Effects of pressure relief holes on coal burst:Insights from true-triaxial unloading tests

Drilling pressure relief is one of the methods to reduce the risk of coal bursts in deep mines.However,the effect of the drill hole orientations has not been studied well enough to understand their impact on the burst failure mechanism.In this study,we investigated two designs of drill hole orientations.The first design includes drill holes located on the upper free face of the rectangular samples and labelled as upper hole(UH)and centre hole(CH)e the long axes of the drill holes are aligned with minor principal stress,s3,direction.The second design includes drill holes at the top(TH)and the side(SH)of the rectangular samples in which the long axes of the drill holes are aligned with the maximum,s1,and intermediate principal stress,s2,directions,respectively.The coal samples with the proposed drill hole orientations were subjected to the true-triaxial unloading coal burst tests.The results show that the drill holes reduce the risk of coal bursts.However,we found that the intensity of coal burst was significantly reduced with the SH-type,followed by the CH-types.We also observed that the coal burst intensity is reduced better for the CH,UH,TH,and SH-type drilling patterns.However,it was found that the orientations of drill holes have little influence on the failure mode(splitting).The acoustic emission(AE)activities for coal with drill holes noticeably decreased,especially for the UH and CH layouts.The drill holes reduced the upper limit of the AE entropy(chaos of microcracks generation).However,regarding reducing the coal burst risk,the TH and SH are less effective than UH and CH.

Thermal oxidation of SiAlON powders synthesized from coal gangue

The oxidation behavior of different SiAlON phases（β-SiAlON,X-phase SiAlON and 12H powders） synthesized from coal gangue in air atmosphere was investigated using isothermal thermogravimetry（TG） and field-emission scanning electron microscopy（FE-SEM）.The effect of ferric oxide impurities in coal gangue was studied.The results show that ferric oxide contributes to the growth of SiAlON crystalline during the synthesis process.In the oxidation experiment,the existence of ferric oxide decreases the oxidation resistance of SiAlON.The reason is that the impurity causes the formation of a liquid phase at a higher temperature.At 1423-1623 K,the oxidation of SiAlON powders is diffusion controlled and it can be described by Chou＇s model.A fair agreement is found between theoretical calculations and the experimental data.

Study on the Evaporation Kinetics of Zinc and Lead in Zn-Pb-Bearing Dust Pellets Mixed with Coal Powder

The study on the evaporation kinetics of zinc and lead in the pellets made of ZnPbbearing dust mixed with carbon ,in nitrogen atmosphere at the temperature range between 1 100 and 1 300 , shows that the reduction temperature has a significant effect on the evaporation rates of zinc and lead and that both the particle size of coal powder and the extra carbon content have no effect on the evaporation rates . The obtained activation energies for the evaporation of zinc and lead are 7942 kJ/mol and 8874kJ/mol respectively. The evaporation rate of zinc is controlled by the reaction between zinc oxide and CO while that of lead is controlled by lead volatilization and the diffusion of gaseous lead through gas boundary layer covering the surface of liquid lead.

A novel method for measuring the moisture content of coal powder by microwave resonator

A novel technique for the quick measurement moisture content of coal powder by microwave was studied. The effects of the various moisture contents on the measurement results were also discussed. The experimental results show that the standard deviation is less than 0.36% when the moisture content of coal powder is 0.74%-16.90% and the standard deviation is less than 0.16% when the moisture content is 0.31%-1.49%. The experimental results indicate that a process of quick measurement moisture content of coal powder by microwave is practical.

Carbothermal Reduction Synthesis of Al_2O_3-SiC Powders from Coal Gangue

The Al2O3 -SiC composite powders were prepared in argon atmosphere rising coal gangue and carbonaceous materials （ carbon black, active carbon and antbravite） as starting materials by carbothermal reduction. Effects of excessive carbon addition, carbon types. temperature, soaking time. shaping pressure, types and amount of additives on phase composition and micro-structure of the Al2O3 - SiC composite powders were investigated. The re.suits indicate that： temperature, soaking time and chloride additi＇ve have significant influence on the synthesized Al2O3 -SiC composite powders. Based on the results, the optimized Al2O3 -SiC composite powders , Al2O3 58 mass% and SiC 42 mass%, with particle size d50 ≤5μm were prepared using coal gangue and carbon black as starting materials after 3 h firing at 1550 ℃. and proper additive addition could reduce the temperattlre by 50 ℃.

STUDY ON THE FUNCTION OF REINFORCED RUBBER OF MODIFIED POWDERED COAL ASH

The powdered coal ash (PCA) was classified, then the ash particle (- 45μm) was modified by a surface active agent and obtained modified powder coal ash (MPCA). The character of the MPC was investigated, when it was used as a new type reinforced filler of rubber.The results show that MPCA can replace or party replace carbon black or silica as reinforced fillers of rubbers.

Study on the removal of Hg^0 from flue gas by coal dry powder gasification coarse slag

The prevention and treatment of mercury in coal-fired power plants has always been the focus and difficulty.How to control the pollution of mercury to human body and ecological environment quickly and effectively is a hot research topic nowadays.As a low cost and potential adsorbent,there is a huge space for the development of coal dry powder gasification coarse slag.In this paper,Mercury osmotic tubes are heated by water bath tank as mercury source,and the scavenging effect of adsorbent on Mercury monomer under different influence conditions is explored.The adsorbent plays an important role in adsorption of mercury monomer because of its special active sites on the surface.The reason is that the adsorbent surface is rich in carboxyl group,hydroxyl functional group,combined with mercury to form complexes.This shows that chemical adsorption facilitates the adsorption process.

Adsorption Behavior of Methyl Orange onto Modified Ultrafine Coal Powder

The adsorption of methyl orange onto ultrafine coal powder （UCP） and modified ultrafine coal powder （MUCP） from aqueous solutions were studied, in which the influence of contact time, dosage, temperature, pH, and methyl orange concentration in the solution were investigated. The adsorption kinetics of methyl orange by UCP and MUCP can be described by the Lagergren first-order and pseudo second-order kinetic models, respectively. The adsorption isotherms of methyl orange onto MUCP at 303, 313 and 323 K follow the Freundlich and Langmuir isotherm equation. Values of △G^0 for methyl orange adsorption onto MUCP are -22.55, -23.10 and -23.79 kJ·mol^-1 at 303, 313, and 323 K, respectively. The values of △H^0 and △S^0 are -3.74 kJ· mol^-1 and 61.99 J·mol^-1, respectively. The adsorption process is spontaneous and exothermic.

STUDY ON THE METHOD FOR FORECASTING DANGEROUSNESS OF COAL FACE AND HEADING FACE OUTBURST BY TWO TEMPERATURE INDEXES

In line with the sensitivity of coal drillings temperature and coalbed temperature to the dangerous zone of coal and gas outburst, two temperature sensitive indexes (△Tm, △tm) for forecasting dangerousness of coal face and heading face outburst are defined, and deal with the foundation on drillings and coalbed temperatures used as sensitive indexes and the principle and method of determining drillings and coalbed temperatures. On the basis of this, we put forward the method for forecasting dangerousness of coal face and heading face outburst by two temperature sensitive indexes and determine the critical values of two temperature sensitive indexes (△Tm= 5.5℃, △tm = 4.5℃) by in-situ observation and requirement for determining sensitive index.

Prediction method for risks of coal and gas outbursts based on spatial chaos theory using gas desorption index of drill cuttings

Based on the evolution of geological dynamics and spatial chaos theory, we proposed the advanced prediction an advanced prediction method of a gas desorption index of drill cuttings to predict coal and gas outbursts. We investigated and verified the prediction method by a spatial series data of a gas desorption index of drill cuttings obtained from the 113112 coal roadway at the Shitai Mine. Our experimental results show that the spatial distribution of the gas desorption index of drill cuttings has some chaotic charac- teristics, which implies that the risk of coal and gas outbursts can be predicted by spatial chaos theory. We also found that a proper amount of sample data needs to be chosen in order to ensure the accuracy and practical maneuverability of prediction. The relative prediction error is small when the prediction pace is chosen carefully. In our experiments, it turned out that the optimum number of sample points is 80 and the optimum prediction pace 30. The corresponding advanced prediction pace basically meets the requirements of engineering applications.

An alternative approach to improve the compatibility of PCE in cement paste blend with coal gangue powder

Coal gangue(CG)is an environmental waste that faces an urgent demand for disposal in China.The utilization of CG in construction materials has broad application prospects and gained increasing interest.However,the poor compatibility of polycarboxylate superplasticizer(PCE)with CG powder hinders its efficiency in a wide range of applications.Here,this paper attempts to improve the compatibility of PCE with CG powder in cement paste based on the regulation of aggregation and the adsorption behavior of PCE.Dynamic light scattering(DLS)and fluorescence spectroscopy tests were carried out to understand the improved mechanism.The results indicated that the addition of CG powder increases the ionic strengths of the cement liquid phase,which makes PCE tend to aggregate at a lower concentration compared with no CG powder introduction.Adding(CH_(3)COO)_(2)Cu is beneficial for enhancing the workability of cement paste by reducing PCE aggregation while maintaining the compressive strength of cement specimens.Therefore,(CH_(3)COO)_(2)Cu extra addition can be regarded as an effective and sustainable way to improve the workability of cement paste with CG powder.

Adsorption of phenol from water by ultrafine coal powders

Seven Shenfu coal powders different in particle size obtained by sieving and ball milling were used to probe their adsorption properties to phenol from water. The results show that the kinetics of phenol on coal powders follow the second-order adsorption kinetic model well. Adsorption processes are governed by film diffusion and the kinetic parameters and the effective diffusion coefficients were calculated through plotting. Adsorption capacities to phenol increase exponentially with decreasing of diameter of coal powders. The phenol adsorption equilibrium for coal powder with d50 of 9.30 μm can be described in terms of Freundlich isotherm, while for ultrafine coal powders with d50 of 4.28 and 4.82 μm fit Langmuir isotherm well.

Three-dimensional numerical simulation of methane drainage by high-level drill holes in a lower protective coal seam with a “U” type face

Different drill-hole positions may produce different drainage results in low protective coal seams.To investigate this possibility,a 3D stope model is established,which covers three kinds of drill holes.The FLUENT computational fluid mechanics software is used to solve the mass,momentum and species conservation equations of the model.The spatial distributions of oxygen and methane was obtained by calculations and the drainage results of different drill-hole positions were compared.The results show that,from top to bottom,methane dilution by oxygen weakens gradually from the intake to the return side,and methane tends to float;methane and oxygen distribute horizontally.The high-level crossing holes contribute to better methane drainage and a greater level of control.Around these holes,the methane density decreases dramatically and a "half circle"distribution is formed.The methane density decreases on the whole,but a proportion of the methane moves back to deep into the goaf.The research findings provide theoretical grounds for methane drainage.

Technique of coal mining and gas extraction without coal pillar in multi-seam with low permeability

Aimed at the low mining efficiency in deep multi-seams because of high crustalstress,high gas content,low permeability,the compound 'three soft' roof and the trouble-somesafety situation encountered in deep level coal exploitation,proposed a new idea ofgob-side retaining without a coal-pillar and Y-style ventilation in the first-mined key pressure-relieved coal seam and a new method of coal mining and gas extraction.The followingwere discovered:the dynamic evolution law of the crannies in the roof is influenced bymining,the formative rule of 'the vertical cranny-abundant area' along the gob-side,thedistribution of air pressure field in the gob,and the flowing rule of pressure-relieved gas ina Y-style ventilation system.The study also established a theoretic basis for a new miningmethod of coal mining and gas extraction which is used to extract the pressure-relievedgas by roadway retaining boreholes instead of roadway boreholes.Studied and resolvedmany difficult key problems,such as,fast roadway retaining at the gob-side without a coalpillar,Y-style ventilation and extraction of pressure-relieved gas by roadway retainingboreholes,and so on.The study innovated and integrated a whole set of technical systemsfor coal and pressure relief gas extraction.The method of the pressure-relieved gasextraction by roadway retaining had been successfully applied in 6 typical working faces inthe Huainan and Huaibei mining areas.The research can provide a scientific and reliabletechnical support and a demonstration for coal mining and gas extraction in gaseous deepmulti-seams with low permeability.

Adsorption of residual amine collector HAY from aqueous solution by refined carbon from coal fly ash and activated carbon

Refined carbon(RC) derived from coal fly ash(CFA) as well as powdered activated carbon(PAC) was investigated as adsorbent to remove residual amine collector HAY from aqueous solution.The RC and PAC were characterized by scanning electron microscopy(SEM),surface area measurement,Zeta potential measurement and Fourier transform infrared(FTIR) spectroscopy.The effect factors and mechanisms of HAY adsorption onto RC and PAC were studied in detail.The results show that the experimental kinetic data agree well with the pseudo second-order equation,and the Langmuir isotherm model is found to be more appropriate to explicate the experimental equilibrium isotherm results than the Freundlich model.The adsorption capacities of PAC and RC increase with pH.It is found that alkaline condition is conducive to the adsorption of HAY onto PAC and RC and the adsorption efficiency of RC is close to PAC at pH near 11.Zeta potential variation of adsorbents suggests that HAY generates electrostatic adsorption onto RC and PAC.FTIR analysis shows that the adsorption is dominantly of a physical process.The Box-Behnken design optimization conditions of process are RC 1 g/L,pH 11,temperature 302 K and initial HAY concentration 100 mg/L.Under these conditions,the measured adsorption ratio and adsorption capacity are 87.91%and 87.91 mg/g,respectively.Thus,the RC is considered to be a potential adsorbent for the removal of residual amine from aqueous solution.

Study on Inorganic Flocculant Prepared from Powdered Coal Ashes

The feasibility of preparing flocculant from powdered coal ashes is studied in detail. By means of orthogonal tests, the influence of various factors, such as the activation temperature, the activation time, the ratio of CaO to Al2O3, the hydrochloric acid concentration, the reaction time and the reaction temperature, on preparation is investigated, and the hest operating condition is determined.

A Petrophysical Approach to Evaluation from Measured While Drilling Gamma Ray, Case Study in the Powder River and Delaware Basins

One of the most common subsurface data sets that is easily accessible and often underutilized is the acquired measuring while drilling (MWD) gamma ray (GR-GAPI) log. Data is acquired from a given gamma ray tool positioned within the drill string and pulsed up to the surface through the mud column in the wellbore. Typical use of the data is for subsurface geologists, drillers and others to correlate the data to known stratigraphic signatures and steer wells through horizontal target zones. Through that correlation, an association to the geologic stratigraphic column can be made and the team of subsurface scientists adjusts where, how fast, and why they choose to continue drilling. The technique of correlation applies to both the conventional and unconventional application. In the unconventional application, the data is also typically acquired along the length of the horizontal wellbore. From a petrophysical standpoint, just acquiring a gamma ray can limit the amount of information and ability to fully evaluate the properties along the length of the well. In this study, we share and demonstrate how to utilize the MWD GR for petrophysical evaluation beyond just a volume of shale or volume of clay interpretation. The workflow will allow full integration of a comprehensive petrophysical evaluation that can then be utilized to support all subsurface understandings and modelling efforts.

松软薄煤层条带消突下斜定向钻孔成孔护孔技术研究与应用

针对松软薄煤层煤巷条带消突长距离下斜钻孔,存在成孔难、易钻遇煤层顶底板、积水堵塞瓦斯抽采通道的难题,提出了氮气排渣下斜定向钻进成孔与护孔技术,采用高压氮气排渣、大功率气动螺杆钻具定向、“波浪式”轨迹控制和三层管护孔排水技术,在河南省平煤股份一矿开展现场试验,完成8个孔深超300 m下斜定向长钻孔,煤层钻遇率90%以上,全孔段下三层护排水管,平均下入深度302 m,支管平均抽采纯量1.66 m^(3)/min,平均瓦斯浓度17.5%。试验结果表明:该技术可有效解决松软薄煤层下斜钻孔长距离定向成孔、全孔段筛管护孔和排水的技术难题,提高了钻孔成孔深度和煤层钻遇率,实现了下斜孔全孔段护孔和排水,保障了瓦斯抽采效果,为松软薄煤层煤巷条带长距离消突提供技术保障,在类似地层条件具有广泛的应用推广价值。