Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based catalysts...Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based catalysts.TMPs have been produced in various morphologies,including hollow and porous nanostructures,which are features deemed desirable for electrocatalytic materials.Templated synthesis routes are often responsible for such morphologies.This paper reviews the latest advances and existing challenges in the synthesis of TMP-based OER and HER catalysts through templated methods.A comprehensive review of the structure-property-performance of TMP-based HER and OER catalysts prepared using different templates is presented.The discussion proceeds according to application,first by HER and further divided among the types of templates used-from hard templates,sacrificial templates,and soft templates to the emerging dynamic hydrogen bubble template.OER catalysts are then reviewed and grouped according to their morphology.Finally,prospective research directions for the synthesis of hollow and porous TMP-based catalysts,such as improvements on both activity and stability of TMPs,design of environmentally benign templates and processes,and analysis of the reaction mechanism through advanced material characterization techniques and theoretical calculations,are suggested.展开更多
Road traffic monitoring is an imperative topic widely discussed among researchers.Systems used to monitor traffic frequently rely on cameras mounted on bridges or roadsides.However,aerial images provide the flexibilit...Road traffic monitoring is an imperative topic widely discussed among researchers.Systems used to monitor traffic frequently rely on cameras mounted on bridges or roadsides.However,aerial images provide the flexibility to use mobile platforms to detect the location and motion of the vehicle over a larger area.To this end,different models have shown the ability to recognize and track vehicles.However,these methods are not mature enough to produce accurate results in complex road scenes.Therefore,this paper presents an algorithm that combines state-of-the-art techniques for identifying and tracking vehicles in conjunction with image bursts.The extracted frames were converted to grayscale,followed by the application of a georeferencing algorithm to embed coordinate information into the images.The masking technique eliminated irrelevant data and reduced the computational cost of the overall monitoring system.Next,Sobel edge detection combined with Canny edge detection and Hough line transform has been applied for noise reduction.After preprocessing,the blob detection algorithm helped detect the vehicles.Vehicles of varying sizes have been detected by implementing a dynamic thresholding scheme.Detection was done on the first image of every burst.Then,to track vehicles,the model of each vehicle was made to find its matches in the succeeding images using the template matching algorithm.To further improve the tracking accuracy by incorporating motion information,Scale Invariant Feature Transform(SIFT)features have been used to find the best possible match among multiple matches.An accuracy rate of 87%for detection and 80%accuracy for tracking in the A1 Motorway Netherland dataset has been achieved.For the Vehicle Aerial Imaging from Drone(VAID)dataset,an accuracy rate of 86%for detection and 78%accuracy for tracking has been achieved.展开更多
The precise syntheses of transition-rare-earth metal clusters with desired structures remain a great challenge.Herein,by utilizing SO_(4)^(2-)anion released by in-situ decomposition of sodium dodecyl sulfate(SDS)as a ...The precise syntheses of transition-rare-earth metal clusters with desired structures remain a great challenge.Herein,by utilizing SO_(4)^(2-)anion released by in-situ decomposition of sodium dodecyl sulfate(SDS)as a template,a series of novel high-nuclearity 3d-4f clusters,formulated as[Ni_(24)Pr_(22)(μ_(3)-OH)_(31)(pida)_(24)(SO_(4))_(4)(NO_(3))_(9)(CH_(3)COO)_(3)]·Br_(4)·(NO_(3))_(11)·_(16)H_(2)O·25CH_(3)OH(1,H_(2)pida=N-phenyliminodiacetic acid),[Ni_(24)Nd_(22)(μ3-OH)_(31)(pida)_(24)(SO_(4))_(4)(NO_(3))_(9)(CH_(3)COO)_(3)]·Br_(4)·(NO_(3))_(11)·14H_(2)O·24CH_(3)OH(2)and[Ni_(24)Gd_(22)(μ3-OH)_(36)(bida)_(24)(SO_(4))_(7)(NO_(3))_(3)(CH_(3)COO)_(3)]·(SO_(4))·Br_(4)·(NO_(3))_(4)·31H_(2)O·32CH_(3)OH(3,H_(2)bida=N-benzyliminodiacetic acid),have been successfully isolated.X-ray crystal structure analyses reveal that all the cationic{Ni_(24)RE_(22)}cores in 1-3 possess a ball-like structure with C_(3v)symmetry,and can be viewed as consisting of an inner{RE_(22)}core and an outer{Ni_(24)}shell.From 1 and 2 to 3,due to the lanthanide contraction effect,the coordination numbers for rare-earth metal centers in{RE_(22)}are different,resulting in different number of SO_(4)^(2-)and NO_(3)^(-)anions to support and stabilize the skeleton structures.Meanwhile,the magnetic properties of complexes 1-3 were also studied.The result revealed that complexes 1-3 show antiferromagnetic/ferrimagnetic interactions,and 3 exhibits magneto-caloric effect at ultralow temperatures with a maximum-ΔSm(magnetic entropy change)value of 33.03 J·kg^(−1)·K^(−1)at 3.0 K and 7 T.展开更多
Lithium-ion batteries(LIBs)have dominated the portable electronic and electrochemical energy markets since their commercialisation,whose high cost and lithium scarcity have prompted the development of other alkali-ion...Lithium-ion batteries(LIBs)have dominated the portable electronic and electrochemical energy markets since their commercialisation,whose high cost and lithium scarcity have prompted the development of other alkali-ion batteries(AIBs)including sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs).Owing to larger ion sizes of Na^(+)and K^(+)compared with Li^(+),nanocomposites with excellent crystallinity orientation and well-developed porosity show unprecedented potential for advanced lithium/sodium/potassium storage.With enticing open rigid framework structures,Prussian blue analogues(PBAs)remain promising self-sacrificial templates for the preparation of various nanocomposites,whose appeal originates from the well-retained porous structures and exceptional electrochemical activities after thermal decomposition.This review focuses on the recent progress of PBA-derived nanocomposites from their fabrication,lithium/sodium/potassium storage mechanism,and applications in AIBs(LIBs,SIBs,and PIBs).To distinguish various PBA derivatives,the working mechanism and applications of PBA-templated metal oxides,metal chalcogenides,metal phosphides,and other nanocomposites are systematically evaluated,facilitating the establishment of a structure–activity correlation for these materials.Based on the fruitful achievements of PBA-derived nanocomposites,perspectives for their future development are envisioned,aiming to narrow down the gap between laboratory study and industrial reality.展开更多
As an ultra-wide bandgap semiconductor,diamond garners significant interest due to its exceptional physical properties^([1–3]).These superior characteristics make diamonds highly promising for applications in power e...As an ultra-wide bandgap semiconductor,diamond garners significant interest due to its exceptional physical properties^([1–3]).These superior characteristics make diamonds highly promising for applications in power electronics^([4]),deep-ultraviolet detectors^([5]),high-energy particle detectors^([6]),and quantum devices based on color centers^([7]).展开更多
The joint entity relation extraction model which integrates the semantic information of relation is favored by relevant researchers because of its effectiveness in solving the overlapping of entities,and the method of...The joint entity relation extraction model which integrates the semantic information of relation is favored by relevant researchers because of its effectiveness in solving the overlapping of entities,and the method of defining the semantic template of relation manually is particularly prominent in the extraction effect because it can obtain the deep semantic information of relation.However,this method has some problems,such as relying on expert experience and poor portability.Inspired by the rule-based entity relation extraction method,this paper proposes a joint entity relation extraction model based on a relation semantic template automatically constructed,which is abbreviated as RSTAC.This model refines the extraction rules of relation semantic templates from relation corpus through dependency parsing and realizes the automatic construction of relation semantic templates.Based on the relation semantic template,the process of relation classification and triplet extraction is constrained,and finally,the entity relation triplet is obtained.The experimental results on the three major Chinese datasets of DuIE,SanWen,and FinRE showthat the RSTAC model successfully obtains rich deep semantics of relation,improves the extraction effect of entity relation triples,and the F1 scores are increased by an average of 0.96% compared with classical joint extraction models such as CasRel,TPLinker,and RFBFN.展开更多
BACKGROUND There is still considerable heterogeneity regarding which features of cryptoglandular anal fistula on magnetic resonance imaging(MRI)and endoanal ultrasound(EAUS)are relevant to surgical decision-making.As ...BACKGROUND There is still considerable heterogeneity regarding which features of cryptoglandular anal fistula on magnetic resonance imaging(MRI)and endoanal ultrasound(EAUS)are relevant to surgical decision-making.As a con-sequence,the quality and completeness of the report are highly dependent on the training and experience of the examiners.AIM To develop a structured MRI and EAUS template(SMART)reporting the minimum dataset of information for the treatment of anal fistulas.METHODS This modified Delphi survey based on the RAND-UCLA appropriateness for consensus-building was conducted between May and August 2023.One hundred and fifty-one articles selected from a systematic review of the lite-rature formed the database to generate the evidence-based statements for the Delphi study.Fourteen questions were anonymously voted by an interdisciplinary multidisciplinary group for a maximum of three iterative rounds.The degree of agreement was scored on a numeric 0–10 scale.Group consensus was defined as a score≥8 for≥80%of the panelists.RESULTS Eleven scientific societies(3 radiological and 8 surgical)endorsed the study.After three rounds of voting,the experts(69 colorectal surgeons,23 radiologists,2 anatomists,and 1 gastroenterologist)achieved consensus for 12 of 14 statements(85.7%).Based on the results of the Delphi process,the six following features of anal fistulas were included in the SMART:Primary tract,secondary extension,internal opening,presence of collection,coexisting le-sions,and sphincters morphology.CONCLUSION A structured template,SMART,was developed to standardize imaging reporting of fistula-in-ano in a simple,systematic,time-efficient way,providing the minimum dataset of information and visual diagram useful to refer-ring physicians.展开更多
Background: As the population age structure gradually ages, more and more elderly people were found to have pulmonary nodules during physical examinations. Most elderly people had underlying diseases such as heart, lu...Background: As the population age structure gradually ages, more and more elderly people were found to have pulmonary nodules during physical examinations. Most elderly people had underlying diseases such as heart, lung, brain and blood vessels and cannot tolerate surgery. Computed tomography (CT)-guided percutaneous core needle biopsy (CNB) was the first choice for pathological diagnosis and subsequent targeted drugs, immune drugs or ablation treatment. CT-guided percutaneous CNB requires clinicians with rich CNB experience to ensure high CNB accuracy, but it was easy to cause complications such as pneumothorax and hemorrhage. Three-dimensional (3D) printing coplanar template (PCT) combined with CT-guided percutaneous pulmonary CNB biopsy has been used in clinical practice, but there was no prospective, randomized controlled study. Methods: Elderly patients with lung nodules admitted to the Department of Oncology of our hospital from January 2019 to January 2023 were selected. A total of 225 elderly patients were screened, and 30 patients were included after screening. They were randomly divided into experimental group (Group A: 30 cases) and control group (Group B: 30 cases). Group A was given 3D-PCT combined with CT-guided percutaneous pulmonary CNB biopsy, Group B underwent CT-guided percutaneous pulmonary CNB. The primary outcome measure of this study was the accuracy of diagnostic CNB, and the secondary outcome measures were CNB time, number of CNB needles, number of pathological tissues and complications. Results: The diagnostic accuracy of group A and group B was 96.67% and 76.67%, respectively (P = 0.026). There were statistical differences between group A and group B in average CNB time (P = 0.001), number of CNB (1 vs more than 1, P = 0.029), and pathological tissue obtained by CNB (3 vs 1, P = 0.040). There was no statistical difference in the incidence of pneumothorax and hemorrhage between the two groups (P > 0.05). Conclusions: 3D-PCT combined with CT-guided percutaneous CNB can improve the puncture accuracy of elderly patients, shorten the puncture time, reduce the number of punctures, and increase the amount of puncture pathological tissue, without increasing pneumothorax and hemorrhage complications. We look forward to verifying this in a phase III randomized controlled clinical study. .展开更多
Expert systems (ESs) are being increasingly applied to the fault diagnosis of engines. Based on the idea of ES template (EST), an object-oriented rule-type EST is emphatically studied on such aspects as the object-ori...Expert systems (ESs) are being increasingly applied to the fault diagnosis of engines. Based on the idea of ES template (EST), an object-oriented rule-type EST is emphatically studied on such aspects as the object-oriented knowledge representation, the heuristic inference engine with an improved depth-first search (DFS) and the graphical user interface. A diagnositic ES instance for debris on magnetic chip detectors (MCDs) is then created with the EST. The spot running shows that the rule-type EST enhances the abilities of knowledge representation and heuristic inference, and breaks a new way for the rapid construction and implementation of ES.展开更多
A color based system using multiple templates was developed and implem ented for detecting human faces in color images. The algorithm consists of three image processing steps. The first step is human skin color stati...A color based system using multiple templates was developed and implem ented for detecting human faces in color images. The algorithm consists of three image processing steps. The first step is human skin color statistics. Then it separates skin regions from non-skin regions. After that, it locates the fronta l human face(s) within the skin regions. In the first step, 250 skin samples from persons of different ethnicities are used to determine the color distribution o f human skin in chromatic color space in order to get a chroma chart showing lik elihoods of skin colors. This chroma chart is used to generate, from the origina l color image, a gray scale image whose gray value at a pixel shows its likelih ood of representing the skin. The algorithm uses an adaptive thresholding proces s to achieve the optimal threshold value for dividing the gray scale image into separate skin regions from non skin regions. Finally, multiple face templates ma tching is used to determine if a given skin region represents a frontal human fa ce or not. Test of the system with more than 400 color images showed that the re sulting detection rate was 83%, which is better than most color-based face dete c tion systems. The average speed for face detection is 0.8 second/image (400×300 pixels) on a Pentium 3 (800MHz) PC.展开更多
Copper azide(CA), as a primary explosive with high energy density, has not been practically used so far because of its high electrostatic sensitivity. The Cu2O@HKUST-1 core-shell structure hybrid material was synthesi...Copper azide(CA), as a primary explosive with high energy density, has not been practically used so far because of its high electrostatic sensitivity. The Cu2O@HKUST-1 core-shell structure hybrid material was synthesized by the “bottle around ship” methodology in this research by regulating the dissolution rate of Cu2O and the generation rate of metal-organic framework(MOF) materials. Cu2O@HKUST-1 was carbonized to form a Cu O@porous carbon(CuO@PC) composite material. CuO@PC was synthesized into a copper azide(CA) @PC composite energetic material through a gas-solid phase in-situ azidation reaction.CA is encapsulated in PC framework, which acts as a nanoscale Faraday cage, and its excellent electrical conductivity prevents electrostatic charges from accumulating on the energetic material’s surface. The CA@PC composite energetic material has a CA content of 89.6%, and its electrostatic safety is nearly 30times that of pure CA(1.47 mJ compared to 0.05 mJ). CA@PC delivers an outstanding balance of safety and energy density compared to similar materials.展开更多
The development of economical,efficient,and robust electrocatalysts toward the hydrogen evolution reaction(HER)is highly imperative for the rapid advancement of renewable H2 energy-associated technologies.Extensive ut...The development of economical,efficient,and robust electrocatalysts toward the hydrogen evolution reaction(HER)is highly imperative for the rapid advancement of renewable H2 energy-associated technologies.Extensive utilization of the heterointerface effect can endow the catalysts with remarkably boosted electrocatalytic performance due to the modified electronic state of active sites.Herein,we demonstrate deliberate crafting of CoP/CoO heterojunction porous nanotubes(abbreviated as CoP/CoO PNTs hereafter)using a self-sacrificial template-engaged strategy.Precise control over the Kirkendall diffusion process of the presynthesized cobalt–aspartic acid complex nanowires is indispensable for the formation of CoP/CoO heterostructures.The topochemical transformation strategy of the reactive templates enables uniform and maximized construction of CoP/CoO heterojunctions throughout all the porous nanotubes.The establishment of CoP/CoO heterojunctions could considerably modify the electronic configuration of the active sites and also improve the electric conductivity,which endows the resultant CoP/CoO PNTs with enhanced intrinsic activity.Simultaneously,the hollow and porous nanotube architectures allow sufficient accessibility of exterior/interior surfaces and molecular permeability,drastically promoting the reaction kinetics.Consequently,when used as HER electrocatalysts,the well-designed CoP/CoO PNTs show Pt-like activity,with an overpotential of only 61 mV at 10mA cm^(−2) and excellent stability in 1.0M KOH medium,exceeding those of the vast majority of the previously reported nonprecious candidates.Density functional theory calculations further substantiate that the construction of CoP/CoO heterojunctions enables optimization of the Gibbs free energies for water adsorption and H adsorption,resulting in boosted HER intrinsic activity.The present study may provide in-depth insights into the fundamental mechanisms of heterojunction-induced electronic regulation,which may pave the way for the rational design of advanced Earth-abundant electrocatalysts in the future.展开更多
The present paper covers the syntheses of 1 D chain, 2 D layered and 3 D microporous aluminophosphates containing organic amines or ammonium in the presence of various amines from alcoholic systems. The rule for th...The present paper covers the syntheses of 1 D chain, 2 D layered and 3 D microporous aluminophosphates containing organic amines or ammonium in the presence of various amines from alcoholic systems. The rule for the crystallization of the above three families of microporous aluminophosphates was summarized and the effects of organic amine, P/Al ratio, sources of aluminum and phosphorous and temperature on the resulted structures were investigated.展开更多
This paper devoted to propose template match object detection for inertial navigation systems (INS). The proposed method is an image processing technique to improve the precision of the INS for detecting and tracking ...This paper devoted to propose template match object detection for inertial navigation systems (INS). The proposed method is an image processing technique to improve the precision of the INS for detecting and tracking the ground objects from flying vehicles. Template matching is one of the methods used for ground object detection and tracking. Robust and reliable object detection is a critical step of object recognition. This paper presents a proposed mathematical morphological template matching method for detection and tracking of ground objects. Our focus is on flying systems equipped with camera to capture photos for the ground and recognize it. The proposed method is independent on the altitude or the orientation of the object. The algorithm is simulated using Matlab program and the numerical experiments are shown which verify the object detection for a wide range altitude and orientation. The results show superiority of this method for identifying and recognizing the ground objects.展开更多
The hollow strontium carbonate pompons was synthesized for the first time by a controlled reaction precipitation method with sodium dodecyl benzene sulfonate(SDBS)and polyvinyl pyrrolidone(PVP)work together as templat...The hollow strontium carbonate pompons was synthesized for the first time by a controlled reaction precipitation method with sodium dodecyl benzene sulfonate(SDBS)and polyvinyl pyrrolidone(PVP)work together as template.The sampled particles were characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen adsorption-desorption measurement,X-ray diffraction(XRD),Energy dispersive X-Ray spectroscopy(EDX),Fourier transform infrared spectroscopy(FTIR),Thermogravimetric analysis and differential scanning calorimetry(TGA-DSC),etc.It is shown that the assynthesized hollow strontium carbonate pompons with the size of about 2μm consist of flake-like particles under the optimal reaction conditions.The formation mechanism of hollow strontium carbonate pompons was preliminarily explored.展开更多
Analysis and recognition of ancient scripts is a challenging task as these scripts are inscribed on pillars,stones,or leaves.Optical recognition systems can help in preserving,sharing,and accelerate the study of the a...Analysis and recognition of ancient scripts is a challenging task as these scripts are inscribed on pillars,stones,or leaves.Optical recognition systems can help in preserving,sharing,and accelerate the study of the ancient scripts,but lack of standard dataset for such scripts is a major constraint.Although many scholars and researchers have captured and uploaded inscription images on various websites,manual searching,downloading and extraction of these images is tedious and error prone.Web search queries return a vast number of irrelevant results,and manually extracting images for a specific script is not scalable.This paper proposes a novelmultistage system to identify the specific set of script images from a large set of images downloaded from web sources.The proposed system combines the two most important pattern matching techniques-Scale Invariant Feature Transform(SIFT)and Template matching,in a sequential pipeline,and by using the key strengths of each technique,the system can discard irrelevant images while retaining a specific type of images.展开更多
This research introduces a challenge in integrating and cleaning the data,which is a crucial task in object matching.While the object is detected and then measured,the vibration at different light intensities may influ...This research introduces a challenge in integrating and cleaning the data,which is a crucial task in object matching.While the object is detected and then measured,the vibration at different light intensities may influence the durability and reliability of mechanical systems or structures and cause problems such as damage,abnormal stopping,and disaster.Recent research failed to improve the accuracy rate and the computation time in tracking an object and in the vibration measurement.To solve all these problems,this proposed research simplifies the scaling factor determination by assigning a known real-world dimension to a predetermined portion of the image.A novel white color sticker of the known dimensions marked with a color dot is pasted on the surface of an object for the best result in the template matching using the Improved Up-Sampled Cross-Correlation(UCC)algorithm.The vibration measurement is calculated using the Finite-Difference Algorithm(FDA),a machine vision systemfitted with a macro lens sensor that is capable of capturing the image at a closer range,which does not affect the quality of displacement measurement from the video frames.Thefield test was conducted on the TAFE(Tractors and Farm Equipment Limited)tractor parts,and the percentage of error was recorded between 30%and 50%at very low vibration values close to zero,whereas it was recorded between 5%and 10%error in most high-accelerations,the essential range for vibration analysis.Finally,the suggested system is more suitable for measuring the vibration of stationary machinery having low frequency ranges.The use of a macro lens enables to capture of image frames at very close-ups.A 30%to 50%error percentage has been reported when the vibration amplitude is very small.Therefore,this study is not suitable for Nano vibration analysis.展开更多
Purpose: The objectives of this study are to explore an effective technique to extract information from weblogs and develop an experimental system to extract structured information as much as possible with this techni...Purpose: The objectives of this study are to explore an effective technique to extract information from weblogs and develop an experimental system to extract structured information as much as possible with this technique. The system will lay a foundation for evaluation, analysis, retrieval, and utilization of the extracted information.Design/methodology/approach: An improved template extraction technique was proposed.Separate templates designed for extracting blog entry titles, posts and their comments were established, and structured information was extracted online step by step. A dozen of data items, such as the entry titles, posts and their commenters and comments, the numbers of views, and the numbers of citations were extracted from eight major Chinese blog websites,including Sina, Sohu and Bokee.Findings: Results showed that the average accuracy of the experimental extraction system reached 94.6%. Because the online and multi-threading extraction technique was adopted, the speed of extraction was improved with the average speed of 15 pages per second without considering the network delay. In addition, entries posted by Ajax technology can be extracted successfully.Research limitations: As the templates need to be established in advance, this extraction technique can be effectively applied to a limited range of blog websites. In addition, the stability of the extraction templates was affected by the source code of the blog pages.Practical implications: This paper has studied and established a blog page extraction system,which can be used to extract structured data, preserve and update the data, and facilitate the collection, study and utilization of the blog resources, especially academic blog resources.Originality/value: This modified template extraction technique outperforms the Web page downloaders and the specialized blog page downloaders with structured and comprehensive data extraction.展开更多
The LiFePO4 nanotubes were successfully fabricated by a sol-gel method with porous anodic aluminum oxide as the template. Transmission electron microscopy and scanning electron microscopy showed that the synthesized L...The LiFePO4 nanotubes were successfully fabricated by a sol-gel method with porous anodic aluminum oxide as the template. Transmission electron microscopy and scanning electron microscopy showed that the synthesized LiFeP04 nanotubes were monodispersed and parallel to one another. Selected area electron diffraction pattern, X-ray diffraction and X-ray photoelectron spectroscopy investigations jointly demonstrated that the synthesized LiFePO4 nanotubes were pure olivine structure. This approach offered a potentially way for fabricating ordered LiFePO4 nanotubes at room temperature and ambient conditions, which might be expected to find promising application as a new cathode material in lithium ion battery,展开更多
基金the support from the CIPHER Project(IIID 2018-008)funded by the Commission on Higher Education-Philippine California Advanced Research Institutes(CHED-PCARI)。
文摘Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based catalysts.TMPs have been produced in various morphologies,including hollow and porous nanostructures,which are features deemed desirable for electrocatalytic materials.Templated synthesis routes are often responsible for such morphologies.This paper reviews the latest advances and existing challenges in the synthesis of TMP-based OER and HER catalysts through templated methods.A comprehensive review of the structure-property-performance of TMP-based HER and OER catalysts prepared using different templates is presented.The discussion proceeds according to application,first by HER and further divided among the types of templates used-from hard templates,sacrificial templates,and soft templates to the emerging dynamic hydrogen bubble template.OER catalysts are then reviewed and grouped according to their morphology.Finally,prospective research directions for the synthesis of hollow and porous TMP-based catalysts,such as improvements on both activity and stability of TMPs,design of environmentally benign templates and processes,and analysis of the reaction mechanism through advanced material characterization techniques and theoretical calculations,are suggested.
基金supported by a grant from the Basic Science Research Program through the National Research Foundation(NRF)(2021R1F1A1063634)funded by the Ministry of Science and ICT(MSIT),Republic of KoreaThe authors are thankful to the Deanship of Scientific Research at Najran University for funding this work under the Research Group Funding Program Grant Code(NU/RG/SERC/13/40)+2 种基金Also,the authors are thankful to Prince Satam bin Abdulaziz University for supporting this study via funding from Prince Satam bin Abdulaziz University project number(PSAU/2024/R/1445)This work was also supported by Princess Nourah bint Abdulrahman University Researchers Supporting Project Number(PNURSP2023R54)Princess Nourah bint Abdulrahman University,Riyadh,Saudi Arabia.
文摘Road traffic monitoring is an imperative topic widely discussed among researchers.Systems used to monitor traffic frequently rely on cameras mounted on bridges or roadsides.However,aerial images provide the flexibility to use mobile platforms to detect the location and motion of the vehicle over a larger area.To this end,different models have shown the ability to recognize and track vehicles.However,these methods are not mature enough to produce accurate results in complex road scenes.Therefore,this paper presents an algorithm that combines state-of-the-art techniques for identifying and tracking vehicles in conjunction with image bursts.The extracted frames were converted to grayscale,followed by the application of a georeferencing algorithm to embed coordinate information into the images.The masking technique eliminated irrelevant data and reduced the computational cost of the overall monitoring system.Next,Sobel edge detection combined with Canny edge detection and Hough line transform has been applied for noise reduction.After preprocessing,the blob detection algorithm helped detect the vehicles.Vehicles of varying sizes have been detected by implementing a dynamic thresholding scheme.Detection was done on the first image of every burst.Then,to track vehicles,the model of each vehicle was made to find its matches in the succeeding images using the template matching algorithm.To further improve the tracking accuracy by incorporating motion information,Scale Invariant Feature Transform(SIFT)features have been used to find the best possible match among multiple matches.An accuracy rate of 87%for detection and 80%accuracy for tracking in the A1 Motorway Netherland dataset has been achieved.For the Vehicle Aerial Imaging from Drone(VAID)dataset,an accuracy rate of 86%for detection and 78%accuracy for tracking has been achieved.
基金support of National Natural Science Foundation of China(22375157 and 22271228)Special Support Plan of Shaanxi Province for Young Top-notch Talent,State Key Laboratory of Electrical Insulation and Power Equipment(No.EIPE23402)+1 种基金"Scientists+Engineers"Team Building Project of Qin Chuang Yuan(2022KXJ-088)the Medical-Engineering Cross Project of the First Affiliated Hospital of XJTU(QYJCO2).
文摘The precise syntheses of transition-rare-earth metal clusters with desired structures remain a great challenge.Herein,by utilizing SO_(4)^(2-)anion released by in-situ decomposition of sodium dodecyl sulfate(SDS)as a template,a series of novel high-nuclearity 3d-4f clusters,formulated as[Ni_(24)Pr_(22)(μ_(3)-OH)_(31)(pida)_(24)(SO_(4))_(4)(NO_(3))_(9)(CH_(3)COO)_(3)]·Br_(4)·(NO_(3))_(11)·_(16)H_(2)O·25CH_(3)OH(1,H_(2)pida=N-phenyliminodiacetic acid),[Ni_(24)Nd_(22)(μ3-OH)_(31)(pida)_(24)(SO_(4))_(4)(NO_(3))_(9)(CH_(3)COO)_(3)]·Br_(4)·(NO_(3))_(11)·14H_(2)O·24CH_(3)OH(2)and[Ni_(24)Gd_(22)(μ3-OH)_(36)(bida)_(24)(SO_(4))_(7)(NO_(3))_(3)(CH_(3)COO)_(3)]·(SO_(4))·Br_(4)·(NO_(3))_(4)·31H_(2)O·32CH_(3)OH(3,H_(2)bida=N-benzyliminodiacetic acid),have been successfully isolated.X-ray crystal structure analyses reveal that all the cationic{Ni_(24)RE_(22)}cores in 1-3 possess a ball-like structure with C_(3v)symmetry,and can be viewed as consisting of an inner{RE_(22)}core and an outer{Ni_(24)}shell.From 1 and 2 to 3,due to the lanthanide contraction effect,the coordination numbers for rare-earth metal centers in{RE_(22)}are different,resulting in different number of SO_(4)^(2-)and NO_(3)^(-)anions to support and stabilize the skeleton structures.Meanwhile,the magnetic properties of complexes 1-3 were also studied.The result revealed that complexes 1-3 show antiferromagnetic/ferrimagnetic interactions,and 3 exhibits magneto-caloric effect at ultralow temperatures with a maximum-ΔSm(magnetic entropy change)value of 33.03 J·kg^(−1)·K^(−1)at 3.0 K and 7 T.
基金financial support from the Special Funds for the Cultivation of Guangdong College Students’Scientific and Technological Innovation(“Climbing Program”Special Funds,pdjh2023b0145)the Scientific Research Innovation Project of Graduate School of South China Normal University(2024KYLX047)financial support from the Australian Research Council,Centre for Materials Science,Queensland University of Technology.
文摘Lithium-ion batteries(LIBs)have dominated the portable electronic and electrochemical energy markets since their commercialisation,whose high cost and lithium scarcity have prompted the development of other alkali-ion batteries(AIBs)including sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs).Owing to larger ion sizes of Na^(+)and K^(+)compared with Li^(+),nanocomposites with excellent crystallinity orientation and well-developed porosity show unprecedented potential for advanced lithium/sodium/potassium storage.With enticing open rigid framework structures,Prussian blue analogues(PBAs)remain promising self-sacrificial templates for the preparation of various nanocomposites,whose appeal originates from the well-retained porous structures and exceptional electrochemical activities after thermal decomposition.This review focuses on the recent progress of PBA-derived nanocomposites from their fabrication,lithium/sodium/potassium storage mechanism,and applications in AIBs(LIBs,SIBs,and PIBs).To distinguish various PBA derivatives,the working mechanism and applications of PBA-templated metal oxides,metal chalcogenides,metal phosphides,and other nanocomposites are systematically evaluated,facilitating the establishment of a structure–activity correlation for these materials.Based on the fruitful achievements of PBA-derived nanocomposites,perspectives for their future development are envisioned,aiming to narrow down the gap between laboratory study and industrial reality.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFB3608600)the Beijing Municipal Science and Technology Commission(Grant No.Z181100004418009)the National Natural Science Foundation of China(Grant No.61927806)。
文摘As an ultra-wide bandgap semiconductor,diamond garners significant interest due to its exceptional physical properties^([1–3]).These superior characteristics make diamonds highly promising for applications in power electronics^([4]),deep-ultraviolet detectors^([5]),high-energy particle detectors^([6]),and quantum devices based on color centers^([7]).
基金supported by the National Natural Science Foundation of China(Nos.U1804263,U1736214,62172435)the Zhongyuan Science and Technology Innovation Leading Talent Project(No.214200510019).
文摘The joint entity relation extraction model which integrates the semantic information of relation is favored by relevant researchers because of its effectiveness in solving the overlapping of entities,and the method of defining the semantic template of relation manually is particularly prominent in the extraction effect because it can obtain the deep semantic information of relation.However,this method has some problems,such as relying on expert experience and poor portability.Inspired by the rule-based entity relation extraction method,this paper proposes a joint entity relation extraction model based on a relation semantic template automatically constructed,which is abbreviated as RSTAC.This model refines the extraction rules of relation semantic templates from relation corpus through dependency parsing and realizes the automatic construction of relation semantic templates.Based on the relation semantic template,the process of relation classification and triplet extraction is constrained,and finally,the entity relation triplet is obtained.The experimental results on the three major Chinese datasets of DuIE,SanWen,and FinRE showthat the RSTAC model successfully obtains rich deep semantics of relation,improves the extraction effect of entity relation triples,and the F1 scores are increased by an average of 0.96% compared with classical joint extraction models such as CasRel,TPLinker,and RFBFN.
文摘BACKGROUND There is still considerable heterogeneity regarding which features of cryptoglandular anal fistula on magnetic resonance imaging(MRI)and endoanal ultrasound(EAUS)are relevant to surgical decision-making.As a con-sequence,the quality and completeness of the report are highly dependent on the training and experience of the examiners.AIM To develop a structured MRI and EAUS template(SMART)reporting the minimum dataset of information for the treatment of anal fistulas.METHODS This modified Delphi survey based on the RAND-UCLA appropriateness for consensus-building was conducted between May and August 2023.One hundred and fifty-one articles selected from a systematic review of the lite-rature formed the database to generate the evidence-based statements for the Delphi study.Fourteen questions were anonymously voted by an interdisciplinary multidisciplinary group for a maximum of three iterative rounds.The degree of agreement was scored on a numeric 0–10 scale.Group consensus was defined as a score≥8 for≥80%of the panelists.RESULTS Eleven scientific societies(3 radiological and 8 surgical)endorsed the study.After three rounds of voting,the experts(69 colorectal surgeons,23 radiologists,2 anatomists,and 1 gastroenterologist)achieved consensus for 12 of 14 statements(85.7%).Based on the results of the Delphi process,the six following features of anal fistulas were included in the SMART:Primary tract,secondary extension,internal opening,presence of collection,coexisting le-sions,and sphincters morphology.CONCLUSION A structured template,SMART,was developed to standardize imaging reporting of fistula-in-ano in a simple,systematic,time-efficient way,providing the minimum dataset of information and visual diagram useful to refer-ring physicians.
文摘Background: As the population age structure gradually ages, more and more elderly people were found to have pulmonary nodules during physical examinations. Most elderly people had underlying diseases such as heart, lung, brain and blood vessels and cannot tolerate surgery. Computed tomography (CT)-guided percutaneous core needle biopsy (CNB) was the first choice for pathological diagnosis and subsequent targeted drugs, immune drugs or ablation treatment. CT-guided percutaneous CNB requires clinicians with rich CNB experience to ensure high CNB accuracy, but it was easy to cause complications such as pneumothorax and hemorrhage. Three-dimensional (3D) printing coplanar template (PCT) combined with CT-guided percutaneous pulmonary CNB biopsy has been used in clinical practice, but there was no prospective, randomized controlled study. Methods: Elderly patients with lung nodules admitted to the Department of Oncology of our hospital from January 2019 to January 2023 were selected. A total of 225 elderly patients were screened, and 30 patients were included after screening. They were randomly divided into experimental group (Group A: 30 cases) and control group (Group B: 30 cases). Group A was given 3D-PCT combined with CT-guided percutaneous pulmonary CNB biopsy, Group B underwent CT-guided percutaneous pulmonary CNB. The primary outcome measure of this study was the accuracy of diagnostic CNB, and the secondary outcome measures were CNB time, number of CNB needles, number of pathological tissues and complications. Results: The diagnostic accuracy of group A and group B was 96.67% and 76.67%, respectively (P = 0.026). There were statistical differences between group A and group B in average CNB time (P = 0.001), number of CNB (1 vs more than 1, P = 0.029), and pathological tissue obtained by CNB (3 vs 1, P = 0.040). There was no statistical difference in the incidence of pneumothorax and hemorrhage between the two groups (P > 0.05). Conclusions: 3D-PCT combined with CT-guided percutaneous CNB can improve the puncture accuracy of elderly patients, shorten the puncture time, reduce the number of punctures, and increase the amount of puncture pathological tissue, without increasing pneumothorax and hemorrhage complications. We look forward to verifying this in a phase III randomized controlled clinical study. .
文摘Expert systems (ESs) are being increasingly applied to the fault diagnosis of engines. Based on the idea of ES template (EST), an object-oriented rule-type EST is emphatically studied on such aspects as the object-oriented knowledge representation, the heuristic inference engine with an improved depth-first search (DFS) and the graphical user interface. A diagnositic ES instance for debris on magnetic chip detectors (MCDs) is then created with the EST. The spot running shows that the rule-type EST enhances the abilities of knowledge representation and heuristic inference, and breaks a new way for the rapid construction and implementation of ES.
文摘A color based system using multiple templates was developed and implem ented for detecting human faces in color images. The algorithm consists of three image processing steps. The first step is human skin color statistics. Then it separates skin regions from non-skin regions. After that, it locates the fronta l human face(s) within the skin regions. In the first step, 250 skin samples from persons of different ethnicities are used to determine the color distribution o f human skin in chromatic color space in order to get a chroma chart showing lik elihoods of skin colors. This chroma chart is used to generate, from the origina l color image, a gray scale image whose gray value at a pixel shows its likelih ood of representing the skin. The algorithm uses an adaptive thresholding proces s to achieve the optimal threshold value for dividing the gray scale image into separate skin regions from non skin regions. Finally, multiple face templates ma tching is used to determine if a given skin region represents a frontal human fa ce or not. Test of the system with more than 400 color images showed that the re sulting detection rate was 83%, which is better than most color-based face dete c tion systems. The average speed for face detection is 0.8 second/image (400×300 pixels) on a Pentium 3 (800MHz) PC.
基金the financial support by Postgraduate Research & Practice Innovation Program from Jiangsu Science and Technology Department under Grant number KYCX19_0320。
文摘Copper azide(CA), as a primary explosive with high energy density, has not been practically used so far because of its high electrostatic sensitivity. The Cu2O@HKUST-1 core-shell structure hybrid material was synthesized by the “bottle around ship” methodology in this research by regulating the dissolution rate of Cu2O and the generation rate of metal-organic framework(MOF) materials. Cu2O@HKUST-1 was carbonized to form a Cu O@porous carbon(CuO@PC) composite material. CuO@PC was synthesized into a copper azide(CA) @PC composite energetic material through a gas-solid phase in-situ azidation reaction.CA is encapsulated in PC framework, which acts as a nanoscale Faraday cage, and its excellent electrical conductivity prevents electrostatic charges from accumulating on the energetic material’s surface. The CA@PC composite energetic material has a CA content of 89.6%, and its electrostatic safety is nearly 30times that of pure CA(1.47 mJ compared to 0.05 mJ). CA@PC delivers an outstanding balance of safety and energy density compared to similar materials.
基金supported by the National Natural Science Foundation of China(Grant Nos.21972068,21875112,and 22075290)the Nanjing IPE Institute of Green Manufacturing Industrythe Beijing Natural Science Foundation(Grant No.Z200012).
文摘The development of economical,efficient,and robust electrocatalysts toward the hydrogen evolution reaction(HER)is highly imperative for the rapid advancement of renewable H2 energy-associated technologies.Extensive utilization of the heterointerface effect can endow the catalysts with remarkably boosted electrocatalytic performance due to the modified electronic state of active sites.Herein,we demonstrate deliberate crafting of CoP/CoO heterojunction porous nanotubes(abbreviated as CoP/CoO PNTs hereafter)using a self-sacrificial template-engaged strategy.Precise control over the Kirkendall diffusion process of the presynthesized cobalt–aspartic acid complex nanowires is indispensable for the formation of CoP/CoO heterostructures.The topochemical transformation strategy of the reactive templates enables uniform and maximized construction of CoP/CoO heterojunctions throughout all the porous nanotubes.The establishment of CoP/CoO heterojunctions could considerably modify the electronic configuration of the active sites and also improve the electric conductivity,which endows the resultant CoP/CoO PNTs with enhanced intrinsic activity.Simultaneously,the hollow and porous nanotube architectures allow sufficient accessibility of exterior/interior surfaces and molecular permeability,drastically promoting the reaction kinetics.Consequently,when used as HER electrocatalysts,the well-designed CoP/CoO PNTs show Pt-like activity,with an overpotential of only 61 mV at 10mA cm^(−2) and excellent stability in 1.0M KOH medium,exceeding those of the vast majority of the previously reported nonprecious candidates.Density functional theory calculations further substantiate that the construction of CoP/CoO heterojunctions enables optimization of the Gibbs free energies for water adsorption and H adsorption,resulting in boosted HER intrinsic activity.The present study may provide in-depth insights into the fundamental mechanisms of heterojunction-induced electronic regulation,which may pave the way for the rational design of advanced Earth-abundant electrocatalysts in the future.
文摘The present paper covers the syntheses of 1 D chain, 2 D layered and 3 D microporous aluminophosphates containing organic amines or ammonium in the presence of various amines from alcoholic systems. The rule for the crystallization of the above three families of microporous aluminophosphates was summarized and the effects of organic amine, P/Al ratio, sources of aluminum and phosphorous and temperature on the resulted structures were investigated.
文摘This paper devoted to propose template match object detection for inertial navigation systems (INS). The proposed method is an image processing technique to improve the precision of the INS for detecting and tracking the ground objects from flying vehicles. Template matching is one of the methods used for ground object detection and tracking. Robust and reliable object detection is a critical step of object recognition. This paper presents a proposed mathematical morphological template matching method for detection and tracking of ground objects. Our focus is on flying systems equipped with camera to capture photos for the ground and recognize it. The proposed method is independent on the altitude or the orientation of the object. The algorithm is simulated using Matlab program and the numerical experiments are shown which verify the object detection for a wide range altitude and orientation. The results show superiority of this method for identifying and recognizing the ground objects.
基金Funded by the National Natural Science Foundation of China(No.22002143)the Natural Science Foundation of Shanxi Province of China(No.201901D211223)the Postgraduate Students Scientific Research Project of North University of China(No.20201766)。
文摘The hollow strontium carbonate pompons was synthesized for the first time by a controlled reaction precipitation method with sodium dodecyl benzene sulfonate(SDBS)and polyvinyl pyrrolidone(PVP)work together as template.The sampled particles were characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen adsorption-desorption measurement,X-ray diffraction(XRD),Energy dispersive X-Ray spectroscopy(EDX),Fourier transform infrared spectroscopy(FTIR),Thermogravimetric analysis and differential scanning calorimetry(TGA-DSC),etc.It is shown that the assynthesized hollow strontium carbonate pompons with the size of about 2μm consist of flake-like particles under the optimal reaction conditions.The formation mechanism of hollow strontium carbonate pompons was preliminarily explored.
文摘Analysis and recognition of ancient scripts is a challenging task as these scripts are inscribed on pillars,stones,or leaves.Optical recognition systems can help in preserving,sharing,and accelerate the study of the ancient scripts,but lack of standard dataset for such scripts is a major constraint.Although many scholars and researchers have captured and uploaded inscription images on various websites,manual searching,downloading and extraction of these images is tedious and error prone.Web search queries return a vast number of irrelevant results,and manually extracting images for a specific script is not scalable.This paper proposes a novelmultistage system to identify the specific set of script images from a large set of images downloaded from web sources.The proposed system combines the two most important pattern matching techniques-Scale Invariant Feature Transform(SIFT)and Template matching,in a sequential pipeline,and by using the key strengths of each technique,the system can discard irrelevant images while retaining a specific type of images.
文摘This research introduces a challenge in integrating and cleaning the data,which is a crucial task in object matching.While the object is detected and then measured,the vibration at different light intensities may influence the durability and reliability of mechanical systems or structures and cause problems such as damage,abnormal stopping,and disaster.Recent research failed to improve the accuracy rate and the computation time in tracking an object and in the vibration measurement.To solve all these problems,this proposed research simplifies the scaling factor determination by assigning a known real-world dimension to a predetermined portion of the image.A novel white color sticker of the known dimensions marked with a color dot is pasted on the surface of an object for the best result in the template matching using the Improved Up-Sampled Cross-Correlation(UCC)algorithm.The vibration measurement is calculated using the Finite-Difference Algorithm(FDA),a machine vision systemfitted with a macro lens sensor that is capable of capturing the image at a closer range,which does not affect the quality of displacement measurement from the video frames.Thefield test was conducted on the TAFE(Tractors and Farm Equipment Limited)tractor parts,and the percentage of error was recorded between 30%and 50%at very low vibration values close to zero,whereas it was recorded between 5%and 10%error in most high-accelerations,the essential range for vibration analysis.Finally,the suggested system is more suitable for measuring the vibration of stationary machinery having low frequency ranges.The use of a macro lens enables to capture of image frames at very close-ups.A 30%to 50%error percentage has been reported when the vibration amplitude is very small.Therefore,this study is not suitable for Nano vibration analysis.
基金supported by the Foundation for Humanities and Social Sciences of the Chinese Ministry of Education(Grant No.:08JC870002)
文摘Purpose: The objectives of this study are to explore an effective technique to extract information from weblogs and develop an experimental system to extract structured information as much as possible with this technique. The system will lay a foundation for evaluation, analysis, retrieval, and utilization of the extracted information.Design/methodology/approach: An improved template extraction technique was proposed.Separate templates designed for extracting blog entry titles, posts and their comments were established, and structured information was extracted online step by step. A dozen of data items, such as the entry titles, posts and their commenters and comments, the numbers of views, and the numbers of citations were extracted from eight major Chinese blog websites,including Sina, Sohu and Bokee.Findings: Results showed that the average accuracy of the experimental extraction system reached 94.6%. Because the online and multi-threading extraction technique was adopted, the speed of extraction was improved with the average speed of 15 pages per second without considering the network delay. In addition, entries posted by Ajax technology can be extracted successfully.Research limitations: As the templates need to be established in advance, this extraction technique can be effectively applied to a limited range of blog websites. In addition, the stability of the extraction templates was affected by the source code of the blog pages.Practical implications: This paper has studied and established a blog page extraction system,which can be used to extract structured data, preserve and update the data, and facilitate the collection, study and utilization of the blog resources, especially academic blog resources.Originality/value: This modified template extraction technique outperforms the Web page downloaders and the specialized blog page downloaders with structured and comprehensive data extraction.
基金supported by tile National Natural Science Foundation of China(No.50375151,No.50323007 and No.50572107)863 Program(No.2002AA302609)"Hundreds Talent Program"of Chinese Academy of Sciences for financial Support.
文摘The LiFePO4 nanotubes were successfully fabricated by a sol-gel method with porous anodic aluminum oxide as the template. Transmission electron microscopy and scanning electron microscopy showed that the synthesized LiFeP04 nanotubes were monodispersed and parallel to one another. Selected area electron diffraction pattern, X-ray diffraction and X-ray photoelectron spectroscopy investigations jointly demonstrated that the synthesized LiFePO4 nanotubes were pure olivine structure. This approach offered a potentially way for fabricating ordered LiFePO4 nanotubes at room temperature and ambient conditions, which might be expected to find promising application as a new cathode material in lithium ion battery,