The existing geometrical solution models for predicting ternary thermodynamic properties from relevant binary ones have been analysed,and a general representation was proposed in an integral form on the bases of these...The existing geometrical solution models for predicting ternary thermodynamic properties from relevant binary ones have been analysed,and a general representation was proposed in an integral form on the bases of these models.展开更多
A new symmetric model for predicting ternary thermodynamic properties from its three binary systems has been presented. The application of this new model to the prediction of the ternary mixing enthalpy of Ga-Bi-Sn sy...A new symmetric model for predicting ternary thermodynamic properties from its three binary systems has been presented. The application of this new model to the prediction of the ternary mixing enthalpy of Ga-Bi-Sn system and the ternary excess Gibbs energy of AgCl-LiCl-KCl system shows that the calculated results are close to the experimental data.展开更多
A model was developed to describe the microstracture evolution in a directionally solidified ternary monotectic alloy.The directional solidification experiments were carried out on Al-3Pb-lSn（wt%） alloys by using a ...A model was developed to describe the microstracture evolution in a directionally solidified ternary monotectic alloy.The directional solidification experiments were carried out on Al-3Pb-lSn（wt%） alloys by using a Bridgman apparatus.The microstracture evolution in the directionally solidified sample was calculated.The numerical results agree well with the experimental ones.It is demonstrated that the nucleation of the minority phase droplets occur at two different positions.One corresponds to the liquid-liquid decomposition,which occurs in front of the solidification interface.The other is at the liquid/solid interface.The nucleation rate of the minority phase droplets at the liquid/solid interface is significantly higher than at the position in front of the solidification interface.The characteristic of the nucleation process leads to a bimodal size distribution of the minority particles in the directionally solidified sample.展开更多
Compared with non-gray model,equivalent gray model has equal calculation accuracy but much higher computing speed.To solve the existing problems of the equivalent gray method,sole ternary model was developed.In the mo...Compared with non-gray model,equivalent gray model has equal calculation accuracy but much higher computing speed.To solve the existing problems of the equivalent gray method,sole ternary model was developed.In the model,coupling solving process of energy balance equations is omitted and the model zone is real closed.Meanwhile,the full furnace temperature and heat flow calculations are avoided,which makes it easier to find the relationship between the equivalent gray gas radiation characteristic parameter and the initial conditions.The radiation characteristic parameter was calculated with different temperature combinations,different model zone sizes and different partial pressures of absorbent gas.The results show the similar variations in the absorption coefficient and emissivity for the equivalent gray model,which both decrease with the increase of the gas temperature and the surface temperature（especially the former one）as well as the model zone size while increase with the increase of the partial pressure of absorbent gas.展开更多
文摘The existing geometrical solution models for predicting ternary thermodynamic properties from relevant binary ones have been analysed,and a general representation was proposed in an integral form on the bases of these models.
文摘A new symmetric model for predicting ternary thermodynamic properties from its three binary systems has been presented. The application of this new model to the prediction of the ternary mixing enthalpy of Ga-Bi-Sn system and the ternary excess Gibbs energy of AgCl-LiCl-KCl system shows that the calculated results are close to the experimental data.
基金supported by the National Natural Science Foundation of China(Nos.51471173,51271185 and 51031003)China Manned Space Engineering
文摘A model was developed to describe the microstracture evolution in a directionally solidified ternary monotectic alloy.The directional solidification experiments were carried out on Al-3Pb-lSn（wt%） alloys by using a Bridgman apparatus.The microstracture evolution in the directionally solidified sample was calculated.The numerical results agree well with the experimental ones.It is demonstrated that the nucleation of the minority phase droplets occur at two different positions.One corresponds to the liquid-liquid decomposition,which occurs in front of the solidification interface.The other is at the liquid/solid interface.The nucleation rate of the minority phase droplets at the liquid/solid interface is significantly higher than at the position in front of the solidification interface.The characteristic of the nucleation process leads to a bimodal size distribution of the minority particles in the directionally solidified sample.
基金Sponsored by National Science and Technology Support Plan of China(2011AA060104)
文摘Compared with non-gray model,equivalent gray model has equal calculation accuracy but much higher computing speed.To solve the existing problems of the equivalent gray method,sole ternary model was developed.In the model,coupling solving process of energy balance equations is omitted and the model zone is real closed.Meanwhile,the full furnace temperature and heat flow calculations are avoided,which makes it easier to find the relationship between the equivalent gray gas radiation characteristic parameter and the initial conditions.The radiation characteristic parameter was calculated with different temperature combinations,different model zone sizes and different partial pressures of absorbent gas.The results show the similar variations in the absorption coefficient and emissivity for the equivalent gray model,which both decrease with the increase of the gas temperature and the surface temperature（especially the former one）as well as the model zone size while increase with the increase of the partial pressure of absorbent gas.
