The pursuit of economic efficiency is the major driver for the birth of contemporary Chinese civil law.Contemporary civil law scholarship has demonstrated a serious concern for efficiency from the very beginning.Howev...The pursuit of economic efficiency is the major driver for the birth of contemporary Chinese civil law.Contemporary civil law scholarship has demonstrated a serious concern for efficiency from the very beginning.However,many examples suggest that the notion of economic efficiency is often diluted or replaced by factors like civil law doctrinal scholasticism,moral notions,inertial thinking of the planned economy or the will of the leader.It has not been systematically attended to or expressed in a detailed and precise way in the contemporary civil law scholarship in China,rendering some economic judgments uneconomical.In the 21 st century,it is necessary for the civil law studies to establish a clearer and more precise notion of efficiency,to conduct more direct and accurate evaluations on civil laws’incentives on people’s behaviors and their socio-economic effects,so as to reduce the cost of social interactions and promote deeper cooperation and winwin outcome among individuals.展开更多
There have emerged ample literature about the Second Law analysis of extraterrestrial and terrestrial solar radiation consequent to the pioneer works by R. Petela and D. C. Spanner, of which most are irrelevant to the...There have emerged ample literature about the Second Law analysis of extraterrestrial and terrestrial solar radiation consequent to the pioneer works by R. Petela and D. C. Spanner, of which most are irrelevant to the frequency distribution of solar radiation. Since the Second Law analysis was introduced to the fields like photovoltaic and photosynthesis, rendering a need for a method closely related to solar radiation spectrum, some authors created wavelength dependent dilute factots to take the various influence of atmosphere on the frequency distribution into consideration. Because of the complexity of the influence on different frequency, it is not convenient and accurate enough to practically apply the present exergy theories of diluted solar radiation to real solar exergy systems at the surface of the earth. This paper shows a numerical method of Second Law analysis in dealing with the cases of diluted solar irradiance on the earth, based on the observed spectra of global direct and diffuse展开更多
In this paper, the mistakes in the traditional first law are pointed out. A new second law of thermodynamics, the law of coupling is mentioned. The Liu's Principle of Free Energy Conservation is stated. And finall...In this paper, the mistakes in the traditional first law are pointed out. A new second law of thermodynamics, the law of coupling is mentioned. The Liu's Principle of Free Energy Conservation is stated. And finally a New Discipline is expressed as A THEORETICAL FLOW SHEET.展开更多
The second law of thermodynamics has been proven by many facts in classical world. Is there any new property of it in quantum world? In this paper, we calculate the change of entropy in T.D. Kieu's model for quantum...The second law of thermodynamics has been proven by many facts in classical world. Is there any new property of it in quantum world? In this paper, we calculate the change of entropy in T.D. Kieu's model for quantum heat engine (QHE) and prove the broad validity of the second law of thermodynamics. It is shown that the entropy of the quantum heat engine neither decreases in a whole cycle, nor decreases in either stage of the cycle. The second law of thermodynamics still holds in this QHE model. Moreover, although the modified quantum heat engine is capable of extracting more work, its efficiency does not improve at all. It is neither beyond the efficiency of T.D. Kieu's initial model,nor greater than the reversible Carnot efficiency.展开更多
A Faraday isolator is shown to develop a temperature difference between its input and output, but still complies with the second law when all the heat carriers, in this case, photons are homogeneous and indistinguisha...A Faraday isolator is shown to develop a temperature difference between its input and output, but still complies with the second law when all the heat carriers, in this case, photons are homogeneous and indistinguishable. This result is a consequence of the H-theorem which assumes homogeneity and indistinguishability of particles. However, when a thermal feedback path is added, in which heat carriers have physical properties different from the photons in the isolator, then a heterogeneous system is formed not covered by the H-theorem, and the second law is violated.展开更多
A Faraday isolator is shown to develop a temperature difference between its input and output, but still complies with the second law when all the heat carriers, in this case, photons are homogeneous and indistinguisha...A Faraday isolator is shown to develop a temperature difference between its input and output, but still complies with the second law when all the heat carriers, in this case, photons are homogeneous and indistinguishable. This result is a consequence of the H-theorem which assumes homogeneity and indistinguishability of particles. However, when a thermal feedback path is added, in which heat carriers have physical properties different from the photons in the isolator, then a heterogeneous system is formed not covered by the H-theorem, and the second law is violated.展开更多
The aim of this numerical investigation is to evaluate the laminar forced convection of biologically synthesized water-silver nanofluid through a heat sink(HS)filled with porous foam(PHS)using first and second laws of...The aim of this numerical investigation is to evaluate the laminar forced convection of biologically synthesized water-silver nanofluid through a heat sink(HS)filled with porous foam(PHS)using first and second laws of thermodynamics.The impacts of inlet velocity(V=0.5–3 m·s^-1)and volume fraction of nanofluid(φ=0–1%)on the performance metrics of HS are assessed and the outcomes are compared with those of the non-porous HS(NHS).The outcomes revealed that for both the PHS and NHS,the increase of V causes an intensification in convection coefficient,pumping power,and entropy generation due to fluid friction,while the maximum CPU temperature,thermal resistance,and entropy generation due to the heat transfer reduces by boosting V.Also,it was found that the augmentation of V results in intensification in convection coefficient,pumping power,overall hydrothermal performance,and frictional entropy generation,while the opposite is true for maximum CPU temperature,thermal resistance,and thermal entropy generation.Furthermore,it was reported that,except forφ=0.5%,the overall hydrothermal performance of NHS is better than that of PHS,while PHS has better second-law performance than NHS in all the studied cases.Also,it can be concluded that the best hydrothermal performance for PHS belongs toφ=1%and V=0.5 m·s^-1,while for NHS,these values are 1%and 2 m·s^-1.展开更多
Refrigeration coefficient, ε, is usually calculated by using the First Law of Thermodynamics. In this paper, a new derivation process is introduced through the combination of the Second Law of Thermodynamics with the...Refrigeration coefficient, ε, is usually calculated by using the First Law of Thermodynamics. In this paper, a new derivation process is introduced through the combination of the Second Law of Thermodynamics with the First Law of Thermodynamics. As a result, two new calculation equations for refrigeration coefficient are proposed. One equation is equivalent to the common method, but its form is a little complicated for real calculation. Another equation is the further simplification, and can be used to calculate the refrigeration coefficient instead of common method with a oermit error.展开更多
Based on the entropy generation concept of thermodynamics, this paper estabfished a general theoretical model for the analysis of entropy generation to optimize fins, in which the minimum entropy generation was select...Based on the entropy generation concept of thermodynamics, this paper estabfished a general theoretical model for the analysis of entropy generation to optimize fins, in which the minimum entropy generation was selected as the object to be studied. The irreversibility due to heat transfer and friction was taken into account so that the minimum entropy generation number has been analyzed with respect to second law of thermodynamics in the forced cross-flow. The optimum dimensions of cylinder pins were discussed. It's found that the minimum entropy generation number depends on parameters related to the fluid and fin physical parameters. Varlatioms of the minimum entropy generation number with different parameters were analyzed.展开更多
In all convective heat transfer situations, losses occur in the flow field (by dissipation) as well as in the temperature field (by conduction). Typically these losses are more or less quantified by the friction f...In all convective heat transfer situations, losses occur in the flow field (by dissipation) as well as in the temperature field (by conduction). Typically these losses are more or less quantified by the friction factorfwith respect to losses in the flow field, and the Nusselt number Nu for the heat transfer quality. Assessing the process of convective heat transfer as a whole, then becomes problematic because two different non-dimensional quantities, f and Nu, have to be combined somehow. From a thermodynamics point of view, there is a reasonable alternative: Since all losses become manifest in corresponding entropy generation rates, these rates are determined in the velocity as well as in the temperature field. Based on the integration of the entropy generation fields, an energy devaluation number is introduced. It basically determines how much oftbe so-called entropic potential of the energy involved in a convective heat transfer process is used within it. This approach is called SLA (second law analysis).展开更多
This study is seeking an answer as to whether the efficient state and the state under the rule of law are indeed irreconcilable, as well as to whether these two categories are by nature to be seen as contrary concepts...This study is seeking an answer as to whether the efficient state and the state under the rule of law are indeed irreconcilable, as well as to whether these two categories are by nature to be seen as contrary concepts. The basic issue is whether efficiency is to be handled as an "extralegal" category, or whether legal regulation, in accordance with public administration traditions in Europe, can in itself meet the requirement of efficiency. Also the study presents the formation of the issue of conflict between the effective state and the state under the rule of law in Hungary after the election held in 2010 in the practice of economic policy and legislation of the Orban government. We are trying to answer the question of the tendency of power concentration to really menace the principles of a traditionally-formed state under the rule of law, as well as whether the economic policy of the government can be implemented effectively in a strongly centralized political and state administrative system.展开更多
The space time variation laws of nitrogen content in different river sections, water periods and years in the Second Songhua River in China is described in detail. The results show that there is direct relation betwee...The space time variation laws of nitrogen content in different river sections, water periods and years in the Second Songhua River in China is described in detail. The results show that there is direct relation between the nitrogen content variation in river water and that in wastewater from cities and runoff water of both banks of the river. Nitrate and nitrite contents in water in flood period are higher than that in mid and low water periods. In flood period, nitrate content in water increases gradually with the extension of river section, ammonia content in polluted river section is higher than that in unpolluted river section. Nitrate and nitrite contents in water in the flood, mid and low water periods from 1985 to 1989 were slightly higher than that from 1980 to 1984 and from 1990 to 1994, ammonia content in water increased annually.展开更多
Power-law ( ) and exponential power-law ( ) functional forms model activity metabolism ( ) for fully submerged swimming animals, and are special cases of the power-law polynomial equation, in which?? is the observed t...Power-law ( ) and exponential power-law ( ) functional forms model activity metabolism ( ) for fully submerged swimming animals, and are special cases of the power-law polynomial equation, in which?? is the observed total metabolic rate measured at an observed steady swimming speed,? . The relationship between the metabolic efficiency of steady swimming and the exponents of?? is addressed in this paper to establish the use of?? () and?? () as optimal efficiencies for comparing the hydrodynamic and muscle metabolic efficiencies among fully submerged animals that engage in steady swimming activities. The metabolic efficiency of steady swimming is transformed into its ideal form ( ) from which??? the optimal hydrodynamic efficiency ( ) and the optimal muscle metabolic efficiency ( ) are derived. These optimal efficiencies are therefore ideal metabolic efficiencies measured at different optimal steady speeds. Subsequently, linear ( ) and exponential ( ) models are approximations with divergent optimal muscle metabolic efficiencies ( and , respectively), but with a similar optimal hydrodynamic efficiency ( ).展开更多
The law of mass action, based on maxwellian statistics, cannot explain recent epicatalysis experiments but does when generalized to non-maxwellian statistics. Challenges to the second law are traced to statistical het...The law of mass action, based on maxwellian statistics, cannot explain recent epicatalysis experiments but does when generalized to non-maxwellian statistics. Challenges to the second law are traced to statistical heterogeneity that falls outside assumptions of homogeneity and indistinguishability made by Boltzmann, Gibbs, Tolman and Von Neumann in their H-Theorems. Epicatalysis operates outside these assumptions. Hence, H-Theorems do not apply to it and the second law is bypassed, not broken. There is no contradiction with correctly understood established physics. Other phenomena also based on heterogeneous statistics include non-maxwellian adsorption, the field-induced thermoelectric effect and the reciprocal Hall effect. Elementary particles have well known distributions such as Fermi-Dirac and Bose Einstein, but composite particles such as those involved in chemical reactions, have complex intractable statistics not necessarily maxwellian and best determined by quantum modeling methods. A step by step solution for finding the quantum thermodynamic properties of a quantum composite gas, that avoids the computational requirement of modeling a large number of composite particles includes 1) quantum molecular modeling of a few particles, 2) determining their available microstates, 3) producing their partition function, 4) generating their statistics, and 5) producing the epicatalytic parameter for the generalized law of mass action.展开更多
It has been shown that the first principle of thermodynamics follows from the conservation laws for energy and linear momentum. And the second principle of thermodynamics follows from the first principle of thermodyna...It has been shown that the first principle of thermodynamics follows from the conservation laws for energy and linear momentum. And the second principle of thermodynamics follows from the first principle of thermodynamics under realization of the integrating factor (namely, temperature) and is a conservation law. The significance of the first principle of thermodynamics consists in the fact that it specifies the thermodynamic system state, which depends on interaction between conservation laws and is non-equilibrium due to a non-commutativity of conservation laws. The realization of the second principle of thermodynamics points to a transition of the thermodynamic system state into a locally-equilibrium state. Phase transitions are examples of such transitions.展开更多
Marx's theory of the law of diminishing land fertility is an indispensable part of Marx's theory of rent. Marx not only denied the non-scientific component of the theory, but also affirmed the scientific component o...Marx's theory of the law of diminishing land fertility is an indispensable part of Marx's theory of rent. Marx not only denied the non-scientific component of the theory, but also affirmed the scientific component of the theory. China's theoretical circles have held a total negative attitude towards the theory for a long term, which has brought serious consequences to research on agricultural economic theory and agricultural production practice. Comprehensively understanding the scientific connotation of Marx's theory of the law of diminishing land fertility has extremely important theoretical and practical significance for reducing the blindness of land investment and improving the investment efficiency of land.展开更多
Make up for deficiencies in the economic development of market mechanisms through macro-control method. Although the market plays a fundamental role in resource allocation, in other means of regulation it plays an irr...Make up for deficiencies in the economic development of market mechanisms through macro-control method. Although the market plays a fundamental role in resource allocation, in other means of regulation it plays an irreplaceable role in regulating the economy, the management of economic activities. However, by the market "invisible hand" spontaneous adjustment, there is "market failure" problem. Market self-regulation mechanisms inevitable cyclical economic fluctuations and economic crisis, the impact of a sustained and stable economic growth will lead to a waste of resources, environmental degradation is caused, but also it produces uneven regional development, causing social polarization between rich and poor, etc. Public goods such as ecological environment should be through legal means, rather than a means to implement the healthy development of the market environment.展开更多
The traditional thermodynamic theory explains the reversible phenomena quite well, except that reversible phenomena are rare or even impossible in practice. Here the purpose is to propose an explanation valid for reve...The traditional thermodynamic theory explains the reversible phenomena quite well, except that reversible phenomena are rare or even impossible in practice. Here the purpose is to propose an explanation valid for reversible and also irreversible phenomena, irreversibility being common or realistic. It previously exposed points tricky to grasp, as the sign of the work exchange, the adiabatic expansion in vacuum (free expansion) or the transfer of heat between two bodies at the same temperature (isothermal transfer). After having slightly modified the concepts of heat transfer (each body produces heat according to its own temperature) and work (distinguishing external pressure from internal pressure), the previous points are more easily explained. At last, an engine efficiency in case of irreversible transfer is proposed. This paper is focused on the form of thermodynamics, on “explanations”;it does not question on “results” (except the irreversible free expansion of 1845...) which remain unchanged.展开更多
Entropy function is used to demonstrate the Carnot efficiency, even if it is not always easy to understand its bases: the reversible movement or the reversible heat transfer. Here, it is proposed to demonstrate the Ca...Entropy function is used to demonstrate the Carnot efficiency, even if it is not always easy to understand its bases: the reversible movement or the reversible heat transfer. Here, it is proposed to demonstrate the Carnot efficiency “without” using the Entropy function. For this, it is necessary to enhance two concepts: heat transfer based on the source temperature and work transfer based on external pressure. This is achieved through 1) a balance exchanged heat, based on the source temperature and the system temperature, and 2) a balance exchanged work, based on the external pressure and the internal pressure. With these enhanced concepts, Laplace function and Carnot efficiency can be demonstrated without using the Entropy function (S). This is only a new formalism. Usual thermodynamics results are not changed. This new formalism can help to get a better description of realistic phenomena, like the efficiency of a realistic cycle.展开更多
With the development of large scale text processing, the dimension of text feature space has become larger and larger, which has added a lot of difficulties to natural language processing. How to reduce the dimension...With the development of large scale text processing, the dimension of text feature space has become larger and larger, which has added a lot of difficulties to natural language processing. How to reduce the dimension has become a practical problem in the field. Here we present two clustering methods, i.e. concept association and concept abstract, to achieve the goal. The first refers to the keyword clustering based on the co occurrence of展开更多
基金funded by the National Social Science Fund of China,“The Research on the Philosophical and Economic Basis of Chinese Private Law”(14CFX006)
文摘The pursuit of economic efficiency is the major driver for the birth of contemporary Chinese civil law.Contemporary civil law scholarship has demonstrated a serious concern for efficiency from the very beginning.However,many examples suggest that the notion of economic efficiency is often diluted or replaced by factors like civil law doctrinal scholasticism,moral notions,inertial thinking of the planned economy or the will of the leader.It has not been systematically attended to or expressed in a detailed and precise way in the contemporary civil law scholarship in China,rendering some economic judgments uneconomical.In the 21 st century,it is necessary for the civil law studies to establish a clearer and more precise notion of efficiency,to conduct more direct and accurate evaluations on civil laws’incentives on people’s behaviors and their socio-economic effects,so as to reduce the cost of social interactions and promote deeper cooperation and winwin outcome among individuals.
文摘There have emerged ample literature about the Second Law analysis of extraterrestrial and terrestrial solar radiation consequent to the pioneer works by R. Petela and D. C. Spanner, of which most are irrelevant to the frequency distribution of solar radiation. Since the Second Law analysis was introduced to the fields like photovoltaic and photosynthesis, rendering a need for a method closely related to solar radiation spectrum, some authors created wavelength dependent dilute factots to take the various influence of atmosphere on the frequency distribution into consideration. Because of the complexity of the influence on different frequency, it is not convenient and accurate enough to practically apply the present exergy theories of diluted solar radiation to real solar exergy systems at the surface of the earth. This paper shows a numerical method of Second Law analysis in dealing with the cases of diluted solar irradiance on the earth, based on the observed spectra of global direct and diffuse
文摘In this paper, the mistakes in the traditional first law are pointed out. A new second law of thermodynamics, the law of coupling is mentioned. The Liu's Principle of Free Energy Conservation is stated. And finally a New Discipline is expressed as A THEORETICAL FLOW SHEET.
基金The project supported by National Natural Science Foundation of China under Grant No. 10404039
文摘The second law of thermodynamics has been proven by many facts in classical world. Is there any new property of it in quantum world? In this paper, we calculate the change of entropy in T.D. Kieu's model for quantum heat engine (QHE) and prove the broad validity of the second law of thermodynamics. It is shown that the entropy of the quantum heat engine neither decreases in a whole cycle, nor decreases in either stage of the cycle. The second law of thermodynamics still holds in this QHE model. Moreover, although the modified quantum heat engine is capable of extracting more work, its efficiency does not improve at all. It is neither beyond the efficiency of T.D. Kieu's initial model,nor greater than the reversible Carnot efficiency.
文摘A Faraday isolator is shown to develop a temperature difference between its input and output, but still complies with the second law when all the heat carriers, in this case, photons are homogeneous and indistinguishable. This result is a consequence of the H-theorem which assumes homogeneity and indistinguishability of particles. However, when a thermal feedback path is added, in which heat carriers have physical properties different from the photons in the isolator, then a heterogeneous system is formed not covered by the H-theorem, and the second law is violated.
文摘A Faraday isolator is shown to develop a temperature difference between its input and output, but still complies with the second law when all the heat carriers, in this case, photons are homogeneous and indistinguishable. This result is a consequence of the H-theorem which assumes homogeneity and indistinguishability of particles. However, when a thermal feedback path is added, in which heat carriers have physical properties different from the photons in the isolator, then a heterogeneous system is formed not covered by the H-theorem, and the second law is violated.
文摘The aim of this numerical investigation is to evaluate the laminar forced convection of biologically synthesized water-silver nanofluid through a heat sink(HS)filled with porous foam(PHS)using first and second laws of thermodynamics.The impacts of inlet velocity(V=0.5–3 m·s^-1)and volume fraction of nanofluid(φ=0–1%)on the performance metrics of HS are assessed and the outcomes are compared with those of the non-porous HS(NHS).The outcomes revealed that for both the PHS and NHS,the increase of V causes an intensification in convection coefficient,pumping power,and entropy generation due to fluid friction,while the maximum CPU temperature,thermal resistance,and entropy generation due to the heat transfer reduces by boosting V.Also,it was found that the augmentation of V results in intensification in convection coefficient,pumping power,overall hydrothermal performance,and frictional entropy generation,while the opposite is true for maximum CPU temperature,thermal resistance,and thermal entropy generation.Furthermore,it was reported that,except forφ=0.5%,the overall hydrothermal performance of NHS is better than that of PHS,while PHS has better second-law performance than NHS in all the studied cases.Also,it can be concluded that the best hydrothermal performance for PHS belongs toφ=1%and V=0.5 m·s^-1,while for NHS,these values are 1%and 2 m·s^-1.
基金Supported by Shanghai Leading Academic Displine Project(No.B604)
文摘Refrigeration coefficient, ε, is usually calculated by using the First Law of Thermodynamics. In this paper, a new derivation process is introduced through the combination of the Second Law of Thermodynamics with the First Law of Thermodynamics. As a result, two new calculation equations for refrigeration coefficient are proposed. One equation is equivalent to the common method, but its form is a little complicated for real calculation. Another equation is the further simplification, and can be used to calculate the refrigeration coefficient instead of common method with a oermit error.
文摘Based on the entropy generation concept of thermodynamics, this paper estabfished a general theoretical model for the analysis of entropy generation to optimize fins, in which the minimum entropy generation was selected as the object to be studied. The irreversibility due to heat transfer and friction was taken into account so that the minimum entropy generation number has been analyzed with respect to second law of thermodynamics in the forced cross-flow. The optimum dimensions of cylinder pins were discussed. It's found that the minimum entropy generation number depends on parameters related to the fluid and fin physical parameters. Varlatioms of the minimum entropy generation number with different parameters were analyzed.
文摘In all convective heat transfer situations, losses occur in the flow field (by dissipation) as well as in the temperature field (by conduction). Typically these losses are more or less quantified by the friction factorfwith respect to losses in the flow field, and the Nusselt number Nu for the heat transfer quality. Assessing the process of convective heat transfer as a whole, then becomes problematic because two different non-dimensional quantities, f and Nu, have to be combined somehow. From a thermodynamics point of view, there is a reasonable alternative: Since all losses become manifest in corresponding entropy generation rates, these rates are determined in the velocity as well as in the temperature field. Based on the integration of the entropy generation fields, an energy devaluation number is introduced. It basically determines how much oftbe so-called entropic potential of the energy involved in a convective heat transfer process is used within it. This approach is called SLA (second law analysis).
文摘This study is seeking an answer as to whether the efficient state and the state under the rule of law are indeed irreconcilable, as well as to whether these two categories are by nature to be seen as contrary concepts. The basic issue is whether efficiency is to be handled as an "extralegal" category, or whether legal regulation, in accordance with public administration traditions in Europe, can in itself meet the requirement of efficiency. Also the study presents the formation of the issue of conflict between the effective state and the state under the rule of law in Hungary after the election held in 2010 in the practice of economic policy and legislation of the Orban government. We are trying to answer the question of the tendency of power concentration to really menace the principles of a traditionally-formed state under the rule of law, as well as whether the economic policy of the government can be implemented effectively in a strongly centralized political and state administrative system.
文摘The space time variation laws of nitrogen content in different river sections, water periods and years in the Second Songhua River in China is described in detail. The results show that there is direct relation between the nitrogen content variation in river water and that in wastewater from cities and runoff water of both banks of the river. Nitrate and nitrite contents in water in flood period are higher than that in mid and low water periods. In flood period, nitrate content in water increases gradually with the extension of river section, ammonia content in polluted river section is higher than that in unpolluted river section. Nitrate and nitrite contents in water in the flood, mid and low water periods from 1985 to 1989 were slightly higher than that from 1980 to 1984 and from 1990 to 1994, ammonia content in water increased annually.
文摘Power-law ( ) and exponential power-law ( ) functional forms model activity metabolism ( ) for fully submerged swimming animals, and are special cases of the power-law polynomial equation, in which?? is the observed total metabolic rate measured at an observed steady swimming speed,? . The relationship between the metabolic efficiency of steady swimming and the exponents of?? is addressed in this paper to establish the use of?? () and?? () as optimal efficiencies for comparing the hydrodynamic and muscle metabolic efficiencies among fully submerged animals that engage in steady swimming activities. The metabolic efficiency of steady swimming is transformed into its ideal form ( ) from which??? the optimal hydrodynamic efficiency ( ) and the optimal muscle metabolic efficiency ( ) are derived. These optimal efficiencies are therefore ideal metabolic efficiencies measured at different optimal steady speeds. Subsequently, linear ( ) and exponential ( ) models are approximations with divergent optimal muscle metabolic efficiencies ( and , respectively), but with a similar optimal hydrodynamic efficiency ( ).
文摘The law of mass action, based on maxwellian statistics, cannot explain recent epicatalysis experiments but does when generalized to non-maxwellian statistics. Challenges to the second law are traced to statistical heterogeneity that falls outside assumptions of homogeneity and indistinguishability made by Boltzmann, Gibbs, Tolman and Von Neumann in their H-Theorems. Epicatalysis operates outside these assumptions. Hence, H-Theorems do not apply to it and the second law is bypassed, not broken. There is no contradiction with correctly understood established physics. Other phenomena also based on heterogeneous statistics include non-maxwellian adsorption, the field-induced thermoelectric effect and the reciprocal Hall effect. Elementary particles have well known distributions such as Fermi-Dirac and Bose Einstein, but composite particles such as those involved in chemical reactions, have complex intractable statistics not necessarily maxwellian and best determined by quantum modeling methods. A step by step solution for finding the quantum thermodynamic properties of a quantum composite gas, that avoids the computational requirement of modeling a large number of composite particles includes 1) quantum molecular modeling of a few particles, 2) determining their available microstates, 3) producing their partition function, 4) generating their statistics, and 5) producing the epicatalytic parameter for the generalized law of mass action.
文摘It has been shown that the first principle of thermodynamics follows from the conservation laws for energy and linear momentum. And the second principle of thermodynamics follows from the first principle of thermodynamics under realization of the integrating factor (namely, temperature) and is a conservation law. The significance of the first principle of thermodynamics consists in the fact that it specifies the thermodynamic system state, which depends on interaction between conservation laws and is non-equilibrium due to a non-commutativity of conservation laws. The realization of the second principle of thermodynamics points to a transition of the thermodynamic system state into a locally-equilibrium state. Phase transitions are examples of such transitions.
文摘Marx's theory of the law of diminishing land fertility is an indispensable part of Marx's theory of rent. Marx not only denied the non-scientific component of the theory, but also affirmed the scientific component of the theory. China's theoretical circles have held a total negative attitude towards the theory for a long term, which has brought serious consequences to research on agricultural economic theory and agricultural production practice. Comprehensively understanding the scientific connotation of Marx's theory of the law of diminishing land fertility has extremely important theoretical and practical significance for reducing the blindness of land investment and improving the investment efficiency of land.
文摘Make up for deficiencies in the economic development of market mechanisms through macro-control method. Although the market plays a fundamental role in resource allocation, in other means of regulation it plays an irreplaceable role in regulating the economy, the management of economic activities. However, by the market "invisible hand" spontaneous adjustment, there is "market failure" problem. Market self-regulation mechanisms inevitable cyclical economic fluctuations and economic crisis, the impact of a sustained and stable economic growth will lead to a waste of resources, environmental degradation is caused, but also it produces uneven regional development, causing social polarization between rich and poor, etc. Public goods such as ecological environment should be through legal means, rather than a means to implement the healthy development of the market environment.
文摘The traditional thermodynamic theory explains the reversible phenomena quite well, except that reversible phenomena are rare or even impossible in practice. Here the purpose is to propose an explanation valid for reversible and also irreversible phenomena, irreversibility being common or realistic. It previously exposed points tricky to grasp, as the sign of the work exchange, the adiabatic expansion in vacuum (free expansion) or the transfer of heat between two bodies at the same temperature (isothermal transfer). After having slightly modified the concepts of heat transfer (each body produces heat according to its own temperature) and work (distinguishing external pressure from internal pressure), the previous points are more easily explained. At last, an engine efficiency in case of irreversible transfer is proposed. This paper is focused on the form of thermodynamics, on “explanations”;it does not question on “results” (except the irreversible free expansion of 1845...) which remain unchanged.
文摘Entropy function is used to demonstrate the Carnot efficiency, even if it is not always easy to understand its bases: the reversible movement or the reversible heat transfer. Here, it is proposed to demonstrate the Carnot efficiency “without” using the Entropy function. For this, it is necessary to enhance two concepts: heat transfer based on the source temperature and work transfer based on external pressure. This is achieved through 1) a balance exchanged heat, based on the source temperature and the system temperature, and 2) a balance exchanged work, based on the external pressure and the internal pressure. With these enhanced concepts, Laplace function and Carnot efficiency can be demonstrated without using the Entropy function (S). This is only a new formalism. Usual thermodynamics results are not changed. This new formalism can help to get a better description of realistic phenomena, like the efficiency of a realistic cycle.
文摘With the development of large scale text processing, the dimension of text feature space has become larger and larger, which has added a lot of difficulties to natural language processing. How to reduce the dimension has become a practical problem in the field. Here we present two clustering methods, i.e. concept association and concept abstract, to achieve the goal. The first refers to the keyword clustering based on the co occurrence of