光催化灭活是公认的控制病原微生物最具前景手段之一。本文以尿素和硫代巴比妥酸为起始原料,通过热聚合反应制备S掺杂g-C_(3)N_(4)(SCN),随后采用光还原法将Ag纳米粒负载于SCN表面获得新颖的可见光响应型Ag/SCN抗菌材料。对所制备纳米...光催化灭活是公认的控制病原微生物最具前景手段之一。本文以尿素和硫代巴比妥酸为起始原料,通过热聚合反应制备S掺杂g-C_(3)N_(4)(SCN),随后采用光还原法将Ag纳米粒负载于SCN表面获得新颖的可见光响应型Ag/SCN抗菌材料。对所制备纳米材料进行XRD、SEM、TEM、XPS及UV-Vis DRS表征,并深入探讨其在可见光下灭活大肠杆菌(E.coli)的性能和机制。结果表明,Ag纳米粒均匀且牢固地负载在SCN表面,纳米材料表现出显著增强的可见光响应能力。当负载量为6%时,Ag/SCN-6呈现出最佳的光催化灭菌活性,60 min内能够将6.2 lg CFU·mL^(-1)的E.coli全部灭活。自由基捕获实验结果表明,超氧自由基(·O-2)是灭活过程中最主要活性物种,它协同光生空穴(h+)和羟基自由基(·OH)主导了光催化抗菌的进程。展开更多
In Africa, agriculture has been identi fled as a prior development area in the China Africa strategic partnership. In its unwavering pursuit to mechanize Africa＇s agriculture and find new markets for its own compani...In Africa, agriculture has been identi fled as a prior development area in the China Africa strategic partnership. In its unwavering pursuit to mechanize Africa＇s agriculture and find new markets for its own companies, China looked upon farming proficiency as one of its first exports to Zambia.展开更多
A model predictive control(MPC)approach based on direct yaw moment control(DYC)was proposed to realize the self-steering drive for a newly autonomous four-wheel independent-drive(4WID)agricultural electric vehicle.The...A model predictive control(MPC)approach based on direct yaw moment control(DYC)was proposed to realize the self-steering drive for a newly autonomous four-wheel independent-drive(4WID)agricultural electric vehicle.The front axle and rear axle of the vehicle chassis could rotate simultaneously around their respective center points and cut the turning radius in half at most through specific mechanical chassis structure design and four-wheel electrical drive.It had great potential to reduce wheel traffic damage to field crops if two rear electrical drive wheels can be controlled to follow wheel tracks of two front wheels during self-steering operation.Therefore,firstly,a two-degree-freedom dynamics model presenting this agricultural electric vehicle was constructed.Then,an MPC controller combined with DYC was applied to arrange torques from four wheels to match desired turning angles,direct yaw moments and travel speeds.The simulation results existed small steady error of steering angles below 0.22%as they were set at 5°,followed with yaw moment under 0.17%and velocity less than 1%.Finally,according to experiment results,the vehicle successfully made a working turning radius of 9.1 m with maximum error of 0.55%when desired steering angles were 5°at the speed of 1 m/s and a minimum turning radius of 1.51 m with maximum error of 6.6%when steering angles were 30°at the speed of 0.5 m/s.It verified that the 4WID agricultural electric vehicle could drive autonomously and steady with small self-steering angle error under the proposed control system and has a feasibility to reduce wheel traffic damage during driving and operation.展开更多
文摘光催化灭活是公认的控制病原微生物最具前景手段之一。本文以尿素和硫代巴比妥酸为起始原料,通过热聚合反应制备S掺杂g-C_(3)N_(4)(SCN),随后采用光还原法将Ag纳米粒负载于SCN表面获得新颖的可见光响应型Ag/SCN抗菌材料。对所制备纳米材料进行XRD、SEM、TEM、XPS及UV-Vis DRS表征,并深入探讨其在可见光下灭活大肠杆菌(E.coli)的性能和机制。结果表明,Ag纳米粒均匀且牢固地负载在SCN表面,纳米材料表现出显著增强的可见光响应能力。当负载量为6%时,Ag/SCN-6呈现出最佳的光催化灭菌活性,60 min内能够将6.2 lg CFU·mL^(-1)的E.coli全部灭活。自由基捕获实验结果表明,超氧自由基(·O-2)是灭活过程中最主要活性物种,它协同光生空穴(h+)和羟基自由基(·OH)主导了光催化抗菌的进程。
文摘In Africa, agriculture has been identi fled as a prior development area in the China Africa strategic partnership. In its unwavering pursuit to mechanize Africa＇s agriculture and find new markets for its own companies, China looked upon farming proficiency as one of its first exports to Zambia.
基金This research work was funded by the National Natural Science Foundation of China(Grant No.51975260)Jiangsu Provincial Key Research and Development Program(Grant No.BE2018372),Jiangsu Natural Science Foundation(Grant No.BK20181443)+1 种基金Zhenjiang City Key Research and Development Program(Grant No.NY2018001)Qing Lan Project of Jiangsu Province,the Priority Academic Program Development(PAPD)of the Jiangsu Higher Education Institutions,China.The authors would like to acknowledge the other colleagues of the team for providing assistance in the experiment.
文摘A model predictive control(MPC)approach based on direct yaw moment control(DYC)was proposed to realize the self-steering drive for a newly autonomous four-wheel independent-drive(4WID)agricultural electric vehicle.The front axle and rear axle of the vehicle chassis could rotate simultaneously around their respective center points and cut the turning radius in half at most through specific mechanical chassis structure design and four-wheel electrical drive.It had great potential to reduce wheel traffic damage to field crops if two rear electrical drive wheels can be controlled to follow wheel tracks of two front wheels during self-steering operation.Therefore,firstly,a two-degree-freedom dynamics model presenting this agricultural electric vehicle was constructed.Then,an MPC controller combined with DYC was applied to arrange torques from four wheels to match desired turning angles,direct yaw moments and travel speeds.The simulation results existed small steady error of steering angles below 0.22%as they were set at 5°,followed with yaw moment under 0.17%and velocity less than 1%.Finally,according to experiment results,the vehicle successfully made a working turning radius of 9.1 m with maximum error of 0.55%when desired steering angles were 5°at the speed of 1 m/s and a minimum turning radius of 1.51 m with maximum error of 6.6%when steering angles were 30°at the speed of 0.5 m/s.It verified that the 4WID agricultural electric vehicle could drive autonomously and steady with small self-steering angle error under the proposed control system and has a feasibility to reduce wheel traffic damage during driving and operation.
