The details of ternary fluoride crystallization in the system NaF-CaF2-AlF3 have been specified. The phases NaCaAlF6, Na2Ca3Al2F14 and NaAlF4 have been obtained by high-temperature synthesis. Their thermal transformat...The details of ternary fluoride crystallization in the system NaF-CaF2-AlF3 have been specified. The phases NaCaAlF6, Na2Ca3Al2F14 and NaAlF4 have been obtained by high-temperature synthesis. Their thermal transformations have been studied using high-temperature X-ray diffraction. The occurring transformations can be considered in a quasibinary system CaF2-NaAlF4, where at T = 745°C - 750°C invariant equilibrium is established with the phases CaF2-NaCaAlF6-Na2Ca3Al2F14-(NaAlF4). The compounds NaCaAlF6 and Na2Ca3Al2F14 are stable in different temperature ranges. The phase NaCaAlF6 was fixed by rapid quenching from the melt. It decomposes at heating before 640°C yielding Na2Ca3Al2F14 and NaAlF4. Direct and inverse transformations between NaCaAlF6 and Na2Ca3Al2F14 occur in the bulk samples of the electrolyte. A thermal treatment procedure was proposed for the solid electrolyte sample to get a sample corresponding to the composition of the melt and providing high phase crystallinity for the purposes of quantitative X-ray phase diffraction analysis.展开更多
Traditional thermal power units are continuously replaced by renewable energies,of which fluctuations and intermittence impose pressure on the frequency stability of the power system.Electrolytic aluminum load(EAL)acc...Traditional thermal power units are continuously replaced by renewable energies,of which fluctuations and intermittence impose pressure on the frequency stability of the power system.Electrolytic aluminum load(EAL)accounts for large amount of the local electric loads in some areas.The participation of EAL in local frequency control has huge application prospects.However,the controller design of EAL is difficult due to the measurement noise of the system frequency and the nonlinear dynamics of the EAL’s electric power consumption.Focusing on this problem,this paper proposes a control strategy for EAL to participate in the frequency control.For the controller design of the EAL system,the system frequency response model is established and the EAL transfer function model is developed based on the equivalent circuit of EAL.For the problem of load-side frequency measurement error,the frequency estimation method based on Kalman-filtering is designed.To improve the performance of EAL in the frequency control,a fuzzy EAL controller is designed.The testing examples show that the designed Kalman-filter has good performance in de-noising the measured frequency,and the designed fuzzy controller has better performance in stabilizing system frequency than traditional methods.展开更多
Growth and passivation of tunnels within Al foil by on-off controlling DC etching in 6 wt.% HCI solution has been investigated. It was found that, in a given etchant solution at a special temperature, the longest tunn...Growth and passivation of tunnels within Al foil by on-off controlling DC etching in 6 wt.% HCI solution has been investigated. It was found that, in a given etchant solution at a special temperature, the longest tunnel length was only a function of the turn-on interval of DC. The potential of Al foil broke at on-off controlling DC by the result from anode polarization curves and potential-time （E-t） responding curves. When DC was switched on, the potential increased abruptly over pitting potential, leading to nucleation of pits at the surface and the growth of tunnels at special length. When DC was switched off, the potential decreased rapidly to a passive value, leading to stoppage of nucleation and death of tunnels. By this way, the longest tunnel length can be controlled and a non-piercing layer can be obtained. Hence, etching of Al foil at this current is beneficial for maintaining a good mechanical strength.展开更多
文摘The details of ternary fluoride crystallization in the system NaF-CaF2-AlF3 have been specified. The phases NaCaAlF6, Na2Ca3Al2F14 and NaAlF4 have been obtained by high-temperature synthesis. Their thermal transformations have been studied using high-temperature X-ray diffraction. The occurring transformations can be considered in a quasibinary system CaF2-NaAlF4, where at T = 745°C - 750°C invariant equilibrium is established with the phases CaF2-NaCaAlF6-Na2Ca3Al2F14-(NaAlF4). The compounds NaCaAlF6 and Na2Ca3Al2F14 are stable in different temperature ranges. The phase NaCaAlF6 was fixed by rapid quenching from the melt. It decomposes at heating before 640°C yielding Na2Ca3Al2F14 and NaAlF4. Direct and inverse transformations between NaCaAlF6 and Na2Ca3Al2F14 occur in the bulk samples of the electrolyte. A thermal treatment procedure was proposed for the solid electrolyte sample to get a sample corresponding to the composition of the melt and providing high phase crystallinity for the purposes of quantitative X-ray phase diffraction analysis.
基金funded by Science and Technology Project of State Grid Corporation of China:Research on the Construction and Evaluation Technology of the Data-Driven-based Adjustable Resource Pool of Typical Industrial Enterprises,Grant No.1400-202016386A-0-0-00.
文摘Traditional thermal power units are continuously replaced by renewable energies,of which fluctuations and intermittence impose pressure on the frequency stability of the power system.Electrolytic aluminum load(EAL)accounts for large amount of the local electric loads in some areas.The participation of EAL in local frequency control has huge application prospects.However,the controller design of EAL is difficult due to the measurement noise of the system frequency and the nonlinear dynamics of the EAL’s electric power consumption.Focusing on this problem,this paper proposes a control strategy for EAL to participate in the frequency control.For the controller design of the EAL system,the system frequency response model is established and the EAL transfer function model is developed based on the equivalent circuit of EAL.For the problem of load-side frequency measurement error,the frequency estimation method based on Kalman-filtering is designed.To improve the performance of EAL in the frequency control,a fuzzy EAL controller is designed.The testing examples show that the designed Kalman-filter has good performance in de-noising the measured frequency,and the designed fuzzy controller has better performance in stabilizing system frequency than traditional methods.
基金This study was financially supported by Beijing Education Commission,China.
文摘Growth and passivation of tunnels within Al foil by on-off controlling DC etching in 6 wt.% HCI solution has been investigated. It was found that, in a given etchant solution at a special temperature, the longest tunnel length was only a function of the turn-on interval of DC. The potential of Al foil broke at on-off controlling DC by the result from anode polarization curves and potential-time （E-t） responding curves. When DC was switched on, the potential increased abruptly over pitting potential, leading to nucleation of pits at the surface and the growth of tunnels at special length. When DC was switched off, the potential decreased rapidly to a passive value, leading to stoppage of nucleation and death of tunnels. By this way, the longest tunnel length can be controlled and a non-piercing layer can be obtained. Hence, etching of Al foil at this current is beneficial for maintaining a good mechanical strength.
