QUANTITATIVE ANALYTIC TECHNOLOGY OF ULTRA-HARDNESS AND WEAR RESISTENT SURFACING MATERIAL

Mathematical models between surfacing welding properties of C, Cr, Mo, V, W alloy system and encode factors of alloy additives are established by test methods of advanced trial optimizing technology and computer assistant design (CAD). They help to draw unitary functions and binary isoclines diagrams through which the influence of encode factorial linearity, nonlinear effect and factors interaction of alloy additives on the performances of surfacing welding can be analyzed directly and quantitatively. Meanwhile, the performances of deposited metal can also be predicted according to the content of alloy additives.

Use of New Water Soluble Surface Film－Forming Material to Reduce Ammonia Loss from Water Solution

A new water soluble surfaCe film-forming material was developed and its effect on reducing ammonia volatilization from an alkaline solution was investigated in laborstory. Results showed that the new film formed by the material was not only more effective in reducing ammonia loss than any other films tested but also much cheaper. The optimum amount of addition of the new film-forming material was about 10times the theoretical amount to form a monomolecular film. Under the experimental conditions, the new film could effectively depress the ammonia volatilization for at least 6 days. The cumulative ammonia loss rates for different films were fitted to a simple logistic equation, and some important parameters such as the cumulative loss, and the maximum and average volatilization rates were calculated. The effect of different films could be, therefore, compared quantitatively, indicating the new film was most effective in depressing ammonia volatilization.

Model Estimation of Volatilization of Ammonia Appliedwith Surface Film-Forming Material

Greenhouse experiments were conducted to determine the ammonia volatilization loss with or withoutapplication of surface film-forming material (SFFM). Ammonia volatilization loss was estimated by the modeldeveloped by Jayaweera and Mikkelsen. The results showed that the model could estimate and predict wellammonia volatilization loss also in case of SFFM addition. There was an emended factor B introduced tothe model calculation when SFPM was used. Simulated calculation showed that the effect of factor B onNHa loss was obvious. The value of B was governed by SFFM and the environmental conditions. Sensitivityanalysis suggested that pH was the main factor coatrolling NH3 volatilization loss from the floodwater.

A Simulation Study on Effect of Surface Film-Forming Material on Water Evaporation

A greenhouse experiment was conducted to investigate the effect of surface film-forming material (SFFM), a mixture of 16-18-octadecanols by emulsification, on water evaporation. Air-dried soil with distilled water was incubated firstly for 7 days to reestablish soil biological activity and then for another 7 days after treated with SFFM at rates of 0, 1, 2, 4, 6 and 8 g m-2, respectively. Everyday during the 7-day incubation after addition of SFFM, water losses due to evaporation were ~measured by an electronic balance. The rate of water evaporation with the addition of SFFM was reduced significantly compared with the control treatment and the effectiveness of SFFM on water evaporation reduced with time. According to the equation expressions of the effect of SFFM on water evaporation, the half-life of electiveness of SFFM on water evaporation was introduced and calculated to analyze quantitative relationship between the effectiveness of SFFM on water evaporation and the addition rate of SFFM. The calculated half-life increased with the addition rate of SFFM and the confidence of the calculated values of the half-life was high, suggesting that the half-life of effectiveness of SFFM on water evaporation could be described quantitatively and may be helpful for ameliorating application method of SFFM and screening surface-film forming materials in order to improve nitrogen fertilizer use efficiency in flooded rice fields.

Research on Effect of Adding Nanomaterial to Propellant on Gun Barrel

The barrel lifes of three small caliber rifles were tested by using the propellant with nanomaterial and the standard propellant respectively. The test results show that the service life increases observably due to adding nanomaterial to the propellant. Then, the influence of the nanomaterial on the tube was researched by splitting the two barrels tested and detecting their inner surfaces. It was found that the erosion of the barrel bore is reduced observably by using the propellant with nanomaterial. And it makes the volume and the size of the gun chamber change less. Therefore, the barrel life can be prolonged by adding the nanomaterial in the propellant.

Universality and Specificity of Fractal Dimension of Fractured Surfaces in Materials

After calculation on the fracture angles under various conditions of specific surface energies with different symmetry operations of rotation, the complicated behavior of dependence of fractal dimension on the structure of crystal is shown. It is found that the crack propagates along the weakest crystal plane no matter what the direction of the maximum stress is if the anisotropy is sufficiently strong; and then, the fractal dimension of the fractured surfaces might be determined by the approximate fractal structure already existed in the material. Specificity of the fractal dimension of fractured surfaces would be easy to appear in this case. Reversely, the crack propagates along the direction of the maximum stress no matter what direction of the weakest crystal plane is if the anisotropy is sufficiently weak. Universality of the fractal dimension of fractured surfaces would be possible to appear in this case. In many real materials, universality and specificity of the materials are associated. The fractal dimension measured may more or less be influenced by the structure of materials and it shows its universality through the specificity of materials.

Carbonation Resistance of Hybrid NanoSiO_(2) Modified Cementitious Surface Protection Materials

Hybrid nanoSiO_(2) (HNS) modified cement pastes were explored as a kind of surface protection material (SPM).The carbonation resistance and mechanical properties of SPMs coated samples were tested.Thermogravimetric analysis (TGA),X-ray diffraction (XRD),scanning electron microscope (SEM),and mercury intrusion porosimetry (MIP) were further employed to evaluate the chemical composition and microstructure characteristics of SPM.Besides,thermodynamic modeling was adopted to simulate the changes in the phase assemblages of SPM under the carbonation process.The results showed that SPM with 1 wt% HNS could effectively enhance the carbonation resistance.The incorporation of HNS could densify the microstructure and refine the pore structure.Moreover,the thaumasite can be stable at ambient temperature with the addition of HNS,which is beneficial to maintain alkalinity under the carbonation process.

Experimental Study on Material Surface Modification of Tool Steel

This paper presents the surface temperature behavior of M42 high-speed tool steel samples during N+ implantation in an industrialized GLZ-100 metal-ion implantation machine. A detail study has been made on the parameters of N+ implantation. Optimized technical parameters have been presented. The microhardness of the sample surface implanted under these parameters has been increased by a factor of 2.3, and the wear-resistance has been improved by about 5.4 times. The research on the mechanism of surface modification of M42 steel by nitrogen ion implantation has also been made.

Surface Modification of Ceramic Materials Using Excimer Laser

Changes of surface morphology following XeCI excimer laser irradiation were investigated for three engineering ceramic materials (Al2O3, Al2O3-SiC nanocomposite and Si3N4). Al2O3 and AI2O3-SiC nanocomposite samples exhibit a smooth rapid melt layer on the surface, and the formation of the metastabfe γ-Al2Oa was observed. A silicon-rich layer on the surface was formed after laser irradiation of Si3N4. The toughness K1c of the materials was measured by the indentation fracture method. After laser irradiation, the toughness of Al2O3, Al2O3-SiC nanocomposite and Si3N4 was improved to various degrees: Al2O3-SiC nanocomposite, 60% (max.); AI203, 40% (max.); Si3N4, 12% (max.).

Analysis on Tribological Properties of Potentially New Friction Material with Response Surface Method

The tribological properties of newly developed friction material were evaluated by statistical analysis of the major affecting factors.The material for investigation was non-metallic friction material synergistically reinforced with aramid fibre and CaSO 4 whisker,which was developed for hoisting applications in coal mine.The response surface method（RSM）was employed to analyze the material performances affected by the independent and interactive effect of the factors under the normal working condition and severe working condition,respectively.Results showed that under the normal working condition,the newly developed material exhibited stable tribological properties which were insensitive to the test conditions.While under the severe working condition,the sliding velocity was the most dominant factor affecting the friction coefficient.Additionally,compared to the commercially available material,the modified material showed superior wear resistance and thermal stability.

Dynamics of a Rotating Sphere on Free Surface of Vibrated Granular Materials

We investigate the rotational dynamics of a low-density sphere on the free surface of a vertically vibrated granular material（VGM）. The dynamical behavior of the sphere is influenced by the external energy input from an electromagnetic shaker which is proportional to ε,where ε is equal to the ratio between the square of the dimensionless acceleration Γ and the square of the vibration frequency f of the container. Empirical results reveal that as the VGM transits from local-to-global convection,an increase in ε generally corresponds to an increase in the magnitudes of the rotational ω（RS） and translational v（CM） velocities of the sphere, an increase in the observed tilting angle θ（bed） of the VGM bed, and a decrease in the time t（wall） it takes the sphere to roll down the tilted VGM bed and hit the container wall. During unstable convection, an increase in ε results in a sharp decrease in the sphere＇s peak and mean ω（RS）,and a slight increase in t（wall）.For the range of ε values covered in this study, the sphere may execute persistent rotation, wobbling or jamming, depending on the vibration parameters and the resulting convective flow in the system.

Non-Thermal Atmospheric Plasma:Can it Be Taken as a Common Solution for the Surface Treatment of Dental Materials?

This study aimed to evaluate the surface roughness and wetting properties of various dental prosthetic materials after different durations of non-thermal atmospheric plasma（NTAP）treatment.One hundred and sixty discs of titanium（Ti）（n：40）,cobalt chromium（Co-Cr）（n：40）,yttrium stabilized tetragonal zirconia polycrystals（Y-TZP）（n：40）and polymethylmethacrylate（PMMA）（n：40）materials were machined and smoothed with silicon carbide papers.The surface roughness was evaluated in a control group and in groups with different plasma exposure times [1-3-5 s].The average surface roughness（Ra）and contact angle（CA）measurements were recorded via an atomic force microscope（AFM）and tensiometer,respectively.Surface changes were examined with a scanning electron microscope（SEM）.Data were analyzed with two-way analysis of variance（ANOVA）and the Tukey HSD test α=0.05）.According to the results,the NTAP surface treatment significantly affected the roughness and wettability properties（P 〈 0.05）.SEM images reveal that more grooves were present in the NTAP groups.With an increase in the NTAP application time,an apparent increment was observed for Ra,except in the PMMA group,and a remarkable reduction in CA was observed in all groups.It is concluded that the NTAP technology could enhance the roughening and wetting performance of various dental materials.

The effect of pulse voltage rise rate on the polypropylene surface hydrophilic modification by ns pulsed nitrogen DBD

The nanosecond(ns) pulsed nitrogen dielectric barrier discharge(DBD) is employed to enhance the hydrophilicity of polypropylene(PP) surface and improve its application effect.The discharge characteristics of the ns pulsed nitrogen DBD with different pulse rise times(from 50to 500 ns) are investigated by electrical and optical diagnostic methods and the discharge uniformity is quantitatively analyzed by image processing method.To characterize the surface hydrophilicity,the water contact angle(WCA) is measured,and the physical morphology and chemical composition of PP before and after modification are analyzed to explore the effect of plasma on PP surface.It is found that with increasing pulse rise time from 50 to 500 ns,DBD uniformity becomes worse,energy efficiency decreases from 20% to 10.8%,and electron density decrease from 6.6 × 10^(11)to 5.5 × 10^(11)cm^(-3).The tendency of electron temperature is characterized with the intensity ratio of N_(2)/N_(2)^(+)emission spectrum,which decreases from 17.4 to15.9 indicating the decreasing of T_(e) with increasing pulse rise time from 50 to 500 ns.The PP surface treated with 50 ns pulse rise time DBD has a lower WCA(~47°),while the WCA of PP treated with 100 to 500 ns pulse rise time DBD expands gradually(~50°–57°).According to the study of the fixed-point WCA values,the DBD-treated PP surface has superior uniformity under50 ns pulse rise time(3° variation) than under 300 ns pulse rise time(8° variation).After DBD treatment,the increased surface roughness from 2.0 to 9.8 nm and hydrophilic oxygencontaining groups on the surface,i.e.hydroxyl(-OH) and carbonyl(C=O) have played the significant role to improve the sample’s surface hydrophilicity.The short pulse voltage rise time enhances the reduced electric field strength(E/n) in the discharge space and improves the discharge uniformity,which makes relatively sufficient physical and chemical reactions have taken place on the PP surface,resulting in better treatment uniformity.

TREATMENT OF METALS, POLYMER FILMS, AND FABRICS WITHA ONE ATMOSPHERE UNIFORM GLOW DISCHARGE PLASMA(OAUGDP) FOR INCREASED SURFACE ENERGY AND DIRECTIONAL ETCHING

Direct exposure of samples to the active species of air generated by a One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) has been used to etch and to increase the surface energy of metallic surfaces, photoresist, polymer films, and nonwoven fab- rics. The OAUGDP is a non-thermal plasma with the classical characteristics of a DC normal glow discharge that operates in air (and other gases) at atmospheric pres- sure. Neither a vacuum system nor batch processing is necessary. A wide range of applications to metals, photoresist, films, fabrics, and polymeric webs can be accom- modated by direct exposure of the workpiece to the plasma in parallel-plate reactors. This technolopy is simple, it produces effects that can be obtained in no other way at one atmosphere; it generates minimal pollutants or unwanted by-products; and it is suitable for individual sample or online treatment of metallic surfaces, wafers, films, and fabrics. Early exposures of solid materials to the OAUGDP required minutes to produce rela- tively small increases of surface energy. These durations appeared too long for com- mercial application to fast-moving webs. Recent improvements in OAUGDP gas com- position, power density, plasma quality, recireulating gas flow, and impedance match- ing of the power supply to the parallel plate plasma reactor have made it possible to raise the surface energy of a variety of polymeric webs (PP, PET PE etc.) to levels of 60 to 70 dynes/cm with one second of exposure. In air plasmas, the high surface ener- gies are not durable, and fall to 50 dynes/cm after periods of weeks to months. Here, we report the exposure of metallic surfaces, photoresist, polymeric films, and nonwo- ven fabrics made of PP and PET to an impedance matched parallel plate OAUGDP for durations ranging from one second to several tens of seconds. Data will be re- ported on the surface energy, wettability, wickability, and aging effect of polymeric films and fabrics as functions of time of exposure, and time after exposure; the rate and uniformity of photoresist etching; and the production of sub-micron structures by OAUGDP etching at one atmosphere.

Effect of nano-oxide layers on the magnetoresistance of ultrathin permalloy films

Ta/NiFe/Ta ultrathin films with and without nano-oxide layers （NOLs） were prepared by magnetron sputtering followed by a vacuum annealing process. The influence of NOLs on the magnetoresistance （MR） ratio of ultrathin permalloy films was studied. The results show that the influence of grain size and textures on the MR ratio becomes weak when the thickness of the NiFe layer is below 15 nm. A higher MR ratio was observed for the thinner （〈 15 nm） NiFe film with NOLs. The MR ratio of a 10 nm NiFe film can be remarkably enhanced by NOLs. The enhanced MR ratio for these ultrathin films can be attributed to the enhanced specular reflection of conduction electrons.

Effect of the graphitic degree of carbon supports on the catalytic performance of ammonia synthesis over Ba-Ru-K/HSGC catalyst

A series of high surface area graphitic carbon materials （HSGCs） were prepared by ball-milling method. Effect of the graphitic degree of HSGCs on the catalytic performance of Ba-Ru-K/HSGC-x （x is the ball-milling time in hour） catalysts was studied using ammonia synthesis as a probe reaction. The graphitic degree and pore structure of HSGC-x supports could be successfully tuned via the variation of ball-milling time. Ru nanoparticles of different Ba-Ru-K/HSGC-x catalysts are homogeneously distributed on the supports with the particle sizes ranging from 1.6 to 2.0 nm. The graphitic degree of the support is closely related to its facile electron transfer capability and so plays an important role in improving the intrinsic catalytic performance of Ba-Ru-K/HSGC-x catalyst.

Microstructure and mechanical properties of hot isostatically pressed cermets with TiN coatings

To increase the adhesion strength between the coating and the substrate, sintered Ti（C,N）-based cermets were selected and deposited with monolayer TiN using a multiarc ion-plating technique; subsequently, hot isostatic pressing （HIPhag） treatment was performed at 1000℃ using nitrogen pressure up to 110 MPa. The mechanical properties of cermets after a coating process and subsequent HIPing treatment have been evaluated with respect to the hardness, the residual stress, and the coating adhesion. The results show that atter the HIPing process, there was a higher increase ha critical load ha the TiN-coated cermets with lower surface roughness compared with those with higher surface roughness. In all cases, the residual stress was found to be compressive. The effects of substrate surface roughness and posttreatment on the adhesion strength of the coatings were thus investigated. It was also fotmd that the HIPing posttreatment process is well suited for hacreasing the adhesion strength between the coating and the substrate.

表面波等离子体暴露下铜表面的氧化特性(英文)

Surface wave plasma(SWP) is a kind of low temperature plasma which can be utilized for material development.In this research,argon and oxygen were used as a working gas for an SWP experiment and the influence of the plasma irradiation on a copper surface was examined.Particular,relation between the spatial characteristics of SWP and wetting characteristics was examined.As a result,it was found that spatial characteristics of the SWP affected the wetting characteristics and the oxidation characteristics.

Fouling Induction Period of CaCO_3 on Heated Surface

Fouling induction period of CaCO3 on heated surface was studied with the micro video technology. The rates of nucleating and nuclei growing were measured under various experimental conditions. The experimental results showed that both nucleating and nuclei growing rates of CaCO3 increased obviously with surface temperature and concentration of reagents. In addition, the experiment of fouling induction period on the surface material of chemical plated nickel-phosphorus-polytetrafluoroethylene indicated that not only the nucleate rate of CaCO3 decreased but also some fouling particles with certain size were easy to peel off from the heated surface under shearing stress, which means that the property of surface material is one of the most important factors influencing fouling induction periods.