arly Mesozoic flexural basins developed in East China include flexural basin with foredeep, compressive flexural basin, transpressional flexural basin and so on. Late Triassic collision between Gondwana and Eurasi...arly Mesozoic flexural basins developed in East China include flexural basin with foredeep, compressive flexural basin, transpressional flexural basin and so on. Late Triassic collision between Gondwana and Eurasian continents led to the formation of large flexural basins with foredeep. Jurassic Tethys geotectonic domain and western Pacific active continental margin activated, resulting in the formation of Early-Middle Jurassic large flexural basins and Late Jurassic small foreland basins. These basins and their marginal orogenic belts were arranged as weakly constrained lateral extrusion structures and constrained lateral extrusion structures, which show a genetic coupling relationship between the orogenic belts and the basins.展开更多
Two polyethylene(PE) resins(samples A and B) are synthesized as high-speed extrusion coatings with similar minimum coating thickness and neck-in performance but different maximum coating speeds. Both samples are s...Two polyethylene(PE) resins(samples A and B) are synthesized as high-speed extrusion coatings with similar minimum coating thickness and neck-in performance but different maximum coating speeds. Both samples are separated into seven fractions using preparative temperature rising elution fractionation. The microstructures of the original samples and their fractions are studied by high-temperature gel permeation chromatography, Fourier transform infrared spectroscopy, 13 C nuclear magnetic resonance spectroscopy, differential scanning calorimetry, and successive self-nucleation/annealing thermal fractionation. Compared with sample B, sample A has a broader MWD, more LCB contents, and less SCB contents. Moreover, sample A contains slightly more 30 ℃ and 50 ℃ fractions with lower molecular weights, and more fractions at 75 ℃ and 85 ℃ with higher molecular weight. The chain structure and its distribution in the two PE resins are studied in detail, and the relationship between the chain structure and resin properties is also discussed.展开更多
A high strength Mg-5.1Zn-3.2Y-0.4Zr-0.4Ca (wt%) alloy containing W phase (Mg3Y2Zn3) prepared by permanent mold direct-chill casting is indirectly extruded at 350 ℃ and 400 ℃, respectively. The extruded alloys sh...A high strength Mg-5.1Zn-3.2Y-0.4Zr-0.4Ca (wt%) alloy containing W phase (Mg3Y2Zn3) prepared by permanent mold direct-chill casting is indirectly extruded at 350 ℃ and 400 ℃, respectively. The extruded alloys show bimodal grain structure consisting of fine dynamic recrystallized (DRXed) grains and unre- crystallized coarse regions containing fine W phase and β2′ precipitates. The fragmented W phase particles induced by extrusion stimulate nucleation of DRXed grains, leading to the formation of fine DRXed grains, which are mainly distributed near the W particle bands along the extrusion direction. The alloy extruded at 350 ℃ exhibits yield strength of 373 MPa, ultimate tensile strength of 403 MPa and elongation to failure of 5.1%. While the alloy extruded at 400 ℃ shows lower yield strength of 332 MPa, ultimate tensile strength of 352 MPa and higher elongation to failure of 12%. The mechanical properties of the as-extruded alloys vary with the distribution and size of W phase. A higher fraction of DRXed grains is obtained due to the homogeneous distribution of micron-scale broken W phase particles in the alloy extruded at 400 ℃, which can lead to higher ductility. In addition, the nano-scale dynamic W phase precipitates distributed in the unDRXed regions are refined at lower extrusion temperature. The smaller size of nano-scale W phase precipitates leads to a higher fraction of unDRXed regions which contributes to higher strength of the alloy extruded at 350 ℃.展开更多
文摘arly Mesozoic flexural basins developed in East China include flexural basin with foredeep, compressive flexural basin, transpressional flexural basin and so on. Late Triassic collision between Gondwana and Eurasian continents led to the formation of large flexural basins with foredeep. Jurassic Tethys geotectonic domain and western Pacific active continental margin activated, resulting in the formation of Early-Middle Jurassic large flexural basins and Late Jurassic small foreland basins. These basins and their marginal orogenic belts were arranged as weakly constrained lateral extrusion structures and constrained lateral extrusion structures, which show a genetic coupling relationship between the orogenic belts and the basins.
基金financially supported by the National Basic Research Program of China(No.2005CB623806)the National Natural Science Foundation of China(Nos.20734006 and 50921062)
文摘Two polyethylene(PE) resins(samples A and B) are synthesized as high-speed extrusion coatings with similar minimum coating thickness and neck-in performance but different maximum coating speeds. Both samples are separated into seven fractions using preparative temperature rising elution fractionation. The microstructures of the original samples and their fractions are studied by high-temperature gel permeation chromatography, Fourier transform infrared spectroscopy, 13 C nuclear magnetic resonance spectroscopy, differential scanning calorimetry, and successive self-nucleation/annealing thermal fractionation. Compared with sample B, sample A has a broader MWD, more LCB contents, and less SCB contents. Moreover, sample A contains slightly more 30 ℃ and 50 ℃ fractions with lower molecular weights, and more fractions at 75 ℃ and 85 ℃ with higher molecular weight. The chain structure and its distribution in the two PE resins are studied in detail, and the relationship between the chain structure and resin properties is also discussed.
基金supported financially by the National Key Research and Development Program of China (No. 2016YFB0301102)the National Natural Science Foundation of China (No. 51571068)
文摘A high strength Mg-5.1Zn-3.2Y-0.4Zr-0.4Ca (wt%) alloy containing W phase (Mg3Y2Zn3) prepared by permanent mold direct-chill casting is indirectly extruded at 350 ℃ and 400 ℃, respectively. The extruded alloys show bimodal grain structure consisting of fine dynamic recrystallized (DRXed) grains and unre- crystallized coarse regions containing fine W phase and β2′ precipitates. The fragmented W phase particles induced by extrusion stimulate nucleation of DRXed grains, leading to the formation of fine DRXed grains, which are mainly distributed near the W particle bands along the extrusion direction. The alloy extruded at 350 ℃ exhibits yield strength of 373 MPa, ultimate tensile strength of 403 MPa and elongation to failure of 5.1%. While the alloy extruded at 400 ℃ shows lower yield strength of 332 MPa, ultimate tensile strength of 352 MPa and higher elongation to failure of 12%. The mechanical properties of the as-extruded alloys vary with the distribution and size of W phase. A higher fraction of DRXed grains is obtained due to the homogeneous distribution of micron-scale broken W phase particles in the alloy extruded at 400 ℃, which can lead to higher ductility. In addition, the nano-scale dynamic W phase precipitates distributed in the unDRXed regions are refined at lower extrusion temperature. The smaller size of nano-scale W phase precipitates leads to a higher fraction of unDRXed regions which contributes to higher strength of the alloy extruded at 350 ℃.