Hollow Ni Mo-based nitride heterojunction with super-hydrophilic/aerophobic surface for efficient urea-assisted hydrogen production

Hydrogen evolution reaction(HER)and urea oxidation reaction(UOR)are key reactions of the watercycling associated catalytic process/device.The design of catalysts with a super-hydrophilic/aerophobic structure and optimized electron distribution holds great promise.Here,we have designed a threedimensional(3D)hollow Ni/NiMoN hierarchical structure with arrayed-sheet surface based on a onepot hydrothermal route for efficient urea-assisted HER based on a simple hydrothermal process.The Ni/NiMoN catalyst exhibits super-hydrophilic/aerophobic properties with a small droplet contact angle of 6.07°and an underwater bubble contact angle of 155.7°,thus facilitating an escape of bubbles from the electrodes.Density functional theory calculations and X-ray photoelectron spectroscopy results indicate the optimized electronic structure at the interface of Ni and NiMoN,which can promote the adsorption/desorption of reactants and intermediates.The virtues combining with a large specific surface area endow Ni/NiMoN with efficient catalytic activity of low potentials of 25 mV for HER and 1.33 V for UOR at10 mA cm^(-2).The coupled HER and UOR system demonstrates a low cell voltage of 1.42 V at 10 mA cm^(-2),which is approximately 209 mV lower than water electrolysis.

Effect of Complex Parameters of Porous Media on Desalination Performance in Air-Gap Diffusion Distillation Based on Multiple Regression Analysis

Air-Gap Diffusion Distillation(AGDD) is a new technology aiming at solving the problem of the safety of drinking water for residents in remote areas that uses a super hydrophilic porous medium as the hot channel and evaporation surface. In the experiment, it was found that the parameters of porous media have a significant influence on the desalination(evaporation) efficiency of AGDD. Although porous media are widely used as evaporation components, the factors affecting their evaporation efficiency are not fully understood. The evaporation process in super hydrophilic porous media is rarely discussed. A large number of experiments have been carried out based on AGDD. The introduction of statistical methods solves the problem that experiments cannot distinguish the contribution of complex parameters of porous media to evaporation efficiency. Stepwise regression analysis is used to reduce the dimensionality of the independent variables and construct regression equations(coefficient of determination R~2 reached 81.3%-96.8%). Evaporation flux correlations and dimensionless mass transfer correlations are established based on porous media parameters. We found that the surface evaporation of super hydrophilic porous media can be divided into three stages: diffusion evaporation, capillary evaporation, and thermal evaporation. The evaporation efficiency of these three stages is controlled by the vapor diffusion process resistance, capillary force, and energy supply. At low saturation, evaporation efficiency is limited by the resistance of the vapor diffusion process. The evaporation efficiency of the porous media is affected predominantly by the pore size, the specific surface area, porosity and the characteristic length. At high saturation, the evaporation efficiency becomes influenced primarily by the permeability. A small thickness and a high hydrophilicity also improve the evaporation efficiency.