Geodynamic mechanism responsible for the generation of Silurian granitoids and the tectonic evolution of the Qilian orogenic belt remains controversial. In this study, we report the results of zircon U–Pb age, and sy...Geodynamic mechanism responsible for the generation of Silurian granitoids and the tectonic evolution of the Qilian orogenic belt remains controversial. In this study, we report the results of zircon U–Pb age, and systematic whole-rock geochemical data for the Haoquangou and Liujiaxia granitoids within the North Qilian orogenic belt and the Qilian Block, respectively, to constrain their petrogenesis, and the Silurian tectonic evolution of the Qilian orogenic belt. Zircon U–Pb ages indicate that the Haoquangou and Liujiaxia intrusions were emplaced at423 ± 3 Ma and 432 ± 4 Ma, respectively. The Haoquangou granodiorites are calc-alkaline, while the Liujiaxia granites belong to the high-K calc-alkaline series.Both are peraluminous in composition and have relatively depleted Nd isotopic [ε_(Nd)(t) =(-3.9 – + 0.6)] characteristics compared with regional basement rocks, implying their derivation from a juvenile lower crust. They show adakitic geochemical characteristics and were generated by partial melting of thickened lower continental crust. Postcollisional extensional regime related to lithospheric delamination was the most likely geodynamic mechanism for the generation of the Haoquangou granodiorite, while the Liujiaxia granites were generated in a compressive setting during continental collision between the Qaidam and Qilian blocks.展开更多
Well-preserved and diversified spores,cryptospores,and acritarchs have been recorded from a relatively continuous sequence that encompasses the Silurian-Devonian boundary in Qujing, Yunnan,southwest China.Four spore a...Well-preserved and diversified spores,cryptospores,and acritarchs have been recorded from a relatively continuous sequence that encompasses the Silurian-Devonian boundary in Qujing, Yunnan,southwest China.Four spore assemblage zones from Late Silurian to Early Devonian in age are proposed based on the first appearance datum（FAD）of characteristic spore species.In ascending stratigraphic order,they are Ambitisporites dilutus-Apiculiretusispora synorea（DS;Late Ludfordian to Early Pridoli）,Synorisporites verrucatus-Apiculiretusispora plicata（VP;Pridoli）,Apiculiretusispora minuta-Leiotriletes ornatus（MO;Lochkovian）,and Verrucosisporites polygonalis-Dibolisporites wetteldorfensis（PW;Pragian）.The acritarch assemblage from the upper part of the Yulongsi Formation,the Xiaxishancun Formation,and the lower-middle parts of the Xitun Formation indicates an age of Late Silurian.Based on palynological evidence,the upper part of the Yulongsi Formation is considered Late Ludfordian to Early Pridoli in age;the Xiaxishancun Formation is believed to be Pridoli in age;the Xitun Formation is considered Late Pridoli to Early Lochkovian in age;the Guijiatun Formation is considered Lochkovian in age;and the Xujiachong Formation is Late Lochkovian to Pragian in age.The Silurian-Devonian boundary is recognized between the VP and the MO spore biozones,and occurs within the middle part of the Xitun Formation.展开更多
Carbon isotope （δ13Corg） analyses of non-marine clastic rocks and neritic carbonates and black shales spanning the Silurian/Devonian transition are compared from two richly fossiliferous sequences in Qujing of East...Carbon isotope （δ13Corg） analyses of non-marine clastic rocks and neritic carbonates and black shales spanning the Silurian/Devonian transition are compared from two richly fossiliferous sequences in Qujing of East Yunnan and Zoige of Sichuan, South China. The two sections, Xishancun and Putonggou sections in South China, reveal positive δ13Corg shifts happening in the Upper Pridoli and Lower Devonian and reaching peak values as heavy as -25.2‰ （Xishancun） and -19.9‰（Putonggou） in the lowermost Lochkovian following the first occurrence of the thelodont Parathelodus and the conodont Icriodus woschmidti woschmidti （only in Putonggou Section and together with Protathyris-Lanceomyonia brachiopod fauna）. These results replicate a globally known positive shift in δ13Corg from the uppermost Silurian to the lowermost Devonian. The δ13Corg variations across the Silurian/Devonian Boundary （SDB） at the two sections in South China exhibit a shift in carbon isotopic composition similar to the detailed SDB curves from the borehole Klonk-1 drilled at top of the Klonk Global Standard Stratotype-Section and Point （GSSP） in the Prague Basin, Czech Republic. In addition, four microvertebrate assemblages, including the Liaojiaoshan, Xishancun, Yanglugou and Xiaputonggou assemblages, are recognized from the Silurian/Devonian transition exposed in the Xishancun and Putonggou sections, respectively. The results from both carbon isotope stratigraphy and microvertebrate assemblage sequences suggest that the SDB in South China is located at the base of the Xishancun Formation （between sample QX-20 and sample QX-21） in the Xishancun Section and the lower part of the Xiaputonggou Formation （between sample ZP-09 and sample ZP-10） in the Putonggou Section. The isotopic trend for organic carbon together with the changes of microvertebrate remains across the SDB can offer an approach to a potential correlation of the SDB from different sedimentary facies, which help to correlate the marine with non-marine deposits.展开更多
A new species of Shuyuidae(Eugaleaspiformes,Galeaspida),Jiangxialepis jiujiangensis sp.nov.,is described from the lower Telychian(Llandovery,Silurian)Qingshui Formation in Jiujiang,Jiangxi Province,China.The new speci...A new species of Shuyuidae(Eugaleaspiformes,Galeaspida),Jiangxialepis jiujiangensis sp.nov.,is described from the lower Telychian(Llandovery,Silurian)Qingshui Formation in Jiujiang,Jiangxi Province,China.The new species differs from the type species J.retrospina from Wuhan,Hubei Province in its sharp and posteriorly positioned median dorsal spine and narrow spine-shaped inner cornual processes.The Silurian strata in Xiushui–Wuning area has provided a standard framework for the correlation of Silurian shallow marine red beds in South China.Thus,the finding of J.jiujiangensis from the Silurian Lower Red Beds(LRBs)in Jiangxi Province bears very important biostratigraphic significance.It can directly compare to Jiangxialepis retrospina from the Fentou Formation in Wuhan,Hubei Province in the genus level.This indicates that the age of the fish-bearing strata in Wuhan is most likely to be the early Telychian rather than middle Telychian as previously assumed.展开更多
The Late Devonian-early Carboniferous deposits of the Anarak section in northeastern Isfahan,Central Iran,evaluated based on conodont biostratigraphy,sedimentary environment and sequence stratigraphy.According to the ...The Late Devonian-early Carboniferous deposits of the Anarak section in northeastern Isfahan,Central Iran,evaluated based on conodont biostratigraphy,sedimentary environment and sequence stratigraphy.According to the field observations,five lithological units were identified.Investigating the conodont fauna of the Late Devonian-Carboniferous(Mississippian-Pennsylvanian)deposits of Bahram,Shishtu,and Qaleh(Sardar 1)formations in Anarak section led to the identification of 67 species of 18 conodont genera,and accordingly 22 conodont biozones were differentiated.The correlation of sea-level change curves,regarding to the conodont biofacies with the global sea-level curve,demonstrates the relative correlation in the mentioned times due to the shallow condition of the central Iran basin compared to the European and American basins.The microfacies analysis led to the identification of 12 microfacies related to the open sea,bioclastic barrier,lagoon and tidal flat sub-sedimentary environments in a homoclinal carbonate ramp environment.Based on sequence stratigraphy studies,three 3rd order sequences were identified.The first sequence,which is of the Late Devonian(upper part of the Bahram Formation,32.5 m),the second sequence(12.5 m)is the Late Devonian(uppermost part of the Bahram Formation),and the third sequence(68 m)is the early Carboniferous(the Shishtu I Formation).展开更多
The relationship between fracture calcite veins and shale gas enrichment in the deep Ordovician Wufeng Formation-Silurian Longmaxi Formation (Wufeng-Longmaxi) shales in southern Sichuan Basin was investigated through ...The relationship between fracture calcite veins and shale gas enrichment in the deep Ordovician Wufeng Formation-Silurian Longmaxi Formation (Wufeng-Longmaxi) shales in southern Sichuan Basin was investigated through core and thin section observations, cathodoluminescence analysis, isotopic geochemistry analysis, fluid inclusion testing, and basin simulation. Tectonic fracture calcite veins mainly in the undulating part of the structure and non-tectonic fracture calcite veins are mainly formed in the gentle part of the structure. The latter, mainly induced by hydrocarbon generation, occurred at the stage of peak oil and gas generation, while the former turned up with the formation of Luzhou paleouplift during the Indosinian. Under the influence of hydrocarbon generation pressurization process, fractures were opened and closed frequently, and oil and gas episodic activities are recorded by veins. The formation pressure coefficient at the maximum paleodepth exceeds 2.0. The formation uplift stage after the Late Yanshanian is the key period for shale gas migration. Shale gas migrates along the bedding to the high part of the structure. The greater the structural fluctuation is, the more intense the shale gas migration activity is, and the loss is more. The gentler the formation is, the weaker the shale gas migration activity is, and the loss is less. The shale gas enrichment in the core of gentle anticlines and gentle synclines is relatively higher.展开更多
Based on analysis of pore features and pore skeleton composition of shale,a“rigid elastic chimeric”pore skeleton model of shale gas reservoir was built.Pore deformation mechanisms leading to increase of shale porosi...Based on analysis of pore features and pore skeleton composition of shale,a“rigid elastic chimeric”pore skeleton model of shale gas reservoir was built.Pore deformation mechanisms leading to increase of shale porosity due to the pore skeleton deformation under overpressure were sorted out through analysis of stress on the shale pore and skeleton.After reviewing the difficulties and defects of existent porosity measurement methods,a dynamic deformed porosity measurement method was worked out and used to measure the porosity of overpressure Silurian Longmaxi Formation shale under real formation conditions in southern Sichuan Basin.The results show:(1)The shale reservoir is a mixture of inorganic rock particles and organic matter,which contains inorganic pores supported by rigid skeleton particles and organic pores supported by elastic-plastic particles,and thus has a special“rigid elastic chimeric”pore structure.(2)Under the action of formation overpressure,the inorganic pores have tiny changes that can be assumed that they don’t change in porosity,while the organic pores may have large deformation due to skeleton compression,leading to the increase of radius,connectivity and ultimately porosity of these pores.(3)The“dynamic”deformation porosity measurement method combining high injection pressure helium porosity measurement and kerosene porosity measurement method under ultra-high variable pressure can accurately measure porosity of unconnected micro-pores under normal pressure conditions,and also the porosity increment caused by plastic skeleton compression deformation.(4)The pore deformation mechanism of shale may result in the"abnormal"phenomenon that the shale under formation conditions has higher porosity than that under normal pressure,so the overpressure shale reservoir is not necessarily“ultra-low in porosity”,and can have porosity over 10%.Application of this method in Well L210 in southern Sichuan has confirmed its practicality and reliability.展开更多
基金funded by Gansu Provincial Natural Science Foundation (Grant Numbers 21JR7RA503 and22JR5RA819)the Fundamental Research Funds for the Central Universities (Grant lzujbky-2021-ct07)+1 种基金the Key Talent Project of Gansu Province (2022-Yangzhenxi)the National Second Expedition to the Tibetan Plateau (2019QZKK0704)。
文摘Geodynamic mechanism responsible for the generation of Silurian granitoids and the tectonic evolution of the Qilian orogenic belt remains controversial. In this study, we report the results of zircon U–Pb age, and systematic whole-rock geochemical data for the Haoquangou and Liujiaxia granitoids within the North Qilian orogenic belt and the Qilian Block, respectively, to constrain their petrogenesis, and the Silurian tectonic evolution of the Qilian orogenic belt. Zircon U–Pb ages indicate that the Haoquangou and Liujiaxia intrusions were emplaced at423 ± 3 Ma and 432 ± 4 Ma, respectively. The Haoquangou granodiorites are calc-alkaline, while the Liujiaxia granites belong to the high-K calc-alkaline series.Both are peraluminous in composition and have relatively depleted Nd isotopic [ε_(Nd)(t) =(-3.9 – + 0.6)] characteristics compared with regional basement rocks, implying their derivation from a juvenile lower crust. They show adakitic geochemical characteristics and were generated by partial melting of thickened lower continental crust. Postcollisional extensional regime related to lithospheric delamination was the most likely geodynamic mechanism for the generation of the Haoquangou granodiorite, while the Liujiaxia granites were generated in a compressive setting during continental collision between the Qaidam and Qilian blocks.
基金supported by the Chinese Academy of Sciences(noKZCX2-YW-105, KZCX2-SW-130)the National Natural Science Foundation of China(no40523004 and 40072005)
文摘Well-preserved and diversified spores,cryptospores,and acritarchs have been recorded from a relatively continuous sequence that encompasses the Silurian-Devonian boundary in Qujing, Yunnan,southwest China.Four spore assemblage zones from Late Silurian to Early Devonian in age are proposed based on the first appearance datum（FAD）of characteristic spore species.In ascending stratigraphic order,they are Ambitisporites dilutus-Apiculiretusispora synorea（DS;Late Ludfordian to Early Pridoli）,Synorisporites verrucatus-Apiculiretusispora plicata（VP;Pridoli）,Apiculiretusispora minuta-Leiotriletes ornatus（MO;Lochkovian）,and Verrucosisporites polygonalis-Dibolisporites wetteldorfensis（PW;Pragian）.The acritarch assemblage from the upper part of the Yulongsi Formation,the Xiaxishancun Formation,and the lower-middle parts of the Xitun Formation indicates an age of Late Silurian.Based on palynological evidence,the upper part of the Yulongsi Formation is considered Late Ludfordian to Early Pridoli in age;the Xiaxishancun Formation is believed to be Pridoli in age;the Xitun Formation is considered Late Pridoli to Early Lochkovian in age;the Guijiatun Formation is considered Lochkovian in age;and the Xujiachong Formation is Late Lochkovian to Pragian in age.The Silurian-Devonian boundary is recognized between the VP and the MO spore biozones,and occurs within the middle part of the Xitun Formation.
基金supported by the Basic Research Projects of Science and Technology: Research on standard sections and some GSSPs in China (2006FY120300-6)the Major State Basic Research Projects (2006CB806400) of MST of China+2 种基金the Creative Research Project of CAS (KZCX2-YW-156)the National Natural Science Foundation of China (40930208)the Important National Science and Technology Specific Projects (2008ZX05008-001)
文摘Carbon isotope （δ13Corg） analyses of non-marine clastic rocks and neritic carbonates and black shales spanning the Silurian/Devonian transition are compared from two richly fossiliferous sequences in Qujing of East Yunnan and Zoige of Sichuan, South China. The two sections, Xishancun and Putonggou sections in South China, reveal positive δ13Corg shifts happening in the Upper Pridoli and Lower Devonian and reaching peak values as heavy as -25.2‰ （Xishancun） and -19.9‰（Putonggou） in the lowermost Lochkovian following the first occurrence of the thelodont Parathelodus and the conodont Icriodus woschmidti woschmidti （only in Putonggou Section and together with Protathyris-Lanceomyonia brachiopod fauna）. These results replicate a globally known positive shift in δ13Corg from the uppermost Silurian to the lowermost Devonian. The δ13Corg variations across the Silurian/Devonian Boundary （SDB） at the two sections in South China exhibit a shift in carbon isotopic composition similar to the detailed SDB curves from the borehole Klonk-1 drilled at top of the Klonk Global Standard Stratotype-Section and Point （GSSP） in the Prague Basin, Czech Republic. In addition, four microvertebrate assemblages, including the Liaojiaoshan, Xishancun, Yanglugou and Xiaputonggou assemblages, are recognized from the Silurian/Devonian transition exposed in the Xishancun and Putonggou sections, respectively. The results from both carbon isotope stratigraphy and microvertebrate assemblage sequences suggest that the SDB in South China is located at the base of the Xishancun Formation （between sample QX-20 and sample QX-21） in the Xishancun Section and the lower part of the Xiaputonggou Formation （between sample ZP-09 and sample ZP-10） in the Putonggou Section. The isotopic trend for organic carbon together with the changes of microvertebrate remains across the SDB can offer an approach to a potential correlation of the SDB from different sedimentary facies, which help to correlate the marine with non-marine deposits.
基金supported by the Strategic Priority Research Program of CAS(XDB26000000)Key Research Program of Frontier Sciences,CAS(QYZDB-SSWDQC040)+1 种基金National Natural Science Foundation of China(41972006,42072026)National Program for Support of Topnotch Young Professionals(W02070206)。
文摘A new species of Shuyuidae(Eugaleaspiformes,Galeaspida),Jiangxialepis jiujiangensis sp.nov.,is described from the lower Telychian(Llandovery,Silurian)Qingshui Formation in Jiujiang,Jiangxi Province,China.The new species differs from the type species J.retrospina from Wuhan,Hubei Province in its sharp and posteriorly positioned median dorsal spine and narrow spine-shaped inner cornual processes.The Silurian strata in Xiushui–Wuning area has provided a standard framework for the correlation of Silurian shallow marine red beds in South China.Thus,the finding of J.jiujiangensis from the Silurian Lower Red Beds(LRBs)in Jiangxi Province bears very important biostratigraphic significance.It can directly compare to Jiangxialepis retrospina from the Fentou Formation in Wuhan,Hubei Province in the genus level.This indicates that the age of the fish-bearing strata in Wuhan is most likely to be the early Telychian rather than middle Telychian as previously assumed.
文摘The Late Devonian-early Carboniferous deposits of the Anarak section in northeastern Isfahan,Central Iran,evaluated based on conodont biostratigraphy,sedimentary environment and sequence stratigraphy.According to the field observations,five lithological units were identified.Investigating the conodont fauna of the Late Devonian-Carboniferous(Mississippian-Pennsylvanian)deposits of Bahram,Shishtu,and Qaleh(Sardar 1)formations in Anarak section led to the identification of 67 species of 18 conodont genera,and accordingly 22 conodont biozones were differentiated.The correlation of sea-level change curves,regarding to the conodont biofacies with the global sea-level curve,demonstrates the relative correlation in the mentioned times due to the shallow condition of the central Iran basin compared to the European and American basins.The microfacies analysis led to the identification of 12 microfacies related to the open sea,bioclastic barrier,lagoon and tidal flat sub-sedimentary environments in a homoclinal carbonate ramp environment.Based on sequence stratigraphy studies,three 3rd order sequences were identified.The first sequence,which is of the Late Devonian(upper part of the Bahram Formation,32.5 m),the second sequence(12.5 m)is the Late Devonian(uppermost part of the Bahram Formation),and the third sequence(68 m)is the early Carboniferous(the Shishtu I Formation).
基金Supported by the PetroChina Science and Technology Project(2022KT1205).
文摘The relationship between fracture calcite veins and shale gas enrichment in the deep Ordovician Wufeng Formation-Silurian Longmaxi Formation (Wufeng-Longmaxi) shales in southern Sichuan Basin was investigated through core and thin section observations, cathodoluminescence analysis, isotopic geochemistry analysis, fluid inclusion testing, and basin simulation. Tectonic fracture calcite veins mainly in the undulating part of the structure and non-tectonic fracture calcite veins are mainly formed in the gentle part of the structure. The latter, mainly induced by hydrocarbon generation, occurred at the stage of peak oil and gas generation, while the former turned up with the formation of Luzhou paleouplift during the Indosinian. Under the influence of hydrocarbon generation pressurization process, fractures were opened and closed frequently, and oil and gas episodic activities are recorded by veins. The formation pressure coefficient at the maximum paleodepth exceeds 2.0. The formation uplift stage after the Late Yanshanian is the key period for shale gas migration. Shale gas migrates along the bedding to the high part of the structure. The greater the structural fluctuation is, the more intense the shale gas migration activity is, and the loss is more. The gentler the formation is, the weaker the shale gas migration activity is, and the loss is less. The shale gas enrichment in the core of gentle anticlines and gentle synclines is relatively higher.
基金Supported by the National Science and Technology Major Project of China(2017ZX05035).
文摘Based on analysis of pore features and pore skeleton composition of shale,a“rigid elastic chimeric”pore skeleton model of shale gas reservoir was built.Pore deformation mechanisms leading to increase of shale porosity due to the pore skeleton deformation under overpressure were sorted out through analysis of stress on the shale pore and skeleton.After reviewing the difficulties and defects of existent porosity measurement methods,a dynamic deformed porosity measurement method was worked out and used to measure the porosity of overpressure Silurian Longmaxi Formation shale under real formation conditions in southern Sichuan Basin.The results show:(1)The shale reservoir is a mixture of inorganic rock particles and organic matter,which contains inorganic pores supported by rigid skeleton particles and organic pores supported by elastic-plastic particles,and thus has a special“rigid elastic chimeric”pore structure.(2)Under the action of formation overpressure,the inorganic pores have tiny changes that can be assumed that they don’t change in porosity,while the organic pores may have large deformation due to skeleton compression,leading to the increase of radius,connectivity and ultimately porosity of these pores.(3)The“dynamic”deformation porosity measurement method combining high injection pressure helium porosity measurement and kerosene porosity measurement method under ultra-high variable pressure can accurately measure porosity of unconnected micro-pores under normal pressure conditions,and also the porosity increment caused by plastic skeleton compression deformation.(4)The pore deformation mechanism of shale may result in the"abnormal"phenomenon that the shale under formation conditions has higher porosity than that under normal pressure,so the overpressure shale reservoir is not necessarily“ultra-low in porosity”,and can have porosity over 10%.Application of this method in Well L210 in southern Sichuan has confirmed its practicality and reliability.
