Lithium secondary batteries(LSBs) with high energy densities need to be further developed for future applications in portable electronic devices, electric vehicles, hybrid electric vehicles and smart grids. Lithium ...Lithium secondary batteries(LSBs) with high energy densities need to be further developed for future applications in portable electronic devices, electric vehicles, hybrid electric vehicles and smart grids. Lithium metal is the most promising electrode for next-generation rechargeable batteries. However, the formation of lithium dendrite on the anode surface leads to serious safety concerns and low coulombic efficiency.Recently, researchers have made great efforts and significant progresses to solve these problems. Here we review the growth mechanism and suppression method of lithium dendrite for LSBs’ anode protection. We also establish the relationship between the growth mechanism and suppression method. The research direction for building better LSBs is given by comparing the advantages and disadvantages of these methods based on the growth mechanism.展开更多
A transmission grating coupled with an X-ray charge coupled device (CCD) is used to quantitatively measure the proportion of high-order harmonics of the soft-X-ray source of beam line 4B7B. The results show that the...A transmission grating coupled with an X-ray charge coupled device (CCD) is used to quantitatively measure the proportion of high-order harmonics of the soft-X-ray source of beam line 4B7B. The results show that the monochromatic X-ray has third-order and second-order harmonics. The proportion of second-order harmonic of 4B7B is less than 9.0% and the third- order harmonic is below 0.7% when no suppressing method is applied. When suppression methods are used, the proportion of second-order harmonic is less than 1.7% and the third-order harmonic is ignorable.展开更多
A component synthesis vibration suppression (CSVS) method for flexible structures is put forward. It can eliminate any unwanted orders of flexible vibration modes while achieves desired rigid motion. This method has ...A component synthesis vibration suppression (CSVS) method for flexible structures is put forward. It can eliminate any unwanted orders of flexible vibration modes while achieves desired rigid motion. This method has robustness to uncertainty of frequency, which makes it practical in engineering. Several time optimal and time-fuel optimal control strategies are designed for a kind of single flexible link. Simulation results validate the feasibility of our method.展开更多
The basic principles of target detection by forward acoustic scattering are presented.A direct blast suppression approach based on adaptive filtering(DBS-AF) is proposed to suppress the direct blast.The DBS-AF techniq...The basic principles of target detection by forward acoustic scattering are presented.A direct blast suppression approach based on adaptive filtering(DBS-AF) is proposed to suppress the direct blast.The DBS-AF technique is extended to the linear frequency modulation(LFM) signal,where the envelope of the signal is regarded as a 'general waveform' and imported into the adaptive filter.Application of the DBS-AF method to the data collected from a lake trial yields an output detection curve,in which the direct blast is mapped to the background while the acoustic field aberration is represented by the peak value fluctuation.The inhibitory effect in single hydrophone is approximately- 5 dB,and is then enhanced by exploiting the mean value removal approach as a preprocessing technique.The direct blast is further suppressed to a level of-10 dB by making full use of multichannel receptions.The main factors affecting the algorithm performance are as follows:the fluctuation degree of the receptions during the weighting vector training period and the power ratio of the forward scattered wave to the direct blast when the target is present.展开更多
Photo-corrosion is one of the major obstacles for CdS application in wet chemical fields, and atomic layer deposition (ALD) has been proposed as an effective way to suppress the corrosion. Here, prior to ALD coating...Photo-corrosion is one of the major obstacles for CdS application in wet chemical fields, and atomic layer deposition (ALD) has been proposed as an effective way to suppress the corrosion. Here, prior to ALD coating, CdS, one facilely corrosive photocatalyst, was synthesized via hydrothermal synthesis to access the fundamental corrosion mechanism and the according corrosive sites. X-ray photoelectron spectros- copy (XPS) and X-ray diffraction (XRD) demonstrated that the failure of catalytic decomposition of methylene blue originated from the formation of soluble CdSO4 by oxidizing S2 of as-prepared CdS. High resolu- tion transmission electron microscopy (HRTEM) further identified the active sites in the V-shaped regions ofCdS nanoparticles, confirmed by the simulated electric field distribution. To rationally coat oxides on CdS, the right candidates and their thicknesses have been considered by our tunneling model with trans- fer matrix method based on quantum mechanism, upon which the thickness of protective layer should be less than 0.5 nm to maintain a high tunneling probability, and thus one cycle of ALD TiO2 or AbO3 was proposed to passivate the CdS powder to balance the carrier transportation and corrosion suppres- sion. Based on HRTEM results, we found that the active V-shaped region was covered by ALD oxides (TiO2 or AbO3). For each case, no soluble CdSO4 has been found before and after photocatalytic reactions based XPS measurements. Importantly, we noticed that with the passivation of one cycle of ALD, the catalyst's lifetime was elongated up to 〉14 times higher than that of the as-prepared CdS.展开更多
基金supported by the State Grid Technology Project(No. DG71-17-010)the Importation and Development of High-Caliber Talents Project of Beijing Municipal Institutions (CIT&TCD 201504019)
文摘Lithium secondary batteries(LSBs) with high energy densities need to be further developed for future applications in portable electronic devices, electric vehicles, hybrid electric vehicles and smart grids. Lithium metal is the most promising electrode for next-generation rechargeable batteries. However, the formation of lithium dendrite on the anode surface leads to serious safety concerns and low coulombic efficiency.Recently, researchers have made great efforts and significant progresses to solve these problems. Here we review the growth mechanism and suppression method of lithium dendrite for LSBs’ anode protection. We also establish the relationship between the growth mechanism and suppression method. The research direction for building better LSBs is given by comparing the advantages and disadvantages of these methods based on the growth mechanism.
文摘A transmission grating coupled with an X-ray charge coupled device (CCD) is used to quantitatively measure the proportion of high-order harmonics of the soft-X-ray source of beam line 4B7B. The results show that the monochromatic X-ray has third-order and second-order harmonics. The proportion of second-order harmonic of 4B7B is less than 9.0% and the third- order harmonic is below 0.7% when no suppressing method is applied. When suppression methods are used, the proportion of second-order harmonic is less than 1.7% and the third-order harmonic is ignorable.
基金This project is supported by National 211 Project.
文摘A component synthesis vibration suppression (CSVS) method for flexible structures is put forward. It can eliminate any unwanted orders of flexible vibration modes while achieves desired rigid motion. This method has robustness to uncertainty of frequency, which makes it practical in engineering. Several time optimal and time-fuel optimal control strategies are designed for a kind of single flexible link. Simulation results validate the feasibility of our method.
基金supported by the National Natural Science Foundation of China(11174235,61571366)
文摘The basic principles of target detection by forward acoustic scattering are presented.A direct blast suppression approach based on adaptive filtering(DBS-AF) is proposed to suppress the direct blast.The DBS-AF technique is extended to the linear frequency modulation(LFM) signal,where the envelope of the signal is regarded as a 'general waveform' and imported into the adaptive filter.Application of the DBS-AF method to the data collected from a lake trial yields an output detection curve,in which the direct blast is mapped to the background while the acoustic field aberration is represented by the peak value fluctuation.The inhibitory effect in single hydrophone is approximately- 5 dB,and is then enhanced by exploiting the mean value removal approach as a preprocessing technique.The direct blast is further suppressed to a level of-10 dB by making full use of multichannel receptions.The main factors affecting the algorithm performance are as follows:the fluctuation degree of the receptions during the weighting vector training period and the power ratio of the forward scattered wave to the direct blast when the target is present.
基金supported by the National Natural Science Foundation of China(Nos.11304161,11104148,21573117,51171082,11404172 and 61322508)the 1000 Youth Talents Plan+2 种基金the Tianjin Natural Science Foundation(Nos.13JCYBJC41100 and 14JCZDJC37700)the National Basic Research Program of China(973 Program,Nos.2014CB931703 and 2013CB328701)the Fundamental Research Funds for the Central Universities
文摘Photo-corrosion is one of the major obstacles for CdS application in wet chemical fields, and atomic layer deposition (ALD) has been proposed as an effective way to suppress the corrosion. Here, prior to ALD coating, CdS, one facilely corrosive photocatalyst, was synthesized via hydrothermal synthesis to access the fundamental corrosion mechanism and the according corrosive sites. X-ray photoelectron spectros- copy (XPS) and X-ray diffraction (XRD) demonstrated that the failure of catalytic decomposition of methylene blue originated from the formation of soluble CdSO4 by oxidizing S2 of as-prepared CdS. High resolu- tion transmission electron microscopy (HRTEM) further identified the active sites in the V-shaped regions ofCdS nanoparticles, confirmed by the simulated electric field distribution. To rationally coat oxides on CdS, the right candidates and their thicknesses have been considered by our tunneling model with trans- fer matrix method based on quantum mechanism, upon which the thickness of protective layer should be less than 0.5 nm to maintain a high tunneling probability, and thus one cycle of ALD TiO2 or AbO3 was proposed to passivate the CdS powder to balance the carrier transportation and corrosion suppres- sion. Based on HRTEM results, we found that the active V-shaped region was covered by ALD oxides (TiO2 or AbO3). For each case, no soluble CdSO4 has been found before and after photocatalytic reactions based XPS measurements. Importantly, we noticed that with the passivation of one cycle of ALD, the catalyst's lifetime was elongated up to 〉14 times higher than that of the as-prepared CdS.