Effect of Anion Surface Active Agent on the Preparation of SrTiO_3 Nano-Crystals

SrTiO_3 nano-crystal samples with floccule or flake crystal morphology,which were indexed as a perovskite-type crystal structure based on the results of XRD and TEM,were successfully prepared by one-step liquid reaction method.And the growth mechanism of the SrTiO_3 nano-crystals under the liquid condition with/without adding the surface active agent was investigated.It was found that adding the surface active agent contributes to the processing in which the ions gathering bodies transit to a more stable phase through the chemical reaction and form the flake SrTiO_3 nano-crystals.

Analysis of the interaction between bolt-reinforced rock and surface support in tunnels based on convergence-confinement method

To investigate the interaction of the bolt-reinforced rock and the surface support,an analytical model of the convergence-confinement type is proposed,considering the sequential installation of the fully grouted rockbolts and the surface support.The rock mass is assumed to be elastic-brittle-plastic material,obeying the linear Mohr-Coulomb criterion or the non-linear Hoek-Brown criterion.According to the strain states of the tunnel wall at bolt and surface support installation and the relative magnitude between the bolt length and the plastic depth during the whole process,six cases are categorized upon solving the problem.Each case is divided into three stages due to the different effects of the active rockbolts and the passive surface support.The fictitious pressure is introduced to quantify the threedimensional(3D)effect of the tunnel face,and thus,the actual physical location along the tunnel axis of the analytical section can be considered.By using the bolt-rock strain compatibility and the rocksurface support displacement compatibility conditions,the solutions of longitudinal tunnel displacement and the reaction pressure of surface support along the tunnel axis are obtained.The proposed analytical solutions are validated by a series of 3D numerical simulations.Extensive parametric studies are conducted to examine the effect of the typical parameters of rockbolts and surface support on the tunnel displacement and the reaction pressure of the surface support under different rock conditions.The results show that the rockbolts are more effective in controlling the tunnel displacement than the surface support,which should be installed as soon as possible with a suitable length.For tunnels excavated in weak rocks or with restricted displacement control requirements,the surface support should also be installed or closed timely with a certain stiffness.The proposed method provides a convenient alternative approach for the optimization of rockbolts and surface support at the preliminary stage of tunnel design.

Outage Behaviors of Active Intelligent Reflecting Surface Enabled NOMA Communications

Active intelligent reflecting surface(IRS)is a novel and promising technology that is able to overcome the multiplicative fading introduced by passive IRS.In this paper,we consider the application of active IRS to nonorthogonalmultiple access(NOMA)networks,where the incident signals are amplified actively through integrating amplifier to reflecting elements.More specifically,the performance of active/passive IRS-NOMA networks is investigated over large and small-scale fading channels.Aiming to characterize the performance of active IRSNOMA networks,the exact and asymptotic expressions of outage probability for a couple of users,i.e.,near-end user n and far-end user m are derived by exploiting a 1-bit coding scheme.Based on approximated analyses,the diversity orders of user n and user m are obtained for active IRS-NOMA.In addition,the system throughput of active IRS-NOMA is discussed in the delay-sensitive transmission.The simulation results are carried out to verify that:i)The outage behaviors of active IRS-NOMAnetworks are superior to that of passive IRS-NOMAnetworks;ii)As the reflection amplitude factors increase,the active IRS-NOMAnetworks are capable of furnishing the enhanced outage performance;and iii)The active IRS-NOMA has a larger system throughput than passive IRS-NOMA and conventional communications.

A concise review on surface and structural modification of porous zeolite scaffold for enhanced hydrogen storage

Investigating zeolites as hydrogen storage scaffolds is imperative due to their porous nature and favorable physicochemical properties.Nevertheless,the storage capacity of the unmodified zeolites has been rather unsatisfactory(0.224%-1.082%(mass))compared to its modified counterpart.Thus,the contemporary focus on enhancing hydrogen storage capacities has led to significant attention towards the utilization of modified zeolites,with studies exploring surface modifications through physical and chemical treatments,as well as the integration of various active metals.The enhanced hydrogen storage properties of zeolites are attributed to the presence of aluminosilicates from alkaline and alkaline-earth metals,resulting in increased storage capacity through interactions with the charge density of these aluminosilicates.Therefore,there is a great demand to critically review their role such as well-defined topology,pore structure,good thermal stability,and tunable hydrophilicity in enhanced hydrogen storage.This article aimed to critically review the recent research findings based on modified zeolite performance for enhanced hydrogen storage.Some of the factors affecting the hydrogen storage capacities of zeolites that can affect the rate of reaction and the stability of the adsorbent,like pressure,structure,and morphology were studied,and examined.Then,future perspectives,recommendations,and directions for modified zeolites were discussed.

Mechanism study on the influence of surface properties on the synthesis of dimethyl carbonate from CO_(2)and methanol over ceria catalysts

The direct synthesis of dimethyl carbonate(DMC)from CO_(2)and methanol has attracted much attention as an environmentally benign and alternative route for conventional routes.Herein,a series of cerium oxide catalysts with various textural features and surface properties were prepared by the one-pot synthesis method for the direct DMC synthesis from CO_(2)and methanol,and the structure-performance relationship was investigated in detail.Characterization results revealed that both of surface acid-base properties and the oxygen vacancies contents decreased with the rising crystallinity at increasingly higher calcination temperature accompanied by an unexpectedly volcano-shaped trend of DMC yield observed on the catalysts.In situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS)studies indicated that the adsorption rate of methanol is slower than that of CO_(2)and the methanol activation state largely influences the formation of key intermediate.Although the enhanced surface acidity-basicity and oxygen vacancies brought by low-temperature calcination could facilitate the activation of CO_(2),the presence of excess strongly basic sites on low-crystallinity sample was detrimental to DMC synthesis due to the preferred formation of unreactive mono/polydentate carbonates as well as the further impediment of methanol activation.Moreover,with the use of 2-cyanopyridine as a dehydration reagent,the DMC synthesis was found to be both influenced by the promotion from the rapid in situ removal of water and the inhibition from the competitive adsorption of hydration products on the same active sites.

Effects of Atmospheric Pressure on Developmental Characteristics and the Stability of Air Entraining Agent for Concrete

In order to ascertain the effects of atmospheric pressure on developmental characteristics and the stability of AEA(air-entraining agent)solution bubbles,AEA solution experiments and AEA solution bubble experiments were,respectively,conducted in Peking(50 m,101.2 kPa)and Lhasa(3,650 m,63.1 kPa).Surface tensions and inflection-point concentrations were tested based on AEA solutions,whilst developmental characteristics,thicknesses and elastic coefficients of liquid films were tested based on air bubbles of AEA solutions.The study involved three types of AEAs,which were TM-O,226A,and 226S.The experimental results show that initial sizes of TM-O,226A,and 226S are,respectively,increased by 43.5%,17.5%,and 3.8%.With the decrease of ambient pressure,the drainage rate and the drainage index of AEA solution bubbles increase.Interference experiments show that the liquid film thicknesses of all tested AEA solution bubbles are in micron scales.When the atmospheric pressure decreases from 101.2 to 63.1 kPa,the liquid film thicknesses of three types of AEA solutions decrease in various degrees;and film elasticities at critical thicknesses increase.Liquid film of 226S solution bubbles is the most stable,presenting as a minimum thickness variation.It should be noted that elastic coefficient of liquid film only represents the level at critical thickness,thus it can not be applied as the only evaluating indicator of bubble stability.For a type of AEA,factors affecting the stability of its bubbles under low atmospheric pressure include initial bubbles size,liquid film thickness,liquid film elasticity,ambient temperature,etc.

Sum-Rate Maximization in Active RIS-Assisted Multi-Antenna WPCN

In this paper,we propose an active reconfigurable intelligent surface(RIS)enabled hybrid relaying scheme for a multi-antenna wireless powered communication network(WPCN),where the active RIS is employed to assist both wireless energy transfer(WET)from the power station(PS)to energyconstrained users and wireless information transmission(WIT)from users to the receiving station(RS).For further performance enhancement,we propose to employ both transmit beamforming at the PS and receive beamforming at the RS.We formulate a sumrate maximization problem by jointly optimizing the RIS phase shifts and amplitude reflection coefficients for both the WET and the WIT,transmit and receive beamforming vectors,and network resource allocation.To solve this non-convex problem,we propose an efficient alternating optimization algorithm with the linear minimum mean squared error criterion,semidefinite relaxation(SDR)and successive convex approximation techniques.Specifically,the tightness of applying the SDR is proved.Simulation results demonstrate that our proposed scheme with 10 reflecting elements(REs)and 4 antennas can achieve 17.78%and 415.48%performance gains compared to the single-antenna scheme with 10 REs and passive RIS scheme with 100 REs,respectively.

Joint Active and Passive Beamforming Design for Hybrid RIS-Aided Integrated Sensing and Communication

Integrated sensing and communication(ISAC) is considered an effective technique to solve spectrum congestion in the future. In this paper, we consider a hybrid reconfigurable intelligent surface(RIS)-assisted downlink ISAC system that simultaneously serves multiple single-antenna communication users and senses multiple targets. Hybrid RIS differs from fully passive RIS in that it is composed of both active and passive elements, with the active elements having the effect of amplifying the signal in addition to phase-shifting. We maximize the achievable sum rate of communication users by collaboratively improving the beamforming matrix at the dual function base station(DFBS) and the phase-shifting matrix of the hybrid RIS, subject to the transmit power constraint at the DFBS, the signal-to-interference-plus-noise-ratio(SINR) constraint of the radar echo signal and the RIS constraint are satisfied at the same time. The builtin RIS-assisted ISAC design problem model is significantly non-convex due to the fractional objective function of this optimization problem and the coupling of the optimization variables in the objective function and constraints. As a result, we provide an effective alternating optimization approach based on fractional programming(FP) with block coordinate descent(BCD)to solve the optimization variables. Results from simulations show that the hybrid RIS-assisted ISAC system outperforms the other benchmark solutions.

Effects of Water-retaining Agents on Growth, Development, Yield and Quality of Soybean under Drought Stress

[Objectives]The paper was to explore the effects of different doses of water-retaining agent on the growth and development indicators,yield and quality of soybean plants subjected to drought stress.[Methods]The effects of drought stress(MDS)and drought stress with low(MDS-L),medium(MDS-M)and high doses(MDS-H)of the water-retaining agent on the growth and development indicators,root activity,MDA content,antioxidant enzyme activity,yield and quality of soybean were studied by field plot test,with the normal water supply serving as the control(CK).[Results]In response to drought stress,the plant height,stem diameter,and yield of soybean exhibited a notable decline.Additionally,the contents of protein,fat,linoleic acid,and linolenic acid in seeds demonstrated a significant reduction.Conversely,the root activity and antioxidant enzyme activity exhibited a noticeable decline,while the MDA content exhibited an increase.The application of varying doses of the water-retaining agent was found to significantly enhance soybean growth,stimulate root activity,and elevate antioxidant enzyme activity,while concurrently reducing MDA content.The observed effects were found to be dose-dependent,with the greatest effects observed at the highest dose.In comparison to MDS,the yields of soybean in the MDS-L,MDS-M,and MDS-H treatments exhibited a 18.38%,25.58%,and 46.26%increase,respectively.Additionally,the content of protein,fat,linoleic acid,and linolenic acid in seeds demonstrated a notable enhancement.[Conclusions]The application of the water-retaining agent has been demonstrated to significantly promote the growth of soybean plants under conditions of drought stress,resulting in an improvement in both the yield and the quality of the soybean crop.The recommended dosage of the water-retaining agent is 3.3 kg/667 m 2.

基于多Agent的锂电池主动均衡策略控制仿真研究

【目的】针对锂电池的荷电状态均衡管理问题,提出一种基于多智能体的电池组荷电状态一致性均衡方案。【方法】首先,将多智能体控制策略引入电池管理的下垂控制中,实现了主动均衡电路拓扑下的自主均衡;其次,建立领航跟随者模型,利用参数已知的虚拟智能体使各个荷电状态不一致的电池的状态向其靠近,实现充放电模式下的荷电状态均衡;最后,对二阶多智能体荷电状态均衡控制策略进行仿真验证。【结果】实验结果表明,相比一阶均衡控制策略,自主均衡时间减少了43.02%,充电模式中均衡时间减少了16.13%,放电模式中均衡时间降低了32.90%。【结论】多智能体系统在电池的均衡管理中能够实现荷电状态的均衡,有效地降低了锂电池荷电状态到达一致性的收敛时间。

Impact of climate change and human activities on the spatiotemporal dynamics of surface water area in Gansu Province, China

Understanding the dynamics of surface water area and their drivers is crucial for human survival and ecosystem stability in inland arid and semi-arid areas.This study took Gansu Province,China,a typical area with complex terrain and variable climate,as the research subject.Based on Google Earth Engine,we used Landsat data and the Open-surface Water Detection Method with Enhanced Impurity Control method to monitor the spatiotemporal dynamics of surface water area in Gansu Province from 1985 to 2022,and quantitatively analyzed the main causes of regional differences in surface water area.The findings revealed that surface water area in Gansu Province expanded by 406.88 km2 from 1985 to 2022.Seasonal surface water area exhibited significant fluctuations,while permanent surface water area showed a steady increase.Notably,terrestrial water storage exhibited a trend of first decreasing and then increasing,correlated with the dynamics of surface water area.Climate change and human activities jointly affected surface hydrological processes,with the impact of climate change being slightly higher than that of human activities.Spatially,climate change affected the'source'of surface water to a greater extent,while human activities tended to affect the'destination'of surface water.Challenges of surface water resources faced by inland arid and semi-arid areas like Gansu Province are multifaceted.Therefore,we summarized the surface hydrology patterns typical in inland arid and semi-arid areas and tailored surface water'supply-demand'balance strategies.The study not only sheds light on the dynamics of surface water area in Gansu Province,but also offers valuable insights for ecological protection and surface water resource management in inland arid and semi-arid areas facing water scarcity.

Characterization on Surface and Interfacial Properties of Nitramine Crystal Fillers and Polymeric Bonding Agents

The surface and interfacial properties of polymeric bonding agents and nitramine crystal fillers were studied. The surface free energy and adhesion work of polymeric bonding agents and nitramine fillers were calculated by using Kaeble′s equations. It was observed that the hydroxyl values of neutral polymeric bonding agents (NPBA) correlate well with the polar components of surface free energies. On the basis of the measurements of swelling ratio and initial modulus, the interfacial bonding through highly crosslinked polymeric shell formation around the nitramine particles and generating interfacial reinforcement were rationalized. The application of Tapping Mode AFM (atomic force micro scope) to observing the surface morphology of NPBA reveals that methyl acrylate monomer appears to play a role for aiding the formation of network like structure when nanometer scale images of NPBA are created.

Surface Modification of Fire-retardant Asphalt with Silane Coupling Agent

The theory and approach of the surface modified of asphalt fire-retardant with silane coupling agent were introduced. The optimum silane dosage was determined, and the structure and properties of the asphalt fire-retardant before and after the surface modification were characterized by infrared spectrum and thermo gravimetric analysis. The dispersion effect of asphalt flre-retardant was studied. The influence of the surface modification on the hydrophilicity and lipophilicity of the asphalt fire-retardant was analyzed. The experimental results showed that there were physical and chemical interactions between the silane coupling agent and the asphalt fire-retardant, which reduced the surface polarity of the asphalt fire retardant. The optimum silane coupling agent dosage was 0.95% of the asphalt fire retardant. The surface modification improved the thermal stability, dispersibility and lipophilicity of the asphalt fire retardant, which enhanced the compatibility between asphalt fire retardant and asphalt.

Implication of Surface Fractal Analysis to Evaluate the Relative Sensitivity of Topography to Active Tectonics,Zagros Mountains, Iran

Fractal geometry is increasingly becoming a useful tool for modeling and quantifying the complex patterns of natural phenomena. The Earth's topography is one of these phenomena that have fractal characteristics. This paper investigates the relative sensitivity of topography to active tectonics using ASTER Global Digital Elevation Model. The covering divider method was used for direct extraction of surface fractal dimension(D surf) to estimate the roughness-surface of topography with aid of geographic information system(GIS)techniques. This evaluation let us highlight the role of the geomorphic and tectonic processes on the spatial variability of fractal properties of natural landforms.Geomorphic zones can be delineated using fractal dimension mapping in which variability of surface fractal dimension reflects the roughness of the landform surface and is a measure of topography texture. Obtained results showed this method can be a quick and easy way to assess the distribution of land surface deformation in different tectonic settings. The loose alluvial deposits and irregularities derived by tectonic activity have high fractal dimensions whereas the competent formations and higher wavelength folded surfaces have lower fractal dimensions.According to the obtained results, the Kazerun Fault Zone has a crucial role in the separation of the Zagros Mountain Ranges into the different lithological,geomorphological and structural zones.

Surface Decontamination of Chemical Agent Surrogates Using an Atmospheric Pressure Air Flow Plasma Jet

An atmospheric pressure dielectric barrier discharge （DBD） plasma jet generator using air flow as the feedstock gas was applied to decontaminate the chemical agent surrogates on the surface of aluminum, stainless steel or iron plate painted with alkyd or PVC. The experi- mental results of material decontamination show that the residual chemical agent on the material is lower than the permissible value of the National Military Standard of China. In order to test the corrosion effect of the plasma jet on different material surfaces in the decontamination pro-cess, corrosion tests for the materials of polymethyl methacrylate, neoprene, polyvinyl chloride （PVC）, polyethylene （PE）, phenolic resin, iron plate painted with alkyd, stainless steel, aluminum, etc. were carried out, and relevant parameters were examined, including etiolation index, chroma- tism, loss of gloss, corrosion form, etc. The results show that the plasma jet is slightly corrosive for part of the materials, but their performances are not affected. A portable calculator, computer display, mainboard, circuit board of radiogram, and a hygrometer could work normally after being treated by the plasma jet.

Validation and application of soil moisture active passive sea surface salinity observation over the Changjiang River Estuary

Using sea surface salinity(SSS)observation from the soil moisture active passive(SMAP)mission,we analyzed the spatial distribution and seasonal variation of SSS around Changjiang River(Yangtze River)Estuary for the period of September 2015 to August 2018.First,we found that the SSS from SMAP is more accurate than soil moisture and ocean salinity(SMOS)mission observation when comparing with the in situ observations.Then,the SSS signature of the Changjiang River freshwater was analyzed using SMAP data and the river discharge data from the Datong hydrological station.The results show that the SSS around the Changjiang River Estuary is significantly lower than that of the open ocean,and shows significant seasonal variation.The minimum value of SSS appears in July and maximum SSS in December.The root mean square difference of daily SSS between SMAP observation and in situ observation is around 3 in both summer and winter,which is much lower than the annual range of SSS variation.In summer,the diffusion direction of the Changjiang River freshwater depicted by SSS from SMAP is consistent with the path of freshwater from in situ observation,suggesting that SMAP observation may be used in coastal seas in monitoring the diffusion and advection of freshwater discharge.

Investigation into the surface active groups of coal

The oxidation heat of coal is the direct reason leading to coal spontaneous combustion. When coal is exposed in oxygen atmosphere, the physical adsorption and chemisorption happened, and then which resulting chemical reaction followed heat between coal and oxygen. Owing to the complexity and uncertain of molecular structure of coal,it was only reduced that bridge bonds, side chains and O 2 containing functional groups in coal may be prone to oxidation in last year, but not to deeply investigate into the structures and the type of the active radicals. In this paper, according to the last achievements in coal structure research, the hypomethylether bond, hypoalkyl bond of α carbon atom with hydroxyl and α carbon atom with hypomethy side chain and hypomethyl bonds linking up two aromatic hydrocarbon in bridge bonds, and methoxy,aldehyde and alkyls of α carbon atom with hydroxy in side bonds are inferred to be free radical easily to lead to oxidize coal under the ambient temperature and pressure. The order from strong to weak of oxide activation of the seven surface active groups is aldehyde side chains, hypomethylether bonds, hypoalkyl bonds of α carbon atom with hydroxyl, hypoalkyl bonds of α carbon atom with hypomethyl, hypomethyl bonds linking up two aromatic hydrocarbon,methoxy, alkyls side chains of α carbon atom with hydroxyl. Because of the two unsaturated molecular tracks of O 2, unpaired electron clouds of the part of surface active groups of coal enter molecular tracks of O 2 to lead to chemisorb on the conjugate effect and induced effect of surface active groups, and then chemical reaction followed heat happens in them. On the basis of change of bond energy, weighted average method is adopted to count the reaction heat value of each mol CO,CO 2 and H 2O. The property of coal spontaneous combustion is different for the different number and oxidability of the active structure in the coal resulting in the different oxidation heat.

Novel Zwitterionic Surfactants: Synthesis and Surface Active Properties of N-(3-Alkoxy-2-Hydroxypropyl)-N, N-Dimethyl glycine Betaines

Five new zwitterionic surfactants with long chain alkyl betaine structure incorporated with hydroxylpropyl group have been synthesized. Their structures were identified by elemental analysis, IR (HNMR)-H-1, and (CNMR)-C-13. Surface tension experiments showed that these surfactants have higher surface activity than those without hydroxypropyl group. The values of CMC and gamma(CMC) of these surfactants have been determined.

Imposing Active Sources during High-Frequency Passive Surface-Wave Measurement

Passive surface-wave utilization has been intensively studied as a means of compensating for the short-age of low-frequency information in active surface-wave measurement, In general, passive surface-wave methods cannot provide phase velocities up to several tens of hertz; thus, active surface-wave methods are often required in order to increase the frequency range, To reduce the amount of field work, we pro-pose a strategy for a high-frequency passive surface-wave survey that imposes active sources during con-tinuous passive surface-wave observation; we call our strategy ＂mixed-source surface-wave （MSW） measurement,＂ Short-duration （within 10 min） passive surface waves and mixed-source surface waves were recorded at three sites with different noise levels： namely, inside a school, along a road, and along a railway, Spectral analysis indicates that the high-frequency energy is improved by imposing active sources during continuous passive surface-wave observation, The spatial autocorrelation （SPAC） method and the multichannel analysis of passive surface waves （MAPS） method based on cross-correlations were performed on the recorded time sequences, The results demonstrate the flexibility and applicability of the proposed method for high-frequency phase velocity analysis, We suggest that it will be constructive to perform MSW measurement in a seismic investigation, rather than exclusively performing either active surface-wave measurement or passive surface-wave measurement,

High surface area biocarbon monoliths for methane storage

New energy sources that reduce the volume of harmful gases such as SO_(x)and NO_(x)released into the atmosphere are in constant development.Natural gas,primarily made up of methane,is being widely used as one reliable energy source for heating and electricity generation due to its high combustion value.Currently,natural gas accounts for a large portion of electricity generation and chemical feedstock in manufacturing plastics and other commercially important organic chemicals.In the near future,natural gas will be widely used as a fuel for vehicles.Therefore,a practical storage device for its storage and transportation is very beneficial to the deployment of natural gas as an energy source for new technologies.In this tutorial review,biomaterials-based carbon monoliths(CMs),one kind of carbonaceous material,was reviewed as an adsorbent for natural gas(methane)adsorption and storage.