Ten 4-substituted bicyclic phosphates were synthesized and their ^(13)C-NMR were also determined.A good relationship was observed between 4-^(13)C chemical shift and Taft σ_X induc- tive paramenters.Substituent effec...Ten 4-substituted bicyclic phosphates were synthesized and their ^(13)C-NMR were also determined.A good relationship was observed between 4-^(13)C chemical shift and Taft σ_X induc- tive paramenters.Substituent effects on ~3J_(P-C) coupling constant were studied.展开更多
基金Project Supported by National Sciences Foundation of China.
文摘Ten 4-substituted bicyclic phosphates were synthesized and their ^(13)C-NMR were also determined.A good relationship was observed between 4-^(13)C chemical shift and Taft σ_X induc- tive paramenters.Substituent effects on ~3J_(P-C) coupling constant were studied.