Associated Gas Utilization Using Gas Turbine Engine, Performance Implication—Nigerian Case Study

Typically, crude oil production in Nigeria always accompanied by surface production of associated gas. With little associated gas recovery facilities in place, majority of associated gas is continuously flared with few portions re-injected into the reservoir for enhance oil recovery (EOR). In addition to environmental hazards, wasting substantial amount of produced associated gas is deemed detrimental to a country currently generating less than 54% of its electric power requirement. Onsite power generation as one of the many means of utilization of associated gas has been conceived. Conversely, the availability and performance of the gas turbine engine for onsite associated gas utilization requires evaluation owing to variations in associated natural gas composition globally and the dependency of associated gas production on reservoirs and oil production activities. This paper presents an analytical investigation of gas turbine engine inspired by GE LMS100 frame engine for onsite utilization of associated gas in Nigeria. Gas turbine performance results are presented and performance parameters are compared against typical commercial natural gas grade.

Conversion and reaction kinetics of coke oven gas over a commercial Fe-Mo/Al_2O_3 catalyst

Producing methanol from coke oven gas(COG) is one of the important applications of COG. Removal of sulfur from COG is a key step of this process. Conversion and reaction kinetics over a commercial Fe-Mo/Al2O3 catalyst(T-202) were studied in a continuous flow fixed bed reactor under pressures of 1.6-2.8 MPa, space time of 1.32-3.55 s and temperatures of 240-360 °C. Though the COG contains about 0.6 mol/mol H2, hydrogenation of CO and CO2 is not significant on this catalyst. The conversions of unsaturated hydrocarbons depend on their molecular structures. Diolefins and alkynes can be completely hydrogenated even at relatively low temperature and pressure. Olefins, in contrast, can only be progressively hydrogenated with increasing temperature and pressure. The hydrodesulfurization(HDS) of CS2 on this catalyst is easy. Complete conversion of CS2 was observed in the whole range of the conditions used in this work. The original COS in the COG can also be easily converted to a low level. However, its complete HDS is difficult due to the relatively high concentration of CO in the COG and due to the limitation of thermodynamics. H2 S can react with unsaturated hydrocarbons to form ethyl mercaptan and thiophene, which are then progressively hydrodesulfurized with increasing temperature and pressure. Based on the experimental observations, reaction kinetic models for the conversion of ethylene and sulfur-containing compounds were proposed; the values of the parameters in the models were obtained by regression of the experimental data.

Covalent Bonds Creation between Gas and Liquid Phase Change: Compatibility with Covalent and Even-Odd Rules Based on a “Specific Periodic Table for Liquids”

A decrease in temperature will eventually turn a gas into liquid and then into a solid. Each of these phase change shows a higher degree in cohesion of molecules. While it is usually admitted that molecules in solids form additional connections, the cohesion of molecules in liquids is usually explained by changes in kinetics of molecules. Given that the density of a solid is nearly the same than that of a liquid, the present paper assumes a different stand and considers that connections between molecules must be similar in liquids and in solids. The difference between gas, in which molecules are entirely loose, and liquid, is therefore the presence of an additional connection between gaseous molecules. This paper describes how and where these connections are built with the help of a few rules and a “specific periodic table for liquids”. The coherence of this approach is reinforced by its capacity to explain phase change of forty well-known molecules containing inorganic and organic elements.

The Effect of Gas Production, Utilization, and Flaring on the Economic Growth of Nigeria

The extent to which a country develops is anchored around its resources;and this is evidenced in how the revenue derived from natural resources (especially the oil and gas industries) has influenced national development strategies. This notwithstanding, the existence of natural resources does not always translate to development, as these often times lead to complacency and mismanagement;Nigeria may have suffered from this. This paper establishes the impact of gas production, utilization, and flaring on the estimated monetary value of the goods and services produced in Nigeria (GDP), using multiple linear regression analysis. The result shows that while gas utilization has a positive impact on the nation’s GDP, gas production and flaring are negatively associated with GDP. The paper concludes that for these to positively stimulate economic growth, there is need to invest more in infrastructure in the industry, and review the regulatory framework guiding operations of the oil and gas industry.

Effects of Stylosanthes scabra Forage Supplementation on in Vitro Gas Production and Fiber Degradation of Eragrostis Grass Hay

Natural pastures constitute a major component of ruminant livestock feed, and are the most cost-effective feed resource available for smallholder subsistence farmers. However, this feed resource does not meet animal nutritional requirement due to deficiency in nitrogen, energy and minerals. In addition, at maturity lignification is the major concern since it reduces digestibility and contributes to methane emission. Thus, the objective of this study was to evaluate the effect of supplementing low-quality Eragrostis grass hay with five (9281, 11,252, 11,255, 11,595 and 11,604) selected Stylosanthes scabra accessions on in vitro ruminal fermentation and neutral detergent fiber degradation. Therefore, in vitro study was conducted on grass hay, accessions and the mixture of grass hay with each accession included at two (15%, 30%) levels. The substrates (grass hay, accessions and the mixtures) were incubated in separate serum bottles for 72 h. Neutral detergent fiber (NDF) of the accessions ranged from 300 to 350 g/kg DM with crude protein (CP) value ranging from 177.5 to 184.1 g/kg DM. Eragrostis grass hay had NDF value of 813 g/kg DM, with CP value of 34.3 g/kg DM. Grass hay fermented slowly, it took 30 h for grass hay to produce gas volume above 50 mL, while Stylosanthes scabra accessions took 12 h. Supplementing grass hay with accessions significantly improved fermentation. However, it was observed that 15% inclusion took 30 h to produce gas volume above 50 mL, whereas at 30% inclusions it took 24 h for accession 9281, 11,595 and 11,604. Accession 11,604 improve grass fermentation by almost three times the value of grass hay in 2 h. Grass hay supplemented with accession 11,604 at 30% had a positive associative effect and significantly improved NDF degradability. In conclusion, accession 11,604 may be fed strategically as forage supplement to low-quality forage for ruminants.

Indicators of δ^(13)C and δ^(18)O of gas hydrate-associated sediments

The analyses of δ13C and δ18O of gas hydrate-associated sediments from two cores on Hydrate Ridge in Cascadia convergent margin offshore Oregon, eastern North Pacific show the values of δ13C from-29.81‰ to -48.28‰(PDB) and δ18O from 2.56‰to 4.28‰ (PDB), which could be plotted into a group called typical carbonate minerals influenced by the methane in cold venting. Moreover, the values of δ13C and δ18O show a consistent trend in both cores from top to bottom with increasing of δ13C and decreasing of δ18O. This trend could be explained as an effect caused by the anaerobic oxidation of methane (AOM) in depth and the oxygen fraction during the formation of gas hydrate in depth together. These characteristics of δ13C and δ18O indicate that the gas hydrate-associated sediments are significantly different from the normal marine carbonates, and they are deeply influenced by the formation and evolution of gas hydrate. So, the distinct characteristics of δ13C and δ18O of gas hydrate-associated

In-depth study on the solubility of elemental sulfur in sour gas mixtures based on the Chrastil's association model

Accurately predicting the solubility of elemental sulfur in sour gas mixtures is a primary task.As a current and widely-used model on the solubility of elemental sulfur in sour gas mixtures,Chrastil's association model has a big error in the process of predicting experimental data based on different fitting methods.This paper combined with experimental data reported by relevant scholars about elemental sulfur solubility in sour gases and selected density,temperature and pressure as three important influential factors.According to different fitting methods,we can calculate the correlation parameters in Chrastil's model.Then different solubility formulas can be used to predict the solubility of elemental sulfur in sour gas mixtures.Through in-depth research and analysis of Chrastil's solubility model from numerical aspects,it's easy to find the irrationality about Chrastil's solubility model and fitting methods.Especially in fitting methods,further improvement of the fitting method is proposed and used to predict the solubility of elemental sulfur in sour gas mixtures.The calculation results show that some improvements of the predicting precision have been achieved by using the improved fitting method in Chrastil's association model.

An isotope study of the accumulation mechanisms of high-sulfur gas from the Sichuan Basin, southwestern China

The mechanism of hydrogen sulfide(H_2S) generation plays a key role in the exploration and development of marine high-sulfur natural gas, of which the major targets are the composition and isotope characteristics of sulfur-containing compounds.Hydrocarbon source rocks, reservoir rocks, natural gases and water-soluble gases from Sichuan Basin have been analyzed with an online method for the content of H_2S and isotopic composition of different sulfur-containing compounds. The results of comparative analysis show that the sulfur-containing compounds in the source rocks are mainly formed by bacterial sulfate reduction(BSR), and the sulfur compounds in natural gas, water and reservoir are mainly formed by thermal sulfate reduction(TSR). Moreover, it has been shown that the isotopically reversion for methane and ethane in high sulfur content gas is caused by TSR. The sulfur isotopic composition of H_2S in natural gas is inherited from the gypsum or brine of the same or adjacent layer,indicating that the generation and accumulation of H_2S have the characteristics of either a self-generated source or a near-source.

Ozone Injections in Orthopaedics: An Effective Substitute for Cortisone Injections in Total Joint Replacement Patients and Other Arthritic Conditions

Background: Total joint replacement (TJR) patients can suffer from tendinitis, bursitis or other inflammatory conditions that are generally treated by cortisone (corticosteroid) injections. Such injections rarely cause complications in the general public, but have resulted in severe implant infections in some patients with joint replacements. The purpose of this study is to review the literature involving joint replacement infections after cortisone injections and present ozone as an alternative to cortisone in a series of joint replacement patients with periarticular inflammatory conditions. Methods: There were 26 combined patients with either total hip replacement (THR), total knee replacement (TKR), total ankle replacement (TAR), or resurfacing shoulder replacement (SR) that developed tendonitis, bursitis or inflammatory problems related to their respective joint arthroplasties. Rather than use cortisone, they were given prolozone injections into the inflammatory regions to relieve them of their pain and dysfunction. This injection was followed by an ice pack for one hour and a return to normal function thereafter. Results: All THR, TKR, SR and TAR pathologies were improved or asymptomatic after one or a series of prolozone injections into the area of inflammation. No cortisone injections were used and no infections were encountered. Conclusions: Prolozone injection therapy is an effective treatment for post-operative inflammatory conditions following total joint replacement. Patients find relief of inflammation symptoms, similar to steroid injections, without the risk of infection or tissue breakdown. Prolozone injection therapy can be useful when conventional injection treatment fails, or is contraindicated.

Isotopic composition charac-teristics and identification of immature and low-mature oils

Isotopic composition characteristics and the significance of immature and low-mature oils are first systematically discussed. The carbon isotopes of the whole oil can be divided into two groups, one has δ13C main peak values ranging from -30‰ to -29 and the other from -27‰ to -25‰, they are related to lacustrine and salt-lake facies or swamp facies, respectively. The carbon isotopic fractionation among different group components is relatively small, usually less than 2‰ and the biggest difference in fractionation often occurs between saturated and aromatic fractions. Their δD values vary between -180‰ and -130‰. The main peak of their δD values concentrates between -170‰ and -150‰, suggesting a domination of lacustrine facies. However, the secondary peak ranges from -160‰ to -150‰, showing a frequent salinization of paleo-water bodies. The average δ13C values of the methane vary between -50‰ and -52‰, about 10‰ lighter than those of mature oils. There is a relatively good