,提出了一种基于变步长恒模算法(Constant Modulus Algorithm, CMA)和判决引导的最小均方(Decision Directed Least Mean Square, DD-LMS)算法的双模式切换盲均衡算法。在算法收敛初期采用CMA算法,以确保算法可以较快收敛。在收敛之后切换至DD-LMS算法,以进一步降低稳态误差。通过设定阈值来切换算法,取相邻多次迭代误差的平均值作为算法的切换值,以确保算法切换时机的合理性。另外,引入Softsign变步长函数并加入3个参数对该函数进行改进,使得Softsign变步长函数可以依据不同信道环境设定最佳参数,同时提高算法的收敛速度。仿真结果表明,在卫星通用信道条件下,所提算法的收敛迭代次数约为1 000次,稳态误差为-12 dB,在信噪比为15 dB时,误码率为1×10~(-6)。与相关算法对比,所提算法的收敛速度较高,误码率和稳态误差较低。展开更多
基金supported by Natural Science Foundation of Jiangxi Province(20202BABL214003)Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation(JXMS202008 and JXMS202009)+4 种基金Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices(PMND201902)Engineering Research Center of Nuclear Technology Application(East China University of Technology)Ministry of Education(HJSJYB2019–5)Science and Technology Project Founded by Education Department of Jiangxi Province(GJJ190406)Research Foundation for Advanced Talents of East China University of Technology(DHBK2019091).
文摘In this work,the microstructure,hydrogen storage properties,anti-oxide ability and rate limiting step of Zr(Cr_(1−x)Co_(x))_(2)(x=0,0.2,0.4 and 0.6)alloys have been investigated.After studying the crystal structure,we found that all alloy samples could show C14-type phase but the alloy sample x=0 could also show a small amount of Cr phase.Rietveld fitting showed that lattice parameter and unit cell volume of C14-type phase decreased with increasing x.After further research,it was clear that the first hydrogen absorption capacity decreased with increasing x.But introducing more Co content had a positive influence on the effective hydrogen storage capacity and cyclic hydrogen absorption and desorption properties of the alloy sample.We also found that adding Co to ZrCr_(2)alloy could improve its anti-oxide ability.In addition to this,the rate limiting step model was also studied.
基金Project supported by the Special Project for Inter-government Collaboration of State Key Research and Development Program,China(Grant No.2016YFE0118400)the Key Project of Science and Technology of Henan Province,China(Grant No.172102410062)the National Natural Science Foundation of China and Henan Provincial Joint Fund Key Project(Grant No.U1604263)
文摘The design of the active region structures,including the modifications of structures of the quantum barrier(QB)and electron blocking layer(EBL),in the deep ultraviolet(DUV)Al Ga N laser diode(LD)is investigated numerically with the Crosslight software.The analyses focus on electron and hole injection efficiency,electron leakage,hole diffusion,and radiative recombination rate.Compared with the reference QB structure,the step-like QB structure provides high radiative recombination and maximum output power.Subsequently,a comparative study is conducted on the performance characteristics with four different EBLs.For the EBL with different Al mole fraction layers,the higher Al-content Al Ga N EBL layer is located closely to the active region,leading the electron current leakage to lower,the carrier injection efficiency to increase,and the radiative recombination rate to improve.
基金Project(51471050105HK0101) supported by the National Key Laboratory of Precision Thermal Treatment, Harbin Institute of Technology,China
文摘2195 aluminum-lithium alloy was widely applied in the aviation and aerospace industry, but it is highly susceptible to pitting and intergranular corrosion undergoing sever corrosive circumstance and moisture atmosphere. To solve this problem and consequently to prolong its service life, a multi-step-heating-rate(MSRC) process was carried out. Investigations were carried out to find the effect of the MSRC process on the alloys corrosion resistance. It is found that the MSRC process is more favorable for the uniform phase precipitation by comparing the corrosion resistance of samples treated by traditional heat treatments. The potential difference between phases can be reduced and intergranular corrosion is able to be prohibited efficiently. Besides, the rare earth infiltration is beneficial to improving the corrosion resistance. As heating time increases, the corrosion resistance declines gradually, samples treated by artificial aging and solid solution also exhibit a better corrosion resistance.
基金financially supported by the Foundation of Heilongjiang Educational Committee(Grant No.12531116)the Harbin Special Funds for Creative Talents in Science and Technology(Grant No.2013RFQXJ102)
文摘In this research, a vermicular graphite cast iron brake drum was produced by cored wire injection in a one-step method. Silica sand and low-density alumina-silicate ceramic were used as molding materials in order to investigate the effect of cooling rate on percentage of vermicular graphite and mechanical properties of the brake drum casting. Several thermocouples were inserted into the casting in the desired positions to measure the temperature change. By means of one-step cored wire injection, the two residual concentrations of Mg and RE were effectively controlled in the ranges of 0.013%-0.017% and 0.019%-0.025%, respectively, which are crucial for the production of vermicular graphite cast iron and the formation of vermicular graphite. In addition, the cooling rate had a significant effect on the vermicular graphite percentage. In the case of the silica mold brake drum casting, there was an obvious difference in the cooling rate with the wall change, leading to a change in vermicular graphite percentage from 70.8% to 90%. In the low-density alumina-silicate ceramic mold casting, no obvious change in temperature was detected by the thermocouples and the percentage of the vermicular graphite was stable at 85%. Therefore, the vermicular graphite cast iron brake drum with a better combination of mechanical properties could be obtained.
基金conducted by the Fundamental Research Center of Artificial Photosynthesis(FReCAP)financially supported by the National Natural Science Foundation of China(22172011 and 22088102)+1 种基金the National Key R&D Program of China(2022YFA0911904)the Fundamental Research Funds for the Central Universities(DUT22LK06,DUT22QN213 and DUT23LAB611)。
文摘Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipathic Ru(bda)-based catalysts(bda=2,2'-bipyrdine-6,6'-dicarbonoxyl acid)and aliphatic chain decorated electrode surfaces,forming lipid bilayer membrane(LBM)-like structures.The Ru(bda)catalysts on electrode-supported LBM films demonstrated remarkable water oxidation performance with different O-O formation mechanisms.However,compared to the slow charge transfer process,the O-O formation pathways did not determine the PEC water oxidation efficiency of the dyesensitized photoanodes,and the different reaction rates for similar catalysts with different catalytic paths did not determine the PEC performance of the DSPECs.Instead,charge transfer plays a decisive role in the PEC water oxidation rate.When an indolo[3,2-b]carbazole derivative was introduced between the Ru(bda)catalysts and aliphatic chain-modified photosensitizer in LBM films,serving as a charge transfer mediator for the tyrosine-histidine pair in PSⅡ,the PEC water oxidation performance of the corresponding photoanodes was dramatically enhanced.
文摘实车动力电池的健康状态(state of health,SOH)评估存在数据质量差、工况不统一、数据利用率低等问题,本文面向阶梯倍率充电工况构建多源特征提取及SOH估计模型。首先,通过数据清洗、切割、填充,获取独立的充电片段;其次,基于不同电流阶段计算容量,实现原始数据利用率达96.9%,并与单独限定SOC范围计算容量的方法相比,误差降低48.1%以上;然后,从当前工况、历史累积两个维度提取多个健康因子,对于当前工况特征值,通过灰色关联度及干扰性随机森林重要度分析双重筛选。对于历史累积特征值,利用Spearson相关性分析和核主成分分析方法(kernel principal component analysis,KPCA)降低信息冗余;最后,对门控循环单元网络模型(gated recurrent unit,GRU)引入注意力机制和龙格库塔优化算法(Runge Kutta optimizer,RUN),建立RUN-GRU-attention模型,基于实车运行数据集与现有5种模型进行对比,实验结果表明,无论是包含单阶段还是多阶段电流的测试样本,优化模型的估计精度更佳,误差不高于0.0086,并且随着充电循环次数增加表现出良好的误差收敛性,可有效预测SOH波动趋势。
