Impact of Hinterland Manufacturing on the Development of Container Ports: Evidence from the Pearl River Delta, China

Container ports and hinterland manufacturing are two important forces of the local participation in economic globalization.This study,taking the Pearl River Delta(PRD),China with an export-oriented economy as an example,applies Huff and panel regres-sion models to evaluate the impact of hinterland manufacturing on the development of container ports during the period of 1993–2019.The results show that 1)the spatial patterns of hinterlands for hub ports help to determine the distribution range and scale of economic variables that affect port throughput;2)the hinterland’s gross manufacturing output has universally positive influence on port through-put,wherein export-oriented processing and the entire manufacturing industry have significantly positive impact on port throughput in 1993–2011 and 2001–2019,respectively;3)the two internal structural factors related to an export-oriented economy,labor-intensive sectors and foreign-funded terminals,have positively moderate the direct influence of hinterland manufacturing on port throughput.Our results highlight the importance of local context in understanding port-manufacturing relationship in developing economies.Based on our findings,policy implications are further proposed to enhance port network organization in PRD.

Evaluation of Ecological Sustainable Development in the Yangtze River Delta Region Based on Ecological Footprint Theory

The ecological footprint was employed as a quantitative indicator of resource inputs,enabling a detailed account of the structure of biological resources and energy occupancy,as well as the variation of resource productivity in the Yangtze River Delta(YRD)Region.From 2004 to 2018,there were notable variations in the ecological productivity of different types of land on basis of China’s equilibrium factor across the three provinces and one city in the YRD region.Jiangsu Province exhibited the highest ecological productivity of arable land,while Anhui Province exhibited the highest ecological productivity of forest land.Shanghai City exhibited the highest ecological productivity of pasture land,while Zhejiang Province exhibited the highest ecological productivity of water area.In 2018,the proportion of arable land within the total ecological carrying capacity of the YRD region reached 74.35%.Furthermore,the contribution of Jiangsu and Anhui provinces to the YRD’s total ecological carrying capacity was 41.36%and 41.26%,respectively.In the construction of a new development pattern in the YRD region,which is dominated by the domestic cycle as the main body and mutually reinforced by domestic and international double-cycle,the YRD region should combine the utilization of natural forces with innovation in science,technology and cooperation mechanisms.Furthermore,the government should guide the concentration of social capital towards green industries.It is also recommended that the moderate reduction of ecological footprints should be encouraged,and that the security of biological resources and energy,the leadership in the field of cutting-edge science and technology should be ensured in YRD region.This will facilitate the formation of a new development pattern of higher-quality integration at the national level firstly.

Impacts of Weather Conditions Modified by Urban Expansion on Surface Ozone: Comparison between the Pearl River Delta and Yangtze River Delta Regions

In this paper, the online weather research and forecasting and chemistry （WRF-Chem） model is used to explore the impacts of urban expansion on regional weather conditions and its implication on surface ozone concentrations over the Pearl River Delta（PRD） and Yangtze River Delta（YRD） regions. Two scenarios of urban maps are used in the WRF-Chem to represent the early 1990s （pre-urbanization） and the current urban distribution in the PRD and the YRD. Month-long simulation results using the above land-use scenarios for March 2001 show that urbanization increases both the day- and night-time 2-m temperatures by about 0.6℃and 1.4℃, respectively. Daytime reduction in the wind speed by about 3.0 m s-1 is larger than that for the nighttime （0.5 to 2 m s-1）. The daytime increase in the PBL height （〉 200 m） is also larger than the nighttime （50-100 m）. The meteorological conditions modified by urbanization lead to detectable ozone-concentration changes in the PRD and the YRD. Urbanization increases the nighttime surface-ozone concentrations by about 4.7%-8.5% and by about 2.9%-4.2% for the daytime. In addition to modifying individual meteorological variables, urbanization also enhances the convergence zones, especially in the PRD. More importantly, urbanization has different effects on the surface ozone for the PRD and the YRD, presumably due to their urbanization characteristics and geographical locations. Even though the PRD has a smaller increase in the surface temperature than the YRD, it has （a） weaker surface wind speed, （b） smaller increase in PBL heights, and （c） stronger convergence zones. The latter three factors outweighed the temperature increase and resulted in a larger ozone enhancement in the PRD than the YRD.

Spatial and Temporal Variations of Pneumoconiosis in the Pearl River Delta Region in 2006–2015

Pneumoconiosis is a restrictive lung disease mostly caused by occupational exposure to dust,including silica dust,asbestos,and other fibers.Inhalable particles smaller than 10μm can enter the bronchioles,injure lung cells,and induce lung fibrosis.This hard-to-cure disease places a substantial burden on patients and society[1].

Legislation on protection of drinking water sources and local management practices in the Pearl River Delta region of China

The protection of drinking water sources is vital to urban development and public health.In this study,the current situation of the mandatory protection area for drinking water source in the Pearl River Delta region was investigated using a method combining Google Earth with the field survey.The gaps between management practices and legislation requirements were analyzed.Finally,several countermeasures for water resource protection were proposed as follows:to promote delineation in a more scientific way,to safeguard the sanctity of the law,to make better plan on water saving,and to encourage public participation in supervision and management.

Impact of the Built Environment on the Spatial Heterogeneity of Regional Innovation Productivity:Evidence from the Pearl River Delta,China

With the global economy increasingly dependent on innovation,urban discourse has shifted to consider what kinds of spatial designs may best nurture innovation.We examined the relationship between the built environment and the spatial heterogeneity of regional innovation productivity(RIP)using the example of China's Pearl River Delta(PRD).Based on a spatial database of 522546 patent data from 2017,this study proposed an innovation-based built environment framework with the following five aspects:healthy en-vironment,daily interaction,mixed land use,commuting convenience,and technology atmosphere.Combining negative binomial regression and Geodetector to examine the impact of the built environment on RIP,the results show that the spatial distribution of innovation productivity in the PRD region is extremely uneven.The negative binomial regression results show that the built environment has a significant impact on the spatial differentiation of RIP,and,specifically,that healthy environment,mixed land use,commuting convenience,and technology atmosphere all demonstrate significant positive impacts.Meanwhile,the Geodetector results show that the built environment factor impacts the spatial heterogeneity of RIP to varying degrees,with technology atmosphere demonstrating the greatest impact intensity.We conclude that as regional development discourse shifts focus to the knowledge and innovation economy,the innovation-oriented design and updating of built environments will become extremely important to policymakers.

Aerosol Optical Properties and Radiative Impacts in the Pearl River Delta Region of China during the Dry Season

Aerosol optical properties and direct radiative effects on surface irradiance were examined using seven years （2006-2012） of Cimel sunphotometer data collected at Panyu--the main atmospheric composition monitoring station in the Pearl River Delta （PRD） region of China. During the dry season （October to February）, mean values of the aerosol optical depth （AOD） at 550 nm, the Angstrom exponent, and the single scattering albedo at 440 nm （SSA） were 0.54, 1.33 and 0.87, respectively. About 90% of aerosols were dominated by fine-mode strongly absorbing particles. The size distribution was bimodal, with fine-mode particles dominating. The fine mode showed a peak at a radius of 0.12 μm in February and October （- 0.10 μm3 μm-2）. The mean diurnal shortwave direct radiative forcing at the surface, inside the atmosphere （FATM）, and at the top of the atmosphere, was -33.4± 7.0, 26.1 ± 5.6 and -7.3 ±2.7 W m-2, respectively. The corresponding mean values of aerosol direct shortwave radiative forcing per AOD were -60.0 ±7.8, 47.3 ± 8.3 and -12.8 ±3.1 W m-2, respectively. Moreover, during the study period, FATM showed a significant decreasing trend （p 〈 0.01） and SSA increased from 0.87 in 2006 to 0.91 in 2012, suggesting a decreasing trend of absorbing particles being released into the atmosphere. Optical properties and radiative impacts of the absorbing particles can be used to improve the accuracy of inversion algorithms for satellite-based aerosol retrievals in the PRD region and to better constrain the climate effect of aerosols in climate models.

Regional Geochemical Characteristics and Influence Factors of Soil Elements in the Pearl River Delta Economic Zone, China

Soil heavy metal pollution is one of the main environmental problems in Pearl River Delta Economic?Zone of China. Based on multi-purpose regional geochemical survey, regional eco-geochemical assessment, local eco-geochemical assessment and comprehensive appraisal, the eco-geochemical survey and assessment in Pearl River Delta Economic Zone of 41,698 km2?were completed. Samples from soils were collected in accordance with the two-layer grid method. Totally 54 elements and indicators for soils were determined. Compared to deep soils, the sampled surface soils are enriched in OrgC, N, P, Cd, S,Hg, Ag, B, Au, S and poor with As, Ni, I, Co, Cr, V, MgO, Sc, Al2O3, Fe2O3?etc. The characteristics of geochemical reference value of element in soil that inherited soil parent material and regional elements combined features reflected that the elements enriched in the soil was interrelated with acid rock, sandstone and shale. The spatial distribution characteristics of element regional geochemistry were conditional by regional environmental geological conditions,and effected by human activities. The Pearl River Delta plain is a typical geochemical landscape area with regional anomaly of multiple-elements. The north, western and eastern parts of the Pearl River Delta Economic Zone are quite different in geochemical features due to regional geological background, soil parent materials, geomorphic characteristics and human activities. Environment quality evaluation results show that the grade I and grade II soil accounted for 19.9% and 57.3% of the total area. Many samples that widely distributed in the economic developed of Pearl River Delta Plain area reached the third-grade of national soil environment standard. The soil enriched in Cd, Hg, As, and the area ratio accounting for 22.8% of the total area. It is mainly controlled by the geochemical background, the Pearl River Delta formation evolution process, especially the marine transgression process lead to Cd, Cu, Zn and Pb enrichment in Pearl River Delta plain. At the same time, under the influence of higher pressure of human activities, all kinds of exogenous input material carrying heavy metal pollutants on soil environmental quality also could not to ignore.

MEASUREMENTS OF PARTICLE NUMBER SIZE DISTRIBUTIONS AND NEW PARTICLE FORMATION EVENTS DURING WINTER IN THE PEARL RIVER DELTA REGION,CHINA

Particle number size distribution(PNSD) between 10 nm and 20 μm were measured in the Pearl River Delta(PRD) region in winter 2011.The average particle number concentration of the nucleation mode(10-20 nm),Aitken mode(20-100 nm),accumulation mode(100 nm-1μm) and coarse mode(1-20 μm) particles were 1 552,7 470,4 012,and 19 cm-3,respectively.The volume concentration of accumulation mode particles with peak at 300 nm accounted for over 70% of the total volume concentration.Diurnal variations and dependencies on meteorological parameters of PNSD were investigated.The diurnal variation of nucleation mode particles was mainly influenced by new particle formation events,while the diurnal variation of Aitken mode particles correlated to the traffic emission and the growth process of nucleation mode particles.When the PRD region was controlled by a cold high pressure,conditions of low relative humidity,high wind speed and strong radiation are favorable for the occurrence of new particle formation(NPF) events.The frequency of occurrence of NPF events was 21.3% during the whole measurement period.Parameters describing NPF events,including growth rate(GR) and source rate of condensable vapor(Q),were slightly larger than those in previous literature.This suggests that intense photochemical and biological activities may be the source of condensable vapor for particle growth,even during winter in the PRD.

The regional nature of nitrate-dominant haze pollution during autumn over the Pearl River Delta area

China has experienced severe haze and visibility degradation problems in recent years because of rapid urbanization and industrialization.In this study,daily atmospheric fine-aerosol samples were concurrently collected at three sites over the Pearl River Delta(PRD)region during 1–29 October 2014.PM2.5 samples were analyzed for organic carbon and elemental carbon using a thermal/optical carbon analyzer.Major water-soluble inorganic ions including F−,Cl−,NO3−,SO42−,Na+,NH4+,K+,Mg2+,and Ca2+were analyzed by ion chromatography.The results show that the temporal variations of PM2.5 concentration at the three sites were highly parallel,with particle pollution events simultaneously observed during 13–19 October(EP1)and 23–27 October(EP2),suggesting that pollution events in the PRD region are usually regional.This can most likely be attributed to the significant influences of synoptic conditions,which regionally facilitate or block diffusion of air pollutants.The chemical compositions of PM2.5 at the three sites were also found to be similar,dominated by organics and sulfates.The results indicate that accumulation of traffic emissions seems to play important roles in particle pollution for the PRD region,leading in this case to elevated nitrate contributions during both EP1 and EP2 at the three sites.Moreover,the authors found that locally emitted aerosols from biomass burning only markedly influenced the air condition at one site,Nanhai,during EP1,while regionally transported biomass burning aerosols from eastern and northern Guangdong Province influenced all three sampling sites when the PRD was dominated by polluted air from these directions during EP2.

Assessment of Spatial Distribution and Submerged Scope for Storm Surge in the Pearl River Delta Region

The aim of this study was to explore the spatial distribution and submerged scope for storm surge in the Pearl River Delta(PRD) region.Based on the data of storm surges in the PRD region in the past 30 years,the return periods of 12 tide-gauge stations for storm surges were calculated separately with the methods of Gumbel and Pearson-III.The data of another six tide-gauge stations in Guangdong Coast was quoted to depict the overall features of storm surges in Guangdong.Using least-square method,the spatial distribution models of storm surges in different return periods were established to reveal the distribution rule of the set-up values of storm surges.The spatial distribution curves of storm surges in different return periods in the PRD Region were drawn up based on the models and the terrain of Guangdong Coast.According to the curves,the extreme set-up values of storm surges in 1 000,100,10 a return periods were determined on each spot of Guangdong Coast.Applying the spatial analysis technology of ArcGIS,with the topography data of the PRD Region,the submerged scopes of flood caused by storm surge in 1 000,100,10 a return periods were drawn up.The loss caused by storm surges was estimated.Results showed that the storm surges and the topography of PRD region jointly led to the serious flood in the PRD region.This assessment would be useful for the planning and design department to make decision and provide government scientific basis for storm surge prediction,coastal engineering designing and the prevention of storm surge disaster.

Leave or Stay?Antecedents of High-level Talent Migration in the Pearl River Delta Megalopolis of China:from a Perspective of Regional Differentials in Housing Prices

Rapid urbanization and population growth have triggered an increase in urban housing demand and rising housing prices,which can influence the migration intention of high-level talents.Much work within the literature has focused more on the migration of the general public.However,antecedents of migration intention and the impact of housing prices on the migration of high-level talents remain unclear.Therefore,based on the push-pull theory,this study investigates the influencing factors of talent migration intention and explores the role of housing prices.This study reveals a complex mechanism underlying migration decisions by using logistic regression models and survey data of high-level talents in the Pearl River Delta(PRD)megalopolis of China.The results indicate that:1)in high house-price regions,social integration is the primary push factor,and the main factors for retaining talents are the expectation of future work and intimate family relationships;2)in medium house-price regions,the main factors that attract talents are the current salary level and close family ties;3)in low house-price regions,living convenience is a determining factor in retaining talents.This study provides a new perspective for talent mobility research and offers valuable inputs for retaining and attracting talents in different economic development regions.Findings are of great significance for formulating talent introduction policies and forming a new pattern of rational spatial docking and effective allocation of human resources.

Annual Fluxes of Heavy Metal Elements in Atmospheric Dry and Wet Depositions in the Pearl River Delta Economic Region, Guangdong Province

There are 158 sampling points to be set up in the Pearl River delta economic region. The collecting period is mostly one year, namely, from July 2007 to July 2008. The eight heavy metal elements of Cr, Ni, Cu, Pb, Zn, As, Hg, and Cd in 474 dry and wet deposition samples were tested in terms of the standard procedures. Their average annual fluxes have no obvious difference between dry deposition and wet deposition. So these elements might be at an equilibrium or quasi-equilibrium state between dry deposition and wet deposition.

Analysis of the Image Space of Rural Landscape of the Pearl River Delta

Through questionnaires and perceptual maps,we made a variation analysis of landscape spatial image to the people in the Pearl River Delta from the viewpoint of the subjective perception.It is found that the people of different ages and different education levels from different areas hold diversified perceptions towards rural landscape space,and they have different ideal rural landscapes.However,there is a common point that the development of rural landscape should retain its excellent local landscape features and the local spirit,which will provide references for building the ideal rural landscape model.

Coupling relationship and genetic mechanisms of shelf-edge delta and deep-water fan source-to-sink:A case study in Paleogene Zhuhai Formation in south subsag of Baiyun Sag,Pearl River Mouth Basin,China

The coupling relationship between shelf-edge deltas and deep-water fan sand bodies is a hot and cutting-edge field of international sedimentology and deep-water oil and gas exploration.Based on the newly acquired high-resolution 3D seismic,logging and core data of Pearl River Mouth Basin(PRMB),this paper dissected the shelf-edge delta to deep-water fan(SEDDF)depositional system in the Oligocene Zhuhai Formation of Paleogene in south subsag of Baiyun Sag,and revealed the complex coupling relationship from the continental shelf edge to deep-water fan sedimentation and its genetic mechanisms.The results show that during the deposition of the fourth to first members of the Zhuhai Formation,the scale of the SEDDF depositional system in the study area showed a pattern of first increasing and then decreasing,with deep-water fan developed in the third to first members and the largest plane distribution scale developed in the late stage of the second member.Based on the development of SEDDF depositional system along the source direction,three types of coupling relationships are divided,namely,deltas that are linked downdip to fans,deltas that lack downdip fans and fans that lack updip coeval deltas,with different depositional characteristics and genetic mechanisms.(1)Deltas that are linked downdip to fans:with the development of shelf-edge deltas in the shelf area and deep-water fans in the downdip slope area,and the strong source supply and relative sea level decline are the two key factors which control the development of this type of source-to-sink(S2S).The development of channels on the continental shelf edge is conducive to the formation of this type of S2S system even with weak source supply and high sea level.(2)Deltas that lack downdip fans:with the development of shelf edge deltas in shelf area,while deep water fans are not developed in the downdip slope area.The lack of“sources”and“channels”,and fluid transformation are the three main reasons for the formation of this type of S2S system.(3)Fans that lack updip coeval deltas:with the development of deep-water fans in continental slope area and the absence of updip coeval shelf edge deltas,which is jointly controlled by the coupling of fluid transformation at the shelf edge and the“channels”in the continental slope area.

Characteristics of transfer zones under the influence of preexisting faults and regional stress transformation:Wenchang A subsag,Zhujiang River Mouth Basin,northern South China Sea

A transfer zone in rift basins preserves important information on regional tectonic evolution and plays significant roles in hydrocarbon accumulation.Based on the systematic analysis of 3D seismic data and hydrocarbon accumulation conditions,the geometry,kinematics,and reservoir control of a large synthetic overlapping transfer zone in the south of the Wenchang A subsag in the Zhujiang(Pearl)River Mouth basin were investigated.Results indicate that the development and evolution of the transfer zone was controlled by the interaction between pre-existing faults and regional stress transformation.The intense rifting of the main faults of the transfer zone controlled the development of source rocks and faultcontrolled slope break paleogeomorphology.The strike-slip overprint since the Oligocene is conducive to the formation of a large-scale fault-anticline trap,and the secondary faults in the transfer zone contribute to the hydrocarbon transportation.The conjugate intersection area of the NE-and NW-trending faults offers more opportunity for hydrocarbon migration and accumulation.

Heavy metal concentrations in edible bivalves and gastropods available in major markets of the Pearl River Delta

Molluscs are able to accumulate heavy metals and impose health hazard to consumers. The main objective of the present study is to investigate the heavy metal concentrations in edible bivalves and gastropods available in major markets of the Pearl River Delta. Fourteen species of edible molluscs were purchased from six markets in Hong Kong and Guangdong Province. The fresh of these biota were tested for their cadmium (Cd), copper (Cu), zinc (Zn), lead (Pb), nickel (Ni), chromium (Cr), antimony (Sb) and tin (Sn) concentrations (based on wet weight). The results indicated that amongst the 14 edible molluscs, only Cd, Pb, Ni, Cr, Sb and Sn concentrations in three species (Ruditapes philippinarum, Perna viridis and Hemifusus tuba) were within the local regulatory limits. Over 60% of bivalve species exceeded maximum permitted levels of Cd (2 mug/g) and Cr (1 mug/g), while over 40% of gastropod species exceeded the maximum levels of Sb (1 mug/g) and Cr (1 mug/g). Most of the samples collected from Hong Kong had significantly higher contents of Pb and Sb, but similar levels of Cd, Cu and Zn when compared with samples collected across the border ( p < 0.05; p 0.01; p < 0.001 respectively). In general, the molluscs purchased in Guangdong markets had higher metal contents than those purchased from the Hong Kong markets. When compared with the Provisional Tolerable Weekly Intake or Maximum Acceptable Daily Load recommended by FAO/WHO Expert Committee on Food Additives, Cd levels of five species (Anadara ferruginea, Pinna pectinata, Chlamys nobilis, Babylonia lutosa and Hemifusus terntanus) and Cr levels of seven species ( Anadara ferruginea, Paphia undulata, Pinna pectinata, Babylonia lutosa, Hemifusus terntanus, Cymbium melo and Cipangopaludina chinensis) were higher than both the human daily acceptable limits (for Cd and Cr respectively) and the local regulatory levels (for Cd and Cr respectively).

Regional accessibility of land traffic network in the Yangtze River Delta

In a given district, the accessibility of any point should be the synthetically evaluation of the internal and external accessibilities. Using MapX component and Delphi, the author presents an information system to calculate and analyze regional accessibility according to the shortest travel time, generating thus a mark diffusing figure. Based on land traffic network, this paper assesses the present and the future regional accessibilities of sixteen major cities in the Yangtze River Delta. The result shows that the regional accessibility of the Yangtze River Delta presents a fan with Shanghai as its core. The top two most accessible cities are Shanghai and Jiaxing, and the bottom two ones are Taizhou （Zhejiang province） and Nantong With the construction of Sutong Bridge, Hangzhouwan Bridge and Zhoushan Bridge, the regional internal accessibility of all cities will be improved. Especially for Shaoxing, Ningbo and Taizhou （Jiangsu province）, the regional internal accessibility will be decreased by one hour, and other cities will be shortened by about 25 minutes averagely. As the construction of Yangkou Harbor in Nantong, the regional external accessibility of the harbor cities in Jiangsu province will be speeded up by about one hour.

Evidences and implications of vegetation damage from ceramic industrial emission on a rural site in the Pearl River Delta of China

Community structure characteristics and vegetation damage degree were investigated and analyzed in a forest around village, which had been long term exposed to ambient atmospheric pollution stress, to study the influence of airborne pollutant emissions from the concentrated ceramic industries on vegetation. Field survey was carried out in a semi natural secondary forest on hilly land, Nanhai District of Guangdong Province, for the tree layer in ten quadrates with the total area of 10 × （10 m×10 m）, and for shrub and herb layers in eight subquadrates with the total area of 4 × （5 m×5 m）. Results showed that exotic Eucalyptus exserta and Eucalyptus urophylla were dominated over the community, followed by native tree species, Scheffiera octophylla and Bambusa gibba, with the importance value （Iv） of 26.75, 17.08, 16.27 and 11.50, respectively. Among all tree species, Eucalyptus exserta and Pinus massoniana were most severely damaged with nearly 100% damaged rate. Bambusa gibba and Dalbergia balansae were injured with damaged rate of 85.1% 68.3%, however, Eucalyptus urophylla, Celtis sinensis, Helicia cochinchinensis, Cinnamomum burmanni and Vitex negundo revealed moderate injuries （45%-57.5%）. Most of other indigenous species including Schefflera octophylla, Viburnum odoratissimum, Desmos chinensis, etc. showed less injured symptoms under the pollution stress. Compared with species in tree layer, damages of undergrowths were largely less. These results suggested that attention and concern should be paid on those introduced Eucalyptus species which had ever been widely used for forest restora tion in degraded hilly lands of south China since 1970-1980s, due to their last growing aspect, The results also demonstrated the potentials and perspectives by developing native species as target plants for restoration of degraded area at similar polluted location, which may provide scientific base for scientists to study and understand the functional aspects of native species and process-based interactions with pollution stress.

A Closure Study of Aerosol Hygroscopic Growth Factor during the 2006 Pearl River Delta Campaign

Measurements of aerosol physical, chemical and optical parameters were carried out in Guangzhou, China from 1 July to 31 July 2006 during the Pearl River Delta Campaign. The dry aerosol scattering coefficient was measured using an integrating nephelometer and the aerosol scattering coefficient for wet conditions was determined by subtracting the sum of the aerosol absorption coefficient, gas scattering coefficient and gas absorption coefficient from the atmospheric extinction coefficient. Following this, the aerosol hygroscopic growth factor, f（RH）, was calculated as the ratio of wet and dry aerosol scattering coefficients. Measurements of size-resolved chemical composition, relative humidity （RH）, and published functional relationships between particle chemical composition and water uptake were likewise used to find the aerosol scattering coe？cients in wet and dry conditions using Mie theory for internally- or externally-mixed particle species [（NH_4）_2SO_4, NH_4NO_3, NaCl, POM, EC and residue]. Closure was obtained by comparing the measured f（RH） values from the nephelometer and other in situ optical instruments with those computed from chemical composition and thermodynamics. Results show that the model can represent the observed f（RH） and is appropriate for use as a component in other higher-order models.