A Simple Cement Hydration Model Considering the Influences ofWater-to-Cement Ratio and Mineral Composition

A simple hydration model is used here by taking the composition of the cement and the initial water: cementratio (w/c) into account explicitly. Its conceptual basis is a combination of the Avrami equation and Bentz’s modelbased on simple spatial considerations. In this model, the Avrami equation determines the initial reaction, andBentz’s model describes the following hydration stage. The model favors engineers for it relies on one experimentalparameter and has a reliable approximation in the practice.

Experimental Investigation on the Performance of[APMIm][NTf_(2)]for Capturing CO_(2)from Flue Gas of the Cement Kiln Tail

Facing the global warming trend,humanity has been paying more and more attention to the Carbon Capture,Utilization and Storage.Large amounts of CO_(2)is emitted with burning fossil fuel as well as by some special industrial processes like the decomposition of calcium carbonate in a cement plant.The cement industry contributes about 7%of the total worldwide CO_(2)emissions and the CO_(2)concentration of flue gas of the cement kiln tail even exceeds 30%.Ionic liquid is considered to be an effective and potential material to capture CO_(2).In order to investigate the performance of ionic liquids for capturing CO_(2)from flue gas of the cement kiln tail,an experiment system was established and an ionic liquid,[APMIm][NTf_(2)](1-aminopropyl-3-imidazolium bis(trifluoromethylsulfonyl)imine),was tested using pure CO_(2)and simulated gas.The results showed that both physical and chemical absorption play roles while physical absorption dominates in the absorption process.Both the absorption capacity and rate decrease with raising the operating temperature.In the experiment with pure CO_(2),the absorption capacity is 0.296molCO_(2)⋅molIL−1 at 30℃ and 0.067molCO_(2)⋅molIL−1 at 70℃.Meanwhile,the ionic liquid can be regenerated for recycling without obvious changes of the absorption capacity.When the ionic liquid is used for flue gas of the cement kiln tail rather than pure CO_(2),a sharp decrease of the absorption capacity and rate was observed obviously.The absorption capacity at 30℃ dropped even to 0.038molCO_(2)⋅mol_(IL)^(−1),12.8%of that for pure CO_(2).Additionally,a natural desorption of CO_(2)from the ionic liquid was observed and affected the experimental results of the absorption capacity and the absorption-desorption rate to some extent.

Evaluation of the cement bond quality through filtering the reflected ultrasonic waves

High cement bond quality is required to keep an oil well from hydraulic commu- nication between zones. In the cement bond evaluation, the ultrasonic echo method is widely used for its capability of channeling azimuth detection. Full waveforms reflected from the cased hole are simulated for different bonding conditions by the generalized transfer matrix method. Because of the high acoustic impedance of casing, the amplitudes of the reflected waves from the cement and the formation are small and cannot easily be used to evaluate the cementing condition. The wave that can propagate into the cement and the formation through the casing concentrates closely on the casing resonant frequency. To reduce the amplitude of the reflected wave from the casing inner surface and highlight the part of the reflected wave which carries the cementing quality information, the reflected full wave is filtered according to the casing resonant frequency. There are several wave packets in the filtered waveform. When the amplitude of the second wave packet is low, the cement bonds well with the casing, otherwise poorly. A low amplitude third wave packet is an indication of a good bond of the cement with the formation, otherwise poor. To reveal the sensitivity of the reflection wave amplitudes to the incident angle, reflected full waveform is modeled when an acoustic beam with finite width is incident on the casing. It is shown that the bond evaluation method based on filtered wave packets is valid for incident angle less than 5 degrees.