The Ross-Amundsen sector is experiencing an accelerating warming trend and a more intensive advective influx of marine air streams.As a result,massive surface melting events of the ice shelf are occurring more frequen...The Ross-Amundsen sector is experiencing an accelerating warming trend and a more intensive advective influx of marine air streams.As a result,massive surface melting events of the ice shelf are occurring more frequently,which puts the West Antarctica Ice Sheet at greater risk of degradation.This study shows the connection between surface melting and the prominent intrusion of warm and humid air flows from lower latitudes.By applying the Climate Feedback-Response Analysis Method(CFRAM),the temporal surge of the downward longwave(LW)fluxes over the surface of the Ross Ice Shelf(RIS)and adjacent regions are identified for four historically massive RIS surface melting events.The melting events are decomposed to identify which physical mechanisms are the main contributors.We found that intrusions of warm and humid airflow from lower latitudes are conducive to warm air temperature and water vapor anomalies,as well as cloud development.These changes exert a combined impact on the abnormal enhancement of the downward LW surface radiative fluxes,significantly contributing to surface warming and the resultant massive melting of ice.展开更多
Laser surface melting(LSM) is a high-energy surface treatment that allows modification of the microstructure and surface properties of Mg alloys. In the present work, an attempt of LSM on magnesium alloy with liquid...Laser surface melting(LSM) is a high-energy surface treatment that allows modification of the microstructure and surface properties of Mg alloys. In the present work, an attempt of LSM on magnesium alloy with liquid nitrogen-assisted cooling(LNSC) was carried out to get the higher cooling rate and improve the surface properties. The experimental results were compared with those of Ar gas protection at room temperature. The samples after LSM with LNSC resulted in a thinner melted layer, a highly homogeneous, refined melted microstructure and formed a lot of worm-like nanocrystals and local amorphous structures. Microhardness of the melted layer with LNAC was improved to HV 90-148 as compared to HV 65-105 of the samples with Ar gas protection. The corrosion resistance of the melted layer in a 3.5% Na Cl solution(mass fraction) was improved because of the grain refinement and redistribution of β-Mg17Al12 phases following rapid quenching associated with the process.展开更多
Two types of composites were prepared with Al-4.5Cu alloy as a matrix using stir casting method.One was reinforced with 10wt.%of Si C and 2wt.%of MoS2.The other was reinforced with 10wt.%of Si C and 4wt.%of MoS2.Their...Two types of composites were prepared with Al-4.5Cu alloy as a matrix using stir casting method.One was reinforced with 10wt.%of Si C and 2wt.%of MoS2.The other was reinforced with 10wt.%of Si C and 4wt.%of MoS2.Their surfaces were remelted using a CO2 laser beam with an objective to study the influence of laser surface melting(LSM).The topography,microhardness,corrosion resistance and wear resistance of the laser melted surfaces were studied.Overall surface integrity after LSM was compared with as-cast surface.LSM enhanced the microhardness and wear resistance of the surface in each case.Porosity of the laser melted surface was low and corrosion resistance was high.Thus,LSM can be conveniently applied to enhancing the surface integrity of the aluminium composites.However,there is an optimum laser specific energy,around 38 J/m^2 in this study,for obtaining the best surface integrity.展开更多
The biocompatibility of orthopedic implants is closely related to their elastic modulus and surface properties.The objective of this study was to determine the effects of cold rolling,recrystallization and laser surfa...The biocompatibility of orthopedic implants is closely related to their elastic modulus and surface properties.The objective of this study was to determine the effects of cold rolling,recrystallization and laser surface melting(LSM)on the microstructure and mechanical properties of a biphase(α″+β)Ti-30Nb-4Sn alloy.X-ray diffraction(XRD)texture analysis of the cold-rolled substrate revealed the[302]α″//ND texture component,while analysis of the recrystallized substrate showed the[302]α″//ND and[110]α″//ND components.Theβ-phase texture could not be directly measured by XRD,but the presence of the[111]β//ND texture component was successfully predicted by considering the orientation relationship between theα″andβphases.Nanoindentation measurements showed that the elastic modulus of the cold-rolled substrate(63GPa)was lower than that of the recrystallized substrate(74GPa).Based on the available literature and the results presented here,it is suggested that this difference is caused by the introduction of crystal defects during cold deformation.The combined nanoindentation/EBSD analysis showed that the nanoindentation results are not affected by crystal orientation.LSM of the deformed alloy produced changes in hardness,elastic modulus and crystallographic texture similar to those produced by recrystallization heat treatment,creating a stiffness gradient between surface and substrate.展开更多
The modified analytic embedded-atom method and molecular dynamics simulations are applied to the investigation of the surface premelting and melting behaviours of the V(110) plane by calculating the interlayer relax...The modified analytic embedded-atom method and molecular dynamics simulations are applied to the investigation of the surface premelting and melting behaviours of the V(110) plane by calculating the interlayer relaxation, the layer structure factor and atomic snapshots in this paper. The results obtained indicate that the premelting phenomenon occurs on the V(110) surface at about 1800K and then a liquid-like layer, which approximately keeps the same thickness up to 2020K, emerges on it. We discover that the temperature 2020K the V(110) surface starts to melt and is in a completely disordered state at the temperature of 2140K under the melting point for the bulk vanadium.展开更多
Microhardness and wear resistance of different rnicrostructures formed by TIG (tungsten inert gas) surface melting and chromium surface alloying (using ferrochromium) of ADI (austempered ductile iron) were studi...Microhardness and wear resistance of different rnicrostructures formed by TIG (tungsten inert gas) surface melting and chromium surface alloying (using ferrochromium) of ADI (austempered ductile iron) were studied. Surface melting resulted in the formation of a ledeburitic structure in the melted zone, and this structure has a hardness up to 896 HV as compared to 360 HV in that of ADI. Moreover, chromium surface alloying resulted in the formation of different structures including: (1) a hypereutectic structure consisting of primary (Fe,Cr)7C3 carbides and a eutectic matrix of transformed austenite (into martensite and retained austenite), as also (Fe,Cr)7C3 carbides, with a hardness of 1078 HV; (2) a hypoeutectic structure consisting of the same eutectic along with transformed primary austenite, with a hardness of 755 HV; and (3) a ledeburitic structure with an acicular morphology and a hardness of 896 HV. The results also indicated that surface melting reduced the wear rate of the ADI by approximately 37%. Also, chromium surface alloying yielded a superior wear behavior and reduced the wear rate of the treated specimens by about 38% and 70%, depending on the structures formed.展开更多
Laser surface melting (LSM) was applied on a cast Ni–Al bronze (NAB), which was a crucial material for marine ship propellers. A 720 μm-thick LSM layer with fine equiaxed and dendritic microstructures was obtained. ...Laser surface melting (LSM) was applied on a cast Ni–Al bronze (NAB), which was a crucial material for marine ship propellers. A 720 μm-thick LSM layer with fine equiaxed and dendritic microstructures was obtained. After immersion for 30 days, the corrosion rate of cast NAB was reduced by 25% after LSM. Preferential corrosion occurred and deep corrosion pits appeared at α + κIII microstructure for the cast NAB. LSM NAB underwent general corrosion, and a much more protective film formed on the surface because of the homogenized microstructure. The mass loss of the cast NAB was approximately 2.1 times larger than that of LSM NAB after cavitation erosion (CE) in 3.5 wt.% NaCl solution for 5 h. For the two materials, the mechanical impact effect was dominantly responsible for CE damage. Therefore, the improved hardness and homogenized microstructure contributed to the improved CE resistance of LSM NAB. CE destructed the film, shifted the open circuit potential toward a more negative value, and raised the current density by an order of magnitude. Corrosion at the cast eutectoid microstructure and the dendrites of LSM NAB facilitates the degradation under the cavitation attack. CE-corrosion synergy was largely caused by corrosion-enhanced-CE.展开更多
Micro plasma arc surface melting of 0Cr19Ni9 shielded metal arc welding joint with a micro plasma arc welder produced a thin surface melted layer with a refined microstructure. The surface treatment changed the anod...Micro plasma arc surface melting of 0Cr19Ni9 shielded metal arc welding joint with a micro plasma arc welder produced a thin surface melted layer with a refined microstructure. The surface treatment changed the anodic polarization behavior in 0.5 mol/L H 2SO 4 solution. The polarization tests showed that for the as welded joint both the heat affected zone and the weld metal decreased in resistance to corrosion compared with the as received parent material while for the micro plasma arc surface melted joint the corrosion resistance increased significantly. This increase in corrosion resistance is attributed to the rapid solidification of the melted layer. Rapid solidification of the melted layer refines its microstructure, decreases its microsegregation, and inhibits the precipitation of chromium carbides at the grain boundaries.展开更多
Satellite-borne microwave radiometers provide essential measurements to study the surface melt state of ice sheets. Therefore, selecting suitable microwave radiometer data is critical to characterize the spatial distr...Satellite-borne microwave radiometers provide essential measurements to study the surface melt state of ice sheets. Therefore, selecting suitable microwave radiometer data is critical to characterize the spatial distribution of surface melt. In this study, we investigated the Greenland Ice Sheet and evaluated the usefulness, as climate indicators, of data acquired by microwave radiometers onboard the F17 satellite of the United States of America Defense Meteorological Satellite Program(DMSP) and the Soil Moisture and Ocean Salinity(SMOS) satellite of the European Space Agency. First, surface melt was simulated using the DMSP dataset as input for a brightness temperature threshold algorithm, the Microwave Emission Model of Layered Snowpacks(MEMLS2), and the SMOS dataset as input for the L-band Specific MEMLS(LS-MEMLS). For accuracy evaluation, the simulation results were then compared with surface melt estimates derived from air temperature measurements at Automatic Weather Stations and from ice surface temperature measurements from the Moderate Resolution Imaging Spectroradiometer(MODIS) satellite-borne instrument. Our results show that global(over Greenland) MEMLS2 simulation performance(overall accuracy 83%) was higher than that of LS-MEMLS(overall accuracy 78%). However, in southeastern Greenland, MEMLS2 omission error was markedly higher than that of LS-MEMLS, whereas LS-MEMLS could detect longer-lasting surface melt than MEMLS2. This analysis showed that DMSP-based surface melt simulations are more accurate than SMOS-based simulations, thereby providing a data selection reference for surface melt studies of the Greenland Ice Sheet.展开更多
The present work explored effects of laser surface melting on microstructure and surface topography evolution in AZ31B magnesium alloy.Thermokinetic effects experienced by the material during laser surface melting wer...The present work explored effects of laser surface melting on microstructure and surface topography evolution in AZ31B magnesium alloy.Thermokinetic effects experienced by the material during laser surface melting were simulated using a multiphysics finite element model.Microstructure and phase evolution were examined using scanning electron microscopy,X-ray diffraction,and electron back scatter diffraction.Surface topography was evaluated using white light interferometry.The interaction of surface melted samples with simulated body fluid was monitored by contact angle measurements and immersion studies up to 7 days.Laser surface melting led to formation of a refined microstructure with predominantly basal crystallographic texture.Concurrently,the amount ofβphase(Mg_(17)Al_(12))increased with an increase in the laser fluence.βphase preferentially decorated the cell boundaries.In terms of topography,the surface became progressively rougher with an increase in laser fluence.As a result,upon immersion in simulated body fluid,the laser surface melted samples showed an improved wettability,corrosion resistance,and precipitation of mineral having composition closer to the hydroxyapatite bone mineral compared to the untreated sample.展开更多
Energy balance at the glacier surface is important for understanding the impacts of climate change on glaciers. Here, we analyzed the characteristics of the glacier surface energy fluxes along with their contributions...Energy balance at the glacier surface is important for understanding the impacts of climate change on glaciers. Here, we analyzed the characteristics of the glacier surface energy fluxes along with their contributions to glacier melt on Bayi Ice Cap in Qilian Mountains by using a point-scale energy balance model. The half-hourly meteorological data from an automatic weather station(AWS) located on the glacier was used to drive the energy balance model. The model simulated results could accurately represent the mass-balance observations from the stake near the weather station during summer 2016. Our results showed the net radiation(86%) played an important role in the surface energy balance, and the contribution of the turbulent heat fluxes(14%) to the energy budget was relatively less important. A distinct behavior of energy balance, as compared to other continental glaciers in China(e.g., two adjacent glaciers Laohugou No. 12 Glacier and Qiyi Glacier), is the fact that a sustained period of positive turbulent latent flux exists on Bayi Ice Cap during August, causing faster melt rate in the month of August. Our study also presented the effect of frequent summer snowfall in slowing down surface melt by changing the surface albedo during the beginning of the melting season.展开更多
The effect of laser surface melting on the corrosion resistance of AZ31 Mg alloy in 0.1 M NaCl solution was investigated using different laser processing conditions(energy densities of 14 and 17 J cm^(-2)).Laser treat...The effect of laser surface melting on the corrosion resistance of AZ31 Mg alloy in 0.1 M NaCl solution was investigated using different laser processing conditions(energy densities of 14 and 17 J cm^(-2)).Laser treatment induced rough surfaces primarily composed of oxidized species of Mg.XPS analysis revealed that the surface concentration of Al increased significantly as a consequence of LSM.Electrochemical impedance spectroscopy showed that the laser treatment remarkably increased the polarization resistance of the AZ31 Mg alloy and induced a passive-like region of about 100 mV,as determined by potentiodynamic polarization.Analysis of the results obtained provide solid evidence that within the immersion times used in this study,LSM treatment increased the corrosion resistance of AZ31 Mg alloy under open circuit conditions and anodic polarization.展开更多
An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO2 laser as a heat generating source. X-ray diffraction ...An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO2 laser as a heat generating source. X-ray diffraction (XRD) was used to identify the phases. Microstructure and properties of laser melted layer of AZ31B magnesium alloy were observed or tested by means of optical microscope (OM), scanning electron microscope (SEM), micro-hardness equipment and electrochemical corrosion equipment etc. The results show that the microstructure of laser melted layer becomes finer significantly and uniform. Compared with the substrate, the content of β-Mg17 Al12 phase of melted layer decreases comparatively. Microhardness of the laser melted layer is improved to 50 -95 HV0. 05 as compared to 40 -45 HV0.05 of the AZ31B Mg alloy substrate. The results of electrochemical corrosion show that the corrosion resistance of laser surface melted layer has been improved.展开更多
In order to reduce the cost of the austenitic stainless steels(ASSs),the expensive austenite former(nickel) is often substituted by manganese.However,manganese is generally seen to have a detrimental effect on the cor...In order to reduce the cost of the austenitic stainless steels(ASSs),the expensive austenite former(nickel) is often substituted by manganese.However,manganese is generally seen to have a detrimental effect on the corrosion resistance.In the present study,the feasibility of laser surface modification of a lean-alloyed ASS(FeCrMn) for enhancing pitting corrosion resistance was investigated.Laser surface modification of FeCrMn was successfully achieved by a 2.3 kW high power diode laser(HPDL).Cyclic polarization tests for FeCrMn after laser surface modification in 3.5% NaCl solution at 25 ℃ were performed by using a potentiostat.The pitting resistance of the laser-modified specimens was found to be significantly improved as reflected by the noble shift in pitting potential.This could be attributed to redistribution of manganese sulphide leading to a more homogenous and refined microstructure.Pitting corrosion resistance of the laser-treated FeCrMn followed by subsequent citric acid passivation was found to be further improved as reflected by the noble shift in pitting potential to 0.18 V.展开更多
The margin of the Greenland ice sheet has undergone rapid changes over the past decade as a result of the thinning, acceleration, and retreat of many fast-flowing tidewater outlet glaciers. Satellite observations show...The margin of the Greenland ice sheet has undergone rapid changes over the past decade as a result of the thinning, acceleration, and retreat of many fast-flowing tidewater outlet glaciers. Satellite observations show that three major tidewater outlet glaciers in Greenland retreated between 2000 and 2005, with synchronous increases in flow speed, causing a deficit in ice sheet mass budget and the potential for sea level rise. In this study, we investigated whether this acceleration was related to surface melt processes, and found that both flow speed and positive degree day (PDD) anomalies of the three glaciers varied together, indicating a causal relationship. Jakobshavn Isbr^e had lower flow speeds before 2000, during which PDD anomalies were negative, except for modest warming in 1993 and 1995. From 1999-2000, during which it is thought a threshold was passed, the flow speed of the glacier started to increase. However, the two glaciers in east Greenland showed a delayed response. Abrupt warming occurred in the vicinity of the two glaciers around 2001, but flow speed did not increase until 2003 for the Helheim Glacier, and until 2004 for the Kangerdlugssuaq Glacier. Furthermore, the two eastern glaciers switched to a deceleration mode more quickly than Jakobshavn lsbr^e. The observed differences in both acceleration and deceleration among the glaciers suggest that the relationship between surface melt and outlet glacier dynamics is not simple but complex.展开更多
Surface melt has great impacts on the Greenland Ice Sheet (GrlS) mass balance and thereby has become the focus of significant GrlS research in recent years. The production, transport, and release processes of surfac...Surface melt has great impacts on the Greenland Ice Sheet (GrlS) mass balance and thereby has become the focus of significant GrlS research in recent years. The production, transport, and release processes of surface meltwater are the keys to understanding the poten- tial impacts of the GrlS surface melt. These hydrological processes can elucidate the following scientific questions: How much melt- water is produced atop the GrlS? What are the characteristics of the meltwater-formed supraglacial hydrological system? How does the meltwater influence the GrlS motion? The GrlS supraglacial hydrology has a number of key roles and yet continues to be poorly understood or documented. This paper summarizes the current understanding of the GrlS surface melt, emphasizing the three essential supraglacial hydrological processes: (1) meltwater production: surface melt modeling is an important approach to acquire surface melt information, and areas, depths, and volumes of supraglacial lakes extracted from remotely sensed imagery can also provide surface melt information; (2) meltwater transport: the spatial distributions of supraglacial lakes, supraglacial sarams, moulins, and crevasses demonstrate the characteristics of the supraglacial hydrological system, revealing the meltwater transport process; and (3) meltwater release: the release of meltwater into the englacial and the subglacial ice sheet has important but undetermined impacts on the GrlS motion. The correlation between surface runoff and the GrlS motion speed is employed to understand these influences.展开更多
Pine Island Glacier(PIG),the largest glacier in the Amundsen Sea Embayment of West Antarctica,has contributed to over a quarter of the observed sea level rise around Antarctica.In recent years,multiple observations ha...Pine Island Glacier(PIG),the largest glacier in the Amundsen Sea Embayment of West Antarctica,has contributed to over a quarter of the observed sea level rise around Antarctica.In recent years,multiple observations have confirmed its continuous retreat,ice flow acceleration and profound surface melt.Understanding these changes is crucial for accurately monitoring ice mass discharge and future Antarctic contributions to sea level rise.Therefore,it is essential to investigate the complex interactions between these variables to comprehend how they collectively affect the overall stability of the intricate PIG system.In this study,we utilized high-resolution remote sensing data and deep learning method to detect and analyze the spatio-temporal variations of surface melt,ice shelf calving,and ice flow velocity of the PIG from 2015 to 2023.We explored the correlations among these factors to understand their long-term impacts on the glacier's stability.Our findings reveal a retreat of 26.3 km and a mass loss of 1001.6 km^(2) during 2015-2023.Notably,extensive surface melting was observed,particularly in the 2016/2017 and 2019/2020 melting seasons.Satellite data vividly illustrate prolonged and intense melting periods,correlating with a significant retreat in the glacier's terminus position in 2019/2020.Furthermore,the comprehensive analysis of surface melting and the cumulative retreat of the ice shelf from 2017 to 2020 on the PIG shows atemporal relationship with subsequent significant changes in ice fow velocity,ranging from 10.9 to 12.2 m d^(-1),with an average acceleration rate of 12%.These empirical findings elucidate the intricate relationship among surface melt,ice flow velocity,and consequential glacier dynamics.A profound understanding of these interrelationships holds paramount importance in glacier dynamic changes and modeling,providing invaluable insights into potential glacier responses to global climate change.展开更多
There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of...There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of heat transfer.Under certain assumptions,the present study builds a mathematical model of melting heat transport nanofluid flow of chemical reactions and joule heating.Nanofluid flow is described by higher-order partial non-linear differential equations.Incorporating suitable similarity transformations and dimensionless parameters converts these controlling partial differential equations into the non-linear ordinary differential equations and resulting system of nonlinear equations is established.Plotted graphic visualizations in MATLAB allow for an indepth analysis of the effects of distinguishing factors on fluid flow.Innovative applications of the findings include electronic cooling,heat transfer,reaction processes,nuclear reactors,micro heat pipes,and other related fields.If the exponential index increases,however,the thermal profile becomes worse.By comparing the current findings to those already published in the literature for this particular example,we find that they are highly congruent,therefore validating the present work.Every one of the numerical findings exhibits asymptotic behavior by meeting the specified boundary conditions.展开更多
Laser surface melting has been applied on a commercially pure Mg. The microstructure and texture modifications encountered in the surface layers were carefully investigated by using electron backscattered diffraction ...Laser surface melting has been applied on a commercially pure Mg. The microstructure and texture modifications encountered in the surface layers were carefully investigated by using electron backscattered diffraction (EBSD) technique. Due to the melting followed by rapid solidification and cooling, a layer having graded microstructures and texture formed. At the bottom of the melted layer, the solidified Mg grains have an elongated shape with a 〈0001 〉 basal fibre texture nearly parallel to sample normal direction, while equiaxed grains were observed in the top melted layer having a much weaker basal fibre texture. Solidification twinning and deformation twinning were found in the vicinity of the melt/substrate interface where the Mg grains grow larger due to the heating. In addition, no epitaxial type grain growth was observed at the melt/substrate interface.展开更多
Solar evaporation based on plasmonic metal nanoparticles(MNPs)is emerging as a promising technology.However,the fine structure of MNPs is unstable,and both the high temperature generated by intensive light and corrosi...Solar evaporation based on plasmonic metal nanoparticles(MNPs)is emerging as a promising technology.However,the fine structure of MNPs is unstable,and both the high temperature generated by intensive light and corrosive ions in water could damage them.The performance will decline after recycling and long-time usage.To address these issues,we adopted a sponge-templating method for preparing sandwich-like nanoplates with the gold nanoparticles(Au NPs)confined in reduced graphene oxide(rGO)nanosheets.Due to the confinement effect,both the surface melting and ion diffusion were suppressed.The solar evaporator based on the sandwich-like nanoplates showed a high solar-vapor conversion efficiency of 85.2%under a high light intensity of 10 kW.After 30 times recycle of seawater desalination,the conversion efficiency scarcely decreased.These sandwich-like nanoplates with enhanced thermal and chemical stability of Au NPs are promising in the practical application of seawater desalination.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 42075028 and 42222502)the Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) (Grant SML2021SP302)
文摘The Ross-Amundsen sector is experiencing an accelerating warming trend and a more intensive advective influx of marine air streams.As a result,massive surface melting events of the ice shelf are occurring more frequently,which puts the West Antarctica Ice Sheet at greater risk of degradation.This study shows the connection between surface melting and the prominent intrusion of warm and humid air flows from lower latitudes.By applying the Climate Feedback-Response Analysis Method(CFRAM),the temporal surge of the downward longwave(LW)fluxes over the surface of the Ross Ice Shelf(RIS)and adjacent regions are identified for four historically massive RIS surface melting events.The melting events are decomposed to identify which physical mechanisms are the main contributors.We found that intrusions of warm and humid airflow from lower latitudes are conducive to warm air temperature and water vapor anomalies,as well as cloud development.These changes exert a combined impact on the abnormal enhancement of the downward LW surface radiative fluxes,significantly contributing to surface warming and the resultant massive melting of ice.
基金Project(51305292)supported by the National Natural Science Foundation of ChinaProject(2014-024)supported by Shanxi Scholarship Council of China
文摘Laser surface melting(LSM) is a high-energy surface treatment that allows modification of the microstructure and surface properties of Mg alloys. In the present work, an attempt of LSM on magnesium alloy with liquid nitrogen-assisted cooling(LNSC) was carried out to get the higher cooling rate and improve the surface properties. The experimental results were compared with those of Ar gas protection at room temperature. The samples after LSM with LNSC resulted in a thinner melted layer, a highly homogeneous, refined melted microstructure and formed a lot of worm-like nanocrystals and local amorphous structures. Microhardness of the melted layer with LNAC was improved to HV 90-148 as compared to HV 65-105 of the samples with Ar gas protection. The corrosion resistance of the melted layer in a 3.5% Na Cl solution(mass fraction) was improved because of the grain refinement and redistribution of β-Mg17Al12 phases following rapid quenching associated with the process.
文摘Two types of composites were prepared with Al-4.5Cu alloy as a matrix using stir casting method.One was reinforced with 10wt.%of Si C and 2wt.%of MoS2.The other was reinforced with 10wt.%of Si C and 4wt.%of MoS2.Their surfaces were remelted using a CO2 laser beam with an objective to study the influence of laser surface melting(LSM).The topography,microhardness,corrosion resistance and wear resistance of the laser melted surfaces were studied.Overall surface integrity after LSM was compared with as-cast surface.LSM enhanced the microhardness and wear resistance of the surface in each case.Porosity of the laser melted surface was low and corrosion resistance was high.Thus,LSM can be conveniently applied to enhancing the surface integrity of the aluminium composites.However,there is an optimum laser specific energy,around 38 J/m^2 in this study,for obtaining the best surface integrity.
基金supported by the Brazilian Funding Agencies CAPES(Federal Agency for the Support and Improvement of Higher Education)(Grant No.33003017)CNPq(National Council for Scientific and Technological Development)(Grant No.233006/2014-1)FAPESP(Sao Paulo Research Foundation)(Grant No.2011/19982-2)
文摘The biocompatibility of orthopedic implants is closely related to their elastic modulus and surface properties.The objective of this study was to determine the effects of cold rolling,recrystallization and laser surface melting(LSM)on the microstructure and mechanical properties of a biphase(α″+β)Ti-30Nb-4Sn alloy.X-ray diffraction(XRD)texture analysis of the cold-rolled substrate revealed the[302]α″//ND texture component,while analysis of the recrystallized substrate showed the[302]α″//ND and[110]α″//ND components.Theβ-phase texture could not be directly measured by XRD,but the presence of the[111]β//ND texture component was successfully predicted by considering the orientation relationship between theα″andβphases.Nanoindentation measurements showed that the elastic modulus of the cold-rolled substrate(63GPa)was lower than that of the recrystallized substrate(74GPa).Based on the available literature and the results presented here,it is suggested that this difference is caused by the introduction of crystal defects during cold deformation.The combined nanoindentation/EBSD analysis showed that the nanoindentation results are not affected by crystal orientation.LSM of the deformed alloy produced changes in hardness,elastic modulus and crystallographic texture similar to those produced by recrystallization heat treatment,creating a stiffness gradient between surface and substrate.
基金supported by the National Natural Science Foundation of China (Grant No 50671035)the Scientific Research Fund of Hunan Provincial Education Department of China (Grant No 07C445)the Grant of the 11th Five-year Plan for Key Construction Academic Subject of Hunan Province,China
文摘The modified analytic embedded-atom method and molecular dynamics simulations are applied to the investigation of the surface premelting and melting behaviours of the V(110) plane by calculating the interlayer relaxation, the layer structure factor and atomic snapshots in this paper. The results obtained indicate that the premelting phenomenon occurs on the V(110) surface at about 1800K and then a liquid-like layer, which approximately keeps the same thickness up to 2020K, emerges on it. We discover that the temperature 2020K the V(110) surface starts to melt and is in a completely disordered state at the temperature of 2140K under the melting point for the bulk vanadium.
文摘Microhardness and wear resistance of different rnicrostructures formed by TIG (tungsten inert gas) surface melting and chromium surface alloying (using ferrochromium) of ADI (austempered ductile iron) were studied. Surface melting resulted in the formation of a ledeburitic structure in the melted zone, and this structure has a hardness up to 896 HV as compared to 360 HV in that of ADI. Moreover, chromium surface alloying resulted in the formation of different structures including: (1) a hypereutectic structure consisting of primary (Fe,Cr)7C3 carbides and a eutectic matrix of transformed austenite (into martensite and retained austenite), as also (Fe,Cr)7C3 carbides, with a hardness of 1078 HV; (2) a hypoeutectic structure consisting of the same eutectic along with transformed primary austenite, with a hardness of 755 HV; and (3) a ledeburitic structure with an acicular morphology and a hardness of 896 HV. The results also indicated that surface melting reduced the wear rate of the ADI by approximately 37%. Also, chromium surface alloying yielded a superior wear behavior and reduced the wear rate of the treated specimens by about 38% and 70%, depending on the structures formed.
基金This research was financially supported by Fundamental Research Funds for the Central Universities of P.R.China(Nos.B210203049,B210204005 and B210203049)Natural Science Foundation of Jiangsu Province(Nos.BK20191161 and BK 20180984)National Natural Science Foundation of China(Nos.51601058,51879089 and 52005228).
文摘Laser surface melting (LSM) was applied on a cast Ni–Al bronze (NAB), which was a crucial material for marine ship propellers. A 720 μm-thick LSM layer with fine equiaxed and dendritic microstructures was obtained. After immersion for 30 days, the corrosion rate of cast NAB was reduced by 25% after LSM. Preferential corrosion occurred and deep corrosion pits appeared at α + κIII microstructure for the cast NAB. LSM NAB underwent general corrosion, and a much more protective film formed on the surface because of the homogenized microstructure. The mass loss of the cast NAB was approximately 2.1 times larger than that of LSM NAB after cavitation erosion (CE) in 3.5 wt.% NaCl solution for 5 h. For the two materials, the mechanical impact effect was dominantly responsible for CE damage. Therefore, the improved hardness and homogenized microstructure contributed to the improved CE resistance of LSM NAB. CE destructed the film, shifted the open circuit potential toward a more negative value, and raised the current density by an order of magnitude. Corrosion at the cast eutectoid microstructure and the dendrites of LSM NAB facilitates the degradation under the cavitation attack. CE-corrosion synergy was largely caused by corrosion-enhanced-CE.
文摘Micro plasma arc surface melting of 0Cr19Ni9 shielded metal arc welding joint with a micro plasma arc welder produced a thin surface melted layer with a refined microstructure. The surface treatment changed the anodic polarization behavior in 0.5 mol/L H 2SO 4 solution. The polarization tests showed that for the as welded joint both the heat affected zone and the weld metal decreased in resistance to corrosion compared with the as received parent material while for the micro plasma arc surface melted joint the corrosion resistance increased significantly. This increase in corrosion resistance is attributed to the rapid solidification of the melted layer. Rapid solidification of the melted layer refines its microstructure, decreases its microsegregation, and inhibits the precipitation of chromium carbides at the grain boundaries.
基金supported by the National Natural Science Foundation of China (Grant no. 42122047)the National Key Research and Development Program of China (Grant no. 2018YFC1406103)the Basic Fund of the Chinese Academy of Meteorological Science (Grant no. 2021Z006)。
文摘Satellite-borne microwave radiometers provide essential measurements to study the surface melt state of ice sheets. Therefore, selecting suitable microwave radiometer data is critical to characterize the spatial distribution of surface melt. In this study, we investigated the Greenland Ice Sheet and evaluated the usefulness, as climate indicators, of data acquired by microwave radiometers onboard the F17 satellite of the United States of America Defense Meteorological Satellite Program(DMSP) and the Soil Moisture and Ocean Salinity(SMOS) satellite of the European Space Agency. First, surface melt was simulated using the DMSP dataset as input for a brightness temperature threshold algorithm, the Microwave Emission Model of Layered Snowpacks(MEMLS2), and the SMOS dataset as input for the L-band Specific MEMLS(LS-MEMLS). For accuracy evaluation, the simulation results were then compared with surface melt estimates derived from air temperature measurements at Automatic Weather Stations and from ice surface temperature measurements from the Moderate Resolution Imaging Spectroradiometer(MODIS) satellite-borne instrument. Our results show that global(over Greenland) MEMLS2 simulation performance(overall accuracy 83%) was higher than that of LS-MEMLS(overall accuracy 78%). However, in southeastern Greenland, MEMLS2 omission error was markedly higher than that of LS-MEMLS, whereas LS-MEMLS could detect longer-lasting surface melt than MEMLS2. This analysis showed that DMSP-based surface melt simulations are more accurate than SMOS-based simulations, thereby providing a data selection reference for surface melt studies of the Greenland Ice Sheet.
文摘The present work explored effects of laser surface melting on microstructure and surface topography evolution in AZ31B magnesium alloy.Thermokinetic effects experienced by the material during laser surface melting were simulated using a multiphysics finite element model.Microstructure and phase evolution were examined using scanning electron microscopy,X-ray diffraction,and electron back scatter diffraction.Surface topography was evaluated using white light interferometry.The interaction of surface melted samples with simulated body fluid was monitored by contact angle measurements and immersion studies up to 7 days.Laser surface melting led to formation of a refined microstructure with predominantly basal crystallographic texture.Concurrently,the amount ofβphase(Mg_(17)Al_(12))increased with an increase in the laser fluence.βphase preferentially decorated the cell boundaries.In terms of topography,the surface became progressively rougher with an increase in laser fluence.As a result,upon immersion in simulated body fluid,the laser surface melted samples showed an improved wettability,corrosion resistance,and precipitation of mineral having composition closer to the hydroxyapatite bone mineral compared to the untreated sample.
基金supported by the National Natural Science Foundation of China(Grant Nos.41401073,41671029 and 41401040)the National Key Research and Development Programs of China(Grant No.2017YFC0504306)the Specialized Research Fund for the Doctoral Program of Higher Education(Grant No.20130211120035)
文摘Energy balance at the glacier surface is important for understanding the impacts of climate change on glaciers. Here, we analyzed the characteristics of the glacier surface energy fluxes along with their contributions to glacier melt on Bayi Ice Cap in Qilian Mountains by using a point-scale energy balance model. The half-hourly meteorological data from an automatic weather station(AWS) located on the glacier was used to drive the energy balance model. The model simulated results could accurately represent the mass-balance observations from the stake near the weather station during summer 2016. Our results showed the net radiation(86%) played an important role in the surface energy balance, and the contribution of the turbulent heat fluxes(14%) to the energy budget was relatively less important. A distinct behavior of energy balance, as compared to other continental glaciers in China(e.g., two adjacent glaciers Laohugou No. 12 Glacier and Qiyi Glacier), is the fact that a sustained period of positive turbulent latent flux exists on Bayi Ice Cap during August, causing faster melt rate in the month of August. Our study also presented the effect of frequent summer snowfall in slowing down surface melt by changing the surface albedo during the beginning of the melting season.
基金the State Research Agency(Ministry of Science and Innovation of Spain),the Spanish National Research Council(CSIC)and the European Regional Development Fund(ERDF)for the support under the project RYC2019-027006-I(AEI/FEDER/UE)。
文摘The effect of laser surface melting on the corrosion resistance of AZ31 Mg alloy in 0.1 M NaCl solution was investigated using different laser processing conditions(energy densities of 14 and 17 J cm^(-2)).Laser treatment induced rough surfaces primarily composed of oxidized species of Mg.XPS analysis revealed that the surface concentration of Al increased significantly as a consequence of LSM.Electrochemical impedance spectroscopy showed that the laser treatment remarkably increased the polarization resistance of the AZ31 Mg alloy and induced a passive-like region of about 100 mV,as determined by potentiodynamic polarization.Analysis of the results obtained provide solid evidence that within the immersion times used in this study,LSM treatment increased the corrosion resistance of AZ31 Mg alloy under open circuit conditions and anodic polarization.
基金The research is supported by the Shanxi Natural Science Foundation (No. 2008011044).
文摘An attempt has been made to improve the surface properties of AZ31B magnesium alloy through solid solution hardening and refinement of microstructures using a CO2 laser as a heat generating source. X-ray diffraction (XRD) was used to identify the phases. Microstructure and properties of laser melted layer of AZ31B magnesium alloy were observed or tested by means of optical microscope (OM), scanning electron microscope (SEM), micro-hardness equipment and electrochemical corrosion equipment etc. The results show that the microstructure of laser melted layer becomes finer significantly and uniform. Compared with the substrate, the content of β-Mg17 Al12 phase of melted layer decreases comparatively. Microhardness of the laser melted layer is improved to 50 -95 HV0. 05 as compared to 40 -45 HV0.05 of the AZ31B Mg alloy substrate. The results of electrochemical corrosion show that the corrosion resistance of laser surface melted layer has been improved.
基金supported by research grant from the Science and Technology Development Fund(FDCT)of MacauSAR(Grant No.070/2011/A3)
文摘In order to reduce the cost of the austenitic stainless steels(ASSs),the expensive austenite former(nickel) is often substituted by manganese.However,manganese is generally seen to have a detrimental effect on the corrosion resistance.In the present study,the feasibility of laser surface modification of a lean-alloyed ASS(FeCrMn) for enhancing pitting corrosion resistance was investigated.Laser surface modification of FeCrMn was successfully achieved by a 2.3 kW high power diode laser(HPDL).Cyclic polarization tests for FeCrMn after laser surface modification in 3.5% NaCl solution at 25 ℃ were performed by using a potentiostat.The pitting resistance of the laser-modified specimens was found to be significantly improved as reflected by the noble shift in pitting potential.This could be attributed to redistribution of manganese sulphide leading to a more homogenous and refined microstructure.Pitting corrosion resistance of the laser-treated FeCrMn followed by subsequent citric acid passivation was found to be further improved as reflected by the noble shift in pitting potential to 0.18 V.
基金Supported by the National Natural Science Foundation of China (No.40906096)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry (No. Y0GQ031001)
文摘The margin of the Greenland ice sheet has undergone rapid changes over the past decade as a result of the thinning, acceleration, and retreat of many fast-flowing tidewater outlet glaciers. Satellite observations show that three major tidewater outlet glaciers in Greenland retreated between 2000 and 2005, with synchronous increases in flow speed, causing a deficit in ice sheet mass budget and the potential for sea level rise. In this study, we investigated whether this acceleration was related to surface melt processes, and found that both flow speed and positive degree day (PDD) anomalies of the three glaciers varied together, indicating a causal relationship. Jakobshavn Isbr^e had lower flow speeds before 2000, during which PDD anomalies were negative, except for modest warming in 1993 and 1995. From 1999-2000, during which it is thought a threshold was passed, the flow speed of the glacier started to increase. However, the two glaciers in east Greenland showed a delayed response. Abrupt warming occurred in the vicinity of the two glaciers around 2001, but flow speed did not increase until 2003 for the Helheim Glacier, and until 2004 for the Kangerdlugssuaq Glacier. Furthermore, the two eastern glaciers switched to a deceleration mode more quickly than Jakobshavn lsbr^e. The observed differences in both acceleration and deceleration among the glaciers suggest that the relationship between surface melt and outlet glacier dynamics is not simple but complex.
基金supported by the Scholarship Award for Excellent Doctoral Student granted by Ministry of Education and the Graduate Education Innovation Project of Jiangsu Province(CXLX12-0039)
文摘Surface melt has great impacts on the Greenland Ice Sheet (GrlS) mass balance and thereby has become the focus of significant GrlS research in recent years. The production, transport, and release processes of surface meltwater are the keys to understanding the poten- tial impacts of the GrlS surface melt. These hydrological processes can elucidate the following scientific questions: How much melt- water is produced atop the GrlS? What are the characteristics of the meltwater-formed supraglacial hydrological system? How does the meltwater influence the GrlS motion? The GrlS supraglacial hydrology has a number of key roles and yet continues to be poorly understood or documented. This paper summarizes the current understanding of the GrlS surface melt, emphasizing the three essential supraglacial hydrological processes: (1) meltwater production: surface melt modeling is an important approach to acquire surface melt information, and areas, depths, and volumes of supraglacial lakes extracted from remotely sensed imagery can also provide surface melt information; (2) meltwater transport: the spatial distributions of supraglacial lakes, supraglacial sarams, moulins, and crevasses demonstrate the characteristics of the supraglacial hydrological system, revealing the meltwater transport process; and (3) meltwater release: the release of meltwater into the englacial and the subglacial ice sheet has important but undetermined impacts on the GrlS motion. The correlation between surface runoff and the GrlS motion speed is employed to understand these influences.
基金This work was supported by the National Natural Science Foundation of China(42376246)the Key Research and Development Project of Guangxi(GuikeAB24010046)the Joint Funds of the National Natural Science Foundation of China(U2268217)。
文摘Pine Island Glacier(PIG),the largest glacier in the Amundsen Sea Embayment of West Antarctica,has contributed to over a quarter of the observed sea level rise around Antarctica.In recent years,multiple observations have confirmed its continuous retreat,ice flow acceleration and profound surface melt.Understanding these changes is crucial for accurately monitoring ice mass discharge and future Antarctic contributions to sea level rise.Therefore,it is essential to investigate the complex interactions between these variables to comprehend how they collectively affect the overall stability of the intricate PIG system.In this study,we utilized high-resolution remote sensing data and deep learning method to detect and analyze the spatio-temporal variations of surface melt,ice shelf calving,and ice flow velocity of the PIG from 2015 to 2023.We explored the correlations among these factors to understand their long-term impacts on the glacier's stability.Our findings reveal a retreat of 26.3 km and a mass loss of 1001.6 km^(2) during 2015-2023.Notably,extensive surface melting was observed,particularly in the 2016/2017 and 2019/2020 melting seasons.Satellite data vividly illustrate prolonged and intense melting periods,correlating with a significant retreat in the glacier's terminus position in 2019/2020.Furthermore,the comprehensive analysis of surface melting and the cumulative retreat of the ice shelf from 2017 to 2020 on the PIG shows atemporal relationship with subsequent significant changes in ice fow velocity,ranging from 10.9 to 12.2 m d^(-1),with an average acceleration rate of 12%.These empirical findings elucidate the intricate relationship among surface melt,ice flow velocity,and consequential glacier dynamics.A profound understanding of these interrelationships holds paramount importance in glacier dynamic changes and modeling,providing invaluable insights into potential glacier responses to global climate change.
文摘There is a strong relationship between analytical and numerical heat transfers due to thermodynamically anticipated findings,making thermo-dynamical modeling an effective tool for estimating the ideal melting point of heat transfer.Under certain assumptions,the present study builds a mathematical model of melting heat transport nanofluid flow of chemical reactions and joule heating.Nanofluid flow is described by higher-order partial non-linear differential equations.Incorporating suitable similarity transformations and dimensionless parameters converts these controlling partial differential equations into the non-linear ordinary differential equations and resulting system of nonlinear equations is established.Plotted graphic visualizations in MATLAB allow for an indepth analysis of the effects of distinguishing factors on fluid flow.Innovative applications of the findings include electronic cooling,heat transfer,reaction processes,nuclear reactors,micro heat pipes,and other related fields.If the exponential index increases,however,the thermal profile becomes worse.By comparing the current findings to those already published in the literature for this particular example,we find that they are highly congruent,therefore validating the present work.Every one of the numerical findings exhibits asymptotic behavior by meeting the specified boundary conditions.
基金support of the Top Discipline Plan for Mechanical Engineering of Shanghai Municipal Education Commission (YLJX12-2)partially supported by the Special Foundation of the Shanghai Science and Technology Committee for Nano-Materials Research (No. 1052nm05000)the National Natural Science Foundation of China (Nos. 51101096, 51271121 and 51002093)
文摘Laser surface melting has been applied on a commercially pure Mg. The microstructure and texture modifications encountered in the surface layers were carefully investigated by using electron backscattered diffraction (EBSD) technique. Due to the melting followed by rapid solidification and cooling, a layer having graded microstructures and texture formed. At the bottom of the melted layer, the solidified Mg grains have an elongated shape with a 〈0001 〉 basal fibre texture nearly parallel to sample normal direction, while equiaxed grains were observed in the top melted layer having a much weaker basal fibre texture. Solidification twinning and deformation twinning were found in the vicinity of the melt/substrate interface where the Mg grains grow larger due to the heating. In addition, no epitaxial type grain growth was observed at the melt/substrate interface.
基金This work was supported by the National Natural Science Foundation of China(51732011,21431006,21761132008,81788101 and 11227901)the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(21521001)+2 种基金the Key Research Program of Frontier Sciences,CAS(QYZDJ-SSW-SLH036)the National Basic Research Program of China(2014CB931800)the Users with Excellence and Scientific Research Grant of Hefei Science Center of CAS(2015HSC-UE007).This work was partially carried out at the USTC Center for Micro and Nanoscale Research and Fabrication.
文摘Solar evaporation based on plasmonic metal nanoparticles(MNPs)is emerging as a promising technology.However,the fine structure of MNPs is unstable,and both the high temperature generated by intensive light and corrosive ions in water could damage them.The performance will decline after recycling and long-time usage.To address these issues,we adopted a sponge-templating method for preparing sandwich-like nanoplates with the gold nanoparticles(Au NPs)confined in reduced graphene oxide(rGO)nanosheets.Due to the confinement effect,both the surface melting and ion diffusion were suppressed.The solar evaporator based on the sandwich-like nanoplates showed a high solar-vapor conversion efficiency of 85.2%under a high light intensity of 10 kW.After 30 times recycle of seawater desalination,the conversion efficiency scarcely decreased.These sandwich-like nanoplates with enhanced thermal and chemical stability of Au NPs are promising in the practical application of seawater desalination.