Conical origami structures are characterized by their substantial out-of-plane stiffness and energy-absorptioncapacity.Previous investigations have commonly focused on the static characteristics of these lightweight s...Conical origami structures are characterized by their substantial out-of-plane stiffness and energy-absorptioncapacity.Previous investigations have commonly focused on the static characteristics of these lightweight struc-tures.However,the efficient analysis of the natural vibrations of these structures is pivotal for designing conicalorigami structures with programmable stiffness and mass.In this paper,we propose a novel method to analyzethe natural vibrations of such structures by combining a symmetric substructuring method(SSM)and a gener-alized eigenvalue analysis.SSM exploits the inherent symmetry of the structure to decompose it into a finiteset of repetitive substructures.In doing so,we reduce the dimensions of matrices and improve computationalefficiency by adopting the stiffness and mass matrices of the substructures in the generalized eigenvalue analysis.Finite element simulations of pin-jointed models are used to validate the computational results of the proposedapproach.Moreover,the parametric analysis of the structures demonstrates the influences of the number of seg-ments along the circumference and the radius of the cone on the structural mass and natural frequencies of thestructures.Furthermore,we present a comparison between six-fold and four-fold conical origami structures anddiscuss the influence of various geometric parameters on their natural frequencies.This study provides a strategyfor efficiently analyzing the natural vibration of symmetric origami structures and has the potential to contributeto the efficient design and customization of origami metastructures with programmable stiffness.展开更多
A graph theory model of the human nature structure( GMH) for machine vision and image/graphics processing is described in this paper. Independent from the motion and deformation of contours,the human nature structure(...A graph theory model of the human nature structure( GMH) for machine vision and image/graphics processing is described in this paper. Independent from the motion and deformation of contours,the human nature structure( HNS) embodies the most basic movement characteristics of the body. The human body can be divided into basic units like head,torso,and limbs. Using these basic units,a graph theory model for the HNS can be constructed. GMH provides a basic model for human posture processing,and the outline in the perspective projection plane is the body contour of an image. In addition,the GMH can be applied to articulated motion and deformable objects,e. g.,in the design and analysis of body posture,by modifying mapping parameters of the GMH.展开更多
A new metal-organic coordination polymer [Zn(pzdc)(mbix)]n·nH2O(H2pzdc = pyrazine-2,3- dicarboxylic acid, mbix = 1,3-bis(imidazol-1-ylmethyl)-benzene) 1 has been hydrothermally synthesized and structurall...A new metal-organic coordination polymer [Zn(pzdc)(mbix)]n·nH2O(H2pzdc = pyrazine-2,3- dicarboxylic acid, mbix = 1,3-bis(imidazol-1-ylmethyl)-benzene) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. Yellow crystals crystallize in monoclinic system, space group P21/n with a = 8.5519(6), b = 14.8764(10), c = 16.4108(11) A, β = 103.4520(10)o, V = 2030.5(2)A^3, C(20)H(18)N6O5Zn, Mr = 487.77, Dc = 1.596 g/cm^3, F(000) = 1000, Z = 4, μ(MoK α) = 1.257 mm^-1, the final R = 0.0260 and w R = 0.0706 for 3445 observed reflections(I 〉 2σ(I)). The structure of 1 exhibits a one-dimensional chain-like structure. In addition, natural bond orbital(NBO) analysis was performed by the PBE0/LANL2DZ method in Gaussian 03 Program. The calculation results show obvious covalent interaction between the coordinated atoms and Zn(Ⅱ) ion.展开更多
A new coordination polymer, [Cd2(NIPH)(L)2(H2O)]n(1, HL = 3-(2-pyridyl)pyrazole and H2NIPH = 5-nitroisophthalic acid), has been synthesized. The structure of complex 1 has been characterized by X-ray single-...A new coordination polymer, [Cd2(NIPH)(L)2(H2O)]n(1, HL = 3-(2-pyridyl)pyrazole and H2NIPH = 5-nitroisophthalic acid), has been synthesized. The structure of complex 1 has been characterized by X-ray single-crystal diffraction, elemental analysis, IR spectrum analysis, thermogravimetric analysis and fluorescence spectrum analysis. Complex 1 belongs to the triclinic system, space group P1 with a = 8.9539(6), b = 11.6252(8), c = 12.2472(8) A^°, α = 80.011(2), β = 80.3850(10), γ = 86.773(2)°, V = 1237.37(14) A^°3, Z = 2, Dc = 1.987 g/cm^3, μ = 1.780 mm^-1, Mr = 740.25, F(000) = 724, the final R = 0.0295 and wR = 0.1015 with I 〉 2σ(I). Two H2NIPH as monodentate and bidentate ligands and two L ligands link four Cd(Ⅱ) ions to form a tetranuclear subunit. Each pair of the tetranuclear subunits is bridged by NIPH ligands to yield a one-dimensional double-chain structure. Furthermore, the 1D chains are linked into a 3D supramolecular framework with hydrogen bonds and π-π interactions. In addition, we analyzed Natural Bond Orbital(NBO) in using the PBE0/LANL2DZ method built in Gaussian 03 Program. The calculation results indicated the obvious covalent interaction between the coordinated atoms and Cd(Ⅱ) ion.展开更多
This paper is a review of the past research of mechanical testing methods for natural fibre honeycomb sandwich structure as well as failure modes analysis at a microscopic level by using Scanning Electron Microscope (...This paper is a review of the past research of mechanical testing methods for natural fibre honeycomb sandwich structure as well as failure modes analysis at a microscopic level by using Scanning Electron Microscope (SEM). As the world is garnering attention towards renewable resources for environmental purposes, studies of natural fibre have been increasing as well as the application of natural fibre throughout various industries such as aerospace, automobiles, and construction sectors. This paper is started with brief information regarding the honeycomb sandwich structure, introduction to natural fibre, its applications as well as the factors affecting the performances of the structure. Next, the mechanical testing methods are listed out as well as the expected outcomes obtained from the respective testing. The mechanical properties are also identified by conducting lab tests according to the ASTM standard for sandwich and core structures. The microstructure of the deformed samples is then examined under Scanning Electron Microscope (SEM) by using different magnifications to study the failure mechanisms of the samples. The images obtained from the SEM test are analyzed by using fractography which will show the failure modes of the samples. This article is based on past research conducted by professional on the related topic.展开更多
A new Co(ll) coordination polymer has been successfully synthesized under hydrothermal conditions [Co(C2O4)(mbix)]n (1, H2C2O4 = oxalic acid, mbix = 1,3-bis(imidazol- l-ylmethyl)benzene). Its structure has b...A new Co(ll) coordination polymer has been successfully synthesized under hydrothermal conditions [Co(C2O4)(mbix)]n (1, H2C2O4 = oxalic acid, mbix = 1,3-bis(imidazol- l-ylmethyl)benzene). Its structure has been determined by elemental analyses, IR, UV spectroscopy and single-crystal X-ray diffraction analysis. Pink crystals crystallize in the triclinic system, space group PI with a = 8.8666(7), b = 9.5859(8), c = 10,8537(9) A,α = 67.6810(10),β= 66.1260(10), γ = 77.1300(10)°, V= 777.77(11), CI6HI4CoN404, Mr = 385.24, Dc = 1.645 g/cm3, F(000) = 394, Z= 2,/z(MoKa) = 1.134 mm% the final R = 0.0482 and wR = 0.1231 for 2968 observed reflections (I〉 2σ(I)). It shows a two-dimensional (2D) network structure. The intermolecular C-H…O hydrogen bonding and π-π stacking interactions extend complex 1 into a 3D supramolecular architecture and play an important role in stabilizing 1. In addition, Natural Bond Orbital (NBO) analysis was performed by using the PBE0/LANL2DZ method built in Gaussian 09 Program. The calculation results showed obvious covalent interaction between the coordinated atoms and Co(II) ion.展开更多
Discussions related to land use in Turkey in recent years has been increasing. These discussions are mostly between those who want to protect the natural environment and those who demand other sectoral investment area...Discussions related to land use in Turkey in recent years has been increasing. These discussions are mostly between those who want to protect the natural environment and those who demand other sectoral investment areas. However, there has not been a comprehensive and holistic study assessment of the land use, except for local studies. For this reason, the present study has been conducted in order to reveal the change in land use in the country’s geography. In order to achieve the aims of the study, the literature was reviewed, institutional data were compiled, and the results of previous local studies were evaluated using appropriate methods. Factors affecting land use were examined in the study and it was seen from the findings that significant land use changes occurred in the last 75 years. Although land use suitable for natural structure was common in advance, after the 1980s sectoral needs came to the fore. With the accelerated urbanization and industrialization, tourism, mining and dam areas have become widespread. It has been determined that there is a need for new scientific studies on land use, revision of ineffective laws, and national land use plans that take into account the sectoral needs in order to reduce the discussions.展开更多
With the vigorous promotion of energy conservation and implementation of clean energy strategies,China's natural gas industry has entered a rapid development phase,and natural gas is playing an increasingly important...With the vigorous promotion of energy conservation and implementation of clean energy strategies,China's natural gas industry has entered a rapid development phase,and natural gas is playing an increasingly important role in China's energy structure.This paper uses a Generalized Weng model to forecast Chinese regional natural gas production,where accuracy and reasonableness compared with other predictions are enhanced by taking remaining estimated recoverable resources as a criterion.The forecast shows that China's natural gas production will maintain a rapid growth with peak gas of 323 billion cubic meters a year coming in 2036;in 2020,natural gas production will surpass that of oil to become a more important source of energy.Natural gas will play an important role in optimizing China's energy consumption structure and will be a strategic replacement of oil.This will require that exploration and development of conventional natural gas is highly valued and its industrial development to be reasonably planned.As well,full use should be made of domestic and international markets.Initiative should also be taken in the exploration and development of unconventional and deepwater gas,which shall form a complement to the development of China's conventional natural gas industry.展开更多
Background:Conceptual models of forest dynamics are powerful cognitive tools,which are indispensable for communicating ecological ideas and knowledge,and in developing strategic approaches and setting targets for for...Background:Conceptual models of forest dynamics are powerful cognitive tools,which are indispensable for communicating ecological ideas and knowledge,and in developing strategic approaches and setting targets for forest conservation,restoration and sustainable management.Forest development through time is conventionally described as a directional,or "linear",and predictable sequence of stages from "bare ground" to old forest representing the "climax-state".However,this simple view is incompatible with the current knowledge and understanding of intrinsic variability of forest dynamics.Hypothesis:Overly simple conceptual models of forest dynamics easily become transformed into biased mental models of how forests naturally develop and what kind of structures they display.To be able to communicate the essential features and diversity of forest dynamics,comprehensive conceptual models are needed.For this end,Kuuluvainen(2009) suggested a relatively simple conceptual model of forest dynamics,which separates three major modes of forest dynamics,and incorporates state changes and transitions between the forest dynamics modes depending on changes in disturbance regime.Conclusions:Conceptual models of forest dynamics should be comprehensive enough to incorporate both longterm directional change and short-term cyclic forest dynamics,as well as transitions from one dynamics mode to another depending on changes in the driving disturbance regime type.Models that capture such essential features of forest dynamics are indispensable for educational purposes,in setting reference conditions and in developing methods in forest conservation,restoration and ecosystem management.展开更多
In many sites on Egypt desert roads collapsible soils <span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">is</spa...In many sites on Egypt desert roads collapsible soils <span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">is</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> broadly classified as a problematic soils contain</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">ing</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> silty fine sand which </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">is </span></span></span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">cemented with low density and low degree of saturation which is susceptible to a large and sudden reduction in their v</span><span style="font-family:Verdana;">olume upon inundation, with or without vibration in its stress. Four sites have been studied for new urban</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">, </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">roads and industry work sits, related to increase in natural water content</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">.</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> These soils go through radical rearrangement of their particles, causing sudden changes in the stress-deformation behavior which caus</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">e</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> differential settlement of foundation and roads. This chan</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">ge in volume can lead to foundation failures and worth of damages under ground public facilities and infrastructure. In this study, the search program </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">is </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">developed to establish their different behavior under wetting in two phase</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">s:</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> field and laboratory work. The obtained results are useful in mapping the trend of the factors affect</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">ed</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> in assessing soil collapsibility rate or collapse potentials which </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">are </span></span></span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">observed in construction with volume change problems. The major factors observed are the natural structure skeleton of the soil particle and its grain size and mechanism of soil sedimentation. The field collapse potentials value assigned for these tested sites along Alexandria</span><span style="font-family:Verdana;">—Cairo desert road indicated that the field measured collapsibility potentials are smaller than those measured on the same extracted undisturbed samples in laboratory by 15%, which can be save</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">d</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> in coast, change in proposed collapsibility improvement method and change in select foundation type. Also, field tests evaluate the collapsibility rate with time and highlight that environmental history and natural soil structure in field are the important factors affected on these soil collapse, and also, knowledgeable by collapsible soils during wetting in these sites studied.</span></span></span>展开更多
Energy-absorbing materials are widely used in transportations,sports,and the military applications.Particularly,porous materials,including natural and artificial materials,have attracted tremendous attentions due to t...Energy-absorbing materials are widely used in transportations,sports,and the military applications.Particularly,porous materials,including natural and artificial materials,have attracted tremendous attentions due to their light weight and excellent energy absorption capability.This review summarizes the recent progresses in the natural and artificial energy-absorbing porous materials.First,we review the typical natural porous materials including cuttlebone,bighorn sheep horn,pomelo peel,and sunflower stem pith.The architectures,energy absorption abilities,and mechanisms of these typical natural materials and their bioinspired materials are summarized.Then,we provide a review on the fabrication methods of artificial energy-absorbing porous materials,such as conventional foaming and three-dimensional(3D)printing.Finally,we address the challenges and prospects for the future development of energy-absorbing porous materials.More importantly,our review provides a direct guidance for the design and fabrication of energy-absorbing porous materials required for various engineering applications.展开更多
The environment structure of natural nidi and epidemic areas of hemorrhagic fever with renal syndrome (HFRS) possesses characteristics of topography, hydrology, climate, soil, vegetation, and animals. The natural nidi...The environment structure of natural nidi and epidemic areas of hemorrhagic fever with renal syndrome (HFRS) possesses characteristics of topography, hydrology, climate, soil, vegetation, and animals. The natural nidi and epidemic areas of HFRS are distributed mainly in plain and hilly regions under 500 meters above the sea level; in plentiful-water zones and transitional zones; in temperate zone and subtropical zone of the eastern monsoon region; in the abundant-aluminum soil region and the sial soil region; in the eastern China damp forest region (agricultural districts and northeast forest districts); in the eastern Asia dampness-prefering animal geographic region. Apodemus agrarius and Rattus norvegicus are the thriving animal population, predominant species or common species as well as the main reservoir hosts and sources of infection in the natural nidi and epidemic areas of HFRS.展开更多
The flow-through electro-Fenton(EF-T)reactor with WBC cathode was designed to remove florfenicol(FF).The activated WBC cathode was prepared by facile carbonization and activation methods,and featured high specific sur...The flow-through electro-Fenton(EF-T)reactor with WBC cathode was designed to remove florfenicol(FF).The activated WBC cathode was prepared by facile carbonization and activation methods,and featured high specific surface area,natural multi-channel structure,abundant oxygen-containing groups,good hydrophilicity,and excellent O_(2)reducing capacity.WBC cathode was located above Ti/Ru-IrO_(2)mesh anode.O_(2)evolved at the anode was carried to the inner wall of channel of WBC by the force of buoyancy and water flow,which increases oxygen source of H_(2)O_(2)generation at the cathode.The flow-through system by using WBC electrode promote the mass transfer of O_(2)and FF.The production amount of H_(2)O_(2)at activated WBC was 32.2 mg/L,which was almost twice as much as that at non-activated WBC(15.0 mg/L).FF removal ratio in EF-T system was 98%,which was much higher than that of traditional flow-by electro-Fenton(EF-B,33%)or single electrooxidation system(EO,16%).EF-T system has the lowest energy consumption(4.367 kWh/kg)among the three electrochemical systems.The cathodic adsorption,anodic electrooxidation,and EF reaction are responsible for the degradation of FF.After five consecutive cycle experiments,FF removal ratio was still 98%,indicating WBC has the good stability.展开更多
基金supported by the National Natural Science Foundation of China(Grants Nos.51978150 and 52050410334)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grants No.SJCX23_0069)the Fundamental Research Funds for the Central Universities.
文摘Conical origami structures are characterized by their substantial out-of-plane stiffness and energy-absorptioncapacity.Previous investigations have commonly focused on the static characteristics of these lightweight struc-tures.However,the efficient analysis of the natural vibrations of these structures is pivotal for designing conicalorigami structures with programmable stiffness and mass.In this paper,we propose a novel method to analyzethe natural vibrations of such structures by combining a symmetric substructuring method(SSM)and a gener-alized eigenvalue analysis.SSM exploits the inherent symmetry of the structure to decompose it into a finiteset of repetitive substructures.In doing so,we reduce the dimensions of matrices and improve computationalefficiency by adopting the stiffness and mass matrices of the substructures in the generalized eigenvalue analysis.Finite element simulations of pin-jointed models are used to validate the computational results of the proposedapproach.Moreover,the parametric analysis of the structures demonstrates the influences of the number of seg-ments along the circumference and the radius of the cone on the structural mass and natural frequencies of thestructures.Furthermore,we present a comparison between six-fold and four-fold conical origami structures anddiscuss the influence of various geometric parameters on their natural frequencies.This study provides a strategyfor efficiently analyzing the natural vibration of symmetric origami structures and has the potential to contributeto the efficient design and customization of origami metastructures with programmable stiffness.
基金Supported by the National Natural Science Foundation of China(No.71373023,61372148,61571045)Beijing Advanced Innovation Center for Imaging Technology(No.BAICIT-2016002)+1 种基金the National Key Technology R&D Program(No.2014BAK08B02,2015BAH55F03)the Importation and Development of High-Caliber Talents Project of Beijing Municipal Institutions(No.CIT&TCD201504039)
文摘A graph theory model of the human nature structure( GMH) for machine vision and image/graphics processing is described in this paper. Independent from the motion and deformation of contours,the human nature structure( HNS) embodies the most basic movement characteristics of the body. The human body can be divided into basic units like head,torso,and limbs. Using these basic units,a graph theory model for the HNS can be constructed. GMH provides a basic model for human posture processing,and the outline in the perspective projection plane is the body contour of an image. In addition,the GMH can be applied to articulated motion and deformable objects,e. g.,in the design and analysis of body posture,by modifying mapping parameters of the GMH.
基金supported by the Science and Technology Development Project of Jilin Provincial Science&Technology Department(201205080)the Science and Technology Research Projects of the Education Office of Jilin Province(No.2013.384)
文摘A new metal-organic coordination polymer [Zn(pzdc)(mbix)]n·nH2O(H2pzdc = pyrazine-2,3- dicarboxylic acid, mbix = 1,3-bis(imidazol-1-ylmethyl)-benzene) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. Yellow crystals crystallize in monoclinic system, space group P21/n with a = 8.5519(6), b = 14.8764(10), c = 16.4108(11) A, β = 103.4520(10)o, V = 2030.5(2)A^3, C(20)H(18)N6O5Zn, Mr = 487.77, Dc = 1.596 g/cm^3, F(000) = 1000, Z = 4, μ(MoK α) = 1.257 mm^-1, the final R = 0.0260 and w R = 0.0706 for 3445 observed reflections(I 〉 2σ(I)). The structure of 1 exhibits a one-dimensional chain-like structure. In addition, natural bond orbital(NBO) analysis was performed by the PBE0/LANL2DZ method in Gaussian 03 Program. The calculation results show obvious covalent interaction between the coordinated atoms and Zn(Ⅱ) ion.
基金supported by the Science and Technology Development Project of Jilin Provincial Science&Technology Department(201205080)the Science and Technology Research Projects of the Education Office of Jilin Province(No.2013.384)
文摘A new coordination polymer, [Cd2(NIPH)(L)2(H2O)]n(1, HL = 3-(2-pyridyl)pyrazole and H2NIPH = 5-nitroisophthalic acid), has been synthesized. The structure of complex 1 has been characterized by X-ray single-crystal diffraction, elemental analysis, IR spectrum analysis, thermogravimetric analysis and fluorescence spectrum analysis. Complex 1 belongs to the triclinic system, space group P1 with a = 8.9539(6), b = 11.6252(8), c = 12.2472(8) A^°, α = 80.011(2), β = 80.3850(10), γ = 86.773(2)°, V = 1237.37(14) A^°3, Z = 2, Dc = 1.987 g/cm^3, μ = 1.780 mm^-1, Mr = 740.25, F(000) = 724, the final R = 0.0295 and wR = 0.1015 with I 〉 2σ(I). Two H2NIPH as monodentate and bidentate ligands and two L ligands link four Cd(Ⅱ) ions to form a tetranuclear subunit. Each pair of the tetranuclear subunits is bridged by NIPH ligands to yield a one-dimensional double-chain structure. Furthermore, the 1D chains are linked into a 3D supramolecular framework with hydrogen bonds and π-π interactions. In addition, we analyzed Natural Bond Orbital(NBO) in using the PBE0/LANL2DZ method built in Gaussian 03 Program. The calculation results indicated the obvious covalent interaction between the coordinated atoms and Cd(Ⅱ) ion.
文摘This paper is a review of the past research of mechanical testing methods for natural fibre honeycomb sandwich structure as well as failure modes analysis at a microscopic level by using Scanning Electron Microscope (SEM). As the world is garnering attention towards renewable resources for environmental purposes, studies of natural fibre have been increasing as well as the application of natural fibre throughout various industries such as aerospace, automobiles, and construction sectors. This paper is started with brief information regarding the honeycomb sandwich structure, introduction to natural fibre, its applications as well as the factors affecting the performances of the structure. Next, the mechanical testing methods are listed out as well as the expected outcomes obtained from the respective testing. The mechanical properties are also identified by conducting lab tests according to the ASTM standard for sandwich and core structures. The microstructure of the deformed samples is then examined under Scanning Electron Microscope (SEM) by using different magnifications to study the failure mechanisms of the samples. The images obtained from the SEM test are analyzed by using fractography which will show the failure modes of the samples. This article is based on past research conducted by professional on the related topic.
基金supported by the Science and Technology Development Project of Jilin Provincial Science&Technology Department(201205080)the Science and Technology Research Projects of the Education Office of Jilin Province(No.2013.384)
文摘A new Co(ll) coordination polymer has been successfully synthesized under hydrothermal conditions [Co(C2O4)(mbix)]n (1, H2C2O4 = oxalic acid, mbix = 1,3-bis(imidazol- l-ylmethyl)benzene). Its structure has been determined by elemental analyses, IR, UV spectroscopy and single-crystal X-ray diffraction analysis. Pink crystals crystallize in the triclinic system, space group PI with a = 8.8666(7), b = 9.5859(8), c = 10,8537(9) A,α = 67.6810(10),β= 66.1260(10), γ = 77.1300(10)°, V= 777.77(11), CI6HI4CoN404, Mr = 385.24, Dc = 1.645 g/cm3, F(000) = 394, Z= 2,/z(MoKa) = 1.134 mm% the final R = 0.0482 and wR = 0.1231 for 2968 observed reflections (I〉 2σ(I)). It shows a two-dimensional (2D) network structure. The intermolecular C-H…O hydrogen bonding and π-π stacking interactions extend complex 1 into a 3D supramolecular architecture and play an important role in stabilizing 1. In addition, Natural Bond Orbital (NBO) analysis was performed by using the PBE0/LANL2DZ method built in Gaussian 09 Program. The calculation results showed obvious covalent interaction between the coordinated atoms and Co(II) ion.
文摘Discussions related to land use in Turkey in recent years has been increasing. These discussions are mostly between those who want to protect the natural environment and those who demand other sectoral investment areas. However, there has not been a comprehensive and holistic study assessment of the land use, except for local studies. For this reason, the present study has been conducted in order to reveal the change in land use in the country’s geography. In order to achieve the aims of the study, the literature was reviewed, institutional data were compiled, and the results of previous local studies were evaluated using appropriate methods. Factors affecting land use were examined in the study and it was seen from the findings that significant land use changes occurred in the last 75 years. Although land use suitable for natural structure was common in advance, after the 1980s sectoral needs came to the fore. With the accelerated urbanization and industrialization, tourism, mining and dam areas have become widespread. It has been determined that there is a need for new scientific studies on land use, revision of ineffective laws, and national land use plans that take into account the sectoral needs in order to reduce the discussions.
基金the National Social Science Funds of China (13&ZD159)the National Natural Science Foundation of China (71303258, 71373285)+1 种基金MOE (Ministry of Education in China) Project of Humanities and Social Sciences (13YJC630148)Science Foundation of China University of Petroleum, Beijing (ZX20150130) for sponsoring this joint research
文摘With the vigorous promotion of energy conservation and implementation of clean energy strategies,China's natural gas industry has entered a rapid development phase,and natural gas is playing an increasingly important role in China's energy structure.This paper uses a Generalized Weng model to forecast Chinese regional natural gas production,where accuracy and reasonableness compared with other predictions are enhanced by taking remaining estimated recoverable resources as a criterion.The forecast shows that China's natural gas production will maintain a rapid growth with peak gas of 323 billion cubic meters a year coming in 2036;in 2020,natural gas production will surpass that of oil to become a more important source of energy.Natural gas will play an important role in optimizing China's energy consumption structure and will be a strategic replacement of oil.This will require that exploration and development of conventional natural gas is highly valued and its industrial development to be reasonably planned.As well,full use should be made of domestic and international markets.Initiative should also be taken in the exploration and development of unconventional and deepwater gas,which shall form a complement to the development of China's conventional natural gas industry.
文摘Background:Conceptual models of forest dynamics are powerful cognitive tools,which are indispensable for communicating ecological ideas and knowledge,and in developing strategic approaches and setting targets for forest conservation,restoration and sustainable management.Forest development through time is conventionally described as a directional,or "linear",and predictable sequence of stages from "bare ground" to old forest representing the "climax-state".However,this simple view is incompatible with the current knowledge and understanding of intrinsic variability of forest dynamics.Hypothesis:Overly simple conceptual models of forest dynamics easily become transformed into biased mental models of how forests naturally develop and what kind of structures they display.To be able to communicate the essential features and diversity of forest dynamics,comprehensive conceptual models are needed.For this end,Kuuluvainen(2009) suggested a relatively simple conceptual model of forest dynamics,which separates three major modes of forest dynamics,and incorporates state changes and transitions between the forest dynamics modes depending on changes in disturbance regime.Conclusions:Conceptual models of forest dynamics should be comprehensive enough to incorporate both longterm directional change and short-term cyclic forest dynamics,as well as transitions from one dynamics mode to another depending on changes in the driving disturbance regime type.Models that capture such essential features of forest dynamics are indispensable for educational purposes,in setting reference conditions and in developing methods in forest conservation,restoration and ecosystem management.
文摘In many sites on Egypt desert roads collapsible soils <span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">is</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> broadly classified as a problematic soils contain</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">ing</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> silty fine sand which </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">is </span></span></span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">cemented with low density and low degree of saturation which is susceptible to a large and sudden reduction in their v</span><span style="font-family:Verdana;">olume upon inundation, with or without vibration in its stress. Four sites have been studied for new urban</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">, </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">roads and industry work sits, related to increase in natural water content</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">.</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> These soils go through radical rearrangement of their particles, causing sudden changes in the stress-deformation behavior which caus</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">e</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> differential settlement of foundation and roads. This chan</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">ge in volume can lead to foundation failures and worth of damages under ground public facilities and infrastructure. In this study, the search program </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">is </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">developed to establish their different behavior under wetting in two phase</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">s:</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> field and laboratory work. The obtained results are useful in mapping the trend of the factors affect</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">ed</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> in assessing soil collapsibility rate or collapse potentials which </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">are </span></span></span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">observed in construction with volume change problems. The major factors observed are the natural structure skeleton of the soil particle and its grain size and mechanism of soil sedimentation. The field collapse potentials value assigned for these tested sites along Alexandria</span><span style="font-family:Verdana;">—Cairo desert road indicated that the field measured collapsibility potentials are smaller than those measured on the same extracted undisturbed samples in laboratory by 15%, which can be save</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">d</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> in coast, change in proposed collapsibility improvement method and change in select foundation type. Also, field tests evaluate the collapsibility rate with time and highlight that environmental history and natural soil structure in field are the important factors affected on these soil collapse, and also, knowledgeable by collapsible soils during wetting in these sites studied.</span></span></span>
基金supported by the National Natural Science Foundation of China(No.22075244)the Zhejiang Provincial Innovation Center of Advanced Chemicals Technology(No.ACTIC-2022-004)+2 种基金the Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering(No.2021SZ-TD009)the Zhejiang Provincial Natural Science Foundation of China(No.LZ22E030001)the Science and Technology Program of Institute of Zhejiang University-Quzhou(Nos.IZQ2021KJ2001 and IZQ2022KJ3013).
文摘Energy-absorbing materials are widely used in transportations,sports,and the military applications.Particularly,porous materials,including natural and artificial materials,have attracted tremendous attentions due to their light weight and excellent energy absorption capability.This review summarizes the recent progresses in the natural and artificial energy-absorbing porous materials.First,we review the typical natural porous materials including cuttlebone,bighorn sheep horn,pomelo peel,and sunflower stem pith.The architectures,energy absorption abilities,and mechanisms of these typical natural materials and their bioinspired materials are summarized.Then,we provide a review on the fabrication methods of artificial energy-absorbing porous materials,such as conventional foaming and three-dimensional(3D)printing.Finally,we address the challenges and prospects for the future development of energy-absorbing porous materials.More importantly,our review provides a direct guidance for the design and fabrication of energy-absorbing porous materials required for various engineering applications.
文摘The environment structure of natural nidi and epidemic areas of hemorrhagic fever with renal syndrome (HFRS) possesses characteristics of topography, hydrology, climate, soil, vegetation, and animals. The natural nidi and epidemic areas of HFRS are distributed mainly in plain and hilly regions under 500 meters above the sea level; in plentiful-water zones and transitional zones; in temperate zone and subtropical zone of the eastern monsoon region; in the abundant-aluminum soil region and the sial soil region; in the eastern China damp forest region (agricultural districts and northeast forest districts); in the eastern Asia dampness-prefering animal geographic region. Apodemus agrarius and Rattus norvegicus are the thriving animal population, predominant species or common species as well as the main reservoir hosts and sources of infection in the natural nidi and epidemic areas of HFRS.
基金supported by the National Science Fund for Distinguished Young Scholars(No.51625801)Major Science and Technology Program for Water Pollution Control and Treatment in China(No.2017ZX07202-001-007)+4 种基金Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme(2017)Guangdong Provincial Science and Technology Project(No.2017A020216014)the National Natural Science Foundation of China(No.21777106)Pearl River S&T Nova Program of Guangzhou,China(No.201710010065)Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology(No.2020B1212060022)。
文摘The flow-through electro-Fenton(EF-T)reactor with WBC cathode was designed to remove florfenicol(FF).The activated WBC cathode was prepared by facile carbonization and activation methods,and featured high specific surface area,natural multi-channel structure,abundant oxygen-containing groups,good hydrophilicity,and excellent O_(2)reducing capacity.WBC cathode was located above Ti/Ru-IrO_(2)mesh anode.O_(2)evolved at the anode was carried to the inner wall of channel of WBC by the force of buoyancy and water flow,which increases oxygen source of H_(2)O_(2)generation at the cathode.The flow-through system by using WBC electrode promote the mass transfer of O_(2)and FF.The production amount of H_(2)O_(2)at activated WBC was 32.2 mg/L,which was almost twice as much as that at non-activated WBC(15.0 mg/L).FF removal ratio in EF-T system was 98%,which was much higher than that of traditional flow-by electro-Fenton(EF-B,33%)or single electrooxidation system(EO,16%).EF-T system has the lowest energy consumption(4.367 kWh/kg)among the three electrochemical systems.The cathodic adsorption,anodic electrooxidation,and EF reaction are responsible for the degradation of FF.After five consecutive cycle experiments,FF removal ratio was still 98%,indicating WBC has the good stability.