Facile Synthesis of Multi-Branched Gold Nanostructures through a TBAB-Assisted Route in Aqueous Solution and Their SERS Property

Facile synthesis of multi-branched gold nanostructures by using the tetrabutyl ammonium bromide （TBAB） as a capping agent is described. The reaction is carried out in a one-step process at mild temperature. Gold nanostructures with more than six sharp branches ranging from 70 to 130 nm in length are synthesized in high yield. It is proposed that the relative weak adsorption capacity of TBAB leads to the incompletely covered gold surface and the growth of nanoparticles occurs on the uncovered gold surface, and therefore short branches appear consequently. Then positively charged TBAB layers on the gold surfaces prevent the branches from aggregating with each other which stimulates the branch growth. The prepared branched gold nanoparticles show efficient surface-enhanced Raman scattering （SERS） properties. Low temperature （4 ℃） is unfavorable to the formation of multi-branched gold nanostructures, and only thin small irregular plate-like nanoparticles are produced. The addition of SDS in TBAB aqueous solution results in forming SDS micelles at much lower concentration of SDS （0.4 mmol/L） as compared to that in pure water, and short branched gold nanoparticles are obtained in the SDS-TBAB system.

An efficient oxidation of benzylic and alicylic compounds with water-soluble copper catalysts in t-butyl hydroperoxide at room temperature

The water soluble catalytic system comprising of CuCl_2 and 2,2-biquinoline-4,4-dicarboxylic acid dipotassium salt（BQC） is highly efficient organic metallic catalysts for selective oxidation of benzyiic and alicyciic compounds to the corresponding ketones, ex：indan to indanone,ethyl benzene to acetophenone.