In-chamber thermocatalytic tar cracking and syngas reforming using char-supported NiO catalyst in an updraft biomass gasifier

The objective of this study was to evaluate the performance of an in-chamber tar cracking and syngas reforming unit.This unit was composed of a two-stage tubular reactor placed within the combustion zone of an updraft biomass gasifier.Heat generated in the exothermic combustion reactions of biomass gasification drove tar cracking and syngas reforming in the tubes,eliminating the need of external heating.The performance of the unit was evaluated using char-supported NiO catalysts and was found to be very effective in tar removal and syngas composition enhancement.A tar removal rate of 95% was achieved at 0.3 s residence time and 10%nickel loading.This condition also gave syngas high-heating value increment of 36%(to 7.3 MJ/m^(3)).The effect of gas residence time and Ni loading on tar removal and syngas composition of the unit was also studied.Gas residence of 0.2-0.3 s and Ni loading of 5%-10% were found appropriate to produce clean syngas with tar content appropriate for industrial applications(<0.6 g/m^(3))in an updraft biomass gasifier without external heating.

Advancements in biomass gasification and catalytic tar-cracking technologies

Biomass,heralded as sustainable“green coal”,plays a crucial role in energy conservation and achieving“dual carbon”objectives through clean conversion.This paper reviews advancements in biomass catalytic gasification,a technology pivotal for converting biomass to hydrogen-rich fuel and syngas.It highlights the efficiency gains afforded by various catalysts,including natural minerals,alkali metals,nickel-based compounds,zeolites,and rare earth-modified composites.The focus is on their influence on hydrogen output,syngas quality,and tar reduction.The synthesis of these insights paves the way for novel catalyst development and optimized gasification processes,hence advancing catalytic gasification technology toward more sustainable energy solutions.