A Study on Hydrogen Peroxide in the Atmosphere

Hydrogen peroxide (H2O2 ) concentrations were measured at two sites. One was on Lushan Mountain in May, 1987. The other was in Beijing in August, 1987 and in December, 1986. The automated fluorometric method was used for the determination of H2O2 . The concentrations of H2O2 ranged from approximately 0.50 to 4.32 ppb on Lushan Mountain. The concentrations of H2O2 ranged from approximately 0.05 to 1.49 ppb in August in Beijing, and it was only 0.01 ppb in December in Beijing.

Study on Microwave Remote Sensing of Atmosphere,Cloud and Rain

In this paper, recent research of microwave remote sensing of atmosphere, cloud and rain in China is presented. It includes the following aspects:(1) Progress in the development of multifrequency radiometer and its characteristics and parameters;(2) Application of microwave remote sensing in prediction of atmospheric boundary layer. The atmospheric temperature profiles are derived with 5 mm (54.5 GHz) radiometer angle-scanning observations. Due to the fact that microwave radiometer could monitor the atmospheric temperature profile continuously and make the initialization of numerical model any time, it is helpful for improving the accuracy in prediction of the evolution of atmospheric boundary layer;(3) Theory and application of microwave radiometers in monitoring atmospheric temperature, humidity and water content in cloud. The field experiment of International Satellite Cloud Climatology Project (ISCCP) at Shionomisaki and Amami Oshima of Japan for studies of cloud and weather has been described;(4) Satellite remote sensing of atmosphere and colud. The TIROS-N TOYS satellite data are used to obtain atmospheric temperature profile. The results are compared with those of radiosonde, with rms deviation smaller than that of the current operational TOVS processing;(5) Microwave remote sensing and communication. The atmospheric attenuations are derived with microwave remote sensing methods such as solar radiation method etc., in order to obtain the local value instantaneously. The characteristics of Beijing's rainfall have been analysed and the probability of microwave attenuation of rain is predicted;(6) For improvement of the accuracy of rainfall measurement, a radiometer-radar system (λ= 3.2 cm) has been developed The variation of rainfall distribution and area-rainfall may be obtained by its measurements, which mav be helpful for hydrological prediction.The prospect of microwave remote sensing in meteorology is also discussed.

An Observational Study of the 30-50 Day Atmospheric Oscillations Part I: Structure and Propagation

Features of structure and propagation of the 30 to SO day atmospheric oscillations are investigated using the ECMWF analysis of 1980-1983. Evidence is provided to confirm the characteristics of the oscillation in the equatorial region. Those in the mid-high latitudes, however, are revealed to be very different from the tropics and pose a strong barotropic structure. Horizontal coherence shows teleconnection patterns which can be identified as EAP and PNA. The wind field of the specified time scale of the oscillation appears as long-lived vortices and vortex pairs. Mid-latitude perturbations propagate clearly westwards, especially during the winter season. In the high latitudes, they propagate westwards in the winter but eastwards in the summer. Meridional propagations are rather different from region to region.

An Experimental Study on Atmospheric Pressure Glow Discharge in Different Gases

Usually, the electrical breakdown of dielectric barrier discharge (DBD) at atmo-spheric pressure leads to a filamentary non-homogeneous discharge. However, it is also possible to obtain a diffuse DBD in homogeneous form, called atmospheric pressure glow discharge (APGD). We obtained a uniform APGD in helium and in the mixture of argon with alcohol, and studied the electrical characteristics of helium APGD. It is found that the relationship between discharge current and source frequency is different depending on the difference in gas gap when the applied voltage is kept constant. The discharge current shows an increasing trend with the increased frequency when gas gap is 0.8 cm, but the discharge current tends to decrease with the increased frequency when the gas gap increases. The discharge current always increases with the increased applied voltage when the source frequency is kept constant. We also observed a glow-like discharge in nitrogen at atmospheric pressure.

An Observational Study of the 30-50 Day Atmospheric Oscillations Part II: Temporal Evolution and Hemispheric Interaction across the Equator

In this part, the temporal evolution and interaction across the equator of 30-50 day oscillation in the atmosphere are investigated further. The annual variation of 30-50 day oscillation is quite obvious in the mid-high latitudes. In the tropical atmosphere, the obvious interannual variation is an important property for temporal evolution of 30-50 day oscillation. The low-frequency wavetrain across the equator over the central Pacific and central Atlantic area, the movement of the long-lived low-frequency system across the equator and the meridional wind component across the equator will obviously show the interaction of 30-50 day oscillation in the atmosphere across the equator.

Study on Clouds and Marine Atmospheric Boundary Layer

A set of remote sensing instruments of Peking University, which includes mainly a dual-channel(22.235GHz and 35.5GHz) microwave radiometer, a 8mm microwave and a 5mm microwave radiometer, has been developed for the Western North-Pacific Cloud-Radiation Experiment (WENPEX). The instruments were used to observe the cloud and marine atmospheric boundary-layer in the southwest sea area of Japan in winter time from 1989 to 1991.In the weather change process, the characteristics of the marine atmospheric boundary-layer and liquid water content in cloud of this area in winter time are studied from observation data. A one-dimensional mixed layer model is presented for the growth and evolution of a cloud-topped marine boundary-layer. The model is used to study in the WENPEX. The simulation results are in agreement with observation data, especially the integral water in cloud.

Mechanism and kinetics study on the ozonolysis reaction of 2,3,7,8-TCDD in the atmosphere

The ozonolysis of 2,3,7,8-tetra-chlorodibenzo-p-dioxin （2,3,7,8-TCDD） is an efficient degradation way in the atmosphere. The ozonolysis process and possible reactions path of Criegee Intermediates with NO and H2O are introduced in detail at the method of MPWB1K/6-31＋G（d,p）//MPWB1K/6- 311＋G（3df,2p） level. In ozonolysis, H2O is an important source of OH radical formation and initiated the subsequent degradation reaction. The Rice-Ramsperger-Kassel-Marcus （RRKM） theory was applied to calculate rate constants with the temperature ranging from 200 to 600 K. The rate constant of reaction between 2,3,7,8-TCDD and 03 is 4.80 × 10^-20 cm3/（mole.sec） at 298 K and 760 Tort. The atmospheric lifetime of the reaction species was estimated according to rate constants, which is helpful for the atmospheric model study on the degradation and risk assessment of dioxin.

NUMERICAL STUDY OF QUASI-BIWEEKLY OSCILLATION IN TROPICAL ATMOSPHERE

By using a P-σ incorporated coordinate five-layer primitive equation spherical band model with surface temperature controlled by the heat balance equation,a simulation is done of disturbance formation in an anomalously warm SST area and of the quasi-biweekly oscillation(QBWO)of the disturbance,and associated rainfall and SST with SST being 1/3 period of oscillational phase ahead of rainfall.The study shows that the oscillation is produced by cloud-radiation interaction.Initial anomalously warm SST in the mid-western Pa- cific causes stronger oscillation than in the eastern.Hence the oscillation gets attenuated during the eastward movement of the disturbance.

Advances in Studies on Nonlinear Atmospheric Waves

A review on the progress in the research of nonlinear atmospheric waves, especially the nonlinear Rossby waves is made in this paper. Many results reported here have been obtained in Peking University.