This study aimed to evaluate the surface roughness and wetting properties of various dental prosthetic materials after different durations of non-thermal atmospheric plasma(NTAP)treatment.One hundred and sixty discs...This study aimed to evaluate the surface roughness and wetting properties of various dental prosthetic materials after different durations of non-thermal atmospheric plasma(NTAP)treatment.One hundred and sixty discs of titanium(Ti)(n:40),cobalt chromium(Co-Cr)(n:40),yttrium stabilized tetragonal zirconia polycrystals(Y-TZP)(n:40)and polymethylmethacrylate(PMMA)(n:40)materials were machined and smoothed with silicon carbide papers.The surface roughness was evaluated in a control group and in groups with different plasma exposure times [1-3-5 s].The average surface roughness(Ra)and contact angle(CA)measurements were recorded via an atomic force microscope(AFM)and tensiometer,respectively.Surface changes were examined with a scanning electron microscope(SEM).Data were analyzed with two-way analysis of variance(ANOVA)and the Tukey HSD test α=0.05).According to the results,the NTAP surface treatment significantly affected the roughness and wettability properties(P 〈 0.05).SEM images reveal that more grooves were present in the NTAP groups.With an increase in the NTAP application time,an apparent increment was observed for Ra,except in the PMMA group,and a remarkable reduction in CA was observed in all groups.It is concluded that the NTAP technology could enhance the roughening and wetting performance of various dental materials.展开更多
Corn stalk is one of heterogeneous materials with anisotropy and variability.As the rind of corn stalk consists of rich lignin and cellulose similar to wood properties,and possessing high mechanical strength,then can ...Corn stalk is one of heterogeneous materials with anisotropy and variability.As the rind of corn stalk consists of rich lignin and cellulose similar to wood properties,and possessing high mechanical strength,then can be used as raw material of stalk artificial board and paper.The corn stalk rind has significant differences in fiber morphology,chemical composition and mechanical properties at different heights.Nano-SiO2 composite material contained in the epidermis of corn stalk rind is not conducive to exert adhesive into a board.To study board-making technology by intact corn stalk rind,the wettability of corn stalk rind at different sampling heights is necessary to be analyzed by keeping or removing the epidermis.To analyze the surface wettability difference,the contact angle with water,element compositions and the chemical compositions of corn stalk rind at different sampling heights were studied before and after removal of epidermis.A Fourier transform infrared(FTIR)analysis was performed.The results showed that the removal of the epidermis could significantly improve the hydrophilicity of corn stalk rind.Before removal of the epidermis,the varying contents of elements including C and Si dominate the surface wettability differences at different sampling heights of corn stalk.With an increase in the sampling height,the mass fraction of C increases while that of Si decreases,which result in increasing hydrophilicity.After removal of the epidermis,the surface wettability of corn stalk rind is mainly determined by the mass fraction of hemicellulose,and the higher the sampling height,the larger the mass fraction of hemicellulose resulting in the increase of hydrophilicity.展开更多
Plasma treatment and 10% NH_4OH solution rinsing were performed on a germanium(Ge) surface.It was found that the Ge surface hydrophilicity after O_2 and Ar plasma exposure was stronger than that of samples subjected...Plasma treatment and 10% NH_4OH solution rinsing were performed on a germanium(Ge) surface.It was found that the Ge surface hydrophilicity after O_2 and Ar plasma exposure was stronger than that of samples subjected to N_2 plasma exposure. This is because the thin Ge Ox film formed on Ge by O_2 or Ar plasma is more hydrophilic than Ge Ox Ny formed by N_2 plasma treatment. A flat(RMS 〈 0:5 nm) Ge surface with high hydrophilicity(contact angle smaller than 3°) was achieved by O_2 plasma treatment, showing its promising application in Ge low-temperature direct wafer bonding.展开更多
The surface tensions and contact angles of Fe_(78)Si_9B_(13) and Fe_(73.5)Cu_1Nb_3Si_(13.5)B_9 alloy melts were studied as a function of temperature in various atmospheres(vacuum, Ar and N_2 gas) and on different subs...The surface tensions and contact angles of Fe_(78)Si_9B_(13) and Fe_(73.5)Cu_1Nb_3Si_(13.5)B_9 alloy melts were studied as a function of temperature in various atmospheres(vacuum, Ar and N_2 gas) and on different substrates(Si C, Al_2O_3 and BN). It is indicated that Si_3N_4, NbN, Fe_2 Al B and B_(13)C_2 are generated as new phases at the interface between the melt and substrate, and reactive wetting behaviour exists during the heating process. The surface tensions of two alloy melts on BN substrate both firstly decrease and then increase along with increasing temperature, leading to V-shaped surface tension versus temperature, which results from atomic diffusion effects in the surface layer during the oxidation of BN and formation of C-rich layer. Comparably, the surface tensions on Al_2O_3 and Si C substrates decrease with increasing temperature throughout the entire temperature range. Among three substrates, BN exhibits the mildest wetting behaviour. The vacuum environment has the strongest protective effect on melt stability among the tested atmospheres. These findings enrich our knowledge about the effects of the substrate and atmosphere on Fe-based alloy melts at a high temperature, and provide theoretical reference for designing jet nozzles in melt-spinning techniques.展开更多
基金supported by the Department of Scientific Research,Eskisehir Osmangazi University,Turkey(No.201441045)
文摘This study aimed to evaluate the surface roughness and wetting properties of various dental prosthetic materials after different durations of non-thermal atmospheric plasma(NTAP)treatment.One hundred and sixty discs of titanium(Ti)(n:40),cobalt chromium(Co-Cr)(n:40),yttrium stabilized tetragonal zirconia polycrystals(Y-TZP)(n:40)and polymethylmethacrylate(PMMA)(n:40)materials were machined and smoothed with silicon carbide papers.The surface roughness was evaluated in a control group and in groups with different plasma exposure times [1-3-5 s].The average surface roughness(Ra)and contact angle(CA)measurements were recorded via an atomic force microscope(AFM)and tensiometer,respectively.Surface changes were examined with a scanning electron microscope(SEM).Data were analyzed with two-way analysis of variance(ANOVA)and the Tukey HSD test α=0.05).According to the results,the NTAP surface treatment significantly affected the roughness and wettability properties(P 〈 0.05).SEM images reveal that more grooves were present in the NTAP groups.With an increase in the NTAP application time,an apparent increment was observed for Ra,except in the PMMA group,and a remarkable reduction in CA was observed in all groups.It is concluded that the NTAP technology could enhance the roughening and wetting performance of various dental materials.
基金The authors gratefully acknowledge financial support from the Specialized Research Fund for the Doctoral Program of Higher Education of China,Grant.No.20124105110004.
文摘Corn stalk is one of heterogeneous materials with anisotropy and variability.As the rind of corn stalk consists of rich lignin and cellulose similar to wood properties,and possessing high mechanical strength,then can be used as raw material of stalk artificial board and paper.The corn stalk rind has significant differences in fiber morphology,chemical composition and mechanical properties at different heights.Nano-SiO2 composite material contained in the epidermis of corn stalk rind is not conducive to exert adhesive into a board.To study board-making technology by intact corn stalk rind,the wettability of corn stalk rind at different sampling heights is necessary to be analyzed by keeping or removing the epidermis.To analyze the surface wettability difference,the contact angle with water,element compositions and the chemical compositions of corn stalk rind at different sampling heights were studied before and after removal of epidermis.A Fourier transform infrared(FTIR)analysis was performed.The results showed that the removal of the epidermis could significantly improve the hydrophilicity of corn stalk rind.Before removal of the epidermis,the varying contents of elements including C and Si dominate the surface wettability differences at different sampling heights of corn stalk.With an increase in the sampling height,the mass fraction of C increases while that of Si decreases,which result in increasing hydrophilicity.After removal of the epidermis,the surface wettability of corn stalk rind is mainly determined by the mass fraction of hemicellulose,and the higher the sampling height,the larger the mass fraction of hemicellulose resulting in the increase of hydrophilicity.
基金Project supported by the Key Project of Natural Science Foundation of China(No.61534005)the National Science Foundation of China(No.61474081)+2 种基金the National Basic Research Program of China(No.2013CB632103)the Natural Science Foundation of Fujian Province(No.2015D020)the Science and Technology Project of Xiamen City(No.3502Z20154091)
文摘Plasma treatment and 10% NH_4OH solution rinsing were performed on a germanium(Ge) surface.It was found that the Ge surface hydrophilicity after O_2 and Ar plasma exposure was stronger than that of samples subjected to N_2 plasma exposure. This is because the thin Ge Ox film formed on Ge by O_2 or Ar plasma is more hydrophilic than Ge Ox Ny formed by N_2 plasma treatment. A flat(RMS 〈 0:5 nm) Ge surface with high hydrophilicity(contact angle smaller than 3°) was achieved by O_2 plasma treatment, showing its promising application in Ge low-temperature direct wafer bonding.
基金supported by the National Natural Science Foundation of China(Grant No.51501043)National Scientific and Technological Support Projects(Grant No.2013BAE08B00)+1 种基金National Key Scientific Instrument and Equiment Development Project(Grant No.2014YQ120351)Science and Technology Program of Beijing(Grant No.Z141100003814007)
文摘The surface tensions and contact angles of Fe_(78)Si_9B_(13) and Fe_(73.5)Cu_1Nb_3Si_(13.5)B_9 alloy melts were studied as a function of temperature in various atmospheres(vacuum, Ar and N_2 gas) and on different substrates(Si C, Al_2O_3 and BN). It is indicated that Si_3N_4, NbN, Fe_2 Al B and B_(13)C_2 are generated as new phases at the interface between the melt and substrate, and reactive wetting behaviour exists during the heating process. The surface tensions of two alloy melts on BN substrate both firstly decrease and then increase along with increasing temperature, leading to V-shaped surface tension versus temperature, which results from atomic diffusion effects in the surface layer during the oxidation of BN and formation of C-rich layer. Comparably, the surface tensions on Al_2O_3 and Si C substrates decrease with increasing temperature throughout the entire temperature range. Among three substrates, BN exhibits the mildest wetting behaviour. The vacuum environment has the strongest protective effect on melt stability among the tested atmospheres. These findings enrich our knowledge about the effects of the substrate and atmosphere on Fe-based alloy melts at a high temperature, and provide theoretical reference for designing jet nozzles in melt-spinning techniques.