Neutral nickel sigma -acetylide complex [Ni(C=CPh)(2)(PBu3)(2)] is a novel initiator for the polymerization of styrene in CHCl3 over a range of polymerization temperature from 40 degreesC to 60 degreesC. The polystyre...Neutral nickel sigma -acetylide complex [Ni(C=CPh)(2)(PBu3)(2)] is a novel initiator for the polymerization of styrene in CHCl3 over a range of polymerization temperature from 40 degreesC to 60 degreesC. The polystyrene obtained was a syndio-rich atactic polymer and its weight-average molecular weight reached 279000. The mechanism of the polymerization was discussed and a radical mechanism was proposed.展开更多
The catalytic activities of nine neutral nickel and palladium a-acetylide complexes [M=(C=CR)2(PR'3)2)M=Ni,Pd; R=Ph,CH2OH,CH2OOCH3,CH2OOCPh,CH2OOCPhOH-o; R'=Ph,Bu] are compared.Among them,Ni(Cs=CPh)2-(PBuj)2 s...The catalytic activities of nine neutral nickel and palladium a-acetylide complexes [M=(C=CR)2(PR'3)2)M=Ni,Pd; R=Ph,CH2OH,CH2OOCH3,CH2OOCPh,CH2OOCPhOH-o; R'=Ph,Bu] are compared.Among them,Ni(Cs=CPh)2-(PBuj)2 shows the highest catalytic activity and gives the polystyrene with high molecular weight(Mw=188800)and a syndio-rich microstructure.The catalytic behavior of transition metal acetylides is related to metal,phosphine,and alkynyl ligands bonded to the metal atoms.展开更多
文摘Neutral nickel sigma -acetylide complex [Ni(C=CPh)(2)(PBu3)(2)] is a novel initiator for the polymerization of styrene in CHCl3 over a range of polymerization temperature from 40 degreesC to 60 degreesC. The polystyrene obtained was a syndio-rich atactic polymer and its weight-average molecular weight reached 279000. The mechanism of the polymerization was discussed and a radical mechanism was proposed.
文摘The catalytic activities of nine neutral nickel and palladium a-acetylide complexes [M=(C=CR)2(PR'3)2)M=Ni,Pd; R=Ph,CH2OH,CH2OOCH3,CH2OOCPh,CH2OOCPhOH-o; R'=Ph,Bu] are compared.Among them,Ni(Cs=CPh)2-(PBuj)2 shows the highest catalytic activity and gives the polystyrene with high molecular weight(Mw=188800)and a syndio-rich microstructure.The catalytic behavior of transition metal acetylides is related to metal,phosphine,and alkynyl ligands bonded to the metal atoms.
