Adiabatic cooling for cold polar molecules on a chip using a controllable high-efficiency electrostatic surface trap

We propose a controllable high-efficiency electrostatic surface trap for cold polar molecules on a chip by using two insulator-embedded charged rings and a grounded conductor plate. We calculate Stark energy structure pattern of ND3 molecules in an external electric field using the method of matrix diagonalization. We analyze how the voltages that are applied to the ring electrodes affect the depth of the efficient well and the controllability of the distance between the trap center and the surface of the chip. To obtain a better understanding, we simulate the dynamical loading and trapping processes of ND3 molecules in a ｜J, KM = ｜1,-1 state by using classical Monte–Carlo method. Our study shows that the loading efficiency of our trap can reach ～ 88%. Finally, we study the adiabatic cooling of cold molecules in our surface trap by linearly lowering the potential-well depth（i.e., lowering the trapping voltage）, and find that the temperature of the trapped ND3 molecules can be adiabatically cooled from 34.5 m K to ～ 5.8 m K when the trapping voltage is reduced from-35 k V to-3 k V.

Surface traps-related nonvolatile resistive switching memory effect in a single SnO2:Sm nanowire

For nanostructure SnO2,it is very difficult for its electric properties to accurately control due to the presence of abundant surface states.The introduction of Sm can improve the traps in surface space charge region of SnO2 nanowires,resulting in a controllable storage charge effect.For the single nanowire-based two-terminal device,two surface state-related back-to-back diodes are formed.At a relatively large voltage,electrons can be injected into the traps in surface space charge region from negative electrode,resulting in a decrease of surface barrier connected with negative electrode,and contrarily electrons can be extracted from the traps in surface space charge region into positive electrode,resulting in an increase of surface barrier connected with positive electrode.The reversible injection and extraction induce a nonvolatile resistive switching memory effect.

Wave Scattering by Twin Surface-Piercing Plates Over A Stepped Bottom:Trapped Wave Energy and Energy Loss

To evaluate the trapped wave energy and energy loss, the problem of wave scattering by twin fixed vertical surface- piercing plates over a stepped bottom is numerically simulated using the open source package OpenFOAM and the associated toolbox waves2Foam. The volume of fluid (VOF) method was employed to capture the free surface in the time domain. The validation of the present numerical model was performed by comparing with both the analytical and experimental results. The effects of the spacing between two plates and the configuration of stepped bottom on the hydrodynamic characteristics, such as reflection and transmission coefficients, viscous dissipation ratio, and relative wave height between the plates (termed as trapped wave energy), were examined. Moreover, the nonlinear effects of the incident wave height on the hydrodynamic characteristics were addressed as well. The results show that the step configuration can be tuned for efficient-performance of wave damping, and the optimum configurations of the step length B, the step height h1 and the spacing b, separately equaling λ/4, 3h/4, and 0.05h (λ and h are the wavelength and the water depth, respectively), are recommended for the trapping of wave energy.

Oblique Wave Trapping by a Surface-Piercing Flexible Porous Barrier in the Presence of Step-Type Bottoms

The present study deals with the oblique wave trapping by a surface-piercing flexible porous barrier near a rigid wall in the presence of step-type bottoms under the assumptions of small amplitude water waves and the structural response theory in finite water depth.The modified mild-slope equation along with suitable jump conditions and the least squares approximation method are used to handle the mathematical boundary value problem.Four types of edge conditions,i.e.,clamped-moored,clamped-free,moored-free,and moored-moored,are considered to keep the barrier at a desired position of interest.The role of the flexible porous barrier is studied by analyzing the reflection coefficient,surface elevation,and wave forces on the barrier and the rigid wall.The effects of step-type bottoms,incidence angle,barrier length,structural rigidity,porosity,and mooring angle are discussed.The study reveals that in the presence of a step bottom,full reflection can be found periodically with an increase in(i)wave number and(ii)distance between the barrier and the rigid wall.Moreover,nearly zero reflection can be found with a suitable combination of wave and structural parameters,which is desirable for creating a calm region near a rigid wall in the presence of a step bottom.

Trap distribution of polymeric materials and its effect on surface flashover in vacuum

The surface trap parameter can significantly affect the development of surface flashover in vacuum,but the effective mode and mechanism are not very clear yet.The trap parameters of three polymeric materials were tested and calculated by means of isothermal surface potential decay.The flashover experiment was developed under different applied voltages.The results show a positive correlation between the withstand voltage and the deep trap,i.e.,the deeper trap energy level is,the higher flashover voltage is.The dynamics process of charge trapping and detrapping was analyzed based on the charge transport model in dielectrics with a single trap level and two discrete trap levels.The time of charge trapping was compared with that of the discharge development.The results show that the charge trapping time is longer than the flashover development time.The way to influence flashover for a trap is not to decrease the secondary electrons in single discharge development,but to change the electric field distribution on the dielectric surface by charge capture.

Effect of reactive surface area of minerals on mineralization trapping of CO_2 in saline aquifers

The reactive surface area, an important parameter controlling mineral reactions, affects the amount of mineralization trapping of CO2 which affects the long-term CO2 storage. The effect of the reactive surface area on the mineralization trapping of CO2 was numerically simulated for CO2 storage in saline aquifers. Three kinds of minerals, including anorthite, calcite and kaolinite, are involved in the mineral reactions. This paper models the relationship between the specific surface area and the grain diameter of anorthite based on experimental data from literature （Brantley and Mellott, 2000）. When the reactive surface areas of anorthite and calcite decrease from 838 to 83.8 m^2/m^3, the percentage of mineralization trapping of CO： after 500 years decreases from 11.8% to 0.65%. The amount of dissolved anorthite and the amounts of precipitated kaolinite and calcite decrease significantly when the reactive surface areas ofanorthite and calcite decrease from 838 to 83.8 m2/m3. Calcite is initially dissolved in the brine and then precipitates during the geochemical reactions between CO2-H20 and the minerals. Different reactive surface areas of anorthite and calcite lead to different times from dissolution to precipitation. The pH of the brine decreases with decreasing reactive surface areas of anorthite and calcite which influences the acidity of the saline aquifer. The gas saturation between the upper and lower parts of the saline aquifer increases with decreasing reactive surface areas of anorthite and calcite. The mass density distribution of brine solution shows that the CO2^＋brine solution region increases with decreasing reactive surface areas ofanorthite and calcite.

Add-on pegylated interferon augments hepatitis B surface antigen clearance vs continuous nucleos(t)ide analog monotherapy in Chinese patients with chronic hepatitis B and hepatitis B surface antigen≤1500 IU/mL:An observational study

BACKGROUND Nucleos(t)ide analog(NA)has shown limited effectiveness against hepatitis B surface antigen(HBsAg)clearance in chronic hepatitis B(CHB)patients.AIM To evaluate the efficacy and safety of add-on peginterferonα-2a(peg-IFNα-2a)to an ongoing NA regimen in CHB patients.METHODS In this observational study,195 CHB patients with HBsAg≤1500 IU/m L,hepatitis B e antigen(HBeAg)-negative(including HBeAg-negative patients or HBeAg-positive patients who achieved HBeAg-negative after antiviral treatment with NA)and hepatitis B virus-deoxyribonucleic acid<1.0×10^2 IU/mL after over 1 year of NA therapy were enrolled between November 2015 and December2018 at the Second Affiliated Hospital of Xi'an Jiaotong University,China.Patients were given the choice between receiving either peg-IFNα-2a add-on therapy to an ongoing NA regimen(add-on group,n=91)or continuous NA monotherapy(monotherapy group,n=104)after being informed of the benefits and risks of the peg-IFNα-2a therapy.Total therapy duration of peg-IFNα-2a was 48 wk.All patients were followed-up to week 72(24 wk after discontinuation of peg-IFNα-2a).The primary endpoint was the proportion of patients with HBsAg clearance at week 72.RESULTS Demographic and baseline characteristics were comparable between the two groups.Intention-to-treatment analysis showed that the HBsAg clearance rate in the add-on group and monotherapy group was 37.4%(34/91)and 1.9%(2/104)at week 72,respectively.The HBsAg seroconversion rate in the add-on group was 29.7%(27/91)at week 72,and no patient in the monotherapy group achieved HBsAg seroconversion at week 72.The HBsAg clearance and seroconversion rates in the add-on group were significantly higher than in the monotherapy group at week 72(P<0.001).Younger patients,lower baseline HBsAg concentration,lower HBsAg concentrations at weeks 12 and 24,greater HBsAg decline from baseline to weeks 12 and 24 and the alanine aminotransferase≥2×upper limit of normal during the first 12 wk of therapy were strong predictors of HBsAg clearance in patients with peg-IFNα-2a add-on treatment.Regarding the safety of the treatment,4.4%(4/91)of patients in the add-on group discontinued peg-IFNα-2a due to adverse events.No severe adverse events were noted.CONCLUSION Peg-IFNα-2a as an add-on therapy augments HBsAg clearance in HBeAg-negative CHB patients with HBsAg≤1500 IU/m L after over 1 year of NA therapy.

Electrostatic surface trap for cold polar molecules on a chip

We propose a simple scheme for trapping cold polar molecules in low-field seeking states on the surface of a chip by using a grounded metal plate and two finite-length charged wires that half embanked in an insulating substrate, calculate the electric field distributions generated by our charged-wire layout in free space and the corresponding Stark potentials for ND3 molecules, and analyze the dependence of the trapping center position on the geometric parameters. Moreover, the loading and trapping processes of cold ND3 molecules are studied by using the Monte Carlo method. Our study shows that the loading efficiency of the trap scheme can reach 11.5%, and the corresponding temperature of the trapped cold molecules is about 26.4 mK.

Surface and Texture Properties of Tb-Doped Ceria-Zirconia Solid Solution Prepared by Sol-Gel Method

The three-way catalysts （TWCs） promoters Ce0.6Zr0.4- x TbxO2-y were prepared by sol-gel method. BET surface areas analysis indicated that an increase of the dopant Tb content from x = 0.05 to x = 0.15 favors an increase of surface area from 66.8 to 80.4 m^2· g^-1 compared with the undoped sample Ce0 .6oZr0.40O2 65.1 m^2·g^- 1 after calcination at 650℃. Transmission electron microscopy （TEM） observation indicated that the doped samples have a higher thermal stability. The XRD and Raman spectra confirmed that the Ce0.6Zr0.4-xTbxO2-y cubic solid solution is formed. XPS analysis revealed that Ce and Tb mainly existed in the form of Ce^4＋ and Tb^3 ＋ , and Zr existed in the form of Zr^4＋ on the surface of the samples. The doped samples were homogenous in composition ; the introduction of Tb into the CeO2-ZrO2 promoters resuited in the formation of a solid solution, and the concentration of surface lattice oxygen was increased.

First-principles Study on Geometric and Electronic Structures of Si（111）-√7× √3-In Surface Reconstruction

In order to determine the structures of Si（111）-√7 √3-In surfaces and to understand their electronic properties, we construct six models of both hexagonal and rectangular types and perform first-principles calculations. Their scanning tunneling microscopic images and work functions are simulated and compared with experimental results. In this way, the hex-H3＇ and rect-T1 models are identified as the experimental configurations for the hexagonal and rectangular types, respectively. The structural evolution mechanism of the In/Si（lll） surface with indium coverage around 1.0 monolayer is discussed. The 4×1 and -√7× √3 phases are suggested to have two different types of evolution mechanisms, consistent with experimental results.

The 30–60-day Intraseasonal Variability of Sea Surface Temperature in the South China Sea during May–September

This study investigates the structure and propagation of intraseasonal sea surface temperature（SST） variability in the South China Sea（SCS） on the 30-60-day timescale during boreal summer（May-September）. TRMM-based SST, GODAS oceanic reanalysis and ERA-Interim atmospheric reanalysis datasets from 1998 to 2013 are used to examine quantitatively the atmospheric thermodynamic and oceanic dynamic mechanisms responsible for its formation. Power spectra show that the 30-60-day SST variability is predominant, accounting for 60% of the variance of the 10-90-day variability over most of the SCS. Composite analyses demonstrate that the 30-60-day SST variability is characterized by the alternate occurrence of basin-wide positive and negative SST anomalies in the SCS, with positive（negative） SST anomalies accompanied by anomalous northeasterlies（southwesterlies）. The transition and expansion of SST anomalies are driven by the monsoonal trough-ridge seesaw pattern that migrates northward from the equator to the northern SCS. Quantitative diagnosis of the composite mixed-layer heat budgets shows that, within a strong 30-60-day cycle, the atmospheric thermal forcing is indeed a dominant factor, with the mixed-layer net heat flux（MNHF） contributing around 60% of the total SST tendency, while vertical entrainment contributes more than 30%. However, the entrainment-induced SST tendency is sometimes as large as the MNHF-induced component, implying that ocean processes are sometimes as important as surface fluxes in generating the30-60-day SST variability in the SCS.

Effects of Zr/Ti molar ratio in SO_4^(2-)/ZrO_(2-)TiO_2 calcined at different temperatures on its surface properties and glucose reactivity in near-critical methanol

Effects of Zr/Ti molar ratio in SO42-/ZrO2-TiO2 solid acid catalyst calcined at different temperatures on its surface properties and catalytic activity were thoroughly investigated in this paper. The physicochemical characteristics of prepared samples were determined by N2 adsorptiondesorption, XRD, NH3-TPD and XPS techniques, respectively. It was found that the crystallization temperature of the samples increased after the combination of ZrO2 and TiO2; and phase transformations from the anatase to the rutile of TiO2 species and the tetragonal to the monoclinic of ZrO2 species were effectively suppressed at higher temperature. The sample with a Zr/Ti molar ratio of 3/1 calcined at 450℃ showed the highest surface area and the most acid sites among all the tested samples. The acid site densities of samples were relatively closed to each other if they were calcined at the same temperature, however, decreased with the calcination temperature. The result indicates that the sulfur content in samples is a crucial factor to control the acid site density. Calcining the sample at 650℃ and higher temperatures resulted in a significant desorption of sulfate ion on the samples. The synthesized samples were evaluated as a potential catalyst for glucose conversion under the near-critical methanol conditions （200℃/4 MPa）. The results suggested that the relatively weaker acid sites of the catalyst were more favorable for the accumulation of methyl glucosides, while the moderate acid sites were responsible for the formation of methyl levulinate. The catalytic activity for methyl levulinate production almost increases linearly with the catalyst acid site density. The catalyst deactivation is due to the loss of sulfate ion and the two catalysts with Zr/Ti molar ratios of 3/1 and 1/3 could effectively alleviate the deactivation caused by sulfate solution in the reaction medium and can be reused after calcination with the reuse rate of over 90% in terms of the methyl levulinate selectivity.

A novel type of transverse surface wave propagating in a layered structure consisting of a piezoelectric layer attached to an elastic half-space

The existence and propagation of transverse surface waves in piezoelectric coupled solids is investigated, in which perfect bonding between a metal/dielectric substrate and a piezoelectric layer of finite-thickness is assumed. Dis- persion equations relating phase velocity to material con- stants for the existence of various modes are obtained in a simple mathematical form for a piezoelectric material of class 6mm. It is discovered and proved by numerical examples in this paper that a novel Bleustein-Gulyaev （B-G） type of transverse surface wave can exist in such piezoelectric cou- pled solid media when the bulk-shear-wave velocity in the substrate is less than that in the piezoelectric layer but greater than the corresponding B-G wave velocity in the same pie- zoelectric material with an electroded surface. Such a wave does not exist in such layered structures in the absence of pie- zoelectricity. The mode shapes for displacement and electric potential in the piezoelectric layer are obtained and discussed theoretically. The study extends the regime of transverse sur- face waves and may lead to potential applications to surface acoustic wave devices.

3D v_P and v_S models of southeastern margin of the Tibetan plateau from joint inversion of body-wave arrival times and surface-wave dispersion data

A new 3D velocity model of the crust and upper mantle in the southeastern （SE） margin of the Tibetan plateau was obtained by joint inversion of body- and sur- face-wave data. For the body-wave data, we used 7190 events recorded by 102 stations in the SE margin of the Tibetan plateau. The surface-wave data consist of Rayleigh wave phase velocity dispersion curves obtained from ambient noise cross-correlation analysis recorded by a dense array in the SE margin of the Tibetan plateau. The joint inversion clearly improves the Vs model because it is constrained by both data types. The results show that at around 10 km depth there are two low-velocity anomalies embedded within three high-velocity bodies along the Longmenshan fault system. These high-velocity bodies correspond well with the Precambrian massifs, and the two located to the northeast of 2013 Ms 7.0 Lushan earthquake are associated with high fault slip areas during the 2008 Wenchuan earthquake. The aftershock gap between 2013 Lushan earthquake and 2008 Wenchuan earthquake is associated with low-velocity anomalies, which also acts as a barrier zone for ruptures of two earthquakes. Generally large earthquakes （M 〉 5） in the region occurring from 2008 to 2015 are located around the high-velocity zones, indicating that they may act as asperities for these large earthquakes. Joint inversion results also clearly show that there exist low-velocity or weak zones in the mid-lower crust, which are not evenly distributed beneath the SE margin of Tibetan plateau.

Experimental Study on Momentum Transfer of Surface Texture in Taylor-Couette Flow

The behavior of Taylor-Couette （TC） flow has been extensively studied. However, no suitable torque prediction models exist for high-capacity fluid machinery. The Eckhardt-Grossmann-Lohse （EGL） theory, derived based on the Navier-Stokes equations, is proposed to model torque behavior. This are the significant energy theory suggests that surfaces transfer interfaces between cylinders and annular flow. This study mainly focuses on the effects of surface texture on momentum transfer behavior through global torque measurement. First, a power-law torque behavior model is built to reveal the relationship between dimensionless torque and the Taylor number based on the EGL theory. Second, TC flow appa- ratus is designed and built based on the CNC machine tool to verify the torque behavior model. Third, four surface texture films are tested to check the effects of surface texture on momentum transfer. A stereo microscope and three-dimensional topography instrument are employed to analyze surface morphology. Global torque behavior is measured by rotating a multi component dynamometer, and the effects of surface texture on the annular flow behavior are observed via images obtained using a high-speed camera. Finally, torque behaviors under four differentsurface conditions are fitted and compared. The experi- mental results indicate that surface textures have a remarkable influence on torque behavior, and that the peak roughness of surface texture enhances the momentum transfer by strengthening the fluctuation in the TC flow.

1,1'-联萘-2,2'-二胺的两种同质异晶的晶体结构及其Hirshfeld Surfaces分析

设计合成了1,1'-联萘-2,2'-二胺的两种同质异晶,利用X-单晶衍射对其单晶结构进行表征,并对其Hirshfeld surfaces进行了分析。结果表明,分子间的弱作用力在化合物的超分子自组装中起着关键作用。

Interaction of Photoactive[Fe(CN)_6]^(4-) with TiO_2 Anatase(101) Surface:A Periodic Density Functional Theory Study

The plane-wave pseudopotential function method, based on density-functional theory, has been used to calculate the adsorption, electronic band structures, orbitals and optical absorption spectrum of [Fe（CN）6]^4- on TiOz anatase（101） surface. Our calculations reveal that the surface-modified anatase system has large adsorption energy and a much narrower band gap. [Fe（CN）6]^4- adsorption on the （101） surface could lead to a large red shift of the anatase optical absorption threshold, which extends into a visible region significantly. The calculated results are in agreement with the experiment and other theoretical studies reasonably. It is very important for the understanding and further development ofphotovoltaic materials that are active under visible light.

Transient surface photoconductivity of GaAs emitter studied by terahertz pump-emission spectroscopy

This paper investigates the ultrafast carrier dynamics and surface photoconductivity of unbiased semi-insulating GaAs in detail by using a terahertz pump-emission technique. Based on theoretical modelling, it finds that transient photoconductivity plays a very important role in the temporal waveform of terahertz radiation pulse. Anomalous enhancement in both terahertz radiation and transient photoconductivity is observed after the excitation of pump pulse and we attribute these phenomena to carrier capture in the EL2 centers. Moreover, the pump power- and temperature- dependent measurements are also performed to verify this trapping model.

白桦脂酸-乙醇(1:1)的晶体结构及Hirshfeld Surface分析

白桦脂酸是一种具有多种药理活性的五环三萜类天然产物,已报道的其单晶体均为白桦脂酸-有机溶剂形式。本研究通过溶剂挥发法制备了白桦脂酸-乙醇(1:1)单晶体,通过X射线衍射法获得了其单晶数据,用Hirshfeld surface分析法对晶体中分子间作用力进行了分析。晶体结构分析结果为揭示其理化性质与成因等提供了基础科学数据,为该晶型的定性、定量分析及制备工艺研究提了标准依据,为白桦脂酸多晶型的筛选及共晶的设计提供了数据参考。

Anomalous Laterally Stressed Kinetically Trapped DNA Surface Conformations

Up to now,the DNA molecule adsorbed on a surface was believed to always preserve its native structure.This belief implies a negligible contribution of lateral surface forces during and after DNA adsorption although their impact has never been elucidated.High-resolution atomic force microscopy was used to observe that stiff DNA molecules kinetically trapped on monomolecular films comprising one-dimensional periodically charged lamellar templates as a single layer or as a sublayer are oversaturated by sharp discontinuous kinks and can also be locally melted and supercoiled.We argue that kink/anti-kink pairs are induced by an overcritical lateral bending stress(>30 pNnm)inevitable for the highly anisotropic 1D-1D electrostatic interaction of DNA and underlying rows of positive surface charges.In addition,the unexpected kink-inducing mechanical instability in the shape of the template-directed DNA confined between the positively charged lamellar sides is observed indicating the strong impact of helicity.The previously reported anomalously low values of the persistence length of the surface-adsorbed DNA are explained by the impact of the surface-induced low-scale bending.The sites of the local melting and supercoiling are convincingly introduced as other lateral stress-induced structural DNA anomalies by establishing a link with DNA high-force mechanics.The results open up the study in the completely unexplored area of the principally anomalous kinetically trapped DNA surface conformations in which the DNA local mechanical response to the surface-induced spatially modulated lateral electrostatic stress is essentially nonlinear.The underlying rich and complex in-plane nonlinear physics acts at the nanoscale beyond the scope of applicability of the worm-like chain approximation.