Tantalum nitride powders with particle size of 20-50 nm were prepared by the homogeneous reduction in liquid ammonia,and were treated at the temperature range from 500 ℃ to 1 170 ℃. The results of XRD analysis indic...Tantalum nitride powders with particle size of 20-50 nm were prepared by the homogeneous reduction in liquid ammonia,and were treated at the temperature range from 500 ℃ to 1 170 ℃. The results of XRD analysis indicate that the powders heated up to 500 ℃ are in the form of amorphous. The powder heated at 600 ℃ tends to transform into crystal,the powder heated to temperatures higher than 700 ℃ is clearly of crystal. The results of surface area analysis by BET show that the surface area of the powder increases as the heating temperature increases,and reaches a maximum value of 21.8 m2/g at the heating temperature around 700 ℃.展开更多
基金Project(2003AA302430) supported by the National Hi-tech Research and Development Program of Chinaproject(50374007) supported by the National Natural Science Foundation of China
文摘Tantalum nitride powders with particle size of 20-50 nm were prepared by the homogeneous reduction in liquid ammonia,and were treated at the temperature range from 500 ℃ to 1 170 ℃. The results of XRD analysis indicate that the powders heated up to 500 ℃ are in the form of amorphous. The powder heated at 600 ℃ tends to transform into crystal,the powder heated to temperatures higher than 700 ℃ is clearly of crystal. The results of surface area analysis by BET show that the surface area of the powder increases as the heating temperature increases,and reaches a maximum value of 21.8 m2/g at the heating temperature around 700 ℃.
