Design,preparation,application of advanced array structured materials and their action mechanism analyses for high performance lithium-sulfur batteries

Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,etc.In various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li PSs.Thus many novel array structured materials are applied to battery for tackling thorny problems mentioned above.In this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are summarized.Meanwhile,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery performances.Lastly,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are generalized.We hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.

The effects of population aging on industrial structure upgrading:Empirical analysis of provincial and threshold characteristics in China

Global population aging trends are intensifying,presenting multifaceted economic and social challenges for countries worldwide.As the world’s largest developing country,China has entered a phase of extreme demographic aging,posing significant questions about its impact on the ongoing upgrading of industrial structures.How does this demographic shift influence the upgrading of industrial structures,and does technological innovation mitigate or exacerbate this impact?The empirical results indicate that population aging impedes upgrading the industrial structure,while technological innovation positively affects the relationship between the two.Moreover,using technological innovation as a threshold variable,the impact of population aging on industrial structure upgrading evolves in a“gradient”manner from“impediment”to“insignificant”to“promotion”as the technological innovation levels increase.These findings offer practical guidance for tailoring industrial policies to different stages of technological advancement.

The Impact of the“Belt and Road”Initiative on Industrial Structure Upgrading Along the Corridor

The“Belt and Road”initiative functions as a novel impetus for China’s external economic development within the framework of the new normal of economic growth.By leveraging panel data from 30 provinces and regions across China for the period of 2010 to 2020,this research assesses the influence of the“Belt and Road”initiative on the enhancement of the industrial structure along its trajectory.The findings indicate that:the most notable influence on the rationalization and progress of the industrial structure is observed in the eastern region,with the central region following suit,whereas the western region has yet to exhibit a significant transformation.The analysis delves into the role of technological innovation,concluding that the initiative primarily catalyzes optimization and upgrading through the effect of technological advancement.The study advances several pertinent policy recommendations to support and enhance these developments.

Technological anxiety:Analysis of the impact of industrial intelligence on employment in China

Employment is the greatest livelihood.Whether the impact of industrial robotics technology materialized in machines on employment in the digital age is an“icing on the cake”or“adding fuel to the fire”needs further study.This study aims to analyze the impact of the installation and application of industrial robots on labor demand in the context of the Chinese economy.First,from the theoretical logic and the economic development law,this study gives the prior judgment and research hypothesis that industrial intelligence will increase jobs.Then,based on the panel data of 269 cities in China from 2006 to 2021,we use the two-way fixed effect model,dynamic threshold model,and two-stage intermediary effect model.The objective is to investigate the impact of industrial intelligence on enterprise labor demand and its path mechanism.Results show that the overall effect of industrial intelligence on the labor force with the installation density index of industrial robots as the proxy variable is the“creation effect”.In other words,advanced digital technology has created additional jobs,and the overall supply of employment in the labor market has increased.The conclusion is still valid after the endogeneity identification and robustness test.In addition,the positive effect has a nonlinear effect on the network scale.When the installation density of industrial robots exceeds a particular threshold value,the division of labor continues to deepen under the combined action of the production efficiency and compensation effects,which will cause enterprises to increase labor demand further.Further research showed that industrial intelligence can increase employment by promoting synergistic agglomeration and improving labor price distortions.This study concludes that in the digital China era,the introduction and installation of industrial robots by enterprises can affect the optimal allocation of the labor market.This phenomenon has essential experience and reference significance for guiding industrial digitalization and intelligent transformation and promoting the high-quality development of people’s livelihood.

Research and Practice on the Construction of Professional Cluster in Application-Oriented Local Undergraduate Universities:Taking Environ-mental Chemical Engineering Professional Cluster in Pingdingshan University as an Example

Based on the analysis of the importance of professional cluster construction by ecological theory,with the change of social demand for talents,this paper explores the practice of environmental chemical professional cluster construction in Pingdingshan University,including gradually perfecting teaching conditions and reforming teaching mode,breaking through the limitations of resources,integrating the boundaries of colleges and departments,integrating multiple resources,innovating systems and mechanisms,reconstructing professional clusters,decon-structing professional connotations,reorganizing curriculum systems,etc.,in order to better build the ecological chain network of education in application-oriented colleges and universities,realize the deep integration of industry and education,train future-oriented interdisciplinary applied talents of new engineering,and realize the construction of characteristic professional cluster in application-oriented colleges.

Investigating the Influence of Digital Economy Growth on Industrial Structural Optimization and Upgrading

With the rapid development of the social economy,science and technology continue to upgrade and optimize,ushering in the digital era,which provides technical support for industrial innovation and development across all sectors.At this stage,vigorously developing the digital economy has gradually become the only means to optimize and upgrade the industrial structure.Therefore,local leaders and relevant departments need to enhance the importance of constructing the digital economy,enabling the local industrial structure to be optimized and upgraded under the impetus of the digital economy,ultimately promoting overall economic high-quality development.To this end,this paper,combined with existing research results,first elaborates on the positive impact of the digital economy on the optimization and upgrading of the industrial structure.It then analyzes the challenges hindering the process of industrial structure optimization and upgrading and proposes practical pathways to address them,benefiting relevant stakeholders.

Empirical analysis of carbon tariff's effect on the export structure of China's manufacturing industry and social welfare based on the GTAP model

In recent years,carbon emissions have gradually evolved from an environment issue into a political and economic one.Carbon tariff has brought about new trade barriers of developed countries,and in order to enhance the industrial competitiveness of developed countries,it will produce unfavorable impact on developing countries.Concentrated on the manufacturing industry,which is the most intensive high-carbon industry in China's export structure,this article studies the relationship between carbon tariff policy and industry structure of export trade and builds up a relation between climate change and international trade.First,by means of establishing a partial equilibrium model,it applies geometric analysis and mathematical analysis to compute the impact on China's manufacturing export trade and the consequences of the introduction of the US carbon tariff to China's manufacturing industry that has already imposed a domestic shipping carbon tax.Furthermore,with the application of the GTAP model,it estimates the overall economic and welfare effects on China's manufacturing industry if the US and Europe introduce carbon tariff by means of four ways,and then analyzes the influence on China's manufacturing industry export structure and social welfare as well.The result shows that the introduction of the US carbon import tariff lowers China's export price and export volume,and the implementation of a domestic carbon tax justifies a higher export price and a lower export volume for China.However,the degree of export reduction is smaller than that under the effect of the US carbon tariff.In the case of developed countries imposing carbon tariff on China's energy-intensive industries,such as chemical rubber products,oil and coal-processing industry and paper industry,whose export would be reduced,the negative impact on the paper industry is the severest,which will decrease the paper industry's export ranging from 1.79%to 6.05%,whereas the other industries' export will increase.Anyhow,it will promote China's manufacturing industry to adjust the export structure to a certain extent.In addition,it will lead to a decrease in China's welfare,with a decrease between $2,134 billion and $8,347 billion.Finally,this paper provides information on international coordination,export structure adjustment and green manufacturing adjustment as a reference for the development of China's manufacturing industry.

Studies on the Structure Evolvement of Organic Agricultural Industry in Taiwan and its Influential Factors

In order to study the development of organic agriculture in Taiwan in recent years,and based on relevant agriculture,economic and social statistics,the general scale of organic agriculture and industrial structure were treated with statistic analysis. Results suggest that the general scale of organic agriculture in Taiwan grew rapidly from 2004 to 2011. The certified organic farmers grew by 140. 59%,and the area with organic plantation grew by 302. 40%. The industrial structure has changed significantly as vegetables have become the No. 1 organic crop instead of rice. Besides of the four major crops,organic plantation has played an increasingly important role. Essential factors influencing the great-leap-forward development include the general trend of agricultural industrial structure adjustment,proliferation of management system and strategic opportunities brought by economic cycles.

Research on the Relationship Between Environmental and Economic Coupling Systems in Bohai Bay Area Based on a Vector Autoregression(VAR)Model

This study analyzed the impact of land-based contaminants and tertiary industrial structure on economic development in the selected Bohai Bay area,China.Based on panel data spanning 2011-2020,a vector autoregressive(VAR)model is used to analyze and forecast the short-run and long-run relationships between three industrial structures,pollutant discharge,and economic development.The results showed that the environmental index had a long-term cointegration relationship with the industrial structure economic index.Per capital chemical oxygen demand(PCOD)and per capita ammonia nitrogen(PNH_(3)N)had a positive impact on delta per capita GDP(dPGDP),while per capita solid waste(PSW),the secondary industry rate(SIR)and delta tertiary industry(dTIR)had a negative impact on dPGDP.The VAR model under this coupling system had stability and credibility.The impulse response results showed that the short-term effect of the coupling system on dPGDP was basically consistent with the Granger causality test results.In addition,variance decomposition was used in this study to predict the long-term impact of the coupling system in the next ten periods(i.e.,ten years).It was found that dTIR had a great impact on dPGDP,with a contribution rate as high as 74.35%in the tenth period,followed by the contribution rate of PCOD up to 3.94%,while the long-term contribution rates of PSW,SIR and PNH3N were all less than 1%.The results show that the government should support the development of the tertiary industry to maintain the vitality of economic development and prevent environmental deterioration.

The Study on Industrial Structure Adjustment of Farmer Economic Net Income Doubled in Mountain Area

The aim was to study the main industry effect the double of the per capi- ta net income of farmers economic. The relation between six industry net income per capita income of farmers including grain, animal husbandry, flue-cured tobacco, walnut, long-term labor expot, seasonal labor export and the net income of farmers per capita in the Wazitian Village of Baoshan, Yunnan was studied by means of the effect main industry doubled net income of farmers per capita economic and the grey correlation analysis. The correlation degree of six industry and the net income of farmers per capita economic was long-term labor export〉seasonal labor export〉 walnut〉grain〉animal husbandry〉flue-cured tobacco. The pillar industry affecting the net income of farmers per capita economic was long-term labor export, seasonal la- bor export and walnut. The study provided the scionce theoretical basis and method of support for net income per capita economic multiplier of farmers in Baoshan, Yunnan province and even a similar low latitude mountain plateau.

Study on the Industry Structure of Employment and Its Optimizing Measures in China

This article studies the change in the industry structure of employment in China based on the practical analysis of data of the change in the industry structure of employment and the production value of three major sectors and GNP. At the same time, the article studies the status quo of the industry structure of employment in China compared with other countries. On the basis of these studies, the article indicates the main problems in the industry structure of employment in China and gives some countermeasures to optimize it.

Optimizing forestry industrial structure based on the framework of rationalization,advancement and ecologicalization

Under the target of the sustainable development,optimization of forestry industrial structure contains rationalization and advancement of forestry industrial structure in the traditional sense,as well as ecologicalization of forestry industrial structure.The connotation of optimization of forestry industrial structure is analyzed at first,and then the paper chooses the typical evaluation indexes from the three sides of rationalization,advancement and ecologicalization to evaluate the current situation of the regional forestry industrial structure.With the aid of the theory of fuzzy mathematics and information entropy,the paper establishes a fuzzy evaluation model which is based on information entropy for optimization of forestry industrial structure,and the evaluation model is applied in the study for the current situation of forestry industrial structure from 2000 to 2006 in Hubei province.The results show that the grade of forestry industrial structure is bad basically during the research,of which the overall level of forestry industrial structure of Hubei province is poor,the degree of utilizing forest resource is lower,and ecological environment in the forest region has been damaged to some extent.On this basis,the author presents the countermeasure to promote the optimization of forestry industrial structure.

The Review of the Research Paradigm of Capital Structure Based on the Theory of Industry Organization

Capital structure is one of the important research aspects of corporate finance. According to methodology, the capital structure research can be classified into two categories： the paradigm of uni-corporation and the paradigm of industry organization. Traditional capital structure research can be attribute to uni-corporation aspect. This paper reviews all literatures concerning the paradigm of industry organization and illustrates the inter-relationship among the feature of industry, the feature of suppliers and customers, the competitive strategy, product life cycle and capital structure.

Advancement in Science and Technology Enhanced the Growth of China's Electric Power Industry

Within the seven years’ period from 1987 to 1994. the total installed capacity of China’s electric power industry doubled from 100 GW to 200 GW. This high rate of growth has imposed new and more stringent requirements on all the branches in the

An Empirical Research on the Relationship of Market Structure,Efficiency and Performance of Chinese Traditional Patent Medicine Industry

Objective To explore the relationship of market structure,efficiency and performance of Chinese traditional patent medicine(CTPM)industry,and to provide suggestions for the government and related enterprises to take the corresponding strategies.Methods Econometric model were empirically analyzed about 44 ongoing sample enterprises from 2007 to 2017,based on market power hypothesis and efficiency structure hypothesis of the industrial organization theory.Results and Conclusion The CTPM industry and the unlisted enterprises only conform to the relative market power hypothesis,and there is a significant positive correlation between performance and market share.The listed enterprises do not conform to the market power hypothesis and efficiency structure hypothesis:There is no significant correlation between performance and efficiency,market structure.There is no significant correlation between market share and efficiencies,while the industrial concentration has a significant correlation with efficiencies.The CTPM industry is relatively immature,so it’s necessary for the government to establish the elimination mechanism of CTPM industry in line with market rules,to enhance the industrial concentration and resource utilization efficiency by encouraging enterprises to improve management and scale production level.The government should improve the innovation policy of CTPM industry to encourage the enterprises to pursue product innovation.The CTPM enterprises,especially the unlisted enterprises should increase the market shares and enterprise performance through production differentiation.

DEVELOP SERIES PRODUCTS OF ROBOTS TO PROMOTE THE TECHNOLOGICAL ADVANCEMENT OF THE MANUFACTURING INDUSTRY

As a typical representative and main technicalmeans of advanced manufacturing technology,robotic technology plays an important role in raisingan enterpse’s engineering level, improving its prod-uct quality and productivity, and realizing civilizedproduction. Currently, there are nearly one millionrobots of various kinds, which are employed widelyin different fields of manufacturing industry. Robot-ics is now one of the high technologies, which arecompetitively developed by the developed coun-

Emerging Trends in Damage Tolerance Assessment:A Review of Smart Materials and Self-Repairable Structures

The discipline of damage tolerance assessment has experienced significant advancements due to the emergence of smart materials and self-repairable structures.This review offers a comprehensive look into both traditional and innovative methodologies employed in damage tolerance assessment.After a detailed exploration of damage tolerance concepts and their historical progression,the review juxtaposes the proven techniques of damage assessment with the cutting-edge innovations brought about by smart materials and self-repairable structures.The subsequent sections delve into the synergistic integration of smart materials with self-repairable structures,marking a pivotal stride in damage tolerance by establishing an autonomous system for immediate damage identification and self-repair.This holistic approach broadens the applicability of these technologies across diverse sectors yet brings forth unique challenges demanding further innovation and research.Additionally,the review examines future prospects that combine advanced manufacturing processes with data-centric methodologies,amplifying the capabilities of these‘intelligent’structures.The review culminates by highlighting the transformative potential of this union between smart materials and self-repairable structures,promoting a sustainable and efficient engineering paradigm.

Impact of an official accountability audit on industrial structure adjustment:a case study of environmental regulation in China

As a unique environmental regulation in China,the official accountability audit was piloted in 2014.With a focus on prioritizing the ecological environment,officials in pilot districts have implemented economic construction,adjusted industrial structures,and promoted coordinated development between the economy and environment.The effects of implementation have garnered widespread attention from society.However,there is limited research on the impact of an accountability audit on industrial structure adjustments.Using the“Accountability Audit of Officials for Natural Resource Assets(Trial)”released in 2015 as a quasi-natural experiment,this study collected panel data from 279 cities between 2013 and 2017.It then empirically analyzed the impact mechanism and effects of the accountability audit on industrial structure adjustment using the Propensity Score Matching and Difference-in-Differences model.The research findings indicate that the accountability audit directly impacted industrial structure adjustment,promoting the upgrading of the primary industry to the secondary industry and restricting the development of the tertiary industry.In addition,the audit is beneficial for enterprise entry,but not conducive to technological innovation,and has no significant impact on foreign direct investment.This conclusion fills a gap in the existing research and provides valuable insights for policymakers.

基于改进Theil指数和Shift-Share模型的2012—2021年中国产业偏离分析

文章首先通过对现有文献的梳理和分析,发现针对产业偏离的测算,传统的产业偏离度E系数、Theil指数及Shift-Share模型均存在一定的缺陷,E系数和Theil指数的缺陷主要体现在计算原理方面,而Shift-Share模型的缺陷主要表现在参照系选择的合理性和数据采集的可行性方面。然后,基于现有模型的基本原理,提出了更为合理和更具可操作性的产业偏离测算方法,再采用实证研究的方法,根据2012—2021年的数据,对中国的产业偏离情况进行具体分析,得出尽管中国存在产业偏离,但产业偏离度在逐渐减小。最后,基于修正模型的计算结果,并结合当前的国际国内环境,提出如下政策建议:1)第一产业要依靠创新和科技引领,促进农村劳动力在城乡间有序转移,实现农业生产的规模化和现代化;2)第二产业要加快产业的升级换代,建立和保持独立、自主、完整的工业体系,加大在基础研究方面的投入,尽早突破美西方的技术封锁;3)第三产业的发展重点应该在金融和科教两个方面,要进一步提升香港地区、上海和北京等城市的世界金融中心地位,依靠金融创新来规避现行国际金融体系的不利约束和影响,同时要将科教兴国战略落到实处,努力探索适合中国国情的从小学到大学各阶段的教育模式。

Optimization of Agricultural Industrial Structure in Changping District of Beijing Based on Grey Relational Analysis

In the economic development of Beijing,although the share of the total amount of agricultural industry in the overall economy is relatively low,it has an important impact on the daily life of residents,social stability and the development of other industries.Changping District,as an important agricultural production base of Beijing,its agricultural development has an indispensable strategic significance for the stability and growth of the entire regional economy.Therefore,it is very important to study the structure of agricultural industry in Changping District.Based on the detailed analysis of the agricultural industrial structure of Changping District,this paper uses the grey relation theory to analyze the different industries in the agricultural industrial structure of Changping District,including planting,forestry,animal husbandry,fishery and agricultural,forestry,service industries,in order to reveal the impact of these industries on the agricultural industrial structure of Changping District.Through this study,it comes up with specific and feasible suggestions for the optimization of agricultural industrial structure in Changping District,and provides valuable reference for the agricultural development of other areas in Beijing.