Effect of temperature and stress on molecular structure and carbon monoxide generation of lignite from Kailuan mining area

In order to analyze the origin of carbon monoxide(CO) in coal seams, stress–strain experiments under temperature of 50, 150 and 250 °C were conducted using lignite from Kailuan mining area. Fourier transform infrared spectroscopy and elemental analysis were carried out before and after deformation of the samples. The results indicated that CO generated at 150 and 250 °C; the gas component was mostly oxygen(O_2), with small amount of carbon dioxide(CO_2), methane(CH_4) and hydrogen(H_2). At 50 °C, O_2 and a little CO_2 were observed and no CO was found. The carbon content of the coal samples increased slightly after deformation, and the oxygen content, H/C ratio, and O/C ratio decreased. The molecular structure of coal displayed different evolution characteristics at various temperatures. At 50 and 150 °C, the falling off of side chains, broken of ether bond and directional realignment of the aliphatic chains resulting in the formation of long chains were the main performance of coal molecular structure evolution. While at 250 °C, the side chains fell off and short chains formed. Furthermore, at both 150 and 250 °C, condensed degree of aromatic ring increased. Under the action of temperature and pressure, CO forms in two ways.The first is that ether bond breaks, oxygen and carbon atoms combine together and forms CO, or O_2 forming in the broken of ether–oxygen bond leads to the oxidation of free radicals and resulting in the formation of CO. And the second is that CO derives from falling off of C=O group.

Slicing and support structure generation for 3D printing directly on B-rep models

Traditional 3D printing is based on stereolithography or standard tessellation language models,which contain many redundant data and have low precision.This paper proposes a slicing and support structure generation algorithm for 3D printing directly on boundary representation(B-rep)models.First,surface slicing is performed by efficiently computing the intersection curves between the faces of the B-rep models and each slicing plane.Then,the normals of the B-rep models are used to detect where the support structures should be located and the support structures are generated.Experimental results show the efficiency and stability of our algorithm.

Viscous flow simulations through multi.lobe progressive cavity pumps

Computational fluid dynamics(CFD)simulations of multi-lobe progressive cavity(PC)pumps are limited in the literature due to the geometric complexity of the pump,which places numerous restrictions on the grid generation process.The present study attempts to alleviate such restrictions by developing a detailed numerical procedure for the numerical simulations of multi-lobe progressive cavity pumps.The profile equations for the multi-lobe configuration at any section at each instant of rotation are presented.A structured grid generation method is developed to generate mesh files required for CFD simulations of multi-lobe PC pumps.Results from the present procedure are validated against single-lobe PC pump numerical results available in the literature.Finally,a numerical parametric study is carried out to investigate the effect of the number of lobes,the stator pitch,the circular fillet and clearance on the volumetric efficiency of PC pumps with viscous oils.

Numerical simulation of vortex-induced drag of elastic swimmer models

We present numerical simulations of simplified models for swimming organisms or robots, using chordwise flexible elastic plates. We focus on the tip vortices originating from three-dimensional effects due to the finite span of the plate. These effects play an important role when predicting the swimmer＇s cruising velocity, since they contribute significantly to the drag force. First we simulate swimmers with rectangular plates of different aspect ratios and compare the results with a recent experimental study. Then we consider plates with expanding and contracting shapes. We find the cruising velocity of the contracting swimmer to be higher than the rectangular one, which in turn is higher than the expanding one. We provide some evidence that this result is due to the tip vortices interacting differently with the swimmer.

Clean Coal Technology and Market in China

This paper briefs the current clean production and consumption levels of coal in China and the pollution harmbrought to the atmospheric environment, present status and orientation of clean coal technology development in Chinacoal industry, progress and perspective of clean coal power generation technology in China, as well as application andmarket of flue gas desulphurization technology in coal-fired power plants.[

Using Computational Intelligence Algorithms to Solve the Coalition Structure Generation Problem in Coalitional Skill Games

Coalitional skill games （CSGs） are a simple model of cooperation in an uncertain environment where each agent has a set of skills that are required to accomplish a variety of tasks and each task requires a set of skills to be completed, but each skill is very hard to be quantified and can only be qualitatively expressed. Thus far, many computational questions surrounding CSGs have been studied. However, to the best of our knowledge, the coalition structure generation problem （CSGP）, as a central issue of CSGs, is extremely challenging and has not been well solved. To this end, two different computational intelligence algorithms are herein evaluated： binary particle swarm optimization （BPSO） and binary differential evolution （BDE）. In particular, we develop the two stochastic search algorithms with two-dimensional binary encoding and corresponding heuristic for individual repairs. After that, we discuss some fundamental properties of the proposed heuristic. Finally, we compare the improved BPSO and BDE with the state-of-the-art algorithms for solving CSGP in CSGs. The experimental results show that our algorithms can find the same near optimal solutions with the existing approaches but take extremely short time, especially under the large problem size.

Magnetic and electro-catalytic properties of a copper complex with 2-(pyridylmethyl)amino-N,N-bis(2-methylene-4,6-difluorophenol)

A new material for both magnetic coupling and electrocatalytic hydrogen generation based on a copper complex,[（HL）CuCl-CuCl（HL）]HCl 1 is prepared by the reaction of 2-（pyridylmethyl）amino-N,N-bis（2-methylene-4,6-difluorophenol）（H2L） and CuCl2·2H2O.In solid,complex 1 is built from two copper units（[（HL）CuCl]）,and exhibits an antiferromagnetic exchange interaction between copper（Ⅱ） ions（J=-160cm^-1）.In liquid,1 can electrocatalyze hydrogen generation both from acetic acid with a turnover frequency（TOF） of 16.3 moles of hydrogen per mole of catalyst per hour at an overpotential（OP）of 941.6 mV（in DMF）,and a neutral buffer with a TOF of 1415.6 moles of hydrogen per mole of catalyst per hour at an OP of 787.6 mV.