The collecting power of tertiary amines（DRN,DEN and DPN） on kaolinite follows the order of DENDPNDRN.After reacting with DRN,DEN and DPN,the surface potentials of kaolinite increase remarkably,and the recruitments c...The collecting power of tertiary amines（DRN,DEN and DPN） on kaolinite follows the order of DENDPNDRN.After reacting with DRN,DEN and DPN,the surface potentials of kaolinite increase remarkably,and the recruitments caused by collectors also follow the order of DENDPNDRN.The results of dynamics simulation show that the geometries of substituent groups bonding to N are deflected and twisted,and some of bond angles are changed when tertiary amines cations adsorb on kaolinite（001） surface.Based on the results of dynamics simulations and quantum chemistry calculations,the electrostatic forces between three tertiary amines cations and 4×4×3（001） plane of kaolinite are 1.38×10？7 N（DRN12H＋）,1.44×10-6 N（DEN12H＋）,1.383×10-6 N（DPN12H＋）,respectively.展开更多
Tertiary amine cationic polyacrylamide with high cationization degree was used as a new cationic agent to pretreat cotton with dip-pad-bake method. The obtained cationic cotton was dyed with reactive dyes in the ab-se...Tertiary amine cationic polyacrylamide with high cationization degree was used as a new cationic agent to pretreat cotton with dip-pad-bake method. The obtained cationic cotton was dyed with reactive dyes in the ab-sence of electrolyte. The effects of the characteristics of the cationic agent and the pretreatment conditions on dye-ability of reactive dye were investigated. The results showed that the fixation and K/S values of the reactive dyes on the cationic cotton were improved compared with those on the untreated one in the presence of salt. Tests on fast-ness properties of the dyed cotton and fabric quality of the pretreated cotton were carried out and the results showed that wash and rub fastness of the salt-free dyeing were both satisfactory. And anti-crease property,tensile and tear strength,and handling of the cationic cotton were also good compared with that of the untreated one.展开更多
The spectophotometry of charge transfer (CT) complexes of tetrachloro-p-benzoquinone(TCB) with tertiary amine [triethylamine (TEA), triphylamine (TPA), N,N-dimethylphenylamine(DMPA), N-ethylcarbazole (ECZ)] have been ...The spectophotometry of charge transfer (CT) complexes of tetrachloro-p-benzoquinone(TCB) with tertiary amine [triethylamine (TEA), triphylamine (TPA), N,N-dimethylphenylamine(DMPA), N-ethylcarbazole (ECZ)] have been studied in dichloromethane in UV-visible region.The CT complexes parameter, molar ratio of reactAnts in complex, molar extinction coefficient equilibrium constant KCT, free energy G and dissociation energy of the CT complex excited stateE, have also been estimated and discussed.展开更多
The flotation of kaolinite using a series of tertiary amines （N,N-dimethyl-dodecyl amine （DRN）, N,N-diethyl-dodecyl amine （DEN）, N,N-dipropyl-dodecyl amine （DPN） and N,N-dibenzyl-bodecyl amine （DBN）） was inv...The flotation of kaolinite using a series of tertiary amines （N,N-dimethyl-dodecyl amine （DRN）, N,N-diethyl-dodecyl amine （DEN）, N,N-dipropyl-dodecyl amine （DPN） and N,N-dibenzyl-bodecyl amine （DBN）） was investigated. The results show that the maximum recoveries of kaolinite for DEN, DPN and DRN are 93%, 88% and 84%, respectively, but that of DBN is very low. On the basis of zeta potential and FT-IR spectra, the ionization of surface hydroxyl and isomorphic exchange of surface ions account for the charging mechanisms of kaolinite surface. The adsorption mechanism of tertiary amines on kaolinite surface is mainly electrostatic. The isoelectric point （IEP） of kaolinite increases from 3.4 to some more positive points after the interaction of kaolinite with the four tertiary amines. The FT-IR spectra of kaolinite change with the presence of some new sharp shapes belonging to the tertiary amines. The inductive electronic effects and space-steric effects of -CH3, -C2H5, -C3H7 and -C7H7 bonding to N atom result in different collecting power of the four tertiary amines.展开更多
The tertiary amine can be used to extract Fe(Ⅲ) very effectively in the pH range resulting in partial hydrolysis of Fe^(3+) ions.The iron extracted into the organic phase can be stripped rather easily with dilute H_2...The tertiary amine can be used to extract Fe(Ⅲ) very effectively in the pH range resulting in partial hydrolysis of Fe^(3+) ions.The iron extracted into the organic phase can be stripped rather easily with dilute H_2SO_4 or even with H_2O.Fe(Ⅲ) is extracted into the tertiary amine sulfate solution in the form of[(R_3NH)_2Fe(OH)(SO_4)_2]_2 complex by adduct formation.Equa- tion was derived to represent the chemical reactions involved during extraction.From the infrared spectrum studies on the extraction species in waxy solid form separated from the so- lution,sulfate group is a bidentate ligand to the iron atom.The extraction species has been considered to contain (FeOH)_2 unit based on the ultra violet spectra.The possible structure of the extraction species has been proposed.展开更多
Non-aqueous absorbents(NAAs)have attracted increasing attention for CO_(2)capture because of their great energy-saving potential.Primary diamines which can provide high CO_(2)absorption loading are promising candidate...Non-aqueous absorbents(NAAs)have attracted increasing attention for CO_(2)capture because of their great energy-saving potential.Primary diamines which can provide high CO_(2)absorption loading are promising candidates for formulating NAAs but suffer disadvantages in regenerability.In this study,a promising strategy that using tertiary amines(TAs)as proton-transfer mediators was proposed to enhance the regenerability of an aminoethylethanolamine(AEEA,diamine)/dimethyl sulfoxide(DMSO)(A/D)NAA.Surprisingly,some employed TAs such as N,N-diethylaminoethanol(DEEA),N,N,N’,N’’,N’’-pentamethyldiethylenetriamine(PMDETA),3-dimethylamino-1-propanol(3DMA1P),and N,N-dimethylethanolamine(DMEA)enhanced not only the regenerability of the A/D NAA but also the CO_(2)absorption performance.Specifically,the CO_(2)absorption loading and cyclic loading were increased by about 12.7%and 15.5%-22.7%,respectively.The TA-enhanced CO_(2)capture mechanism was comprehensively explored via nuclear magnetic resonance technique and quantum chemical calculations.During CO_(2)absorption,the TA acted as an ultimate proton acceptor for AEEA-zwitterion and enabled more AEEA to form carbamate species(AEEACOO-)to store CO_(2),thus enhancing CO_(2)absorption.For CO_(2)desorption,the TA first provided protons directly to AEEACOO-as a proton donor;moreover,it functioned as a proton carrier and facilitated the low-energy step-wise proton transfer from protonated AEEA to AEEACOO-.Consequently,the presence of TA made it easier for AEEACOO-to obtain protons to decompose,resulting in enhanced CO_(2)desorption.In a word,introducing the TA as a proton-transfer mediator into the A/D NAA enhanced both the CO_(2)absorption performance and the regenerability,which was an efficient way to“kill two birds with one stone”.展开更多
Over the past decade, biopolymers have gained great interests especially in biomedicine due to their physical properties and/or chemical structures changes in response to external stimuli in a certain time fiarne or a...Over the past decade, biopolymers have gained great interests especially in biomedicine due to their physical properties and/or chemical structures changes in response to external stimuli in a certain time fiarne or at a specific location. Among them, poly（β-amino ester）s, methacrylate-based block copolymers and polypeptide with tertiary amine groups have been extensively studied and exhibit pH sensitive properties due to the protonation of tertiary amine groups. The pH values in normal organs, tissues, and subcellular compartments are always different from those in pathological tissues. These interesting properties allow their applications in a variety of fields ranging from diagnosis and therapeutics of diseases. Here, we review the recent progress of poly（β-amino ester）s, methacrylate-based block copolymers and polypeptide with tertiary amine groups and their applications in drug delivery and bioimaging.展开更多
In this paper,we have investigated the formation of the third-phase in tertiary amine(N235)-PtCl62--HCl system and the microscopic phase structural evolution of platinum-loaded organic phases before and after the occu...In this paper,we have investigated the formation of the third-phase in tertiary amine(N235)-PtCl62--HCl system and the microscopic phase structural evolution of platinum-loaded organic phases before and after the occurrence of the third-phase.The third-phase is characterized by various spectroscopic techniques,and the small angle X-ray scattering(SAXS) experiments demonstrate the appearance of nano-aggregates,i.e.,water-in-oil reversed micelles,in the third phase.The experimental results indicate that(1) formation of the third phase is related to the aggregation behaviors of nano-reversed micelles in which a super-concentrated hydrochloric acid formed with the H+ to H2O molar ratio being much higher than that of the conventional 37 wt% saturated hydrochloric acid.(2) The occurrence of the super-concentrated HCl results in a great amount of H+ and Cl-ions enriched and confined within the nano-water pools of W/O reversed micelles in third phase.Therefore,the coordination behaviors of platinum complex ions in that super-concentrated hydrochloric acid are very different from their corresponding behaviors in bulk aqueous solutions.It is possible that H+ ions participate in the formation of such complexes as HmPtCl6z+ in the super-concentrated hydrochloric acid.(3) The relative contents of various HmPtCl6z+ complexes are different corresponding to the H+ ion concentrations in confined nanowater pools.The association ability of the acidified tertiary amine N235 molecules(R3NH+) with various HmPtCl6z+ complexes plays an important role in affecting the platinum extraction behaviors.展开更多
Lewis base-catalyzed annulations of allenoates have been one of the most powerful synthetic strategies for the synthesis of various valuable cycles,especially in the preparation of biologically active natural products...Lewis base-catalyzed annulations of allenoates have been one of the most powerful synthetic strategies for the synthesis of various valuable cycles,especially in the preparation of biologically active natural products and pharmaceuticals.Generally,the effective Lewis bases mainly include tertiary phosphine,NHC and tertiary amine catalysts,among those catalysis,tertiary amine Lewis bases have proven to be effective catalysts for a range of synthetic transformations.In the past decades,tremendous progress in-volving tertiary amines-promoted cycloaddition of allenoates has been made in the chemoselective con-struction of valuable motifs.This review describes a comprehensive and updated summary of tertiary amine Lewis base-promoted annulation reactions of allenoates.Diverse reactivities,chemoselectivties and detailed reaction mechanisms will be highlighted in this review.展开更多
The polymerization mechanism of various vinyl monomers in the presence of aromatic tertiary amines has been studied. It is found that the mechanisms of different monomers vary with the structure of the monomer. The mo...The polymerization mechanism of various vinyl monomers in the presence of aromatic tertiary amines has been studied. It is found that the mechanisms of different monomers vary with the structure of the monomer. The monomer containing a-CH3 group on double bond such展开更多
An oxidative amidation of tertiary amines with carboxylic acids has been developed in the presence of FeC13- 6H20 as catalyst and oxygen as oxidant. A variety of tertiary amides were obtained in good to excellent yiel...An oxidative amidation of tertiary amines with carboxylic acids has been developed in the presence of FeC13- 6H20 as catalyst and oxygen as oxidant. A variety of tertiary amides were obtained in good to excellent yields from inexpensive and readily available reagents. The possible reaction pathways were investigated.展开更多
基金Project (2005CB623701) supported by the National Basic Research Program of China Project (201011031) supported by National Department Public Benefit Research Foundation from Ministry of Land and Resources of China+1 种基金 Project (2935) supported by the Foundation for the Author of Zhengzhou Institute of Multipurpose Utilization of Mineral Resources CAGS, China Project (1212011120304) supported by the Geological Surrey Program
文摘The collecting power of tertiary amines（DRN,DEN and DPN） on kaolinite follows the order of DENDPNDRN.After reacting with DRN,DEN and DPN,the surface potentials of kaolinite increase remarkably,and the recruitments caused by collectors also follow the order of DENDPNDRN.The results of dynamics simulation show that the geometries of substituent groups bonding to N are deflected and twisted,and some of bond angles are changed when tertiary amines cations adsorb on kaolinite（001） surface.Based on the results of dynamics simulations and quantum chemistry calculations,the electrostatic forces between three tertiary amines cations and 4×4×3（001） plane of kaolinite are 1.38×10？7 N（DRN12H＋）,1.44×10-6 N（DEN12H＋）,1.383×10-6 N（DPN12H＋）,respectively.
基金Supported by the National Science Foundation for Distinguished Young Scholar of China（20525620） the National Natural Science Foundation of China（20806013） the Program for Changjiang Scholar and Innovative Research Team in University（IRT 0711）
文摘Tertiary amine cationic polyacrylamide with high cationization degree was used as a new cationic agent to pretreat cotton with dip-pad-bake method. The obtained cationic cotton was dyed with reactive dyes in the ab-sence of electrolyte. The effects of the characteristics of the cationic agent and the pretreatment conditions on dye-ability of reactive dye were investigated. The results showed that the fixation and K/S values of the reactive dyes on the cationic cotton were improved compared with those on the untreated one in the presence of salt. Tests on fast-ness properties of the dyed cotton and fabric quality of the pretreated cotton were carried out and the results showed that wash and rub fastness of the salt-free dyeing were both satisfactory. And anti-crease property,tensile and tear strength,and handling of the cationic cotton were also good compared with that of the untreated one.
文摘The spectophotometry of charge transfer (CT) complexes of tetrachloro-p-benzoquinone(TCB) with tertiary amine [triethylamine (TEA), triphylamine (TPA), N,N-dimethylphenylamine(DMPA), N-ethylcarbazole (ECZ)] have been studied in dichloromethane in UV-visible region.The CT complexes parameter, molar ratio of reactAnts in complex, molar extinction coefficient equilibrium constant KCT, free energy G and dissociation energy of the CT complex excited stateE, have also been estimated and discussed.
基金Project(2005CB623701) supported by the National Basic Research Program of China
文摘The flotation of kaolinite using a series of tertiary amines （N,N-dimethyl-dodecyl amine （DRN）, N,N-diethyl-dodecyl amine （DEN）, N,N-dipropyl-dodecyl amine （DPN） and N,N-dibenzyl-bodecyl amine （DBN）） was investigated. The results show that the maximum recoveries of kaolinite for DEN, DPN and DRN are 93%, 88% and 84%, respectively, but that of DBN is very low. On the basis of zeta potential and FT-IR spectra, the ionization of surface hydroxyl and isomorphic exchange of surface ions account for the charging mechanisms of kaolinite surface. The adsorption mechanism of tertiary amines on kaolinite surface is mainly electrostatic. The isoelectric point （IEP） of kaolinite increases from 3.4 to some more positive points after the interaction of kaolinite with the four tertiary amines. The FT-IR spectra of kaolinite change with the presence of some new sharp shapes belonging to the tertiary amines. The inductive electronic effects and space-steric effects of -CH3, -C2H5, -C3H7 and -C7H7 bonding to N atom result in different collecting power of the four tertiary amines.
文摘The tertiary amine can be used to extract Fe(Ⅲ) very effectively in the pH range resulting in partial hydrolysis of Fe^(3+) ions.The iron extracted into the organic phase can be stripped rather easily with dilute H_2SO_4 or even with H_2O.Fe(Ⅲ) is extracted into the tertiary amine sulfate solution in the form of[(R_3NH)_2Fe(OH)(SO_4)_2]_2 complex by adduct formation.Equa- tion was derived to represent the chemical reactions involved during extraction.From the infrared spectrum studies on the extraction species in waxy solid form separated from the so- lution,sulfate group is a bidentate ligand to the iron atom.The extraction species has been considered to contain (FeOH)_2 unit based on the ultra violet spectra.The possible structure of the extraction species has been proposed.
基金supported by the Natural Science Foundation of Guangxi Province(Nos.2023GXNSFAA026381 and 2020GXNSFBA297071)the National Natural Science Foundation of China(Nos.22006027 and 52260023)。
文摘Non-aqueous absorbents(NAAs)have attracted increasing attention for CO_(2)capture because of their great energy-saving potential.Primary diamines which can provide high CO_(2)absorption loading are promising candidates for formulating NAAs but suffer disadvantages in regenerability.In this study,a promising strategy that using tertiary amines(TAs)as proton-transfer mediators was proposed to enhance the regenerability of an aminoethylethanolamine(AEEA,diamine)/dimethyl sulfoxide(DMSO)(A/D)NAA.Surprisingly,some employed TAs such as N,N-diethylaminoethanol(DEEA),N,N,N’,N’’,N’’-pentamethyldiethylenetriamine(PMDETA),3-dimethylamino-1-propanol(3DMA1P),and N,N-dimethylethanolamine(DMEA)enhanced not only the regenerability of the A/D NAA but also the CO_(2)absorption performance.Specifically,the CO_(2)absorption loading and cyclic loading were increased by about 12.7%and 15.5%-22.7%,respectively.The TA-enhanced CO_(2)capture mechanism was comprehensively explored via nuclear magnetic resonance technique and quantum chemical calculations.During CO_(2)absorption,the TA acted as an ultimate proton acceptor for AEEA-zwitterion and enabled more AEEA to form carbamate species(AEEACOO-)to store CO_(2),thus enhancing CO_(2)absorption.For CO_(2)desorption,the TA first provided protons directly to AEEACOO-as a proton donor;moreover,it functioned as a proton carrier and facilitated the low-energy step-wise proton transfer from protonated AEEA to AEEACOO-.Consequently,the presence of TA made it easier for AEEACOO-to obtain protons to decompose,resulting in enhanced CO_(2)desorption.In a word,introducing the TA as a proton-transfer mediator into the A/D NAA enhanced both the CO_(2)absorption performance and the regenerability,which was an efficient way to“kill two birds with one stone”.
文摘Over the past decade, biopolymers have gained great interests especially in biomedicine due to their physical properties and/or chemical structures changes in response to external stimuli in a certain time fiarne or at a specific location. Among them, poly（β-amino ester）s, methacrylate-based block copolymers and polypeptide with tertiary amine groups have been extensively studied and exhibit pH sensitive properties due to the protonation of tertiary amine groups. The pH values in normal organs, tissues, and subcellular compartments are always different from those in pathological tissues. These interesting properties allow their applications in a variety of fields ranging from diagnosis and therapeutics of diseases. Here, we review the recent progress of poly（β-amino ester）s, methacrylate-based block copolymers and polypeptide with tertiary amine groups and their applications in drug delivery and bioimaging.
基金Supported by the National Natural Science Foundation of China (Grant Nos. 50404004, 50673005)China Postdoctoral Science Foundation Funded Project (Grant Nos. 20070410002, 200801007)
文摘In this paper,we have investigated the formation of the third-phase in tertiary amine(N235)-PtCl62--HCl system and the microscopic phase structural evolution of platinum-loaded organic phases before and after the occurrence of the third-phase.The third-phase is characterized by various spectroscopic techniques,and the small angle X-ray scattering(SAXS) experiments demonstrate the appearance of nano-aggregates,i.e.,water-in-oil reversed micelles,in the third phase.The experimental results indicate that(1) formation of the third phase is related to the aggregation behaviors of nano-reversed micelles in which a super-concentrated hydrochloric acid formed with the H+ to H2O molar ratio being much higher than that of the conventional 37 wt% saturated hydrochloric acid.(2) The occurrence of the super-concentrated HCl results in a great amount of H+ and Cl-ions enriched and confined within the nano-water pools of W/O reversed micelles in third phase.Therefore,the coordination behaviors of platinum complex ions in that super-concentrated hydrochloric acid are very different from their corresponding behaviors in bulk aqueous solutions.It is possible that H+ ions participate in the formation of such complexes as HmPtCl6z+ in the super-concentrated hydrochloric acid.(3) The relative contents of various HmPtCl6z+ complexes are different corresponding to the H+ ion concentrations in confined nanowater pools.The association ability of the acidified tertiary amine N235 molecules(R3NH+) with various HmPtCl6z+ complexes plays an important role in affecting the platinum extraction behaviors.
基金the National Natural Science Foundation of China(No.21702189)Key Scientific and Technological Project of Henan Province(No.202102310004)Zhengzhou University(No.JC21253007)of China for financial support.
文摘Lewis base-catalyzed annulations of allenoates have been one of the most powerful synthetic strategies for the synthesis of various valuable cycles,especially in the preparation of biologically active natural products and pharmaceuticals.Generally,the effective Lewis bases mainly include tertiary phosphine,NHC and tertiary amine catalysts,among those catalysis,tertiary amine Lewis bases have proven to be effective catalysts for a range of synthetic transformations.In the past decades,tremendous progress in-volving tertiary amines-promoted cycloaddition of allenoates has been made in the chemoselective con-struction of valuable motifs.This review describes a comprehensive and updated summary of tertiary amine Lewis base-promoted annulation reactions of allenoates.Diverse reactivities,chemoselectivties and detailed reaction mechanisms will be highlighted in this review.
文摘The polymerization mechanism of various vinyl monomers in the presence of aromatic tertiary amines has been studied. It is found that the mechanisms of different monomers vary with the structure of the monomer. The monomer containing a-CH3 group on double bond such
基金financially supported by the Fundamental Research Funds for the Central Universitiesthe Research Funds of Renmin University of China(10XNL017)
文摘An oxidative amidation of tertiary amines with carboxylic acids has been developed in the presence of FeC13- 6H20 as catalyst and oxygen as oxidant. A variety of tertiary amides were obtained in good to excellent yields from inexpensive and readily available reagents. The possible reaction pathways were investigated.
