Underwater Gas Leakage Flow Detection and Classification Based on Multibeam Forward-Looking Sonar

The risk of gas leakage due to geological flaws in offshore carbon capture, utilization, and storage, as well as leakage from underwater oil or gas pipelines, highlights the need for underwater gas leakage monitoring technology. Remotely operated vehicles(ROVs) and autonomous underwater vehicles(AUVs) are equipped with high-resolution imaging sonar systems that have broad application potential in underwater gas and target detection tasks. However, some bubble clusters are relatively weak scatterers, so detecting and distinguishing them against the seabed reverberation in forward-looking sonar images are challenging. This study uses the dual-tree complex wavelet transform to extract the image features of multibeam forward-looking sonar. Underwater gas leakages with different flows are classified by combining deep learning theory. A pool experiment is designed to simulate gas leakage, where sonar images are obtained for further processing. Results demonstrate that this method can detect and classify underwater gas leakage streams with high classification accuracy. This performance indicates that the method can detect gas leakage from multibeam forward-looking sonar images and has the potential to predict gas leakage flow.

Effects of Shading Degree on Storage Rate and Growth of Phoebe bournei Seedlings in Fields

In the research, four shading treatments were set, including the treatments with shading degrees at 0, 40%, 60% and 70%, in order to explore storage rate and seedling growth of annual Phoebe bournei. The results showed that the storage rate is growing upon shading degree. In the research, for example, storage rate reached the peak with the shading degree at 70%, and only 42.2% with shading degree at 0. In addition, seedling height and ground diameter showed extremely significant differences among treatments, and the treatment with shading degree at 60% was the best.

Electromagnetic Calculation and Plasma Leakage Rate Analysis of the Magnetically Confined Plasma Rocket

An electromagnetic calculation and the parameters of the magnet system of the magnetically confined plasma rocket were established. By using ANSYS code, it was found that the leakage rate depends on the current intensity of the magnet and the change of the magnet position.

Prediction of Leakage Rates Through Sealing Connections with Nonmetallic Gaskets

In this work, a model of gas leakage through nonmetallic gaskets was developed in order to predict leakage rate of gasket sealing connections. The model was verified by the leakage experiments on two types of gaskets： compressed non-asbestos fiber gasket and flexible graphite gasket reinforced with tanged metal sheet. The coefficients in the leakage rate formula were obtained by regression of experimental data for each type of gasket, The model was also validated against the experimental leakage data by other researchers and shown to produce accurate predications. Furthermore, the model was applied to a bolted flanged connection in service in order to assess the tightness of the connection.

CO_2 Leakage Identification in Geosequestration Based on Real Time Correlation Analysis Between Atmospheric O_2 and CO_2

The paper describes a method for monitoring CO2 leakage in geological carbon dioxide sequestration. A real time monitoring parameter, apparent leakage flux(ALF), is presented to monitor abnormal CO2 leakage, which can be calculated by atmospheric CO2 and O2 data. The computation shows that all ALF values are close to zero-line without the leakage. With a step change or linear perturbation of concentration to the initial CO2 concentration data with no leakage, ALF will deviate from background line. Perturbation tests prove that ALF method is sensitive to linear perturbation but insensitive to step change of concentration. An improved method is proposed based on real time analysis of surplus CO2 concentration in least square regression process, called apparent leakage flux from surplus analysis(ALFs), which is sensitive to both step perturbation and linear perturbations of concentration. ALF is capable of detecting concentration increase when the leakage occurs while ALFs is useful in all periods of leakage. Both ALF and ALFs are potential approaches to monitor CO2 leakage in geosequestration project.

Theoretical Investigation on Internal Leakage and Its Effect on the Efficiency of Fluid Switcher-Energy Recovery Device for Reverse Osmosis Desalting Plant

This work is focused on the theoretical investigation of internal leakage of a newly developed pi lotscale fluid switcherenergy recovery device （FSERD） for reverse osmosis （RO） system. For the purpose of in creasing FSERD efficiency and reducing the operating cost of RO, it is required to control the internal leakage in a low level. In this work, the internal leakage rates at different leakage gaps and retentate brine pressures are investigated by computational fluid dynamics （CFD） method and validating experiments. It is found that the internal leak age has a linear relationship with the retentate brine pressure and a polynomial relationship with the scale of leakage gap. The results of the present work imply that low internal leakage and high retentate brine pressure bring benefits to achieve high FSRD efficiency.

Gas leakage recognition for CO2 geological sequestration based on the time series neural network

The leakage of stored and transported CO2 is a risk for geological sequestration technology. One of the most challenging problems is to recognize and determine CO2 leakage signal in the complex atmosphere background. In this work, a time series model was proposed to forecast the atmospheric CO2 variation and the approximation error of the model was utilized to recognize the leakage. First, the fitting neural network trained with recently past CO2 data was applied to predict the daily atmospheric CO2. Further, the recurrent nonlinear autoregressive with exogenous input(NARX) model was adopted to get more accurate prediction. Compared with fitting neural network, the approximation errors of NARX have a clearer baseline, and the abnormal leakage signal can be seized more easily even in small release cases. Hence, the fitting approximation of time series prediction model is a potential excellent method to capture atmospheric abnormal signal for CO2 storage and transportation technologies.

Numerical and experimental investigation of leakage behavior at null position of high-pressure electro-pneumatic servo valve

The high-pressure electro-pneumatic servo valve(HESV)is a core element of the high-pressure pneumatic servo system.The annular clearance and the rounded corner of the spool-sleeve can cause the leakage at null position,thereby affecting high-precision control and stability of the servo system.This paper investigates the effects of the clearance structure on leakage behavior at null position of the HESV.A numerical approach was employed to evaluate the effects,and then a mathematical model was established to obtain the variation law of leakage flow rate at null position.The results indicate that the leakage flow rate at null position varies linearly with supply pressure and rounded corner radius,and is nonlinear as a quadratic concave function with annular clearance.The leakage flow rate of the annular clearance and the rounded corner varies with the valve opening in an invariable−nonlinear−linear trend.A test rig system of leakage behavior at null position of the HESV was built to confirm the validity of the numerical model,which agrees well with the conducted experimental study.

Flow and Leakage Characteristics in Sealing Chamber of a Variable Geometry Hypersonic Inlet

When the variable geometry hypersonic inlet is sealed with ceramic wafers,the cavity flows inside the sealing chamber can be affected by the boundary layer near the side wall.To study the influence of the boundary layer thickness near the side wall on the flow and leakage characteristics in sealing chamber,the numerical calculation of the cavity flow in the sealing chamber under different inflow boundary layer thicknesses is carried out.The results show that three-dimensional cavity flow structures are close to being asymmetric,and the entrance pressure of the leakage path can also be affected by asymmetry;with the increase of the thickness of the boundary layer,the pressure at the cavity floor and the seal entrance decreases.Finally,the existing leakage prediction model is modified according to the distribution rule of the cavity floor and the flow properties in the leakage path.

Energy Saving Technology for Lowering Air Leakage of Sintering Pallets and Dust Collectors in Sinter Plant

The hot-wire type anemometers were used for measuring the velocity of effective air flowing through sinter bed in this study.Meanwhile,microphones were installed beside the pathway and close to the outer sidewall of travelling pallets for monitoring sound pressure generated by an abnormal air leakage.For identifying the passing pallet,a thermal-resistant type RFID technology was adopted.Based on the measured data via anemometers,the air leakage rate of sintering machine was calculated with the mass balance method,and pallets with the abnormal leakage can be detected and ranked in the severity of leakage from the measured sound pressure with the relevant criteria.In addition,for examining the leakage situation,this study set up a capillary type of differential pressure gauge to double cone valve(DCV)below the electrostatic precipitator(EP)in sintering plant for collecting the larger dust.The criteria of determining leaked DCV and the patterns for replacing the DCV were proposed to develop a detecting and predicting system on the air leakage into dust collectors of sinter machine.It offered field staff a basis of maintaining or renewing DCV via a warning reminding and reducing air leakage to increase EP efficiency for avoiding the dust emission from the stack.These technologies had been implemented in the sintering plants of China Steel Corporation,and they can effectively reduce the air leakage rate by5%at least and further decrease the electricity consumption of the suction fan and coke rate,increase the production for the sintering machine.

Wellbore leakage risk management in CO_(2) geological utilization and storage: A review

CO_(2) geological utilization and storage(CGUS)is an important technology to achieve a deep cut of global CO_(2) emissions.CO_(2) leakage from the subsurface may impair the performance of CGUS projects,and the CO_(2) leakage through wellbores is the most common leakage pathway.This paper proposes a workflow for wellbore CO_(2) leakage risk management,and the workflow consists of the following steps:i)leakage risk identification;ii)leakage risk evaluation;iii)leakage risk monitoring;iv)leakage handling.Representative approaches in each step of the workflow are systematically reviewed.Key challenges of wellbore CO_(2) leakage risk management include:lack of effective detection and evaluation approaches to tackle the CO_(2) leakage risk induced by cement failure;lack of low-cost acid resistance alloys and CO_(2)-resistant cement;lack of automated monitoring systems that could enable automated shutdowns of the wellbore whenever certain warning criteria are met.

Enhanced Anion-Derived Inorganic-Dominated Solid Electrolyte Interphases for High-Rate and Stable Sodium Storage

It is highly desirable for the promising sodium storage possessing high rate and long stable capability,which are mainly hindered by the unstable yet conventional solvent-derived organic-rich solid electrolyte interphases.Herein,an electrolyte solvation chemistry is elaborately manipulated to produce an enhanced anion-derived and inorganic components-dominated solid electrolyte interphases by introducing a low permittivity(4.33)bis(2,2,2-trifluoroethyl)ether diluent into the sodium bis(trifluoromethylsulfonyl)imidedimethoxyethane-based high concentration electrolyte to obtain a localized high concentration electrolyte.The bis(2,2,2-trifluoroethyl)ether breaks the balance of original cation solvation structure and tends to interact with Na^(+)-coordinated dimethoxyethane solvent rather than Na^(+)in high concentration electrolyte,leaving an enhanced Coulombic interaction between Na^(+)and(FSO_(2))_(2)N^(-),and more(FSO_(2))_(2)N^(-)can enter the Na^(+)solvation shell,forming a further increased number of Na^(+)-(FSO_(2))_(2)N^(-)-dimethoxyethane clusters(from 82.0%for high concentration electrolyte to 94.3%for localized high concentration electrolyte)at a low salt dosage.The preferential reduction of this(FSO_(2))_(2)N^(-)-enriched clusters rather than the dimethoxyethane-dominated Na^(+)solvation structure produces an enhanced anion-derived and inorganic components-dominated solid electrolyte interphases.The reversible charge storage process of Na is decoupled by operando Raman along with a shift of D and G peaks.Benefiting from the enhanced anion-derived electrode-electrolyte interface,the commercial hard carbon anode in localized high concentration electrolyte shows a well rate capability(5 A g^(−1),70 mAh g^(−1)),cycle performance and stability(85%of initial capacity after 700 cycles)in comparison to that of high concentration electrolyte(68%)and low concentration electrolyte(only 5%after 400 cycles),indicative of uniqueness and superiorities towards stable Na storage.

Dual-ion carrier storage through Mg^(2+) addition for high-energy and long-life zinc-ion hybrid capacitor

Cation additives can efficiently enhance the total electrochemical capabilities of zinc-ion hybrid capacitors (ZHCs).However their energy storage mechanisms in zinc-based systems are still under debate.Herein,we modulate the electrolyte and achieve dual-ion storage by adding magnesium ions.And we assemble several Zn//activated carbon devices with different electrolyte concentrations and investigate their electrochemical reaction dynamic behaviors.The zinc-ion capacitor with Mg^(2+)mixed solution delivers 82 mAh·g^(-1)capacity at 1 A·g^(-1) and maintains 91%of the original capacitance after 10000 cycling.It is superior to the other assembled zinc-ion devices in single-component electrolytes.The finding demonstrates that the double-ion storage mechanism enables the superior rate performance and long cycle lifetime of ZHCs.

Microscopic experiment on efficient construction of underground gas storages converted from water-invaded gas reservoirs

Based on the microfluidic technology,a microscopic visualization model was used to simulate the gas injection process in the initial construction stage and the bottom water invasion/gas injection process in the cyclical injection-production stage of the underground gas storage(UGS)rebuilt from water-invaded gas reservoirs.Through analysis of the gas-liquid contact stabilization mechanism,flow and occurrence,the optimal control method for lifecycle efficient operation of UGS was explored.The results show that in the initial construction stage of UGS,the action of gravity should be fully utilized by regulating the gas injection rate,so as to ensure the macroscopically stable migration of the gas-liquid contact,and greatly improve the gas sweeping capacity,providing a large pore space for gas storage in the subsequent cyclical injection-production stage.In the cyclical injection-production stage of UGS,a constant gas storage and production rate leads to a low pore space utilization.Gradually increasing the gas storage and production rate,that is,transitioning from small volume to large volume,can continuously break the hydraulic equilibrium of the remaining fluid in the porous media,which then expands the pore space and flow channels.This is conducive to the expansion of UGS capacity and efficiency for purpose of peak shaving and supply guarantee.

Hydrocarbon indication in Rio Bonito Formation sandstone:Implication for CO_(2)storage in São Paulo,Brazil

São Paulo State has witnessed CO_(2)storage-based investigations considering the availability of suitable geologic structures and proximity to primary CO_(2)source sinks related to bioenergy and carbon capture and storage(BECCS)activities.The current study presents the hydrocarbon viability evaluations and CO_(2)storage prospects,focusing on the sandstone units of the Rio Bonito Formation.The objective is to apply petrophysical evaluations with geochemical inputs in predicting future hydrocarbon(gas)production to boost CO_(2)storage within the study location.The study used data from eleven wells with associated wireline logs(gamma ray,resistivity,density,neutron,and sonic)to predict potential hydrocarbon accumulation and fluid mobility in the investigated area.Rock samples(shale and carbonate)obtained from depths>200 m within the study location have shown bitumen presence.Organic geochemistry data of the Rio Bonito Formation shale beds suggest they are potential hydrocarbon source rocks and could have contributed to the gas accumulations within the sandstone units.Some drilled well data,e.g.,CB-1-SP and TI-1-SP,show hydrocarbon(gas)presence based on the typical resistivity and the combined neutron-density responses at depths up to 3400 m,indicating the possibility of other hydrocarbon members apart from the heavy oil(bitumen)observed from the near-surface rocks samples.From the three-dimensional(3-D)model,the free fluid indicator(FFI)is more significant towards the southwest and southeast of the area with deeper depths of occurrence,indicating portions with reasonable hydrocarbon recovery rates and good prospects for CO_(2)injection,circulation and permanent storage.However,future studies based on contemporary datasets are required to establish the hydrocarbon viability further,foster gas production events,and enhance CO_(2)storage possibilities within the region.

Fundamental Analysis of Helium-Gas Coolant Leakage Rate Through First-Wall Cracks in Tokamak Fusion Reactors

A fundamental analysis of helium-gas coolant leakage rate through first-wall cracks in Tokamak fusion reactors was made. Criteria for ascertaining the correct flow models were thoroughly investigated. After testing the criteria, it was determined that the correct model is the compressible choked flow for the helium-gas coolant under the normal operating conditions in the Tokamak fusion reactors. The upper bound leakage rates through metallic wall for two crack sizes were calculated. The calculated maximum numbers of allowable cracks through metallic and silicon-carbon composite wall were also reported. The experimental data of specimen S-23 (the small crack size), checked with the predicted or calculated leakage rate. But the experimental data of specimen S-4 (the large crack size, which is only 4.4 times larger than the crack size of specimen S-23) were two orders of magnitude higher than the calculated value. This is probably due to the many through-cracks undetected and therefore, not reported in the experiment, and not due to the difference in crack sizes. It should be noted that since there are only two test data points, it is recommended that more testing or experimental data will be needed. The results of two previous investigations about the calculated leakage values, their equations used, and their flow models employed were also reviewed. It is concluded that the correct model for the analysis is the compressible choked flow, and that helium can be as an effective coolant for fusion power reactors. Several recommendations are also made. Specifically, more experiments for helium, and similar analysis and experiments for lithium and water coolant are needed; and should be encouraged.

Study on High Rate Discharge Performance and Mechanism of AB_5 Type Hydrogen Storage Alloys

The effects of surface treatment, particle size distribution,rare earth composition and B additive on the high rate discharge performance of hydrogen storage alloys were investigated. It is found that the activity, discharge capacity and high rate dischargeability of the alloys are improved after physical and chemical modification as a result of the increase of the surface area and formation of the electrocatalysis layers, which increase both the electrochemical reaction rate on the alloy surface and H diffusion rate in the alloy bulk. It is also found that both the over-coarse and over-fine particle size increase the contact resistance of the electrode, resulting in a decrease of discharge capacity, deterioration of high rate dischargeability and lower discharge plateau. In another word, a suitable particle size distribution can enhance the alloy activity, discharge capacity and high rate dischargeability. In addition, the high rate dischargeability is enhanced by increasing La content and decreasing Ce content of the alloy composition because of enlargement of the unit cell volume and the improvement of the surface activity. Moreover, B additive resultes in the formation of the second phase, and makes the alloys easier pulverization, which greatly improves the activity, discharge capacity and high rate dischargeability.

RECENT ADVANCES IN HYDRATE-BASED TECHNOLOGIES FOR NATURAL GAS STORAGE——A REVIEW

Interest in the possibility of storing and transporting natural gas in the form of clathrate hydrates has been increasing in recent years, particularly in some gas-importing and exporting countries.The technologies necessary for realizing this possibility may be classified into those relevant to the four serial processes (a) the formation of a hydrate, (b) the processing (dewatering, pelletizing, etc. ) of the formed hydrate, (c) the storage and transportation of the processed hydrate, and (d) the regasification (dissociation) of the hydrate. The technological development of any of these processes is still at an early stage. For hydrate formation, for example, various rival operations have been proposed. However,many of them have never been subjected to actual tests for practical use. More efforts are required for examining the different hydrate-formation technologies and for rating them by comparison. The general design of the processing of the formed hydrate inevitably depends on both the hydrate-formation process and the storage/transportation process, hence it has a wide variability. The major uncertainty in the storage-process design lies in the as-yet unclarified utility of the "self-preservation" effect of the naturalgas hydrates. The process design as well as the relevant cost evaluation should strongly depend on whether the hydrates are well preserved at atmospheric pressure in large-scale storage facilities. The regasification process has been studied less extensively than the former processes. The state of the art of the technological development in each of the serial processes is reviewed, placing emphasis on the hydrate formation process.

Intensification of methane and hydrogen storage inclathrate hydrate and future prospect

Gas hydrate is a new technology for energy gas（methane/hydrogen）storage due to its large capacity of gas storage and safe.But industrial application of hydrate storage process was hindered by someproblems.For methane,the main problems are low formation rateand storage capacity,which can be solved by strengthening mass andheat transfer,such as adding additives,stirring,bubbling,etc.Onekind of additives can change the equilibrium curve to reduce the formation pressure of methane hydrate,and the other kind of additivesis surfactant,which can form micelle with water and increase the interface of water-gas.Dry water has the similar effects on the methanehydrate as surfactant.Additionally,stirring,bubbling,and sprayingcan increase formation rate and storage capacity due to mass transferstrengthened.Inserting internal or external heat exchange also canimprove formation rate because of good heat transfer.For hydrogen,the main difficulties are very high pressure for hydrate formed.Tetrahydrofuran（THF）,tetrabutylammonium bromide（TBAB） andtetrabutylammonium fluoride（TBAF） have been proved to be able todecrease the hydrogen hydrate formation pressure significantly.