Segment Anything Model(SAM)is a cutting-edge model that has shown impressive performance in general object segmentation.The birth of the segment anything is a groundbreaking step towards creating a universal intellige...Segment Anything Model(SAM)is a cutting-edge model that has shown impressive performance in general object segmentation.The birth of the segment anything is a groundbreaking step towards creating a universal intelligent model.Due to its superior performance in general object segmentation,it quickly gained attention and interest.This makes SAM particularly attractive in industrial surface defect segmentation,especially for complex industrial scenes with limited training data.However,its segmentation ability for specific industrial scenes remains unknown.Therefore,in this work,we select three representative and complex industrial surface defect detection scenarios,namely strip steel surface defects,tile surface defects,and rail surface defects,to evaluate the segmentation performance of SAM.Our results show that although SAM has great potential in general object segmentation,it cannot achieve satisfactory performance in complex industrial scenes.Our test results are available at:https://github.com/VDT-2048/SAM-IS.展开更多
Surface defects,including dents,spalls,and cracks,for rolling element bearings are the most common faults in rotating machinery.The accurate model for the time-varying excitation is the basis for the vibration mechani...Surface defects,including dents,spalls,and cracks,for rolling element bearings are the most common faults in rotating machinery.The accurate model for the time-varying excitation is the basis for the vibration mechanism analysis and fault feature extraction.However,in conventional investigations,this issue is not well and fully addressed from the perspective of theoretical analysis and physical derivation.In this study,an improved analytical model for time-varying displacement excitations(TVDEs)caused by surface defects is theoretically formulated.First and foremost,the physical mechanism for the effect of defect sizes on the physical process of rolling element-defect interaction is revealed.According to the physical interaction mechanism between the rolling element and different types of defects,the relationship between time-varying displacement pulse and defect sizes is further analytically derived.With the obtained time-varying displacement pulse,the dynamic model for the deep groove bearings considering the internal excitation caused by the surface defect is established.The nonlinear vibration responses and fault features induced by surface defects are analyzed using the proposed TVDE model.The results suggest that the presence of surface defects may result in the occurrence of the dual-impulse phenomenon,which can serve as indexes for surface-defect fault diagnosis.展开更多
The effects of crystallite size on the physicochemical properties and surface defects of pure monoclinic ZrO_(2) catalysts for isobutene synthesis were studied.We prepared a series of monoclinic ZrO_(2) catalysts with...The effects of crystallite size on the physicochemical properties and surface defects of pure monoclinic ZrO_(2) catalysts for isobutene synthesis were studied.We prepared a series of monoclinic ZrO_(2) catalysts with different crystallite size by changing calcination temperature and evaluated their catalytic performance for isobutene synthesis from syngas.ZrO_(2) with small crystalline size showed higher CO conversion and isobutene selectivity,while samples with large crystalline size preferred to form dimethyl ether(DME)instead of hydrocarbons,much less to isobutene.Oxygen defects(ODefects)analyzed by X-ray photoelectron spectroscopy(XPS)provided evidence that more ODefectsoccupied on the surface of ZrO_(2) catalysts with smaller crystalline size.Electron paramagnetic resonance(EPR)and ultraviolet–visible diffuse reflectance(UV–vis DRS)confirmed the presence of high concentration of surface defects and Zr3+on mZrO_(2)-5.9 sample,respectively.In situ diffuse reflectance infrared Fourier transform spectroscopy(in situ DRIFTS)analysis indicated that the adsorption strength of formed formate species on catalyst reduced as the crystalline size decreased.These results suggested that surface defects were responsible for CO activation and further influenced the adsorption strength of surface species,and thus the products distribution changed.This study provides an in-depth insight for active sites regulation of ZrO_(2) catalyst in CO hydrogenation reaction.展开更多
Co-catalysts play a critical role in enhancing the efficiency of inorganic semiconductor photocatalysts;however,synthetic approaches to tailoring cocatalyst properties are rarely the focus of research efforts.A photom...Co-catalysts play a critical role in enhancing the efficiency of inorganic semiconductor photocatalysts;however,synthetic approaches to tailoring cocatalyst properties are rarely the focus of research efforts.A photomediated route to control the dispersion and oxidation state of a platinum(Pt)cocatalyst through defect generation in the P25 titania photocatalyst substrate is reported.Titania photoirradiation in the presence of methanol induces longlived surface defects which subsequently promote the photodeposition of highly dispersed(2.2±0.8 nm)and heavily reduced Pt nanoparticles on exposure to H2 PtCl6.The optimal methanol concentration of 20 vol%produces the highest density of metallic Pt nanoparticles.Photocatalytic activity for water splitting and associated hydrogen(H2)production under UV irradiation mirrors the methanol concentration employed during the P25 photoirradiation pretreatment and resulting Pt loading resulting in a common mass-normalized H2 productivity of 3800±130 mmol gpt-1 h-1.Photomediated surface defects(arising in the presence of a methanol hole scavenger)provide electron traps that regulate subsequent photodeposition of a Pt co-catalyst over P25,offering a facile route to tune photocatalytic efficiency.展开更多
Although a high-quality homoepitaxial layer of 4H‑silicon carbide(4H-SiC)can be obtained on a 4°off-axis substrate using chemical vapor deposition,the reduction of defects is still a focus of research.In this stu...Although a high-quality homoepitaxial layer of 4H‑silicon carbide(4H-SiC)can be obtained on a 4°off-axis substrate using chemical vapor deposition,the reduction of defects is still a focus of research.In this study,several kinds of surface defects in the 4H-SiC homoepitaxial layer are systemically investigated,including triangles,carrots,surface pits,basal plane dislocations,and step bunching.Themorphologies and structures of surface defects are further discussed via optical microscopy and potassium hydroxide-based defect selective etching analysis.Through research and analysis,we found that the origin of surface defects in the 4H-SiC homoepitaxial layer can be attributed to two aspects:the propagation of substrate defects,such as scratches,dislocation,and inclusion,and improper process parameters during epitaxial growth,such as in-situ etch,C/Si ratio,and growth temperature.It is believed that the surface defects in the 4H-SiC homoepitaxial layer can be significantly decreased by precisely controlling the chemistry on the deposition surface during the growth process.展开更多
This paper reports the performance enhancement benefits in diamond turning of the silicon wafer by incorporation of the surface defect machining(SDM)method.The hybrid micromachining methods usually require additional ...This paper reports the performance enhancement benefits in diamond turning of the silicon wafer by incorporation of the surface defect machining(SDM)method.The hybrid micromachining methods usually require additional hardware to leverage the added advantage of hybrid technologies such as laser heating,cryogenic cooling,electric pulse or ultrasonic elliptical vibration.The SDM method tested in this paper does not require any such additional baggage and is easy to implement in a sequential micro-machining mode.This paper made use of Raman spectroscopy data,average surface roughness data and imaging data of the cutting chips of silicon for drawing a comparison between conventional single-point diamond turning(SPDT)and SDM while incorporating surface defects in the(i)circumferential and(ii)radial directions.Complementary 3D finite element analysis(FEA)was performed to analyse the cutting forces and the evolution of residual stress on the machined wafer.It was found that the surface defects generated in the circumferential direction with an interspacing of 1 mm revealed the lowest average surface roughness(Ra)of 3.2 nm as opposed to 8 nm Ra obtained through conventional SPDT using the same cutting parameters.The observation of the Raman spectroscopy performed on the cutting chips showed remnants of phase transformation during the micromachining process in all cases.FEA was used to extract quantifiable information about the residual stress as well as the sub-surface integrity and it was discovered that the grooves made in the circumferential direction gave the best machining performance.The information being reported here is expected to provide an avalanche of opportunities in the SPDT area for low-cost machining solution for a range of other nominal hard,brittle materials such as SiC,ZnSe and GaAs as well as hard steels.展开更多
The monomolecular surface layer of acceptor doped CeO_(2) may become neutral and metallic or charged and semiconducting.This is revealed in the theoretical analysis of the oxygen pressure dependence of the surface def...The monomolecular surface layer of acceptor doped CeO_(2) may become neutral and metallic or charged and semiconducting.This is revealed in the theoretical analysis of the oxygen pressure dependence of the surface defects concentration in acceptor doped ceria with two different dopant types and operated under different oxygen pressures.Recently published experimental data for highly reduced Sm0.2Ce0.8O1.9-x(SDC)containing a fixed valence dopant Sm3+are very different from those published for Pr0.1Ce0.9O_(2)-x(PCO) with the variable valence dopant Pr4+/Pr3+being reduced under milder conditions.The theoretical analysis of these experimental results fits very well the experimental results of SDC and PCO.It leads to the following predictions:the highly reduced surface of SDC is metallic and neutral,the metallic surface electron density of state is gs=0.9×10^(38)J-1·m^(-2)(1.4×1015eV^(-1)·cm^(-2)),the electron effective mass is meff,s=3.3me,and the phase diagram of the reduced surface has theα(fcc)structure as in the bulk.In PCO a double layer is predicted to be formed between the surface and the bulk with the surface being negatively charged and semiconducting.The surface of PCO maintains high Pr^(3+) defect concentration as well as relative high oxygen vacancy concentration at oxygen pressures higher than in the bulk.The reasons for the difference between a metallic and semiconducting surface layer of acceptor doped CeO_(2) are reviewed,as well as the key theoretical considerations applied in coping with this problem.For that we make use of the experimental data and theoretical analysis available for acceptor doped ceria.展开更多
Spinel oxide(NiCo_(2)O_(4))has demonstrated great potential to replace noble metal catalysts for the oxidation reaction of air pollutants.To further boost the oxidation ability of such catalysts,in this study,a facile...Spinel oxide(NiCo_(2)O_(4))has demonstrated great potential to replace noble metal catalysts for the oxidation reaction of air pollutants.To further boost the oxidation ability of such catalysts,in this study,a facile surface-engineering strategy wherein NiCo_(2)O_(4) was treated with different alkali solvents was developed.The obtained catalyst(NiCo_(2)O_(4)-OH)showed a higher surface alkalinity and more surface defects compared to the pristine spinel oxide,including enhanced structural distortion as well as promoted oxygen vacancies.The propane oxidation ability of NiCo_(2)O_(4)-OH was greatly enhanced,with a propane conversion rate that was approximately 6.4 times higher than that of pristine NiCo_(2)O_(4) at a reaction temperature 193℃.This work sets a valuable paradigm for the surface modulation of spinel oxide via alkali treatment to ensure a high-performance oxidation catalyst.展开更多
Printed Circuit Board(PCB)surface tiny defect detection is a difficult task in the integrated circuit industry,especially since the detection of tiny defects on PCB boards with large-size complex circuits has become o...Printed Circuit Board(PCB)surface tiny defect detection is a difficult task in the integrated circuit industry,especially since the detection of tiny defects on PCB boards with large-size complex circuits has become one of the bottlenecks.To improve the performance of PCB surface tiny defects detection,a PCB tiny defects detection model based on an improved attention residual network(YOLOX-AttResNet)is proposed.First,the unsupervised clustering performance of the K-means algorithm is exploited to optimize the channel weights for subsequent operations by feeding the feature mapping into the SENet(Squeeze and Excitation Network)attention network;then the improved K-means-SENet network is fused with the directly mapped edges of the traditional ResNet network to form an augmented residual network(AttResNet);and finally,the AttResNet module is substituted for the traditional ResNet structure in the backbone feature extraction network of mainstream excellent detection models,thus improving the ability to extract small features from the backbone of the target detection network.The results of ablation experiments on a PCB surface defect dataset show that AttResNet is a reliable and efficient module.In Torify the performance of AttResNet for detecting small defects in large-size complex circuit images,a series of comparison experiments are further performed.The results show that the AttResNet module combines well with the five best existing target detection frameworks(YOLOv3,YOLOX,Faster R-CNN,TDD-Net,Cascade R-CNN),and all the combined new models have improved detection accuracy compared to the original model,which suggests that the AttResNet module proposed in this paper can help the detection model to extract target features.Among them,the YOLOX-AttResNet model proposed in this paper performs the best,with the highest accuracy of 98.45% and the detection speed of 36 FPS(Frames Per Second),which meets the accuracy and real-time requirements for the detection of tiny defects on PCB surfaces.This study can provide some new ideas for other real-time online detection tasks of tiny targets with high-resolution images.展开更多
A numerical model is presented in this article to investigate the interactions between laser generated ultrasonic and the microdefects(0.01 to 0.1 mm),which are on the surface of the laser powder bed fusion additive m...A numerical model is presented in this article to investigate the interactions between laser generated ultrasonic and the microdefects(0.01 to 0.1 mm),which are on the surface of the laser powder bed fusion additive manufactured 316L stainless steel.Firstly,the influence of the transient sound field and detection positions on Rayleigh wave signals are investigated.The interactions between the varied microdefects and the laser ultrasonic are studied.It is shown that arrival time of reflected Rayleigh(RR)waves wave is only related to the location of defects.The depth can be checked from the feature point Q,the displacement amplitude and time delay of converted transverse(RS)wave,while the width information can be evaluated from the RS wave time delay.With the aid of fitting curves,it is found to be linearly related.This simulation study provides a theoretical basis for quantitative detection of surface microdefects of additive manufactured 316L stainless steel components.展开更多
Two-dimensional(2D) alternating cation(ACI) perovskite surface defects,especially dominant iodine vacancies(V_Ⅰ) and undercoordinated Pb^(2+),limit the performance of perovskite solar cells(PVSCs).To address the issu...Two-dimensional(2D) alternating cation(ACI) perovskite surface defects,especially dominant iodine vacancies(V_Ⅰ) and undercoordinated Pb^(2+),limit the performance of perovskite solar cells(PVSCs).To address the issue,1-butyl-3-methylimidazolium trifluoro-methane-sulfonate(BMIMOTF) and its iodide counterpart(BMIMI) are utilized to modify the perovskite surface respectively.We find that BMIMI can change the perovskite surface,whereas BMIMOTF shows a nondestructive and more effective defect passivation,giving significantly reduced defect density and suppressed charge-carrier nonradiative recombination.This mainly attributes to the marked passivation efficacy of OTF-anion on V_Ⅰ and undercoordinated Pb^(2+),rather than BMIMI^(+) cation.Benefiting from the rational surface-modification of BMMIMOTF,the films exhibit an optimized energy level alignment,enhanced hydrophobicity and suppressed ion migration.Consequently,the BMIMOTF-modified devices achieve an impressive efficiency of 21.38% with a record open-circuit voltage of 1.195 V,which is among the best efficiencies reported for 2D PVSCs,and display greatly enhanced humidity and thermal stability.展开更多
To guarantee the safety of railway operations,the swift detection of rail surface defects becomes imperative.Traditional methods of manual inspection and conventional nondestructive testing prove inefficient,especiall...To guarantee the safety of railway operations,the swift detection of rail surface defects becomes imperative.Traditional methods of manual inspection and conventional nondestructive testing prove inefficient,especially when scaling to extensive railway networks.Moreover,the unpredictable and intricate nature of defect edge shapes further complicates detection efforts.Addressing these challenges,this paper introduces an enhanced Unified Perceptual Parsing for Scene Understanding Network(UPerNet)tailored for rail surface defect detection.Notably,the Swin Transformer Tiny version(Swin-T)network,underpinned by the Transformer architecture,is employed for adept feature extraction.This approach capitalizes on the global information present in the image and sidesteps the issue of inductive preference.The model’s efficiency is further amplified by the windowbased self-attention,which minimizes the model’s parameter count.We implement the cross-GPU synchronized batch normalization(SyncBN)for gradient optimization and integrate the Lovász-hinge loss function to leverage pixel dependency relationships.Experimental evaluations underscore the efficacy of our improved UPerNet,with results demonstrating Pixel Accuracy(PA)scores of 91.39%and 93.35%,Intersection over Union(IoU)values of 83.69%and 87.58%,Dice Coefficients of 91.12%and 93.38%,and Precision metrics of 90.85%and 93.41%across two distinct datasets.An increment in detection accuracy was discernible.For further practical applicability,we deploy semantic segmentation of rail surface defects,leveraging connected component processing techniques to distinguish varied defects within the same frame.By computing the actual defect length and area,our deep learning methodology presents results that offer intuitive insights for railway maintenance professionals.展开更多
Bimetalic platinum-copper(Pt-Cu)alloy nanowires have emerged as a novel class of fuel cell electrocatalysts for oxygen reduction reaction(ORR)due to their intrinsic high catalytic activity and durability,but preparing...Bimetalic platinum-copper(Pt-Cu)alloy nanowires have emerged as a novel class of fuel cell electrocatalysts for oxygen reduction reaction(ORR)due to their intrinsic high catalytic activity and durability,but preparing such electrocatalysts with clean surface via facile method is still a challenge.Herein,PtCu alloy with nanowire networks(NWNs)structure is obtained by a simple modified polyol method accompanied with a salt-mediated self-assembly process in a water/ethylene glycol(EG)mixing media.The formation mechanism of PtCu NWNs including the morphological evolution and the relevant experimental parameters has been investigated systematically.We propose that a micro-interface in H2O-EG media formed with the assistance of disodium dihydrogen pyrophosphate(Na2H2P2O7)and its unique nature of coordinating with Pt^2+ or Cu^2+ play critical roles in the formation of NWNs.When tested as ORR catalyst,the PtCuNWNs/C exhibits much higher activity and durability than that of PtNWNs/C and commercial PtC,even exceeding the target of DOE in 2020.The excellent performance of PtCuNWNs/C could be attributed to the unique structure of NWNs with 2.4 nm ultrathin wavy nanowires and plentiful surface defects and the modified electronic effect caused by alloying with Cu atoms.展开更多
Least squares support vector machine (LS-SVM) plays an important role in steel surface defects classification because of its high speed. However, the defect samples obtained from the real production line may be noise....Least squares support vector machine (LS-SVM) plays an important role in steel surface defects classification because of its high speed. However, the defect samples obtained from the real production line may be noise. LS-SVM suffers from the poor classification performance in the classification stage when there are noise samples. Thus, in the classification stage, it is necessary to design an effective algorithm to process the defects dataset obtained from the real production line. To this end, an adaptive weight function was employed to reduce the adverse effect of noise samples. Moreover, although LSSVM offers fast speed, it still suffers from a high computational complexity if the number of training samples is large. The time for steel surface defects classification should be as short as possible. Therefore, a sparse strategy was adopted to prune the training samples. Finally, since the steel surface defects classification belongs to unbalanced data classification, LSSVM algorithm is not applicable. Hence, the unbalanced data information was introduced to improve the classification performance. Comprehensively considering above-mentioned factors, an improved LS-SVM classification model was proposed, termed as ILS-SVM. Experimental results show that the new algorithm has the advantages of high speed and great anti-noise ability.展开更多
Defect classification is the key task of a steel surface defect detection system.The current defect classification algorithms have not taken the feature noise into consideration.In order to reduce the adverse impact o...Defect classification is the key task of a steel surface defect detection system.The current defect classification algorithms have not taken the feature noise into consideration.In order to reduce the adverse impact of feature noise,an anti-noise multi-class classification method was proposed for steel surface defects.On the one hand,a novel anti-noise support vector hyper-spheres(ASVHs)classifier was formulated.For N types of defects,the ASVHs classifier built N hyper-spheres.These hyper-spheres were insensitive to feature and label noise.On the other hand,in order to reduce the costs of online time and storage space,the defect samples were pruned by support vector data description with parameter iteration adjustment strategy.In the end,the ASVHs classifier was built with sparse defect samples set and auxiliary information.Experimental results show that the novel multi-class classification method has high efficiency and accuracy for corrupted defect samples in steel surface.展开更多
Hypo-peritectic steels are widely used in various industrial fields because of their high strength,high toughness,high processability,high weldability,and low material cost.However,surface defects are liable to occur ...Hypo-peritectic steels are widely used in various industrial fields because of their high strength,high toughness,high processability,high weldability,and low material cost.However,surface defects are liable to occur during continuous casting,which includes depression,longitudinal cracks,deep oscillation marks,and severe level fluctuation with slag entrapment.The high-efficiency production of hypo-peritectic steels by continuous casting is still a great challenge due to the limited understanding of the mechanism of peritectic solidification.This work reviews the definition and classification of hypo-peritectic steels and introduces the formation tendency of common surface defects related to peritectic solidification.New achievements in the mechanism of peritectic reaction and transformation have been listed.Finally,countermeasures to avoiding surface defects of hypo-peritectic steels duiring continuous casting are summarized.Enlightening certain points in the continuous casting of hypo-peritectic steels and the development of new techniques to overcome the present problems will be a great aid to researchers.展开更多
Contour bevel gears have the advantages of high coincidence,low noise and large bearing capacity,which are widely used in automobile manufacturing,shipbuilding and construction machinery.However,when the surface quali...Contour bevel gears have the advantages of high coincidence,low noise and large bearing capacity,which are widely used in automobile manufacturing,shipbuilding and construction machinery.However,when the surface quality is poor,the effective contact area between the gear mating surfaces decreases,affecting the stability of the fit and thus the transmission accuracy,so it is of great significance to optimize the surface quality of the contour bevel gear.This paper firstly analyzes the formation process of machined surface roughness of contour bevel gears on the basis of generating machining method,and dry milling experiments of contour bevel gears are conducted to analyze the effects of cutting speed and feed rate on the machined surface roughness and surface topography of the workpiece.Then,the surface defects on the machined surface of the workpiece are studied by SEM,and the causes of the surface defects are analyzed by EDS.After that,XRD is used to compare the microscopic grains of the machined surface and the substrate material for diffraction peak analysis,and the effect of cutting parameters on the microhardness of the workpiece machined surface is investigated by work hardening experiment.The research results are of great significance for improving the machining accuracy of contour bevel gears,reducing friction losses and improving transmission efficiency.展开更多
This scientific paper presents a study investigating the effects of defects at the CdS/CIGS and CdS/SDL interfaces on the performance of CIGS solar cells. The objective of this study is to analyze the influence of def...This scientific paper presents a study investigating the effects of defects at the CdS/CIGS and CdS/SDL interfaces on the performance of CIGS solar cells. The objective of this study is to analyze the influence of defects at the interface between the CdS buffer layer and the CIGS absorber, as well as the surface defect layer (SDL), on CIGS solar cell performance. The study explores three key aspects: the impact of the conduction band offset (CBO) at the CdS/CIGS interface, the effects of interface defects and defect density on performance, and the combined influence of CBO and defect density at the CdS/ SDL and SDL/CIGS interfaces. For interface defects not exceeding 10<sup>13</sup> cm<sup>-2</sup>, we obtained a good efficiency of 22.9% when -0.1 eV analyzing the quality of CdS/SDL and SDL/CIGS junctions, it appears that defects at the SDL/CIGS interface have very little impact on the performances of the CIGS solar cell. By optimizing the electrical parameters of the CdS/SDL interface defects, we achieved a conversion efficiency of 23.1% when -0.05 eV < CBO < 0.05 eV.展开更多
In the viewpoint of ammonia economy,electrochemical N2 reduction reaction(NRR)under mild condition is a very promising approach for sustainable development.By virtue of robust activity and low cost,transition-metalbas...In the viewpoint of ammonia economy,electrochemical N2 reduction reaction(NRR)under mild condition is a very promising approach for sustainable development.By virtue of robust activity and low cost,transition-metalbased materials become one kind of the most attractive electrocatalysts in realizing ammonia synthesis to the industrial level.However,the investigation related to NRR electrocatalysts still mainly rely on costly substance or fabrication process,which greatly restrict their large-scale applications.In this work,a simple fabricated FeS2 electrode is adopted as NRR catalysts.The abundant surface defects due to the existence of Cr element,as well as the synergistic effect between FeS2 crystal planes provided excellent electrocatalytic performance with a high NH3 yield rate(11.5μg h^-1mg^-1 Fe)and Faradaic efficiency(14.6%)at-0.2 V vs.reversible hydrogen electrode(RHE)toward NRR under ambient conditions.The superior catalytic performance of such non-precious metal catalysts would strongly promote the application of NRR process industrially.展开更多
Designing defect-engineered semiconductor heterojunctions can effectively promote the charge carrier separation.Herein,novel ceria(CeO2) quantum dots(QDs) decorated sulfur-doped carbon nitride nanotubes(SCN NTs) were ...Designing defect-engineered semiconductor heterojunctions can effectively promote the charge carrier separation.Herein,novel ceria(CeO2) quantum dots(QDs) decorated sulfur-doped carbon nitride nanotubes(SCN NTs) were synthesized via a thermal polycondensation coupled in situ depositionprecipitation method without use of template or surfactant.The structure and morphology studies indicate that ultrafine CeO2 QDs are well distributed inside and outside of SCN NTs offering highly dispersed active sites and a large contact interface between two components.This leads to the promoted formation of rich Ce^(3+) ion and oxygen vacancies as confirmed by XPS.The photocatalytic performance can be facilely modulated by the content of CeO2 QDs introduced in SCN matrix while bare CeO2 does not show activity of hydrogen production.The optimal catalyst with 10% of CeO2 loading yields a hydrogen evolution rate of 2923.8 μmol h-1 g-1 under visible light,remarkably higher than that of bare SCN and their physical mixtures.Further studies reveal that the abundant surface defects and the created 0 D/1 D junctions play a critical role in improving the separation and transfer of charge carriers,leading to superior solar hydrogen production and good stability.展开更多
基金supported by the National Natural Science Foundation of China(51805078)Project of National Key Laboratory of Advanced Casting Technologies(CAT2023-002)the 111 Project(B16009).
文摘Segment Anything Model(SAM)is a cutting-edge model that has shown impressive performance in general object segmentation.The birth of the segment anything is a groundbreaking step towards creating a universal intelligent model.Due to its superior performance in general object segmentation,it quickly gained attention and interest.This makes SAM particularly attractive in industrial surface defect segmentation,especially for complex industrial scenes with limited training data.However,its segmentation ability for specific industrial scenes remains unknown.Therefore,in this work,we select three representative and complex industrial surface defect detection scenarios,namely strip steel surface defects,tile surface defects,and rail surface defects,to evaluate the segmentation performance of SAM.Our results show that although SAM has great potential in general object segmentation,it cannot achieve satisfactory performance in complex industrial scenes.Our test results are available at:https://github.com/VDT-2048/SAM-IS.
基金This work is sponsored by the National Natural Science Foundation of China(Nos.52105117&52105118).
文摘Surface defects,including dents,spalls,and cracks,for rolling element bearings are the most common faults in rotating machinery.The accurate model for the time-varying excitation is the basis for the vibration mechanism analysis and fault feature extraction.However,in conventional investigations,this issue is not well and fully addressed from the perspective of theoretical analysis and physical derivation.In this study,an improved analytical model for time-varying displacement excitations(TVDEs)caused by surface defects is theoretically formulated.First and foremost,the physical mechanism for the effect of defect sizes on the physical process of rolling element-defect interaction is revealed.According to the physical interaction mechanism between the rolling element and different types of defects,the relationship between time-varying displacement pulse and defect sizes is further analytically derived.With the obtained time-varying displacement pulse,the dynamic model for the deep groove bearings considering the internal excitation caused by the surface defect is established.The nonlinear vibration responses and fault features induced by surface defects are analyzed using the proposed TVDE model.The results suggest that the presence of surface defects may result in the occurrence of the dual-impulse phenomenon,which can serve as indexes for surface-defect fault diagnosis.
基金financially supported by the Natural Science Foundation of China(21978312,21908235 and 21802155)the Key Research Program of Frontier Sciences,CAS(QYZDB–SSW–JS C043)+1 种基金Foundation of State Key Laboratory of Highefficiency Utilization of Coal and Green Chemical Engineering(2019-KF-05 and 2018-K22)Supported by Shanxi Scholarship Council of China and Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province are also greatly appreciated。
文摘The effects of crystallite size on the physicochemical properties and surface defects of pure monoclinic ZrO_(2) catalysts for isobutene synthesis were studied.We prepared a series of monoclinic ZrO_(2) catalysts with different crystallite size by changing calcination temperature and evaluated their catalytic performance for isobutene synthesis from syngas.ZrO_(2) with small crystalline size showed higher CO conversion and isobutene selectivity,while samples with large crystalline size preferred to form dimethyl ether(DME)instead of hydrocarbons,much less to isobutene.Oxygen defects(ODefects)analyzed by X-ray photoelectron spectroscopy(XPS)provided evidence that more ODefectsoccupied on the surface of ZrO_(2) catalysts with smaller crystalline size.Electron paramagnetic resonance(EPR)and ultraviolet–visible diffuse reflectance(UV–vis DRS)confirmed the presence of high concentration of surface defects and Zr3+on mZrO_(2)-5.9 sample,respectively.In situ diffuse reflectance infrared Fourier transform spectroscopy(in situ DRIFTS)analysis indicated that the adsorption strength of formed formate species on catalyst reduced as the crystalline size decreased.These results suggested that surface defects were responsible for CO activation and further influenced the adsorption strength of surface species,and thus the products distribution changed.This study provides an in-depth insight for active sites regulation of ZrO_(2) catalyst in CO hydrogenation reaction.
基金supported by the financial support from National Science Foundation of China(21872093)funding support from Center of Hydrogen Science,Shanghai Jiao Tong University,China
文摘Co-catalysts play a critical role in enhancing the efficiency of inorganic semiconductor photocatalysts;however,synthetic approaches to tailoring cocatalyst properties are rarely the focus of research efforts.A photomediated route to control the dispersion and oxidation state of a platinum(Pt)cocatalyst through defect generation in the P25 titania photocatalyst substrate is reported.Titania photoirradiation in the presence of methanol induces longlived surface defects which subsequently promote the photodeposition of highly dispersed(2.2±0.8 nm)and heavily reduced Pt nanoparticles on exposure to H2 PtCl6.The optimal methanol concentration of 20 vol%produces the highest density of metallic Pt nanoparticles.Photocatalytic activity for water splitting and associated hydrogen(H2)production under UV irradiation mirrors the methanol concentration employed during the P25 photoirradiation pretreatment and resulting Pt loading resulting in a common mass-normalized H2 productivity of 3800±130 mmol gpt-1 h-1.Photomediated surface defects(arising in the presence of a methanol hole scavenger)provide electron traps that regulate subsequent photodeposition of a Pt co-catalyst over P25,offering a facile route to tune photocatalytic efficiency.
基金This work was supported by the Provincial Government of Shanxi[Grant No.20201102012].
文摘Although a high-quality homoepitaxial layer of 4H‑silicon carbide(4H-SiC)can be obtained on a 4°off-axis substrate using chemical vapor deposition,the reduction of defects is still a focus of research.In this study,several kinds of surface defects in the 4H-SiC homoepitaxial layer are systemically investigated,including triangles,carrots,surface pits,basal plane dislocations,and step bunching.Themorphologies and structures of surface defects are further discussed via optical microscopy and potassium hydroxide-based defect selective etching analysis.Through research and analysis,we found that the origin of surface defects in the 4H-SiC homoepitaxial layer can be attributed to two aspects:the propagation of substrate defects,such as scratches,dislocation,and inclusion,and improper process parameters during epitaxial growth,such as in-situ etch,C/Si ratio,and growth temperature.It is believed that the surface defects in the 4H-SiC homoepitaxial layer can be significantly decreased by precisely controlling the chemistry on the deposition surface during the growth process.
基金financial support provided by CSIR,India through the project grant MLP0056the financial support provided by the UKRI via Grants Nos.EP/L016567/1,EP/S013652/1,EP/S036180/1,EP/T001100/1 and EP/T024607/1+2 种基金Royal Academy of Engineering via Grants Nos.IAPP18-19\295,TSP1332 and EXPP2021\1\277,EURAMET EMPIR A185(2018)H2020 EU Cost Actions(CA15102,CA18125,CA18224 and CA16235)Newton Fellowship award from the Royal Society(NIF\R1\191571)。
文摘This paper reports the performance enhancement benefits in diamond turning of the silicon wafer by incorporation of the surface defect machining(SDM)method.The hybrid micromachining methods usually require additional hardware to leverage the added advantage of hybrid technologies such as laser heating,cryogenic cooling,electric pulse or ultrasonic elliptical vibration.The SDM method tested in this paper does not require any such additional baggage and is easy to implement in a sequential micro-machining mode.This paper made use of Raman spectroscopy data,average surface roughness data and imaging data of the cutting chips of silicon for drawing a comparison between conventional single-point diamond turning(SPDT)and SDM while incorporating surface defects in the(i)circumferential and(ii)radial directions.Complementary 3D finite element analysis(FEA)was performed to analyse the cutting forces and the evolution of residual stress on the machined wafer.It was found that the surface defects generated in the circumferential direction with an interspacing of 1 mm revealed the lowest average surface roughness(Ra)of 3.2 nm as opposed to 8 nm Ra obtained through conventional SPDT using the same cutting parameters.The observation of the Raman spectroscopy performed on the cutting chips showed remnants of phase transformation during the micromachining process in all cases.FEA was used to extract quantifiable information about the residual stress as well as the sub-surface integrity and it was discovered that the grooves made in the circumferential direction gave the best machining performance.The information being reported here is expected to provide an avalanche of opportunities in the SPDT area for low-cost machining solution for a range of other nominal hard,brittle materials such as SiC,ZnSe and GaAs as well as hard steels.
基金financially supported by the Technion V.P.for Research Fund(No.2023320)。
文摘The monomolecular surface layer of acceptor doped CeO_(2) may become neutral and metallic or charged and semiconducting.This is revealed in the theoretical analysis of the oxygen pressure dependence of the surface defects concentration in acceptor doped ceria with two different dopant types and operated under different oxygen pressures.Recently published experimental data for highly reduced Sm0.2Ce0.8O1.9-x(SDC)containing a fixed valence dopant Sm3+are very different from those published for Pr0.1Ce0.9O_(2)-x(PCO) with the variable valence dopant Pr4+/Pr3+being reduced under milder conditions.The theoretical analysis of these experimental results fits very well the experimental results of SDC and PCO.It leads to the following predictions:the highly reduced surface of SDC is metallic and neutral,the metallic surface electron density of state is gs=0.9×10^(38)J-1·m^(-2)(1.4×1015eV^(-1)·cm^(-2)),the electron effective mass is meff,s=3.3me,and the phase diagram of the reduced surface has theα(fcc)structure as in the bulk.In PCO a double layer is predicted to be formed between the surface and the bulk with the surface being negatively charged and semiconducting.The surface of PCO maintains high Pr^(3+) defect concentration as well as relative high oxygen vacancy concentration at oxygen pressures higher than in the bulk.The reasons for the difference between a metallic and semiconducting surface layer of acceptor doped CeO_(2) are reviewed,as well as the key theoretical considerations applied in coping with this problem.For that we make use of the experimental data and theoretical analysis available for acceptor doped ceria.
基金financially supported by the National Natural Science Foundation of China(No.22072069)the Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials(Wuhan University of Science and Technology No.WKDM202303).
文摘Spinel oxide(NiCo_(2)O_(4))has demonstrated great potential to replace noble metal catalysts for the oxidation reaction of air pollutants.To further boost the oxidation ability of such catalysts,in this study,a facile surface-engineering strategy wherein NiCo_(2)O_(4) was treated with different alkali solvents was developed.The obtained catalyst(NiCo_(2)O_(4)-OH)showed a higher surface alkalinity and more surface defects compared to the pristine spinel oxide,including enhanced structural distortion as well as promoted oxygen vacancies.The propane oxidation ability of NiCo_(2)O_(4)-OH was greatly enhanced,with a propane conversion rate that was approximately 6.4 times higher than that of pristine NiCo_(2)O_(4) at a reaction temperature 193℃.This work sets a valuable paradigm for the surface modulation of spinel oxide via alkali treatment to ensure a high-performance oxidation catalyst.
基金supported by the National Natural Science Foundation of China(No.61976083)Hubei Province Key R&D Program of China(No.2022BBA0016).
文摘Printed Circuit Board(PCB)surface tiny defect detection is a difficult task in the integrated circuit industry,especially since the detection of tiny defects on PCB boards with large-size complex circuits has become one of the bottlenecks.To improve the performance of PCB surface tiny defects detection,a PCB tiny defects detection model based on an improved attention residual network(YOLOX-AttResNet)is proposed.First,the unsupervised clustering performance of the K-means algorithm is exploited to optimize the channel weights for subsequent operations by feeding the feature mapping into the SENet(Squeeze and Excitation Network)attention network;then the improved K-means-SENet network is fused with the directly mapped edges of the traditional ResNet network to form an augmented residual network(AttResNet);and finally,the AttResNet module is substituted for the traditional ResNet structure in the backbone feature extraction network of mainstream excellent detection models,thus improving the ability to extract small features from the backbone of the target detection network.The results of ablation experiments on a PCB surface defect dataset show that AttResNet is a reliable and efficient module.In Torify the performance of AttResNet for detecting small defects in large-size complex circuit images,a series of comparison experiments are further performed.The results show that the AttResNet module combines well with the five best existing target detection frameworks(YOLOv3,YOLOX,Faster R-CNN,TDD-Net,Cascade R-CNN),and all the combined new models have improved detection accuracy compared to the original model,which suggests that the AttResNet module proposed in this paper can help the detection model to extract target features.Among them,the YOLOX-AttResNet model proposed in this paper performs the best,with the highest accuracy of 98.45% and the detection speed of 36 FPS(Frames Per Second),which meets the accuracy and real-time requirements for the detection of tiny defects on PCB surfaces.This study can provide some new ideas for other real-time online detection tasks of tiny targets with high-resolution images.
基金supported by the National Key Research and Development Program of China(No.2017YFB1103900)the National Natural Science Foundation of China(No.51605340)。
文摘A numerical model is presented in this article to investigate the interactions between laser generated ultrasonic and the microdefects(0.01 to 0.1 mm),which are on the surface of the laser powder bed fusion additive manufactured 316L stainless steel.Firstly,the influence of the transient sound field and detection positions on Rayleigh wave signals are investigated.The interactions between the varied microdefects and the laser ultrasonic are studied.It is shown that arrival time of reflected Rayleigh(RR)waves wave is only related to the location of defects.The depth can be checked from the feature point Q,the displacement amplitude and time delay of converted transverse(RS)wave,while the width information can be evaluated from the RS wave time delay.With the aid of fitting curves,it is found to be linearly related.This simulation study provides a theoretical basis for quantitative detection of surface microdefects of additive manufactured 316L stainless steel components.
基金financially supported by the National Natural Science Foundation of China (62174021 and 62104028)the Creative Research Groups of the National Natural Science Foundation of Sichuan Province (2023NSFSC1973)+7 种基金the Sichuan Science and Technology Program (MZGC20230008)the Natural Science Foundation of Sichuan Province (2022NSFSC0899)the China Postdoctoral Science Foundation (2021M700689)the Grant SCITLAB (20012) of Intelligent Terminal Key Laboratory of Sichuan ProvinceFundamental Research Funds for the Central Universities (ZYGX2019J054)the Guangdong Basic and Applied Basic Research Foundation (2019A1515110438)sponsored by the University of Kentuckythe Sichuan Province Key Laboratory of Display Science and Technology。
文摘Two-dimensional(2D) alternating cation(ACI) perovskite surface defects,especially dominant iodine vacancies(V_Ⅰ) and undercoordinated Pb^(2+),limit the performance of perovskite solar cells(PVSCs).To address the issue,1-butyl-3-methylimidazolium trifluoro-methane-sulfonate(BMIMOTF) and its iodide counterpart(BMIMI) are utilized to modify the perovskite surface respectively.We find that BMIMI can change the perovskite surface,whereas BMIMOTF shows a nondestructive and more effective defect passivation,giving significantly reduced defect density and suppressed charge-carrier nonradiative recombination.This mainly attributes to the marked passivation efficacy of OTF-anion on V_Ⅰ and undercoordinated Pb^(2+),rather than BMIMI^(+) cation.Benefiting from the rational surface-modification of BMMIMOTF,the films exhibit an optimized energy level alignment,enhanced hydrophobicity and suppressed ion migration.Consequently,the BMIMOTF-modified devices achieve an impressive efficiency of 21.38% with a record open-circuit voltage of 1.195 V,which is among the best efficiencies reported for 2D PVSCs,and display greatly enhanced humidity and thermal stability.
基金supported in part by the National Natural Science Foundation of China(Grant No.62066024)Gansu Province Higher Education Industry Support Plan(2021CYZC34)Lanzhou Talent Innovation and Entrepreneurship Project(2021-RC-27,2021-RC-45).
文摘To guarantee the safety of railway operations,the swift detection of rail surface defects becomes imperative.Traditional methods of manual inspection and conventional nondestructive testing prove inefficient,especially when scaling to extensive railway networks.Moreover,the unpredictable and intricate nature of defect edge shapes further complicates detection efforts.Addressing these challenges,this paper introduces an enhanced Unified Perceptual Parsing for Scene Understanding Network(UPerNet)tailored for rail surface defect detection.Notably,the Swin Transformer Tiny version(Swin-T)network,underpinned by the Transformer architecture,is employed for adept feature extraction.This approach capitalizes on the global information present in the image and sidesteps the issue of inductive preference.The model’s efficiency is further amplified by the windowbased self-attention,which minimizes the model’s parameter count.We implement the cross-GPU synchronized batch normalization(SyncBN)for gradient optimization and integrate the Lovász-hinge loss function to leverage pixel dependency relationships.Experimental evaluations underscore the efficacy of our improved UPerNet,with results demonstrating Pixel Accuracy(PA)scores of 91.39%and 93.35%,Intersection over Union(IoU)values of 83.69%and 87.58%,Dice Coefficients of 91.12%and 93.38%,and Precision metrics of 90.85%and 93.41%across two distinct datasets.An increment in detection accuracy was discernible.For further practical applicability,we deploy semantic segmentation of rail surface defects,leveraging connected component processing techniques to distinguish varied defects within the same frame.By computing the actual defect length and area,our deep learning methodology presents results that offer intuitive insights for railway maintenance professionals.
基金the National Major Research Project(No.2018YFB0105601)the National Natural Science Foundation of China(No.21576257)+1 种基金the Natural Science Foundation-Liaoning United Fund(No.U 1508202)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB06050303).
文摘Bimetalic platinum-copper(Pt-Cu)alloy nanowires have emerged as a novel class of fuel cell electrocatalysts for oxygen reduction reaction(ORR)due to their intrinsic high catalytic activity and durability,but preparing such electrocatalysts with clean surface via facile method is still a challenge.Herein,PtCu alloy with nanowire networks(NWNs)structure is obtained by a simple modified polyol method accompanied with a salt-mediated self-assembly process in a water/ethylene glycol(EG)mixing media.The formation mechanism of PtCu NWNs including the morphological evolution and the relevant experimental parameters has been investigated systematically.We propose that a micro-interface in H2O-EG media formed with the assistance of disodium dihydrogen pyrophosphate(Na2H2P2O7)and its unique nature of coordinating with Pt^2+ or Cu^2+ play critical roles in the formation of NWNs.When tested as ORR catalyst,the PtCuNWNs/C exhibits much higher activity and durability than that of PtNWNs/C and commercial PtC,even exceeding the target of DOE in 2020.The excellent performance of PtCuNWNs/C could be attributed to the unique structure of NWNs with 2.4 nm ultrathin wavy nanowires and plentiful surface defects and the modified electronic effect caused by alloying with Cu atoms.
基金the Natural Science Foundation of Liaoning Province,China(20180550067)Liaoning Province Ministry of Education Scientific Study Project(2020LNZD06 and 2017LNQN11)University of Science and Technology Liaoning Talent Project Grants(601011507-20 and 601013360-17).
文摘Least squares support vector machine (LS-SVM) plays an important role in steel surface defects classification because of its high speed. However, the defect samples obtained from the real production line may be noise. LS-SVM suffers from the poor classification performance in the classification stage when there are noise samples. Thus, in the classification stage, it is necessary to design an effective algorithm to process the defects dataset obtained from the real production line. To this end, an adaptive weight function was employed to reduce the adverse effect of noise samples. Moreover, although LSSVM offers fast speed, it still suffers from a high computational complexity if the number of training samples is large. The time for steel surface defects classification should be as short as possible. Therefore, a sparse strategy was adopted to prune the training samples. Finally, since the steel surface defects classification belongs to unbalanced data classification, LSSVM algorithm is not applicable. Hence, the unbalanced data information was introduced to improve the classification performance. Comprehensively considering above-mentioned factors, an improved LS-SVM classification model was proposed, termed as ILS-SVM. Experimental results show that the new algorithm has the advantages of high speed and great anti-noise ability.
基金This work was supported by the National Natural Science Foundation of China(No.51674140)Natural Science Foundation of Liaoning Province,China(No.20180550067)+2 种基金Department of Education of Liaoning Province,China(Nos.2017LNQN11 and 2020LNZD06)University of Science and Technology Liaoning Talent Project Grants(No.601011507-20)University of Science and Technology Liaoning Team Building Grants(No.601013360-17).
文摘Defect classification is the key task of a steel surface defect detection system.The current defect classification algorithms have not taken the feature noise into consideration.In order to reduce the adverse impact of feature noise,an anti-noise multi-class classification method was proposed for steel surface defects.On the one hand,a novel anti-noise support vector hyper-spheres(ASVHs)classifier was formulated.For N types of defects,the ASVHs classifier built N hyper-spheres.These hyper-spheres were insensitive to feature and label noise.On the other hand,in order to reduce the costs of online time and storage space,the defect samples were pruned by support vector data description with parameter iteration adjustment strategy.In the end,the ASVHs classifier was built with sparse defect samples set and auxiliary information.Experimental results show that the novel multi-class classification method has high efficiency and accuracy for corrupted defect samples in steel surface.
基金financially supported by the Fundamental Research Funds for the Central Universities(No.FRF-TP-19-017A3)the National Natural Science Foundation of China(No.51874026)。
文摘Hypo-peritectic steels are widely used in various industrial fields because of their high strength,high toughness,high processability,high weldability,and low material cost.However,surface defects are liable to occur during continuous casting,which includes depression,longitudinal cracks,deep oscillation marks,and severe level fluctuation with slag entrapment.The high-efficiency production of hypo-peritectic steels by continuous casting is still a great challenge due to the limited understanding of the mechanism of peritectic solidification.This work reviews the definition and classification of hypo-peritectic steels and introduces the formation tendency of common surface defects related to peritectic solidification.New achievements in the mechanism of peritectic reaction and transformation have been listed.Finally,countermeasures to avoiding surface defects of hypo-peritectic steels duiring continuous casting are summarized.Enlightening certain points in the continuous casting of hypo-peritectic steels and the development of new techniques to overcome the present problems will be a great aid to researchers.
基金National Key R&D Program of China(Grant No.2019YFE0121300)Yancheng Hali Power Transmission and Intelligent Equipment Industrial Research Institute Project。
文摘Contour bevel gears have the advantages of high coincidence,low noise and large bearing capacity,which are widely used in automobile manufacturing,shipbuilding and construction machinery.However,when the surface quality is poor,the effective contact area between the gear mating surfaces decreases,affecting the stability of the fit and thus the transmission accuracy,so it is of great significance to optimize the surface quality of the contour bevel gear.This paper firstly analyzes the formation process of machined surface roughness of contour bevel gears on the basis of generating machining method,and dry milling experiments of contour bevel gears are conducted to analyze the effects of cutting speed and feed rate on the machined surface roughness and surface topography of the workpiece.Then,the surface defects on the machined surface of the workpiece are studied by SEM,and the causes of the surface defects are analyzed by EDS.After that,XRD is used to compare the microscopic grains of the machined surface and the substrate material for diffraction peak analysis,and the effect of cutting parameters on the microhardness of the workpiece machined surface is investigated by work hardening experiment.The research results are of great significance for improving the machining accuracy of contour bevel gears,reducing friction losses and improving transmission efficiency.
文摘This scientific paper presents a study investigating the effects of defects at the CdS/CIGS and CdS/SDL interfaces on the performance of CIGS solar cells. The objective of this study is to analyze the influence of defects at the interface between the CdS buffer layer and the CIGS absorber, as well as the surface defect layer (SDL), on CIGS solar cell performance. The study explores three key aspects: the impact of the conduction band offset (CBO) at the CdS/CIGS interface, the effects of interface defects and defect density on performance, and the combined influence of CBO and defect density at the CdS/ SDL and SDL/CIGS interfaces. For interface defects not exceeding 10<sup>13</sup> cm<sup>-2</sup>, we obtained a good efficiency of 22.9% when -0.1 eV analyzing the quality of CdS/SDL and SDL/CIGS junctions, it appears that defects at the SDL/CIGS interface have very little impact on the performances of the CIGS solar cell. By optimizing the electrical parameters of the CdS/SDL interface defects, we achieved a conversion efficiency of 23.1% when -0.05 eV < CBO < 0.05 eV.
基金Liaoning Revitalization Talents Program-Pan Deng Scholars(XLYC1802005)Liaoning Bai-QianWan Talents Program,the National Science Fund of Liaoning Province for Excellent Young Scholars,Science and Technology Innovative Talents Support Program of Shenyang(RC180166)+2 种基金Australian Research Council(ARC)through Discovery Early Career Researcher Award(DE150101306)Linkage Project(LP160100927)Faculty of Science Strategic Investment Funding 2019 of University of Newcastle,and CSIRO Energy,Australia.
文摘In the viewpoint of ammonia economy,electrochemical N2 reduction reaction(NRR)under mild condition is a very promising approach for sustainable development.By virtue of robust activity and low cost,transition-metalbased materials become one kind of the most attractive electrocatalysts in realizing ammonia synthesis to the industrial level.However,the investigation related to NRR electrocatalysts still mainly rely on costly substance or fabrication process,which greatly restrict their large-scale applications.In this work,a simple fabricated FeS2 electrode is adopted as NRR catalysts.The abundant surface defects due to the existence of Cr element,as well as the synergistic effect between FeS2 crystal planes provided excellent electrocatalytic performance with a high NH3 yield rate(11.5μg h^-1mg^-1 Fe)and Faradaic efficiency(14.6%)at-0.2 V vs.reversible hydrogen electrode(RHE)toward NRR under ambient conditions.The superior catalytic performance of such non-precious metal catalysts would strongly promote the application of NRR process industrially.
基金financially supported by the National Natural Science Foundation of China (21872065, 21763013, and 21503100)the Natural Science Foundation of Jiangxi Province (20192ACBL21027 and 20192BAB203007)the Project of Education Department of Jiangxi Province (GJJ170227)。
文摘Designing defect-engineered semiconductor heterojunctions can effectively promote the charge carrier separation.Herein,novel ceria(CeO2) quantum dots(QDs) decorated sulfur-doped carbon nitride nanotubes(SCN NTs) were synthesized via a thermal polycondensation coupled in situ depositionprecipitation method without use of template or surfactant.The structure and morphology studies indicate that ultrafine CeO2 QDs are well distributed inside and outside of SCN NTs offering highly dispersed active sites and a large contact interface between two components.This leads to the promoted formation of rich Ce^(3+) ion and oxygen vacancies as confirmed by XPS.The photocatalytic performance can be facilely modulated by the content of CeO2 QDs introduced in SCN matrix while bare CeO2 does not show activity of hydrogen production.The optimal catalyst with 10% of CeO2 loading yields a hydrogen evolution rate of 2923.8 μmol h-1 g-1 under visible light,remarkably higher than that of bare SCN and their physical mixtures.Further studies reveal that the abundant surface defects and the created 0 D/1 D junctions play a critical role in improving the separation and transfer of charge carriers,leading to superior solar hydrogen production and good stability.