Isotope Tracking of Surface Water Groundwater Interaction in the Beninese Part of the Iullemeden Aquifer System

The Kandi basin is located in northeast Benin (West Africa). This study is focused on the estimation of water fluxes exchanged between the river Niger (and its tributaries) and the transboundary Iullemeden Aquifer System. In that framework, an innovative approach based on the application of the Bayesian Mixing Model (MixSIAR) analysis on water isotopes (oxygen-18, deuterium and tritium) was performed. Moreover, to assess the relevance of the model outputs, Pearson’s correlation and Principal Component Analysis (PCA) have been done. A complex relationship between surface water and groundwater has been found. Sixty percent (60%) of groundwater samples are made of more than 70% river water and rainwater;while 31.25% of surface water samples are made of about 84% groundwater. To safeguard sustainable water resources for the well-being of the local communities, surface water and groundwater must be managed as a unique component in the Kandi basin.

Linking bacterial and archaeal community dynamics to related hydrological,geochemical and environmental characteristics between surface water and groundwater in a karstic estuary

Subterranean estuaries(STEs)are characterized by the mixing of terrestrial fresh groundwater and seawater in coastal aquifers.Although microorganisms are important components of coastal groundwater ecosystems and play critical roles in biogeochemical transformations in STEs,limited information is available about how their community dynamics interact with hydrological,geochemical and environmental characteristics in STEs.Here,we studied bacterial and archaeal diversities and distributions with 16S rRNA-based Illumina MiSeq sequencing technology between surface water and groundwater in a karstic STE.Principal-coordinate analysis found that the bacterial and archaeal communities in the areas where algal blooms occurred were significantly separated from those in other stations without algal bloom occurrence.Canonical correspondence analysis showed that nutrients and salinity can explain the patterns of bacterial and archaeal community dynamics.The results suggest that hydrological,geochemical and environmental characteristics between surface water and groundwater likely control the bacterial and archaeal diversities and distributions in STEs.Furthermore,we found that some key species can utilize terrestrial pollutants such as nitrate and ammonia in STEs,indicating that these species(e.g.,Nitrosopumilus maritimus,Limnohabitans parvus and Simplicispira limi)may be excellent candidates for in situ degradation/remediation of coastal groundwater contaminations concerned with the nitrate and ammonia.Overall,this study reveals the coupling relationship between the microbial communities and hydrochemical environments in STEs,and provides a perspective of in situ degradation/remediation for coastal groundwater quality management.

Regime of subsurface water resources in shallow groundwater agricultural fields

In shallow groundwater agricultural fields, water exchanges between groundwater and soil water happen frequently and intensively. This paper analyzes the regale of subsurface water during the growing period of winter wheat from October 1998 to June 1999 in Yucheng area. During an 8- month period of winter wheat growth. 456.66 mm of evapotranspiration and 75.61mm of groundwater evaporation were measured with a new model lysimeter. Groundwater at 1.60-2.40 m depth of water tables contributed 16.6% of total water used by winter wheat under natural. precipitation and irrigation treatment.The results showed that a significant proportion of field evapotranspiration was supplied by groundwater evaporation, whereas the role of groundwater evaporation was not considered during irrigation, leading to soil water percolation into groundwater.In order to improve water use efficiency of crops, some measures were put forward in the paper. Effective use of groundwater and soil water is a key countermeasure for sustainable development of water-saving agriculture and Water resource exploitation in Yucheng area

Impact of transferred water on the hydrochemistry and water quality of surface water and groundwater in Baiyangdian Lake,North China

The hydrochemical composition of surface water and groundwater is a key parameter for understanding the evolution of water and its quality.In particular,little is known about the impact of transferred water on surface water and groundwater.In this study,Baiyangdian Lake was selected as a typical area for extensive groundwater exploration and surface water transfer in the North China Plain.Surface water and groundwater samples were sampled in dry/wet seasons and then analyzed before/after the water transfer,respectively.Generally,surface water and groundwater are extensively hydrologically connected based on hydrochemical evidence.It was found that the hydrochemical composition of the shallow groundwater is affected by the surface water and that the water quality of the deep groundwater is stable.However,inter-aquifer recharge processes from the shallow groundwater to the deep groundwater existed in the anthropogenic region impacted with high nitrate-ion concentrations.Also,the hydrochemical composition of the surface water and groundwater was dominated by rock-weathering and evaporation-precipitation processes.Due to the existence of the deep vadose zone in the alluvial fan,Na^(+)was exchanged into soil matrices during the leakage of the surface water.In addition,the transferred water resulted in surface water with good quality,and it also played as an important recharge source to groundwater.As the most important water resource for irrigation and drinking,deep groundwater should be paid more attention in the alluvial fan with frequent water transfer and extensive groundwater exploration.

Hydro-geochemistry of groundwater and surface water in Dschang town(West Cameroon):Alkali and alkaline-earth elements ascertain lithological and anthropogenic constraints

The study aims to identify a suitable site for open and bore well in a farmhouseusing ground magnetic survey in south India.It also aims to define depth to granitoid and structural elements which traverse the selected area.Magnetic data(n=84)measured,processed and interpreted as qualitative and quantitatively.The results of total magnetic intensities indicate that the area is composed of linear magnetic lows trending NE-SW direction and circular to semi-circular causative bodies.The magnetic values ranged from-137 nT to 2345 nT with a mean of 465 nT.Reduction to equator shows significant shifting of causative bodies in the southern and northern directions.Analytical signal map shows exact boundary of granitic bodies.Cosine directional filter has brought out structural element trending NE-SW direction.Results of individual profile brought to light structurally weak zone between 90 m and 100 m in all the profile lines.Sudden decrease of magnetic values from 2042 nT to 126 nT noticed in profile line 6 between 20 m and 30 m indicates fault occurrence.Magnetic breaks obtained from these maps were visualized,interpreted and identified two suitable sites for open and bore well.Radially averaged power spectrum estimates depth of shallow and deep sources in 5 m and 50 m,respectively.Euler method has also been applied to estimate depth of granitoid and structural elements using structural indexes 0,1,2,and 3 and found depth ranges from<10 m to>90 m.Study indicates magnetic method is one of the geophysical methods suitable for groundwater exploration and site selection for open and borewells.

Linear Alkylbenzene Sulfonates in the Groundwater and Surface Waters： Ergene Basin Case Study

Ergene Basin is one of the most important industrial centers due to the geographical location in Turkey. Uncontrolled and rapidly increasing industrialization brings together a large number of environmental problems in the basin. In this study, pollution was investigated in the water samples taken at time intervals and different parts of groundwater and surface water resources located within Ergene Basin by methylene blue anionic surfactants （MBAS） analysis method. Turbidity, temperature, pH, electrical conductivity （EC）, concentrations of total P and linear alkylbenzene sulfonates （LAS） were simultaneously determined in the investigated water resources. The results were compared with the Turkish Water Pollution Control Regulation specified in the Quality Criteria of the Inland Water Resources according to their class. The total P and LAS concentrations of surface waters are generally higher than groundwater. In terms of LAS concentrations, the groundwater is Ⅰ-Ⅱ class and the surface water is Ⅱ-Ⅳ class.

Determining the groundwater basin and surface watershed boundary of Dalinuoer Lake in the middle of Inner Mongolian Plateau,China and its impacts on the ecological environment

The surface watershed and groundwater basin have fixed recharge scale,which are not only the basic unit for hydrologic cycle research but also control the water resources formation and evolution and its corresponding eco-geological environment pattern.To accurately identify the boundary of the surface watershed and groundwater basin is the basis for properly understanding hydrologic cycle and conducting the water balance analysis at watershed scale in complicated geologic structure area,especially when the boundary are inconsistent.In this study,the Dalinuoer Lake located in the middle of the Inner Mongolian Plateau which has complicated geologic structure was selected as the representative case.Based on the multidisciplinary comprehensive analysis of topography,tectonics,hydrogeology,groundwater dynamics and stable isotopes,the results suggest the following:(1)The surface watershed ridge and groundwater basin divide of Dalinuoer Lake are inconsistent.The surface watershed was divided into two separate groundwater systems almost having no groundwater exchange by the SW-NE Haoluku Anticlinorium Fault which has obvious water-blocking effect.The surface drainage area of Dalinuoer Lake is 6139 km^(2).The northern regional A is the Dalinuoer Lake groundwater system with an area of 4838 km^(2),and the southern regional B is the Xilamulun Riverhead groundwater system with an area of 1301 km^(2).(2)The groundwater in the southern of regional A and the spring-feeding river are the important recharge sources for the Dalinuoer Lake,and it has greater recharge effects than the northern Gonggeer River system.(3)It is speculated that the trend of Haoluku Anticlinorium Fault is the boundary of the westerlies and the East Asian summer Monsoon(EASM)climate systems,which further pinpoints the predecessor’s understanding of this boundary line.At present,the Dalinuoer Lake watershed is proved to have gone through a prominent warming-drying trend periods,which leads to the precipitation reduction,temperature rise,human activities water usage increasement.So the hydrological cycle and lake eco-environment at watershed scale will still bound to be change,which may pose the potential deterioration risk on the suitability of fish habitat.The results can provide basic support for better understanding water balance evolution and lake area shrinkage cause as well as the ecological protection and restoration implementation of Dalinuoer Lake watershed.

Trace Metal Levels of Groundwater,Surface Water and Sediments in Kinsevere Industrial Zone and Its Surroundings,Southeastern Democratic Republic of Congo

Arsenic,barium,bismuth,cadmium,cesium,chromium,cobalt,copper,iron,lead,manganese,molybdenum,nickel,strontium,thallium,tungsten,uranium,vanadium,and zinc concentrations were investigated in forty-two groundwater samples,twenty-four surface water and six surface sediment samples in Kinsevere industrial zone and its surroundings in February and march 2017,January,February and March 2018 to evaluate the potential human health risk.Chemical analyses were carried out by using ICP-SF-MS(Inductively Coupled Plasma-Sector Field Mass Spectrometry,Thermo Scientific Element II).The trace metals were detected at various concentrations in all the analyzed samples.Pb,Mn and Fe concentrations exceeded the European Union acceptable maximum limits for water intended for human consumption in 4.76%,28.57%and 61.90%of the groundwater samples,respectively and in 0%,50%and 100%of the surface water samples,respectively.As,Cr,Cu and Ni concentrations exceeded the recommended lower sediment quality guideline values in 33.33%,50%,83.33%and 83.33%of the surface sediment samples,respectively.All those elevated trace metal concentrations in the groundwater,surface water and sediments represent a risk for the health of local population as well as for aquatic organisms.

Correlation Analysis between Surface Water of Gusong River and Coastal Shallow Groundwater

According to the measured groundwater pollution concentration at two monitoring sections of Gusong River coast,adopting progressive dislocation correlation analysis method,correlation between surface water of Gusong River and groundwater pollution was analyzed.Result showed that propagation time of pollutant between river water and groundwater was longer.According to the water level observation data,river water level was＆gt;1 m higher than groundwater table.The groundwater infiltration parameter was determined through the field permeability test data.The Dupuit formula was used to calculate recharge and discharge relationship between river surface water and groundwater.It was obtained that the daily average recharge capacity of right-bank river water to groundwater was 3 m3,and pollution of river surface water had very small influence on groundwater.Using MATLAB software for data analysis and processing,regression equation was established.The chloride as correlation analysis example,results showed that groundwater chloride had the maximum correlation with observation well distance,and correlation with time and monitoring value of surface water was very small.The linear relationship between surface water and groundwater was not obvious.

Evaluation of Interaction between Surface Water and Groundwater in the South of Hanoi City by Stable Isotope Technique

The δ18O and δ2H stable isotope techniques for studying properties of groundwater and surface help us to understand more clearly about the distribution and movement of groundwater in the South of Hanoi area. There were 68 water samples from the studying area and analyzed by a Liquid Water Isotope Analyzer (LWIA-24D). The stable isotope values of the groundwater from Pleistocene aquifers were range from -3.21‰ to -9.55‰ δ18O and -35.32‰ to -67.44‰ δ2H;rainwater from -8.18‰ to -4.13‰ δ18O and -61.19‰ to -17.93‰ δ2H;Red river water from -7.51‰ to -5.29‰ δ18O and -51.60‰ to -38.99‰ δ2H. Based on stable isotope characteristics, the results show that there was a relationship between surface water and groundwater in the South of Hanoi city. It is that groundwater recharges for river water in the dry season with 74%, and in the rainfall season groundwater is recharged from river with 87%.

Hydrogeological Investigations of Groundwater and Surface Water Interactions in the Berg River Catchment, Western Cape, South Africa

The Berg River Catchment based in the Western Cape Province,South Africa services the greater Cape Town area with water,subsequent to supplying the vast agricultural activities that exist in the middle and the lower reaches.This study thus investigates the hydrogeochemical interactions between surface and groundwater in the Berg River Catchment with the aim of establishing trends and transfer of constituents between the surface and groundwater systems,investigates the role that geology plays in water chemistry as well as identifies the geochemical processes controlling surface and groundwater chemistry in the catchment.This study was carried out using three types of research designs namely i)experimental research design;ii)field research design and meta-analysis research design.Furthermore,the study made use of hydrochemical data ranging from 2003 to 2013 obtained from the National Water Monitoring Database owned and maintained by the Department of Water and Sanitation and data that were sampled in 2016 by authors and analyzed using the ICP-MS Technique Ground Water Chart,Arc-GIS and Geosoft(Oasis Montaj)were further employed to model the data.The results indicated that:i)in the Upper Berg there is not much interaction and transfer of constituents between surface and groundwater;ii)the Middle Berg,however,indicated a degree of interaction with the sharing of constituents between the two water systems and iii)the Lower Berg indicated only NaCl water type also noting that the area situated near the river mouth whereby there is the mixing of river and seawater.

Environmental Isotopic Characterization of Groundwater and Surface Water in Northeast Missan Province,South Iraq

The present work studies the environmental isotopes assess groundwater characteristics of the different parts of the main aquifer in the northeast Missan Province in south of Iraq. Water samples of groundwater and surface water were collected for two dry and wet seasons during the water year of 2011-2012. The study shows that most of the groundwater in the aquifer falls above the global meteoric water line, and all the samples fall below the Mediterranean meteoric water line, indicating that these samples are a mixture of two water types. The tritium content of these samples supports this conclusion. The overall conclusion of this study indicates that there are two sources of groundwater recharge in the studied area： the ephemeral streams （Teeb and Dewerge） and major precipitation sources. According to the tritium levels at or below one tritium unit （TU） obtained from the water, supply wells are highly confined or ＂not vulnerable＂. Overall, the 3^H results imply that recent recharge has taken place during the last four to five decades. In the recharge area, the high tritium content in the southern part of the Teeb area suggests that the recharge originates from rapid infiltration of surface runoff. Therefore, the groundwater resources in the study area should be protected from contamination, because it will influence the aquifer in a relatively short period of time if any contamination enters the recharge areas of the aquifer.

Characteristics of the main inorganic nitrogen accumulation in surface water and groundwater of wetland succession zones

Based on the observation of a complete hydrological year from June 2014 to May 2015, the temporal and spatial variations of the main inorganic nitrogen (MIN, referring to NO3^--N, NO2^--N, NH4^+-N) in surface water and groundwater of the Li River and the Yuan River wetland succession zones are analyzed. The Li River and the Yuan River are located in agricultural and non-agricultural areas, and this study focus on the influence of surface water level and groundwater depth and precipitation on nitrogen pollution. The results show that NO3^--N in surface water accounts for 70%-90% of MIN, but it does not exceed the limit of national drinking water surface water standard. Groundwater is seriously polluted by NH4^+-N.Based on the groundwater quality standard of NH4^+-N, the groundwater quality in the Li River exceeds Class III water standard throughout the year, and the exceeding months' proportion of Yuan River reaches 58.3%. Compared with the Yuan River, MIN in groundwater of the Li River shows significant temporal and spatial variations owing to the influence of agricultural fertilization. The correlation between the concentrations of MIN and surface water level is poor, while the fitting effect of quadratic correlation between NH4^+-N concentration and groundwater depth is the best (R^2=0.9384), NO3^--N is the next (R^2=0.5128), NO2^--N is the worst (R^2=0.2798). The equation of meteoric water line is δD =7.83δ^18O+12.21, indicating that both surface water and groundwater come from atmospheric precipitation. Surface infiltration is the main cause of groundwater NH4^+-N pollution. Rainfall infiltration in non-fertilization seasons reduces groundwater nitrogen pollution, while rainfall leaching farming and fertilization aggravate groundwater nitrogen pollution.

Synthetic Detergents (Surfactants) and Organochlorine Pesticide Signatures in Surface Water and Groundwater of Greater Kolkata, India

An assessment on the concentration of surfactants and pesticides of chlorinated hydrocarbon group in surface and groundwater, is made from Greater Kolkata located in the Western Ganga Delta, one of the largest urban agglomerate in Asia. Concentration of both anionic synthetic detergents and organochlorine pesticide resi-dues analysed from 54 and 19 sampling stations covering groundwater and surface water sources respec-tively, are generally found to be within the tolerance limit for human consumption. The concentration of synthetic detergent ranges from 0.084 to 0.425mg/l. Residues of organochlorine pesticides are analysed from different sources like tanks, lakes, rivers and groundwater. Lindane (0.01-0.43μg/l) and DDT (0.03-0.65 μg/l) are the most widely detected pesticide residues. Howerer, the two have not exceeded the limits for drinking anywhere. High value of aldrin and dieldrin (0.9μg/l) is obtained in the river Hugli at Barakpur-Seoraphuli, 20 km north of Kolkata. Likewise high value of Heptachloreis detected in a canal water sample at Palta (0.05 μg/l), a suburban area. Seasonally, the pesticide concentration in surface water is maximum during winter due to their higher application and minimum during monsoon. In groundwater, however, this relationship is reverse due to higher infiltration of surface water during monsoon.

Estimating interaction between surface water and groundwater in a permafrost region of the northern Tibetan Plateau using heat tracing method

Understanding the interaction between groundwater and surface water in permafrost regions is essential to study flood frequencies and river water quality, especially in the high latitude/altitude basins. The application of heat tracing method,based on oscillating streambed temperature signals, is a promising geophysical method for identifying and quantifying the interaction between groundwater and surface water. Analytical analysis based on a one-dimensional convective-conductive heat transport equation combined with the fiber-optic distributed temperature sensing method was applied on a streambed of a mountainous permafrost region in the Yeniugou Basin, located in the upper Heihe River on the northern Tibetan Plateau. The results indicated that low connectivity existed between the stream and groundwater in permafrost regions.The interaction between surface water and groundwater increased with the thawing of the active layer. This study demonstrates that the heat tracing method can be applied to study surface water-groundwater interaction over temporal and spatial scales in permafrost regions.

Physico-Chemical and Bacterial Characteristics of Groundwater and Surface Water Quality in the Lagbe Town: Treatment Essays with <i>Moringa oleifera</i>Seeds

The river water and groundwater from Lagbe town in Benin Republic were collected and analyzed for physical, chemical and microbiological parameters. The surface water samples were treated with alum, Moringa oleifera seeds powder and the combination of alum and Moringa oleifera seeds. The jar-test essays were carried out with two water samples at initial turbidities 7.2 NTU and 14.4 NTU. The water samples analyzed are fairly mineralized (conductivity varies between 166 and 687 μS/cm), enough soft and contain the nitrate (104 mg/L for W4 sample). They are greatly polluted by pathogenic microorganisms such as Escherichia coli, Klebsiella, Enterococcus, Vibrio, Serratia. The optimal dosages of Moringa are 96 mg/L and 80 mg/L respectively. We have observed a reduction of 60% of turbidity and a substantial remove of all pathogenic microorganisms after water treatment with Moringa oleifera seeds. For the combination treatment, 93% of initial turbidity and 92% of initial concentration of organic matter in the sample E2 were eliminated. The pH remained almost constant during the treatment.

Laboratory Validation of an Integrated Surface Water— Groundwater Model

The hydrodynamic surface water model DIVAST has been extended to include horizontally adjacent groundwater flows. This extended model is known as DIVAST-SG (Depth Integrated Velocities and Solute Transport with Surface Water and Groundwater). After development and analytical verification the model was tested against a novel laboratory set-up using open cell foam (60 pores per inch—ppi) as an idealised porous media representing a riverbank. The Hyder Hydraulics Laboratory at Cardiff University has a large tidal basin that was adapted to simulate a surface water—groundwater scenario using this foam, and used to validate the DIVAST-SG model. The properties of the laboratory set-up were measured and values were determined for hydraulic conductivity (permeability) and porosity, evaluated as 0.002 m/s and 75% respectively. Lessons learnt in this initial experimentation were used to modify the flume construction and improve the experimental procedure, with further experimentation being undertaken of both water level variations and tracer movement. Valuable data have been obtained from the laboratory experiments, allowing the validity of the numerical model to be assessed. Modifications to the input file to include representations of the joints between the foam blocks allowed a good fit between the observed and modelled water levels. Encouraging correlation was observed in tracer experiments using Rhodamine-WT dye between the observed exit points of the tracer from the foam, and the modelled exit points with time.

Impact of Surface Water and Groundwater Pollutions on Irrigated Soil, El Minia Province, Northern Upper Egypt

Current research has been focused on heavy metals pollution in surface water and groundwater and effect on irrigated soil from El Minia Province, north Upper Egypt. Concentration of heavy metals (e.g., As, Co, Hg, Ni, Se, Cd and Cr) in surface water, groundwater and irrigated soil samples is most significantly affected by leachate of many pollutants as the factories, agricultural activities, urban and natural processes. Microbiological parameters and microscopic investigations are revealed that some localities are common by micro-organisms, which are unsuitable for drinking waters.

Conjunctive Use Modeling of Groundwater and Surface Water

In this study, conjunctive use of surface and groundwater in the Maraghe area was investigated. The objective function used for the overall conjunctive use model was maximizing sum of relative yields of crops in the command area. Declining groundwater levels was selected as criteria of groundwater limitation. The simulation was done for four years and began by a dry year to normal year. GMS software was used to simulate groundwater aquifer. In this model, different well discharges in the study area for different scenarios were used and decline in groundwater level at the end of simulation time was calculated. In order to model surface water and calculate the objective function, a program in Visual Basic was developed. Two types of scenario, annual and seasonal, were defined by specifying the ratio of the allocation of surface water to that of groundwater pumping at the crop level for entire irrigated area. For different scenarios, declining groundwater levels and objective functions were calculated. With attention to maximize objective function that the water table drawdown is not greater than the limited criterion, the best scenario was obtained. In annual scenarios, The results showed that in scenario of 75 - 25 (75% surface water to 25% groundwater), the purpose function rate was 12.2 and water table draw down was 2.6, which was lower than allowable limitation. Therefore, it was chosen as a selective scenario. Also in seasonal scenarios, The best scenario was chosen 100-40-60 (the percentage of surface water share in spring, summer and fall & winter respectively), which amount of purpose function was 12.57 and the water table draw down was around 3 m at the end of the simulation period.