Dimensionality regulation in tin halide perovskite solar cells: Toward high performance and stability

Tin halide perovskites(THPs)have received extensive attention due to their low toxicity and excellent optoelectronic properties,and are considered to be the most promising alternatives to develop efficient lead-free perovskite solar cells.However,due to the unique and inherent characteristics of Sn^(2+)being easily oxidized to Sn^(4+)and fast crystallization,tin perovskite solar cells(TPSCs)show relatively poor performance and stability,compared to the lead counterparts.Recently,the introduction of bulky organic spacers into three-dimensional(3D)THPs for dimensional regulation can not only prevent the intrusion of water and oxygen,but also inhibit the self-doping effect and ion migration.In this review,we will detail how dimensional regulation enables TPSCs with high performance and superior stability.First,we summarize the intrinsic properties of THPs and analyze the root causes of their poor performance and instability.Next,we discuss the specific structure and types of the dimensional regulation strategy.Then,the mechanism of dimensional regulation is discussed in detail,mainly from inhibiting the Sn^(2+)oxidation,optimizing crystallization,passivating defects,and improving energy level alignment.Finally,future challenges and prospects for dimensional regulation are elaborated to help researchers develop more efficient and stable TPSCs.

A short overview of the lead iodide residue impact and regulation strategies in perovskite solar cells

Lead iodide(PbI2) is a vital raw material for preparing perovskite solar cells(PSCs),and it not only takes part in forming the light absorption layer but also remains in the grain boundary as a passivator.In other words,the PbI2 content in the precursor and as formed film will affect the efficiency and stability of the PSCs.With moderate residual PbI2,it passivates the bulk/surface defects of perovskite,reduces the interfacial recombination,promotes the perovskite stability,minimizes the device hysteresis,and so on.Deficient PbI2 residue will reduce the interfacial passivation effect and device performance.In addition to facilitating the non-radiative recombination,over PbI2 residue can also lead to electronic insulation in the grain boundary and deteriorate the device performance.However,the impact and regulation of PbI2 residue on the device performance and stability is still not fully understood.Herein,a comprehensive and detailed review is presented by discussing the PbI2 residue impact and its regulation strategies(i.e., elimination,facilitation and conversion of the residue PbI2) to manipulate the PbI2 content,distribution and forms.Finally,we also show future outlooks in this field,with an aim to help further the progression of high-efficiency and stable PSCs.

Electrolyte Concentration Regulation Boosting Zinc Storage Stability of High-Capacity K0.486V2O5 Cathode for Bendable Quasi-Solid-State Zinc Ion Batteries

Vanadium-based cathodes have attracted great interest in aqueous zinc ion batteries(AZIBs)due to their large capacities,good rate performance and facile synthesis in large scale.However,their practical application is greatly hampered by vanadium dissolution issue in conventional dilute electrolytes.Herein,taking a new potassium vanadate K0.486V2O5(KVO)cathode with large interlayer spacing(~0.95 nm)and high capacity as an example,we propose that the cycle life of vanadates can be greatly upgraded in AZIBs by regulating the concentration of ZnCl2 electrolyte,but with no need to approach“water-in-salt”threshold.With the optimized moderate concentration of 15 m ZnCl2 electrolyte,the KVO exhibits the best cycling stability with ~95.02% capacity retention after 1400 cycles.We further design a novel sodium carboxymethyl cellulose(CMC)-moderate concentration ZnCl2 gel electrolyte with high ionic conductivity of 10.08 mS cm^-1 for the first time and assemble a quasi-solid-state AZIB.This device is bendable with remarkable energy density(268.2 Wh kg^−1),excellent stability(97.35% after 2800 cycles),low self-discharge rate,and good environmental(temperature,pressure)suitability,and is capable of powering small electronics.The device also exhibits good electrochemical performance with high KVO mass loading(5 and 10 mg cm^-2).Our work sheds light on the feasibility of using moderately concentrated electrolyte to address the stability issue of aqueous soluble electrode materials.

Aggregator-based demand response mechanism for electric vehicles participating in peak regulation in valley time of receiving-end power grid

With the increase in the power receiving proportion and an insufficient peak regulation capacity of the local units, the receiving-end power grid struggles to achieve peak regulation in valley time. To solve this problem while considering the potential of the large-scale charge load of electric vehicles(EVs), an aggregator-based demand response(DR) mechanism for EVs that are participating in the peak regulation in valley time is proposed in this study. In this aggregator-based DR mechanism, the profits for the power grid’s operation and the participation willingness of the EV owners are considered. Based on the characteristics of the EV charging process and the day-ahead unit generation scheduling, a rolling unit commitment model with the DR is established to maximize the social welfare. In addition, to improve the efficiency of the optimization problem solving process and to achieve communication between the independent system operator(ISO) and the aggregators, the clustering algorithm is utilized to extract typical EV charging patterns. Finally, the feasibility and benefits of the aggregator-based DR mechanism for saving the costs and reducing the peak-valley difference of the receiving-end power grid are verified through case studies.

Role of optimal transmission switching in accommodating renewable energy in deep peak regulation-enabled power systems

Due to the shortage of fossil energy and the pollution caused by combustion of fossil fuels,the proportion of renewable energy in power systems is gradually increasing across the world.Accordingly,the capacity of power systems to accommodate renewable energy must be improved.However,integration of a large amount of renewable energy into power grids may result in network congestion.Hence,in this study,optimal transmission switching(OTS)is considered as an important method of accommodating renewable energy.It is incorporated into the operation of a power grid along with deep peak regulation of thermal power units,forming an interactive mode of coordinated operation of source and network.A stochastic unit commitment model consider!ng deep peak regulation and OTS is established,and the role of OTS in promoting the accommodation of renewable energy is analyzed quantitatively.The results of case studies involving the IEEE 30-bus system demonstrate that OTS can enable utilization of the potential of deep peak regulation and facilitate the accommodation of renewable energy.

Dependence of lithium metal battery performances on inherent separator porous structure regulation

Boosting of rechargeable lithium metal batteries(LMBs) holds challenges because of lithium dendrites germination and high-reactive surface feature.Separators may experience structure-determined chemical deterioration and worsen Li plating-stripping behaviors when smoothly shifting from lithium-ion batteries(LIBs) to LMBs.This study precisely regulations the crystal structure of β-polypropylene and separator porous construction to investigate the intrinsic porous structure and mechanical properties determined electrochemical performances and cycling durability of LMBs.Crystal structure characterizations,porous structure analyses,and electrochemical cycling tests uncover appropriate annealing thermal stimulation concentrates β-lamellae thickness and enhances lamellae thermal stability by rearranging molecular chain in inferior β-lamellae,maximally homogenizing biaxial tensile deformation and resultant porous constructions.These even pores with high connectivity lower ion migration barriers,alleviate heterogeneous Li^(+) flux dispersion,stabilize reversible Li plating-stripping behaviors,and hinder coursing and branching of Li dendrites,endowing steady cell cycling durability,especially at higher currents due to the highlighted uncontrollable cumulation of dead Li,which offers new insights for the current pursuit of high-power density battery and fast charging technology.The suggested separator structure-chemical nature functions in ensuring cyclic cell stability and builds reliable relationships between separator structure design and practical LMBs applications.

Enhancement of oxygen reduction activity and stability via introducing acid-resistant refractory Mo and regulating the near-surface Pt content

Although Pt Ni catalyst possesses good oxygen reduction activity, its poor stability is the main obstacle for the commercialization of proton exchange membrane fuel cells(PEMFCs). In this work, we introduce the acid-resistant refractory Mo to enhance the structure stability and modify the electronic structure of Pt in the prepared PtNi catalyst, improving the catalytic activity for oxygen reduction reaction(ORR). In addition, near-surface Pt content in the nanoparticle is also optimized to balance the ORR activity and stability. The electrochemical results show that the alloy formed by Mo and Pt Ni is obviously more stable than the PtNi alloy alone, because the acid-resistant Mo and its oxides effectively prevent the dissolution of Pt. Especially, the Pt3 Ni3 MoN/C exhibits the optimal ORR catalytic performance in O2-saturated 0.1 mol L^(-1) HClO4 aqueous solutions, with mass activity(MA) of 900 m A mg^(-1) Pt at 0.90 V vs. RHE, which is 3.75 times enhancement compared with the commercial Pt/C(240 mA mg^(-1) Pt). After 30 k accelerated durability tests, its MA(690 m A mg^(-1) Pt) is still 2.88 times higher than the pristine Pt/C. This study thus provides a valuable method to design stable ORR catalysts with high efficiency and has great significance for the commercialization of PEMFCs.

Optimization of Minimum Power Output for Combined Heat and Power Units Considering Peak Load Regulation Ability

Northern China has rich wind power and photovoltaic renewable resources. Combined Heat and Power (CHP) Units to meet the load demand and limit its peaking capacity in winter, to a certain extent, it results in structural problems of wind-solar power and thermoelectric. To solve these problems, this paper proposes a plurality of units together to ensure supply of heat load on the premise, by building a thermoelectric power peaking considering thermal load unit group dynamic scheduling model, to achieve the potential of different thermoelectric properties peaking units of the excavation. Simulation examples show, if the unit group exists obvious relationship thermoelectric individual differences, the thermal load dynamic scheduling can be more significantly improved overall performance peaking unit group, effectively increase clean energy consumptive.

Error reachable set based stabilization of switched linear systems with bounded peak disturbances

This paper investigates the error reachable set based stabilization problem for a class of discrete-time switched linear systems with bounded peak disturbances under persistent dwell-time(PDT)constraint.A double-clockdependent control scheme is presented that can split the disturbed switched system into a nominal system and an error system,and assign to each system a controller scheduled by a clock.A necessary and sufficient convex stability criterion is presented for the nominal system,and is further extended to the stabilization controller design with a nominal clock.In the presence of bounded peak disturbances,another stabilization controller with an error clock is developed for the error system,with the purpose of‘‘minimizing’’the reachable set of the error system by the ellipsoidal techniques.It is demonstrated that the disturbed system is also globally exponentially stable in the sense of converging to an over approximation of the reachable set of the error system,i.e.,a union of a family of bounding ellipsoids,that can also be regarded as the cross section of a tube containing the trajectories of the disturbed system.Two numerical examples are provided to verify the effectiveness of the developed results.

Boosting thermal stability and crystallization of closed-loop-recyclable biodegradable poly(p-dioxanone) by end-group regulation

A chemically closed-loop-recyclable biodegradable polymer,poly(p-dioxanone)(PPDO),is one of the ideal candidates for single-use plastic products due to its suitability for different application scenarios.Fascinatingly,when PPDO wastes can be collected,its monomer p-dioxanone(PDO) will be obtained through chemical recycling of these wastes;when cannot be collected,the wastes are able to be biodegraded into harmless substances.However,unsatisfied thermal stability and low crystallization rate of PPDO restrict its wider applications.Herein,based on end-group regulation,we simultaneously realized the significant enhancement of thermal stability and crystallization of PPDO through the simple melt processing with tributyl phosphite(TBP) or triphenyl phosphite(TPP).The model reactions were conducted to investigate the reaction mechanism and theoretical products during the preparation of PPDO/phosphite compounds.Two kinds of phosphites were proved to act as the end-capped reagent and chain extender in the melt processing,while TBP presented better reactivity.As a result,the activation energy of thermal decomposition was largely elevated,and the unprecedented T_(5%)(the temperature at a weight loss of 5%) and Tmax(the temperature at a maximum rate of weight loss) of PPDO were obtained,i.e.,T_(5%)of ~330 ℃ and Tmaxof ~385 ℃ in N_(2) atmosphere,T_(5%)of ~240 ℃ and Tmaxof ~317 ℃ in air atmosphere,respectively.Furthermore,the increased crystallization rate,crystallinity,crystalline orderliness,and realizable monomer recovery(yield >90%,purity >99.9%) of PPDO/phosphite compounds were confirmed.

Self-Triggered Set Stabilization of Boolean Control Networks and Its Applications

Set stabilization is one of the essential problems in engineering systems, and self-triggered control(STC) can save the storage space for interactive information, and can be successfully applied in networked control systems with limited communication resources. In this study, the set stabilization problem and STC design of Boolean control networks are investigated via the semi-tensor product technique. On the one hand, the largest control invariant subset is calculated in terms of the strongly connected components of the state transition graph, by which a graph-theoretical condition for set stabilization is derived. On the other hand, a characteristic function is exploited to determine the triggering mechanism and feasible controls. Based on this, the minimum-time and minimum-triggering open-loop, state-feedback and output-feedback STCs for set stabilization are designed,respectively. As classic applications of self-triggered set stabilization, self-triggered synchronization, self-triggered output tracking and self-triggered output regulation are discussed as well. Additionally, several practical examples are given to illustrate the effectiveness of theoretical results.

Stability Study and Modelling of a Pilot Controlled Regulator

With the increase of gas consumption and the expansion of the associated distribution network, Gaz de France set up a research program to develop a methodology and a library of models to study the stability of any type of pressure regulator. The pressure level is controlled by pressure regulating stations. The objective of this study is to point out the working conditions that lead to instabilities. Some experiments and numerical simulations have been carried out to identify the relative influence of several parameters on the amplitude of oscillations. It turned out from measurements and simulations that the amplitudes of the downstream pressure are especially sensitive to the upstream pressure and to the size of the downstream volume.

POSITIVE PERIODIC SOLUTION FOR A NONAUTONOMOUS LOGISTIC MODEL WITH LINEAR FEEDBACK REGULATION

A nonautonomous delayed logistic model with linear feedback regulation is proposed in this paper. Sufficient conditions are derived for the existence, uniqueness and global asymptotic stability of positive periodic solution of the model

Combination of Reactive Current Droop Compensation and Line Drop Compensation for Improving Voltage Stability

Recent events related to power system failure have shown that voltage collapse can be a cause of widespread outages.The thrust of this paper is to discuss and establish means of mitigating system voltage instability by using a combination of both reactive current droop compensation and line drop compensation.It is shown that the point that the voltage regulator controls can be defined by a new method which is based on a widely accepted voltage stability analysis tool.This tool can be used to determine which generators will have an impact on the maximum permissible loading of a bus.Dynamic analysis was carried out on the CIGRE Nordic test system to study the impact of control point location on time to collapse and it is shown that the new scheme can improve the voltage stability.

Dynamic analysis and regulation of the flexible pipe conveying fluid with a hard-magnetic soft segment

The recently developed hard-magnetic soft(HMS)materials can play a significant role in the actuation and control of medical devices,soft robots,flexible electronics,etc.To regulate the mechanical behaviors of the cantilevered pipe conveying fluid,the present work introduces a segment made of the HMS material located somewhere along the pipe length.Based on the absolute node coordinate formulation(ANCF),the governing equations of the pipe conveying fluid with an HMS segment are derived by the generalized Lagrange equation.By solving the derived equations with numerical methods,the static deformation,linear vibration characteristic,and nonlinear dynamic response of the pipe are analyzed.The result of the static deformation of the pipe shows that when the HMS segment is located in the middle of the pipe,the downstream portion of the pipe centerline will keep a straight shape,providing that the pipe is stable with a relatively low flow velocity.Therefore,it is possible to precisely regulate the ejection direction of the fluid flow by changing the magnetic and fluid parameters.It is also found that the intensity and direction of the external magnetic field greatly affect the stability and dynamic response of the pipe with an HMS segment.In most cases,the magnetic actuation increases the critical flow velocity for the flutter instability of the pipe system and suppresses the vibration amplitude of the pipe.

Tuning method for governor control parameters of hydropower generator in isolated grid considering primary frequency performance and small-signal stability

This paper presents a method of tuning governor control parameters of an isolated hydropower generator considering the primary frequency performance and small-signal stability. First, generators that can be operated in isolated state are identified. Second, different schemes are proposed for generator mode switching from on-grid to off-grid state through comparison and mechanism analysis. Third, the time domain model and frequency domain model of the isolated generator governor are constructed to respectively estimate the primary frequency performance and small signal stability. Parameter sets that satisfy the primary frequency performance and small signal stability are acquired as optimal values of governor control parameters. Finally, the measurement-based parameters of the governor are identified and validated using simulations to demonstrate the feasibility and effectiveness of the method.

OUTPUT REGULATION OF THE GENERAL NONLINEARDISCRETE-TIME SYSTEM

With the use of centre manifold and dynamic system theory, the necessary and sufficient conditions are obtained for the solvabilities of the output regulator problems for the general nonlinear discrete-time system. This work generalizes and refines the corresponding results by Isidori and Byrnes on the affine nonlinear continuous-time 'system.

Research on the attitude regulation of 3-DOF hover system

Quadrotor helicopter is emerging as a popular platform for unmanned aerial vehicle re- search, due to its simplicity of structure and maintenance as well as the capability of hovering and vertical take-off and landing. The attitude controller is an important feature of quadrotor helicopter since it allows the vehicle to keep balance and perform the desired maneuver. In this paper, nonlin- ear control strategies including active disturbance rejection control （ADRC）, sliding mode control （SMC） and backstepping method are studied and implemented to stabilize the attitude of a 3-DOF hover system. ADRC is an error-driven control law, with extended state observer （ESO） estimating the unmodeled inner dynamics and external disturbance to dynamically compensate their impacts. Meanwhile; both backstepping technique and SMC are developed based on the mathematical model, whose stability is ensured by Lyapunov global stability theorem. Furthermore, the performance of each control algorithm is evaluated by experiments. The results validate effectiveness of the strate- gies for attitude regulation. Finally, the respective characteristics of the three controllers are high- lighted by-comparison, and conclusions are drawn on the basis of the theoretical and experimental a- nalysis.

Post-transcriptional regulation of vascular endothelial growth factor: Implications for tumor angiogenesis

脉管的内皮生长因素(VEGF ) 是一个有势力为批评的分泌 mitogen 生理并且肿瘤血管生成。VEGF 的规定发生在几个层次，包括抄写， mRNA 稳定，翻译，和各种各样的 isoforms 的微分细胞的本地化。在我们 VEGF 的 post-transcriptional 规定的理解的最近的进展在 VEGF mRNA 的 5'UTR 包括内部 ribosomal 入口地点的稳定的 mRNA 绑定蛋白质，投，和发现的鉴定。Monoclonal anti-VEGF 抗体最近在人为使用被同意，但是为高全身的剂量受不了需要。RNA 干扰(RNAi ) 技术正在被使用在试管内并且在有有希望的结果的动物模型。这里，我们在 VEGF 的 post-transcriptional 规定上考察文学并且在为治疗学的利益指向这些机制描述最近的进步。

Family stability as a moderator of the relationship between family life changes and sleep behavior

The aim of the study was to evaluate the associations between aspects of family stability and sleep behavior and quality as indicators of health and well-being. Participants were 312 (166 female and 146 male) undergraduate students, ranging in age from 17 to 29 (M = 19.10). Participants’ global and molecular family stability in their families of origin was assessed using the Family Life Changes Survey (FLCS) and the Stability of Activities in the Family Environment (SAFE-R), respectively. Current sleep habits and quality were measured using a modified version of the Pittsburgh Sleep Quality Inventory (PSQI). Analyses suggest family stability is related to aspects of sleep. Furthermore, it appears molecular family stability moderates the relationship between family life changes, an aspect of global family stability, and subjective sleep quality in college students. Results are important in that they suggest high levels of molecular family stability may buffer against the impact of family life changes on subjective sleep quality.