The development of active and durable non-Pt electrocatalysts with well-defined microstructure is of great importance to both fuel cell applications and fundamental understanding.Herein,we report a surface-doping proc...The development of active and durable non-Pt electrocatalysts with well-defined microstructure is of great importance to both fuel cell applications and fundamental understanding.Herein,we report a surface-doping process to prepare well-defined W-doped Pd nanocubes with a tunable atomic percent of W from 0 to 1.5%by using the Pd nanocubes as seeds.The obtained 1.2%W-doped Pd nanocubes/C exhibited greatly enhanced electrocatalytic performance toward oxygen reduction reaction in alkaline media,presenting an enhancement factor of 4.7 in specific activity and 2.5 in mass activity compared to the activity of a commercial Pt/C catalyst.The downshift of the d-band center due to a negative charge transfer from W to Pd intrinsically accounts for such improvement in activity by weakening the adsorption of reaction intermediates.Also,the 1.2%W-doped Pd nanocubes/C showed superior catalytic properties for the ethanol oxidation reaction,showing great potential for serving as a bifunctional electrocatalyst in fuel cells.展开更多
We demonstrate a high-efficiency and high-power quasi-three-level laser based on a trapezoidal composite slab architecture with a 270 μm-thick Yb-doping surface. The design of a surface-doped slab architecture,temper...We demonstrate a high-efficiency and high-power quasi-three-level laser based on a trapezoidal composite slab architecture with a 270 μm-thick Yb-doping surface. The design of a surface-doped slab architecture,temperature effects, laser oscillator model, and laser oscillator experiments with a surface-doped slab as a laser host medium have been presented. By theoretical calculation, the temperature rise in the surface-doped slab is only one seventh of that in the bulk-doped slab at the same maximum pump power of 30 kW. Finally, in the laser oscillator experiments, an output energy of 21.6 J is obtained when the pump energy is 48 J with a repetition rate of 5 Hz and a pulse width of 1 ms. The optical-optical efficiency is 45%.展开更多
基金supported by Collaborative Innovation Center of Suzhou Nano ScienceTechnology, MOST of China (2014CB932700)+5 种基金the National Natural Science Foundation of China (21603208, 21573206)Key Research Program of Frontier Sciences of the CAS (QYZDBSSW-SLH017)Anhui Provincial Key Scientific and Technological Project (1704a0902013)Major Program of Development Foundation of Hefei Center for Physical Science and Technology (2017FXZY002)Fundamental Research Funds for the Central UniversitiesCAS-TWAS president’s fellowship~~
文摘The development of active and durable non-Pt electrocatalysts with well-defined microstructure is of great importance to both fuel cell applications and fundamental understanding.Herein,we report a surface-doping process to prepare well-defined W-doped Pd nanocubes with a tunable atomic percent of W from 0 to 1.5%by using the Pd nanocubes as seeds.The obtained 1.2%W-doped Pd nanocubes/C exhibited greatly enhanced electrocatalytic performance toward oxygen reduction reaction in alkaline media,presenting an enhancement factor of 4.7 in specific activity and 2.5 in mass activity compared to the activity of a commercial Pt/C catalyst.The downshift of the d-band center due to a negative charge transfer from W to Pd intrinsically accounts for such improvement in activity by weakening the adsorption of reaction intermediates.Also,the 1.2%W-doped Pd nanocubes/C showed superior catalytic properties for the ethanol oxidation reaction,showing great potential for serving as a bifunctional electrocatalyst in fuel cells.
基金funded by the Science and Technology on Solid-State Laser Laboratory
文摘We demonstrate a high-efficiency and high-power quasi-three-level laser based on a trapezoidal composite slab architecture with a 270 μm-thick Yb-doping surface. The design of a surface-doped slab architecture,temperature effects, laser oscillator model, and laser oscillator experiments with a surface-doped slab as a laser host medium have been presented. By theoretical calculation, the temperature rise in the surface-doped slab is only one seventh of that in the bulk-doped slab at the same maximum pump power of 30 kW. Finally, in the laser oscillator experiments, an output energy of 21.6 J is obtained when the pump energy is 48 J with a repetition rate of 5 Hz and a pulse width of 1 ms. The optical-optical efficiency is 45%.
