Effect of long reaction distance on gas composition from organic-rich shale pyrolysis under high-temperature steam environment

When high-temperature steam is used as a medium to pyrolyze organic-rich shale,water steam not only acts as heat transfer but also participates in the chemical reaction of organic matter pyrolysis,thus affecting the generation law and release characteristics of gas products.In this study,based on a long-distance reaction system of organic-rich shale pyrolysis via steam injection,the effects of steam temperature and reaction distance on gas product composition are analyzed in depth and compared with other pyrolysis processes.The advantages of organic-rich shale pyrolysis via steam injection are then evaluated.The volume concentration of hydrogen in the gas product obtained via the steam injection pyrolysis of organic-rich shale is the highest,which is more than 60%.The hydrogen content increases as the reaction distance is extended;however,the rate of increase changes gradually.Increasing the reaction distance from 800 to 4000 mm increases the hydrogen content from 34.91%to 69.68%and from 63.13%to 78.61%when the steam temperature is 500℃ and 555℃,respectively.However,the higher the heat injection temperature,the smaller the reaction distance required to form a high concentration hydrogen pyrolysis environment(hydrogen concentration>60%).When the steam pyrolysis temperature is increased from 500℃ to 555℃,the reaction distance required to form a high concentration of hydrogen is reduced from 3800 to 800 mm.Compared with the direct retorting process,the volume concentration of hydrogen obtained from high-temperature steam pyrolysis of organic-rich shale is 8.82 and 10.72 times that of the commonly used Fushun and Kivite furnaces,respectively.The pyrolysis of organic-rich shale via steam injection is a pyrolysis process in a hydrogen-rich environment.

Preference-based multiobjective artificial bee colony algorithm for optimization of superheated steam temperature control

In order to incorporate the decision maker＇s preference into multiobjective optimization a preference-based multiobjective artificial bee colony algorithm PMABCA is proposed.In the proposed algorithm a novel reference point based preference expression method is addressed.The fitness assignment function is defined based on the nondominated rank and the newly defined preference distance.An archive set is introduced for saving the nondominated solutions and an improved crowding-distance operator is addressed to remove the extra solutions in the archive.The experimental results of two benchmark test functions show that a preferred set of solutions and some other non-preference solutions are achieved simultaneously.The simulation results of the proportional-integral-derivative PID parameter optimization for superheated steam temperature verify that the PMABCA is efficient in aiding to making a reasonable decision.

Controllable synthesis of CuAlO_(2) via solid-phase method and its catalytic performance for methanol steam reforming to hydrogen

This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investigation in methanol steam reforming(MSR).Various catalysts were prepared under different conditions,such as calcination temperature,calcination atmosphere,and heating rate.Characterization techniques including BET,XRD,XPS,SEM and H2-TPR were employed to analyze the samples.The results revealed significant effects of calcination temperature on the phase compositions,specific surface area,reduction performance,and surface properties of the CA-T catalysts.Based on the findings,a synthesis route of CuAlO_(2) via the solid-phase method was proposed,highlighting the importance of high calcination temperature,nitrogen atmosphere,and low heating rate for CuAlO_(2) formation.Catalytic evaluation data demonstrated that CuAlO_(2) could catalyze MSR without pre-reduction,with the catalytic performance of CA-T catalysts being notably influenced by calcination temperature.Among the prepared catalysts,the CA-1100 catalyst exhibited the highest catalytic activity and stability.The findings of this study might be useful for the further study of the catalytic material for sustained release catalysis,including the synthesis of catalytic materials and the regulation of sustained release catalytic performance.

ExperimentonPerformanceofLow-TemperatureExhaustSteamReclamation

针对不同的喉嘴距、面积比，实验研究了不同的进水压力、进水温度和出水压力对低温乏汽回收利用装置性能的影响规律．发现在进水压力为0．14～O．50MPa、进水温度为23～60℃、出水压力为0．096-0．110MPa，以及4种喉嘴距、3种面积比的实验条件范围内，随着喉嘴距和面积比的增加，加热温升和流量比先增大后减小，得到最佳归一化喉嘴距L=4．50，以及最佳面积比m=6．25，使得加热温升和流量比最大．同时，加热温升和流量比均随着进水压力和进水温度的增加而减小，当出水压力升高时，装置性能变差，加热温升和流量比均减小．

Neuro-fuzzy generalized predictive control of boiler steam temperature

Power plants are nonlinear and uncertain complex systems. Reliable control of superheated steam temperature is necessary to ensure high efficiency and high load-following capability in the operation of modem power plant. A nonlinear generalized predictive controller based on neuro-fuzzy network （NFGPC） is proposed in this paper. The proposed nonlinear controller is applied to control the superheated steam temperature of a 200MW power plant. From the experiments on the plant and the simulation of the plant, much better performance than the traditional controller is obtained,

Aquathermolysis of conventional heavy oil with superheated steam

This paper presents a new aquathermolysis study of conventional heavy oil in superheated steam. A new high temperature autoclave was designed, where volume and pressure could be adjusted. Aquathermolysis was studied on two different conventional heavy oil samples under different reaction times and temperatures. Experimental results show that aquathermolysis does take place for conventional heavy oil. As reaction time increases, the oil viscosity reduces. However, the reaction will reach equilibrium after a certain period of time and won＇t be sensitive to any further reaction time any more. Analysis shows that, while resin and asphaltenes decrease, saturated hydrocarbons and the H/C ratio increase after reaction. The main mechanism of aquathermolysis includes hydrogenization, desulfuration reaction of resin and asphaltenes, etc.

Thermal Hydraulic Design and Analysis of a Water-Cooled Ceramic Breeder Blanket with Superheated Steam for CFETR

The water-cooled ceramic breeder blanket（WCCB） is one of the blanket candidates for China fusion engineering test reactor（CFETR）.In order to improve power generation efficiency and tritium breeding ratio,WCCB with superheated steam is under development.The thermal-hydraulic design is the key to achieve the purpose of safe heat removal and efficient power generation under normal and partial loading operation conditions.In this paper,the coolant flow scheme was designed and one self-developed analytical program was developed,based on a theoretical heat transfer model and empirical correlations.Employing this program,the design and analysis of related thermal-hydraulic parameters were performed under different fusion power conditions.The results indicated that the superheated steam water-cooled blanket is feasible.

External Heat Transfer in Moist Air and Superheated Steam for Softwood Drying

In kiln drying of softwood timber, external heat and moisture mass transfercoefficients are important in defining boundary temperature and moisture content at the woodsurface. In addition, superheated steam drying of wood is a promising technology but this has notbeen widely accepted commercially, partially due to the lack of understanding of the dryingphenomena occurred during drying. In this work, experimental investigation was performed to quantifythe heat transfer between wood surface and surrounding moist air or superheated steam. In theexperiment, saturated radiata pine sapwood samples were dried using dry-bulb/wet-bulb temperaturesof 60℃/50℃, 90℃/60℃, 120℃/70℃, 140℃/90℃, 160℃/90℃, 140℃/100℃ and 160℃/100℃. The lasttwo schedules were for superheated steam drying as the wet-bulb temperature was set at 100℃. Thecirculation velocity over the board surface was controlled at 4.2m·s^(-1). Two additional runs(90℃/60℃) using air velocities of 2.4 m·s^(-1) and 4.8 m·s^(-1) were performed to check theeffect of the circulation velocity. During drying, sample weight and temperatures at wood surfaceand different depths were continuously measured. Prom these measurements, changes in woodtemperature and moisture content were calculated and external heat-transfer coefficient wasdetermined for both the moist air and the superheated steam drying.

Outlet Temperature Correlation and Prediction of Transfer Line Exchanger in an Industrial Steam Ethylene Cracking Process

Predicting the best shutdown time of a steam ethylene cracking furnace in industrial practice remains a challenge due to the complex coking process. As well known, the shutdown time of a furnace is mainly determined by coking condition of the transfer line exchangers （TLE） when naphtha or other heavy hydrocarbon feedstocks are cracked. In practice, it is difficult to measure the coke thickness in TLE through experimental method in the complex industrial situation. However, the outlet temperature of TLE （TLEOT） can indirectly characterize the coking situation in TLE since the coke accumulation in TLE has great influence on TLEOT. Thus, the TLEOT could be a critical factor in deciding when to shut down the furnace to decoke. To predict the TLEOT, a paramewic model was proposed in this work, based on theoretical analysis, mathematic reduction, and parameters estimation. The feasibility of the proposed model was further checked through industrial data and good agreements between model prediction and industrial data with maximum deviation 2% were observed.

Application of PID Controller Based on BP Neural Network in Export Steam’s Temperature Control System

By combining the Back-Propagation （BP） neural network with conventional proportional Integral Derivative （PID） controller, a new temperature control strategy of the export steam in supercritical electric power plant is put forward. This scheme can effectively overcome the large time delay, inertia of the export steam and the influencee of object in varying operational parameters. Thus excellent control quality is obtaitud. The present paper describes the development and application of neural network based controller to control the temperature of the boiler＇s export steam. Through simulation in various situations, it validates that the control quality of this control system is apparently superior to the conventional PID control system.

Analyzing the effect of steam quality and injection temperature on the performance of steam flooding

The heavy oil reservoirs are currently mainly targeted by thermal enhanced oil recovery technologies,particularly,steam flooding.Steam flooding is carried out by introducing heat into the reservoir to unlock the recovery of heavy oil by reducing oil viscosity.Several investigations were carried out to improve oil recovery by steam flooding.Most recently,high steam flooding is reported as an effective approach to improve recovery in high pressure heavy oil reservoirs.The oil recovery from steam flooding is sub-stantially affected by the steam quality and injection temperature.In this study,an attempt was made to look into the integration of parameters,i.e.steam quality and injection temperature upon steam flooding on oil recovery by using a simulation approach via ECLIPSE.The results obtained indicated that high temperature along with the moderate value of steam quality gives the best result regarding oil recovery for steam flooding in an economical way.

Drying Characteristics of Wood under Vacuum-superheated Steam

This paper presents comparison and analysis of thermal-dynamic characteristics of air-drying and superheated steam drying under vacuum. The result reveals that for both convective heat transfer coefficient and resistance of mass transfer on the surface, superheated steam drying under vacuum is superior to air-drying under the same condition. With Masson pine as specimen, we found that the inversion temperature really exists through comparable experiments of air-drying and superheated steam drying under vacuum. When temperature is above inversion point of temperature, drying speed is faster than that of air-drying; however, if temperature is below the point, the result is opposite. The inversion temperature of experiment ranges from 80 to 85 ℃.

Low CO content hydrogen production from oxidative steam reforming of ethanol over CuO-CeO_2 catalysts at low-temperature

CuO-CeO2 catalysts were prepared by a urea precipitation method for the oxidative steam reforming of ethanol at low-temperature.The catalytic performance was evaluated and the catalysts were characterized by inductively coupled plasma atomic emission spectroscopy,X-ray diffraction,temperature-programmed reduction,field emission scanning electron microscopy and thermo-gravimetric analysis.Over CuOCeO2 catalysts,H2 with low CO content was produced in the whole tested temperature range of 250–450 C.The non-noble metal catalyst 20CuCe showed higher H2production rate than 1%Rh/CeO2 catalyst at 300–400 C and the advantage was more obvious after 20 h testing at400 C.These results further confirmed that CuO-CeO2 catalysts may be suitable candidates for low temperature hydrogen production from ethanol.

Reclamation of CO_(2) sodium silicate used sands by steam leaching

The bond film on the surface of the CO_(2) sodium silicate used sands is not easy to decompose,therefore,it is difficult to reclaim used sands.A new reclamation method of CO_(2) sodium silicate used sands was developed by steam leaching,which can reduce the water consumption of reclamation and improve the removal effect of sodium silicate bond film.Firstly,the leaching effect of the sodium silicate sands after 20/200/400/600/800/1,000°C heat preservation treatment was simulated.Furthermore,the influence of the leaching time on the removal effect of the sodium silicate bond film was studied.Finally,the casting properties of the reclaimed sands after the leaching reclamation treatment were tested.The results show for simulated used sands after 30 min of steam leaching,the removal ratio of the alkali exceeds 84.1%,the removal ratio of silicate is 86.2%,and the removal ratio of carbonate is 93.6%.The removal rate of alkali,silicate and carbonate is relatively low in the leaching time of 30-50 min.Considering the reclamation effect and cost,the leaching time is controlled in 30 min.Water consumption is only 60%of the mass of used sands for 30 min steam leaching,while it is 200%for wet reclamation.Morphological analysis shows that most of the hazardous substances in the used sands are removed in 30 min steam leaching,and the reclaimed sands surface after steam leaching in 50 min is as smooth as new sands.After 30 min of steam leaching,the alkali removal effect of the factory used sands can reach 81.5%,the water consumption by the steam leaching reclamation is 58%of the mass of the used sand,which is similar to the result of simulated used sands.The performance of reclaimed sands obtained after 30 min steam leaching is better than that of new sands when the amount of sodium silicate added is 6%of the mass of the reclaimed sands and the CO_(2) blowing time is 15 s:the 24 h ultimate compressive strength of reclaimed sands is 5.6 MPa(equated with new sands),and the collapsibility compressive strength is 5.2 MPa,which is lower than the collapsibility compressive strength of new sands(7.7 MPa).This indicates that the reclamation of CO_(2) sodium silicate used sands by steam leaching is a feasible method.

Coupling of Wind Energy and Biogas with a High Temperature Steam Electrolyser for Hydrogen and Methane Production

The production of environment friendly green fuels is based on energy from renewable sources. Among the renewable sources, wind power is a very growing power technology. An example which has been discussed very widely is hydrogen which is an ideal fuel for a fuel cell. Hydrogen is the energy of the future. It will be used as energy carrier as well as reactant to produce green fuels, like methane which is easier to handle. Direct coupling of a High Temperature Steam Electrolyser (HTSE) with a wind turbine can be used to generate hydrogen. Indeed performing the electrolysis process at high temperatures offers the advantage of achieving higher efficiencies compared to the conventional water electrolysis. The hydrogen produced can be then reacted with the CO2 content of biogas to form methane as green fuel. Thus, the concept presented in this paper illustrates the potential of the HTSE technology coupled with a wind turbine, this system being combined with biogas in a methanation unit. Developing scenarios and flow sheets and using mass and energy balance, the technical performance of the concept is investigated. A plant capacity of 10 MWel is considered. An annual production of 1104 metric tons per year (Mt/a) hydrogen and thus of 5888 Mt/a methane is reached. The overall plant efficiency is calculated to be 38%. The combination of wind power and biogas offers thus many advantages which can facilitate the penetration of the wind resource and the progression to the hydrogen economy.

Methane Production via High Temperature Steam Electrolyser from Renewable Wind Energy: A German Study

The transformation of the energy supply needs further development of energy storage technologies in order to integrate the fluctuating renewable energy. The conversion of renewable wind power into green methane offers a technical approach with the necessary storage and transport capacities. Thus, the concept of Power-to-Gas which is illustrated here by the coupling of wind energy with a High Temperature Steam Electrolyser (HTSE) and a methanation unit enabling the production of green fuel like hydrogen and methane is presented is this paper. In fact, hydrogen can be used as energy carrier as well for the production of green fuels, like methane which is simpler to store and to transport and which can be thus used as storage medium for the stabilization of the electrical power supply as well as fuel for transport and heat sector. Its production using high temperature electrolysis is able to reduce the carbon dioxide emissions if performed with renewable resources. This is the case if the electricity needed for the HTSE comes from a wind turbine and the CO2 needed for the methanation step comes from biogas. For such a plant, the location and the boundary conditions have a great importance. Thus, this study considers the coupling of a HTSE with a wind turbine and a methanation reactor, and focuses about the site selection, depending of the geographical and economic considerations. The study is limited first to the European area. Schleswig-Holstein is found as a very good location for this plant. It is one of the regions with the largest wind reserves in Germany. This region has also available a lot of biogas and meets all the other necessary requirements.

Monitoring of steam chamber in steam-assisted gravity drainage based on the temperature sensitivity of oil sand

Thermosensitivity experiments and simulation calculations were conducted on typical oil sand core samples from Kinosis,Canada to predict the steam chamber development with time-lapse seismic data during the steam-assisted gravity drain-age(SAGD).Using an ultrasonic base made of polyether ether ketone resin instead of titanium alloy can improve the signal en-ergy and signal-to-noise ratio and get clear first arrival;with the rise of temperature,heavy oil changes from glass state(at-34.4℃),to quasi-solid state,and to liquid state(at 49.0℃)gradually;the quasi-solid heavy oil has significant frequency dis-persion.For the sand sample with high oil saturation,its elastic property depends mainly on the nature of the heavy oil,while for the sand sample with low oil saturation,the elastic property depends on the stiffness of the rock matrix.The elastic property of the oil sand is sensitive to temperature noticeably,when the temperature increases from 10℃ to 175℃,the oil sand samples decrease in compressional and shear wave velocities significantly.Based on the experimental data,the quantita-tive relationship between the compressional wave impedance of the oil sand and temperature was worked out,and the tem-perature variation of the steam chamber in the study area was predicted by time-lapse seismic inversion.

Hydrogen production at intermediate temperatures with proton conducting ceramic cells:Electrocatalytic activity,durability and energy efficiency

Proton conducting ceramic cells(PCCs)are an attractive emerging technology operating in the intermediate temperature range of 500 to 700℃.In this work,we evaluate the production of hydrogen at intermediate temperatures by proton conducting ceramic cell electrolysis(PCCEL).We demonstrate a highperformance steam electrolysis owing to a composite positrode based on BaGd_(0.8)La_(0.2)Co_(2)O_(6-δ)(BGLC1082)and BaZr0.5Ce0.4Y0.1O3-δ(BZCY541).The high reliability of PCCEL is demonstrated for 1680 h at a current density as high as-0.8 A cm^(-2)close to the thermoneutral cell voltage at 600℃.The electrolysis cell showed a specific energy consumption ranging from 54 to 66 kW h kg^(-1)that is comparable to state-of-the-art low temperature electrolysis technologies,while showing hydrogen production rates systematically higher than commercial solid oxide ceramic cells(SOCs).Compared to SOCs,the results verified the higher performances of PCCs at the relevant operating temperatures,due to the lower activation energy for proton transfer comparing with oxygen ion conduction.However,because of the p-type electronic conduction in protonic ceramics,the energy conversion rate of PCCs is relatively lower in steam electrolysis.The faradaic efficiency of the PCC in electrolysis mode can be increased at lower operating temperatures and in endothermic conditions,making PCCEL a technology of choice to valorize high temperature waste heat from industrial processes into hydrogen.To increase the faradaic efficiency by optimizing the materials,the cell design,or the operating strategy is a key challenge to address for future developments of PCCEL in order to achieve even more superior techno-economic merits.

Model Identification Based on Subspace Model Identification of Main Steam Temperature in Ultra-Supercritical Coal-Fired Power Unit

Ultra-supercritical(USC) unit is more and more popular in coal-fired power industry.In this paper,closed-loop identification based on subspace model identification(SMI) is introduced for superheated steam temperature system of USC unit.Closed-loop SMI is applied to building step response model of the unit directly.The parameters selection method is proposed to deal with the parameter sensitivity and improve the reliability of the model.Finally,the model is used in model identification of real USC unit.

溶剂低压过热蒸汽热裂解塑料制油过程特性

低碳清洁处理塑料垃圾对环境保护和循环经济发展具有重要意义。本文提出了一种在低压过热溶剂蒸汽体系中高效热裂解液化塑料的方法,以聚丙烯(PP)和高密度聚乙烯(HDPE)为原料,研究了塑料在溶剂低压过热蒸汽环境中(≤5MPa)热裂解液化过程特性,并提出了两种塑料热液化过程中的降解机制。结果表明:低压有机溶剂蒸汽体系能在相对温和的条件下实现塑料的高效液化,330℃是本研究中实现塑料快速热裂解液化的起始温度。在此温度下,PP在甲醇、乙醇、丙酮中的热裂解液化率均为100%,HDPE在三种溶剂中的热裂解液化率分别为100%、72.9%和71.03%。在本研究条件下,塑料液化中小分子更容易发生缩聚反应,放出大量热并使反应体系温度出现不同幅度的飞升,从而为塑料进一步解聚为小分子提供能量,提高塑料的热裂解液化率。PP热裂解液化油中含氧化合物的质量分数大于40%,而HDPE的热裂解液化油中氧化物含量低,且烃类的质量分数大于80%,作为燃料使用的潜力大。