Recent advances in the utilization of copper sulfide compounds for electrochemical CO2 reduction

Converting carbon dioxide(CO2)into value-added chemicals by CO2 reduction has been considered as a potential way to solve the current energy crisis and environmental problem.Among the methods of CO2 reduction,the electrochemical method has been widely used due to its mild reaction condition and high reaction efficiency.In the electrochemical reduction system,the CO2 electrocatalyst is the most important part.Although many CO2 electrocatalysts have been developed,efficient catalysts with high activity,selectivity and stability are still lacking.Copper sulfide compound,as a low-toxicity and emerging material,has broad prospects in the field of CO2 reduction due to its unique structural and electrochemical properties.Much progress has been achieved with copper sulfide nanocrystalline and the field is rapidly developing.This paper summarizes the preparation,recent progress in development,and factors affecting the electrocatalytic CO2 reduction performance with copper sulfide compound as a catalyst.Prospects for future development are also outlined,with the aim of using copper sulfide compound as a highly active and stable electrocatalyst for CO2 reduction.

Synthesis and Crystal Structure of a New Quaternary Sulfide FeSm6Si2S14

One new quaternary rare-earth sulfide, FeSm6Si2S（14）, has been synthesized by a facile solid-state route with boron as the reducing reagent. It crystallizes in the noncentrosymmetric hexagonal space group P63, belonging to the Ce6Al（3.33）S（14） structure-type, and the AxRE3MQ7 family. Its crystal structure features a 3-D framework constructed by SmS 8 bicapped trigonal prisms, where Fe and Si atoms occupy the octahedral（2a） and tetrahedral（2c） voids, respectively. The FeS 6 octahedra are connected with each other to form a chain along the b direction. FeSm6Si2S（14） represents a new chemical composition among the large family of AxRE3MQ7 compounds. The other related compounds containing transition metal are also discussed.

Origin of the unusually high dibenzothiophene concentrations in Lower Ordovician oils from the Tazhong Uplift,Tarim Basin,China

The origin of the unusually high dibenzothiophene （DBT） concentrations in Lower Ordovician oils from the Tazhong Uplift,Tarim Basin was studied by Fourier transform ion cyclotron resonance mass spectrometry （FT-ICR MS）.The most abundant sulfur compounds in the oils are S 1 species with doublebond equivalent （DBE） values of 1-19 and 11-48 carbon atoms.The range of the number of carbon atoms in the sulfur compounds detected by the FT-ICR MS （S 1 species with DBE=9） is about ten times larger than that for sulfur compounds detected by GC/MS （DBTs）.This suggests that FT-ICR MS is a much better approach than GC/MS for characterization of DBTs in crude oils.The abundance of S 1 species with DBE=1-8 decreased with increasing thermal maturity,while the abundance of S 1 species with DBE=9 （primarily DBTs） increased.Therefore,thermal maturity is an important factor in the formation of oils with high DBT concentrations.Unusually high abundances of S 1 species with low DBE values （1-8）,which include sulfide,thiophene and benzothiophene,were observed in several oils,especially the TZ83 （O 1） oil with high or very high thermal maturity.Thermochemical sulfate reduction （TSR） was thought to be the reason for the high abundance of these low DBE compounds in deep reservoirs,and thermochemical sulfate reduction could affect the distribution and composition of DBTs in the oils.According to the results of FT-ICR MS analysis,there are no signs that TSR is occurring or has occurred recently for most of the Lower Ordovician oils.

Analysis of Formation and Mechanisms of Black and Smelly River Water in Island Cities

The causes of formation of black and smelly river water were summarized,including the entry of organic pollutants into rivers,such as domestic waste,three industrial wastes,thermal pollution caused by industrial hot drainage,pollution of the river bottom and resuspension movement,and so on. The existing modes and valence changes of iron,sulfur and other elements in black and smelly water were discussed. It is clear that the formation of the black and stink is mainly caused by blackening factors and stink-causing factors. It is concluded that the main blackening factors are ferrous sulfide,manganese sulphide,and the main stink-causing factors are hydrogen sulfide,ammonia or sulfides( VOSCs),josamidine and 2-dimethyl isobenol based on sulfur elements. It provides theoretical reference for the control of black and smelly river water in island cities.

Metal halide perovskite nanocrystals with enhanced photoluminescence and stability toward anti-counterfeiting highperformance flexible fibers

As a new type of light-collecting and luminescent material,all-inorganic cesium lead halide CsPbX_(3)(X=Cl,Br,I)perovskite nanocrystals(NCs)are expected to have a wide range of applications in the fields of photovoltaics,optoelectronics,and fluorescence anti-counterfeiting,etc.Therefore,improving the fluorescence performance and stability of CsPbX_(3)perovskite NCs to prompt their applications would promise both fundamental and practical significance for in-depth research in the field of halide perovskites.In this paper,we developed a modification strategy to introduce a halogen source,zinc bromide(ZnBr_(2))in hexane,to CsPbX_(3)perovskite that can be conducted under atmospheric conditions with reduced reaction cost and easier operation.The first work in this paper was to apply the modification strategy to CsPbI_(3)nanowires(NWs).Compared with the untreated NWs,the ZnBr_(2)/hexane modified CsPbI_(3)NWs exhibited better fluorescence properties.Subsequently,based on the study of perovskite NWs,we investigated perovskite nanocrystal-CsPbI_(3)nanorods(NRs)with different morphologies and sizes.It was found that the luminescence properties of nanorods(NRs)were superior.Later,we infiltrated the modified NRs into the aramid/polyphenylene sulfide(ACFs/PPS)composite paper yielded from our previous work to study its fluorescence performance for anti-counterfeiting.Their luminescence properties under ultraviolet light irradiation enable better performance in fluorescence anti-counterfeiting.The ZnBr_(2)/hexane modification strategy and the applications studied in this work will expand the scope of perovskite research,laying the foundation for the applications of fluorescent anti-counterfeiting,nano-photoelectric devices,and fluorescent composite materials.

Highly efficient and magnetically separable nano-CuFe_2O_4 catalyzed S-arylation of thiourea by aryl/heteroaryl halides

The non-toxic and magnetically separable nano-CuFeOcatalyzed synthesis of symmetrical aryl sulfides by the reaction of thiourea with a wide variety of aryl halides,including aryl chlorides has been reported.Excellent yields of products have been obtained under ligand-free conditions and without the use of any expensive catalyst,such as palladium.