Variation of Surface Adhesion Force During the Formation of OTS Self-assembled Monolayer Investigated by AFM

Variation of the surface adhesion force during the formation of octadecyl trichlorosilane (OTS) self-assembled monolayer on a glass substrate surface was investigated by atomic force microscope (AFM). The research shows that the hydrophobicity and the adhesion force of the sample surface increases gradually while the substrate surface is covered by OTS molecules as the reaction proceeds. After 15min reaction, a close-packed and smooth OTS self-assembled monolayer could form on the glass substrate surface with an advancing contact angle of 105° and an interfacial energy of 55.79mJ·m-2.

ADHESION STRENGTH OF COATING SUBSTRATE AND SURFACE MORPHOLOGY OF PRETREATMENT

Premature failure of coated tool often results from a poor adhesion of coating-substrate and shortens the lifetime of the tool. The results of increasing the adhesion strength of thin film coatings on cutting tool inserts by pretreating the inserts with sandblasting technique to obtain a desirable surface morphology of the inserts are presented. A geometric model representing the ideal surface morphology is established to enhance the nucleation density and adhesion strength of coating-substrate. Thin film coating experiment is conducted on the substrates of four different sample groups. Indentation and wear tests are performed on coated inserts to evaluate the effect of sandblasting on the adhesion strength of the coatings. A theoretical analysis is provided on the formation and growth of atom clusters in terms of the contact angle and the thermodynamic barrier of a substrate to predict thin film nucleation.

Platelet adhesion to the surface of a sudden tubular expansion tube under swirling flow condition

The size mismatch in an end-to-end vascular anastomosis between the host vessel and the graft may cause flow disturbance and predispose to thrombosis [1].Although a number of techniques have been employed to reduce the risk of anastomotic thrombosis due to the size mismatch。

Femtosecond laser-mediated anchoring of polymer layers on the surface of a biodegradable metal

Mg has received much attention as a next-generation implantable material owing to its biocompatibility,bone-like mechanical properties,and biodegradability in physiological environments.The application of various polymer coatings has been conducted in the past to reduce the rapid formation of hydrogen gas and the local change in pH during the initial phase of the chemical reaction with the body fluids.Here,we propose femtosecond(fs)laser-mediated Mg surface patterning for significant enhancement of the binding strength of the coating material,which eventually reduces the corrosion rate.Analyses of the structural,physical,crystallographic,and chemical properties of the Mg surface have been conducted in order to understand the mechanism by which the surface adhesion increases between Mg and the polymer coating layer.Depending on the fs laser conditions,the surface structure becomes rough owing to the presence of several microscaled pits and grooves of nanoporous MgO,resulting in a tightly bonded poly(lactic-co-glycolic acid)(PLGA)layer.The corrosion rate of the PLGA-coated,fs laser-treated Mg is considerably slow compared with the non-treated Mg;the treated Mg is also more biocompatible compared with the non-treated Mg.The fs laser-based surface modification technique offers a simple and quick method for introducing a rough coating on Mg;further,it does not require any chemical treatment,thereby overcoming a potential obstacle for its clinical use.

Discrete element method for adhesion properties evaluation of deep-sea sediment from macro and micro perspectives

The adhesion between the mining machine and the deep-sea sediments will significantly affect the driving performance of the mining machine in the deep-sea environment.When the mining machine and the deep-sea sediment interaction simulation was carried out,the accuracy of the particle interaction parameters will directly affect the simulation results.This study proposed a method to systematically calibrate the interaction parameters between deep-sea sediment and grouser through the combination of experiment and simulation.The uniaxial compression test and macro adhesion test and corresponding discrete element numerical simulation were carried out,modifying the contact parameters until the simulation results are close to the experimental results.Then the micro-parameters of the JKR adhesion contact model were back calibrated with the test results,and the contact parameters between soil particle-soil particle and soil particle-metal are calibrated.Besides,the adhesion test shows that the adhesion forces were ranked in the order of 5052<STi80<TA2<TC4 under the same surface roughness,which indicates the aluminum alloy 5052 has the best anti-adhesion performance.The relationship between surface adhesion force and microscopic contact parameters was studied by discrete element numerical simulation,and the result shows that the coefficient of static friction and the coefficient of rolling friction has little effect on adhesion force.While it is mainly affected by the coefficient of restitution and surface energy,the surface adhesion force tends to decrease with the increase of the coefficient of restitution and increase with the growth of surface energy.The obtained parameters of soil particle to soil particle and soil particle to metal affecting the adhesion can contribute to the design optimization for the grouser of mining machines to decrease surface adhesion and enhance its movability and mining efficiency.

Nanoscale viscoelastic properties and adhesion of polydimethylsiloxane for tissue engineering

It has shown that altering crosslink density of biopolymers will regulate the morphology of Mesenchymal Stem Cells （MSCs） and the subsequent MSCs differentia- tion. These observations have been found in a wide range of biopolymers. However, a recent work published in Nature Materials has revealed that MSCs morphology and differen- tiation was unaffected by crosslink density of polydimethyl- siloxane （PDMS）, which remains elusive. To understand such unusual behaviour, we use nanoindentation tests and modelling to characterize viscoelastic properties and sur- face adhesion of PDMS with different base：crosslink ratio varied from 50：1 （50D） to 10：1 （10D）. It has shown that lower crosslink density leads to lower elastic moduli. De- spite lower nanoindentation elastic moduli, PDMS with lowest crosslink density has higher local surface adhesion which would affect cell-biomaterials interactions. This work suggests that surface adhesion is likely another important physical cue to regulate cell-biomaterials interactions.

Surface adhesive properties of continuous PBO fiber after air-plasma-grafting-epoxy treatment

It was found that air dielectric barrier discharge(DBD) plasma contributed to the grafting of epoxy resin onto continuous PBO fiber surface. This air-plasma-grafting-epoxy method yielded a noticeable enhancement in the interfacial adhesion between PBO fiber and thermoplastic matrix resin, with the interlaminar shear strength of the resulting composites increased by 66.7%. DSC and FTIR analyses were then used to study the curing behavior of epoxy coating on PBO fiber surface, deduce the possible grafting reactions and investigate the grafting mechanism. More importantly, TGA measurement showed that the grafting of epoxy onto PBO fiber had almost no effect on the composite heat resistance, and there was more thermoplastic matrix resin adhering to the fiber surface; the latter could also be clearly found in the SEM photos. Thereby, the air-plasma-grafting-epoxy treatment was proved to be an effective method for the improvement of continuous PBO fiber surface adhesive properties.

Investigation of Adhesive Perception Based on Friction and Brain Activation

The enhancement of adhesive perception is crucial to maintaining a stable and comfortable grip of the skin-touch products.To study the tactile perception of adhesive surfaces,subjective evaluation,skin friction and vibrations,and neurophysiological response of the brain activity were investigated systematically.Silicone materials,which are commonly used for bionic materials and skin-touch products,were chosen for the tactile stimulus.The results showed that with the increasing of surface adhesion,the dominant friction transferred from a combination of adhesive friction and deformation friction to adhesive friction.The friction coefficient and vibration amplitude had strong correlations with the perceived adhesion of surfaces.The parietal lobe and occipital lobe were involved in adhesive perceptions,and the area and intensity of brain activation increased with the increasing surface adhesion.Surfaces with larger adhesion tended to excite a high P300 amplitude and short latency,indicating that the judgment was faster and that more attentional resources were involved in adhesive perception.Furthermore,the electroencephalograph signals of the adhesive perception were simulated by the neural mass model.It demonstrated that the excitability and intensity of brain activity,and the connectivity strength between two neural masses increased with the increasing surface adhesion.This study is meaningful to understand the role of surface adhesion in tactile friction and the cognitive mechanism in adhesive perception to improve the tactile experience of adhesive materials.

Gecko-Like Dry Adhesive Surfaces and Their Applications: A Review

Gecko has the ability to climb flexibly on various natural surfaces because of its fine layered adhesion system of foot,which has motivated researchers to carry out a lot of researches on it.Significant progresses have been made in the gecko-like dry adhesive surfaces in the past 2 decades,such as the mechanical measurement of adhesive characteristics,the theoretical modeling of adhesive mechanism and the production of synthetic dry adhesive surfaces.Relevant application researches have been carried out as well.This paper focuses on the investigations made in recent years on the gecko-like dry adhesive surfaces,so as to lay the foundation for further research breakthroughs.First,the adhesion system of gecko’s foot and its excellent adhesive characteristics are reviewed,and the adhesive models describing the gecko adhesion are summarily reviewed according to the diff erent contact modes.Then,some gecko-like dry adhesive surfaces with outstanding adhesive characteristics are presented.Next,some application researches based on the gecko-like dry adhesive surfaces are introduced.Finally,the full text is summarized and the problems to be solved on the gecko-like dry adhesive surfaces are prospected.

Fabrication of a biomimetic controllable adhesive surface by ultraprecision multistep and layered scribing and casting molding

Wedge-shaped microstructures have the ability to reproduce the excellent adhesive properties of geckos’feet because of their unique anisotropic structure.In particular,the controllability of the wedge-shaped microstructures on adhesion is beneficial to the undisturbed grasp or the capture of space targets.However,the problem currently remains of how to process it efficiently and with high quality.Here a strategy called ultraprecision multistep and layered scribing is proposed for the manufacture of the biomimetic controllable adhesive surface.The results show that the metal master mold prepared based on the manufacturing strategy has not only good surface topography but also high reliability and durability.Furthermore,the controllable adhesive surface of 1.96 cm2,fabricated by the proposed manufacturing strategy,has a normal adhesion of 1.012 N,and the corresponding shear friction and adhesion coefficient are 3.105 N and 4.82,respectively.Additionally,the controllable adhesive surface has been shown to be approximately superhydrophobic and also to possess the properties of controllable adhesion and dynamic adhesion.Also,after 250 adhesion-detachment cycles,the normal adhesion and shear friction only decrease by 5%and 3%,respectively.The research realizes an environmentally friendly and efficient method by which to manufacture a durable metal mold for fabricating a biomimetic controllable adhesive surface,laying a foundation for its effective application in the adherence of space-floating targets.

半导体薄膜表面粘附的非对称性偏压调控

电调控表面粘附对微机电系统是至关重要的,同时相对于外加电压极性常具有对称性.本文以二硫化钼为研究对象,以石墨烯、氮化硼和n型硅为参照组展示半导体薄膜表面的非对称粘附行为.研究主要通过导电原子力显微镜和理论模拟来揭示金探针与金基底上二硫化钼之间的偏压调控粘附力的行为.结果反映二硫化钼表面偏压对粘附的调控能力远大于参照组材料,这种非对称行为主要来源于半导体薄膜与背电极之间形成的肖特基结中的内建电场.