Comparative Toxicity of “Tin Free” Self-Polishing Copolymer Antifouling Paints and Their Inhibitory Effects on Larval Development of a Non-Target Organism

Toxic substances released as a result of leaching from painted surfaces to the aquatic environment affect both fouling organisms and “non-target” biota. Artemia fransiscana nauplii have been considered a useful test system for the examination of toxicity for antifouling paints. In this study, we examined the effect of four “tin free” self-polishing copolymer (SPC) antifouling paints on the larval development of Artemia nauplii. Based on the L(S/V)50 values the order of toxicity of the antifouling paints was: ANTI F > SHARKSKIN > OCEAN T/F > MICRON. Furthermore, the body size of Artemia nauplii was significantly affected at lethal and above lethal L(S/V)5024h values. The body size of 48 h-aged nauplii exposed for the last 24 hours to each of the four SPC antifouling paints was significantly lower than that of the 48 h-aged controls (0.88 ± 0.030 mm). In addition, the body size of 72 h-aged nauplii maintained for the last 24 hours to pure synthetic seawater after exposure for 24 hours to each of the four SPC antifouling paints was significantly lower than that of the 72 h-aged controls (0.96 ±0.027 mm). Overall, the SPCs examined here were substantially toxic to Artemia nauplii, but with different toxicities and modes of action, as a result of the synergistic action of distinct components of the antifouling paints.

Phosphine-free synthesis of FeTe2 nanoparticles and self-assembly into tree-like nanoarchitectures

Manipulating the self-assembly of transition metal telluride nanocrystals(NCs) creates opportunities for exploring new properties and device applications. Iron ditelluride(FeTe2) has recently emerged as a new class of magnetic semiconductor with three-dimensional(3D) magnetic ordering and narrow band gap structure, yet the self-assembly of FeTe2 NCs has not been achieved. Herein, the tree-like FeTe2 nanoarchitectures with orthorhombic crystal structure have been successfully synthesized by hot-injection solvent thermal approach using phosphine-free Te precursor. The morphology, size, and crystal structure have been investigated using transmission electron microscopy(TEM), high-resolution TEM(HRTEM),and powder x-ray diffraction(XRD). We study the formation process of tree-like FeTe2 NCs according to trace the change of the sample morphology with the reaction time. It was found that the FeTe2 nanoparticles show oriented aggregation and self-assembly behavior with the increase of reaction time, which is attributed to size-dependent magnetism properties of the samples. The magnetic interaction is thought to be the driving force of nanoparticle self-organization.

Preparation of Self-crosslinked Fluorocarbon Polymer Emulsion with Core-shell Structure by the Method of Soap-free Emulsion Polymerization

Using methyl methacrylate （MMA）, butyl acrylate（BA） and hexafluorobutyl acrylate（HFBA） as main raw materials, we prepared self-crosslinked fluorocarbon polymer emulsion with core-shell structure via soap-free emulsion polymerization when the conception of particle design and polymer morphology was adopted. Moreover, the influence of mole ratio of BA to MAA, pH value on the oligomer was studied. And the effects of the added amount of oligomer, self-crosslinked monomer and HFBA, mass ratio of BA to MMA, reaction temperature and the initiator on the polymerization technology and the performance of the product, were investigated and optimized. The structure and performance of the fluorocarbon polymer emulsion were characterized and tested with FTIR, TEM, MFT and contact angle and water absorption of the latex film. The experimental results show that the optimal conditions for preparing fluorocarbon polymer emulsion are as follows： for preparing the oligomer, tool ratio of BA to MAA is equal to 1.0 ： 1.60, and pH value is controlled within the range of 8.0 and 9.0; for preparing fluorocarbon polymer emulsion, the added amount of oligmer[P（BA/MANa）] is 6%; mass ratio of BA to MMA is 40 ＂ 60; the added amount of self-crosslinked monomer is 2%, the added amount of HFBA is 15 %; reaction temperature is 80 ℃; the mixture of potassium persulfate and sodium bisulfite is used as the initiator. The film-forming stability of the fluorocarbon polymer emul- sion and the performance of the latex film, which is prepared with the soap-free emulsion polymerization, are better than that prepared with the conventional emulsion polymerization.

Salicylic Acid Induced Self-excision of the Marker Gene npt Ⅱ Using CreloxP System from Transgenic Tobacco

Transgenic plants, despite a great deal of scientifi c evidences, have induced a number of environmental and consumer concerns for long time because various antibiotic resistance genes, according to common

A Physical Insight into the Origin of the Corrections to the Magnetic Moment of Free and Bound Electron

The main goal of the present work is a unitary approach of the physical origin of the corrections to the magnetic moment of free and bound electron. Based on this approach, estimations of lowest order corrections were easily obtained. In the non-relativistic limit, the Dirac electron appears as a distribution of charge and current extended over a region of linear dimension of the order of Compton wavelength, which generates its magnetic moment. The e.m. mass (self-energy) of electron outside this region does not participate to this internal dynamics, and consequently does not contribute to the mass term in the formula of the magnetic moment. This is the physical origin of the small increase of the magnetic moment of free electron compared to the value given by Dirac equation. We give arguments that this physical interpretation is self-consistent with the QED approach. The bound electron being localized, it has kinetic energy which means a mass increase from a relativistic point of view, which determines a magnetic moment decrease (relativistic Breit correction). On the other hand, the e.m. mass of electron decreases at the formation of the bound state due to coulomb interaction with the nucleus. We estimated this e.m. mass decrease of bound electron only in its internal dynamics region, and from it the corresponding increase of the magnetic moment (QED correction). The corrections to the mass value are at the origin of the lowest order corrections to the magnetic moment of free and bound electron.

The Global Analysis of a Stochastic Two-Scale Network Epidemic Dynamic Model with Varying Immunity Period

A stochastic SIR epidemic dynamic model with distributed-time-delay, for a two-scale dynamic population is derived. The distributed time delay is the varying naturally acquired immunity period of the removal class of individuals who have recovered from the infection, and have acquired natural immunity to the disease. We investigate the stochastic asymptotic stability of the disease free equilibrium of the epidemic dynamic model, and verify the impact on the eradication of the disease.

Self-assembled Synthesis of Porous TiO_2 Film on the Electrophoretic-deposited Titanate Nanoribbon Film

The porous TiOz film was self-assembled on the surface of electrophoretic-deposited titanate nanoribbon film without the addition of templates by using TiF4 as the precursor. It was found that the hydrolysis of TiF4 was accompanied with the self-assembly processes of TiO2 nanoparticles on the surface of electrophoretic-deposited titanate nanoribbon film, resulting in the formation of porous TiO2 structures. Titanate nanoribbon film was demonstrated to provide the active sites for the effective self-assembly of porous TiO2 nanostructures owing to a large amount of hydroxyl groups. Compared with the nonporous TiO2 film, the prepared porous TiO2 films obviously showed an enhanced photocatalytic activity, which could be attributed to the rapider diffusion and more efficient transport of various reactants and products during photocatalytic reaction in the t^orous structures.

Accuracy and effectiveness of self-gating signals in free-breathing three-dimensional cardiac cine magnetic resonance imaging

Conventional multiple breath-hold two-dimensional （2D） balanced steady-state free precession （SSFP） presents many difficulties in cardiac cine magnetic resonance imaging （MRI）. Recently, a self-gated free-breathing three-dimensional （3D） SSFP technique has been proposed as an alternative in many studies. However, the accuracy and effectiveness of selfgating signals have been barely studied before. Since self-gating signals are crucially important in image reconstruction, a systematic study of self-gating signals and comparison with external monitored signals are needed. Previously developed self-gated free-breathing 3D SSFP techniques are used on twenty-eight healthy volunteers. Both electrocardiographic （ECG） and respiratory bellow signals are also acquired during the scan as external signals. Self-gating signal and external signal are compared by trigger and gating window. Gating window is proposed to evaluate the accuracy and effectiveness of respiratory self-gating signal. Relative deviation of the trigger and root-mean-square-deviation of the cycle duration are calculated. A two-tailed paired t-test is used to identify the difference between self-gating and external signals. A Wilcoxon signed rank test is used to identify the difference between peak and valley self-gating triggers. The results demonstrate an excellent correlation （P = 0, R 〉 0.99） between self-gating and external triggers. Wilcoxon signed rank test shows that there is no significant difference between peak and valley self-gating triggers for both cardiac （H = 0, P 〉 0.10） and respiratory （H = 0, P 〉 0.44） motions. The difference between self-gating and externally monitored signals is not significant （two-tailed paired-sample t-test： H = 0, P 〉 0.90）. The self-gating signals could demonstrate cardiac and respiratory motion accurately and effectively as ECG and respiratory bellow. The difference between the two methods is not significant and can be explained. Furthermore, few ECG trigger errors appear in some subjects while these errors are not found in self-gating signals.

CHAOTIC ELECTRON TRAJECTORIES IN A CIRCULAR FREE ELECTRON LASER

The motion of a relativistic electron is analyzed in the field configuration consisting of a circular wiggler magnetic field, an axial magnetic field, and the equilibrium self-electric and self-magnetic fields produced by the non-neutral electron ring. By generating Poincare surface-of-section maps, it is shown that when the equilibrium self-fields is strong enough, the electron motions become chaotic. Although the realistic circular wiggler magnetic field destroys the inte-grability of the electron motion as the equilibrium self-fields do, the role the latter plays to make the motions become chaotic is stronger than the former does. In addition, the axial magnetic field can restrain the occurrence of the chaoticity.

SELF-ASSEMBLY OF ROD-COIL DIBLOCK COPOLYMERS——INFLUENCE OF THE ROD LENGTH

The self-assembly of five narrowly distributed novel rod-coil diblock copolymers, poly(styrene-block-(2, 5-bis[4-methoxy-phenyl]oxycarbonyl) styrene) (PS-b-PMPCS), in p-xylene, a selective solvent at room temperature, was studied. Therod-coil copolymers, which have the same PS length but different PMPCS length, were synthesized by 2,2,6,6-tetramethyl-I-piperidinyloxy (TEMPO) mediated living free radical polymerization. The influence of the rod length on the self-assemblymorphology was studied by transmission electron microscopy (TEM). At a concentration of 2.0 mg/mL, those copolymerswith relatively shorter PMPCS length (copolymers 1 and 2) form individual spherical micelles; those with relatively longerPMPCS length (copolymer 3 and 4) form 'pearl chains' coexisting with individual spherical micelles; the ones with longestPMPCS length form 'pearl chains' coexisting with occasionally formed nanofibers. The diameter of all the morphologieswas controlled by the rod length. This gives us a way to govern the self-assembly morphology by altering the length of oneblock in the block copolymer.

Expansive Performance of Self-stressing and Self-compacting Concrete Confined with Steel Tube

Combining with the technology of self-compacting concrete, self-stressing concrete and concrete-filled steel tube, we can get self-compacting and self-stressing concrete-filled steel tube. In order to study the expansive mechanism of self-stressing concrete, the continuous observation of 47 days on six specimens was carried on. The specimens have different steel area to concrete area ratio. The expansive process in hoop and axial direction were studied, and the expansive mechanism was discussed too. The experimental results identify that the creep and elastic deformation take a large proportion in effective free expansion. The calculating formulas of self-stress in hoop and axial directions were presented here.

Studies on the Self-condensing Vinyl Living Radical Polymerization of a Novel Acrylate Inimer

A novel acrylate inimer, 2-（2-chloroacetyloxy） ethyl acrylate, was prepared by the reaction of 2-hydroxyethyl acrylate with chloroacetyl chloride in the presence of triethylamine. The self-condensing vinyl living radical polymerization of the inimer was studied and the hyperbranched macromolecules containing ester linkages on their backbone were prepared. All the polymerization products were characterized by 1H NMR. The polymerization degree and the branching parameter were calculated based on the 1H NMR spectra. It has been shown that this inimer exhibits a very distinctive polymerization behavior. Similar to step-growth polymerization, the polymerization degree of the products formed increased exponentially during the early stage of the polymerization, and then the increasing rate slowed down. However, the inimer remained present throughout the polymerization consistent with conventional free radical polymerization. Also, if much longer polymerization time was used, the polymerization system would become gel due to the crosslinking reaction derived from radical-radical recombination. As a result of the unequal reactivity of -CH2Cl and >CHCl, an almost linear product was obtained at a molar ratio of bipy to inimer=0.05, while a relatively high ratio of bipy to inimer 1 favored the formation of the branched structure. The macromolecules formed at a high ratio of bipy to inimer 1 exhibited an excellent solubility in organic solvents such as acetone.

THE MUTUAL VARIATIONAL PRINCIPLE OF FREE WAVE PROPAGATION IN PERIODIC STRUCTURES

By taking infinite periodic beams as examples,the mutual variational principle for analyzing the free wave propagation in periodic structures is established and demonstrated through the use of the propaga- tion constant in the present paper,and the corresponding hierarchical finite element formulation is then de- rived.Thus,it provides the numerical analysis of that problem with a firm theoretical basis of variational prin- ciples,with which one may conveniently illustrate the mathematical and physical mechanisms of the wave prop- agation in periodic structures and the relationship with the natural vibration.The solution is discussed and ex- amples are given.

Does Life Need Water or Can It Be Generated by Other Fluids?

In the present work the Stochastic generalization of the quantum hydrodynamic analogy (SQHA) is used to obtain the far-from-equilibrium kinetics for a real gas and its fluid phase. In gases and their liquids, interacting by Lennard-Jones potentials whose mean distance is bigger than the quantum correlation distance and the molecular interaction distance r0, it is possible to define a Fokker-Plank type equation of motion as a function of the mean phase space molecular volume that far-from-equilibrium shows maximizing the dissipation of a part of the generalized SQHA-free energy. In the case of a real gas with no chemical reactions with small temperature gradients, the principle disembogues into the maximum free energy dissipation confirming the experimental outputs of electro-convective instability. In this case, the model shows that the transition to stationary states with higher free energy can happen and that in incompressible fluids, the increase of free energy is almost given by a decrease of entropy leading to the appearance of self-ordered structures. The output of the theory showing that the generation of order via energy dissipation, is more efficient in fluids than in gases, because of their incompressibility, which leads to the reconciliation between physics and biology furnishing the explanation why the life was born in water. The theoretical output also suggests that the search for life out of the earth must consider the possibility to find it in presence of liquid phases different from water.

无线传感器网络Range-free自身定位算法仿真分析

定位技术是无线传感器网络重要的支撑技术之一。文章在总结有关定位算法的文献和研究成果的基础上。介绍了6种代表性的Range-free定位算法的原理，在Matlab环境下构造了网络拓扑场景进行了仿真实验，对6种代表性算法的性能进行比较并分析总结，指出了今后无线传感器网络定位算法的研究中所需解决的问题。

基于呋喃、马来酰亚胺Diels-Alder反应的自修复水性聚丙烯酸酯涂料的制备及性能研究

基于呋喃和马来酰亚胺之间的可逆Diels-Alder(DA)反应,成功制得一种通过热驱动而具备自修复特性的水性聚丙烯酸酯涂料,并对自修复的条件进行了探索和优化。首先合成带呋喃官能团的丙烯酸酯单体(FEEMA),将其与常用的丙烯酸单体无皂乳液共聚合,得到稳定的水性丙烯酸酯乳液,并对其进行红外光谱、凝胶渗透色谱和粒径测试。其次设计合成出能够水分散的、带聚醚链的双马来酰亚胺(D-400-BMI),使其与水性丙烯酸酯乳液进行Diels-Alder反应得到水性聚丙烯酸酯交联膜。利用红外光谱及差示扫描量热法跟踪不同条件下的Diels-Alder反应和retro-DA过程,结果表明当聚合物中的FEEMA质量分数为30%、甲基丙烯酸甲酯与丙烯酸丁酯质量比为1∶5时,由自制的较软链段分子D-400-BMI制备的交联膜有较好的修复性能。交联膜被划伤后,经140℃热处理再缓慢冷却至室温,可对表面划伤和摩擦痕迹有良好的修复效果。此外,制备的交联膜还具备良好的耐热性能和机械性能,在表面涂层划痕和微裂纹自修复方面有潜在应用前景。

ULF electric and magnetic anomalies accompanying the cracking of rock sample

The anomalies of electric-magnetic field and self-potential before earthquakes are important precursory phenom-ena. A simulating experiment study on the variations in ultra-low frequency (ULF) magnetic field and self-poten-tial during rock cracking was carried out in a magnetic field-free space. The results revealing in detail the whole process of the occurrences of electric and magnetic anomalies are significant for understanding the microscopic mechanism of ULF electric and magnetic signals. The experiment indicated that at the initial stage the slow changes in strain, self-potential and magnetic field with small amounts appeared firstly near the source of initial cracking, and then extended as the crack developed on. In the time domain, the self-potential anomaly emerged first and ULF magnetic field changes arose then. The shape of the ULF electric and magnetic anomaly varied ob-viously in early-, mid- and late-term of the test. The authors attributed the pulse-like changes of self-potential to the generation and movement of the accumulated electric charges during the cracking caused by charge separation on the crack tips within the sample. While the magnetic pulses of shorter-period at the last stage of the test, may be induced by instantaneous electric current of the accumulated charge during the cracking acceleration. The technical method and the observational results of this experiment are given in detail and the microscopic mechanism of elec-tric and magnetic precursors before earthquake are discussed in the present paper as well.

一维可压Navier-Stokes方程自由边值问题的自模解

研究黏性系数μ(ρ)=1+θρθ时一维可压Navier-Stokes方程自模解的非存在性.首先通过建立能量估计式,熵估计式得到密度函数ρ的正的下界,然后对能量函数进行定量分析,利用能量爆破理论证明了θ>0时一维可压Navier-Stokes方程不存在具有有限总能量的自模解.最后将常黏性系数Navier-Stokes方程自模解的方法推广到黏性系数依赖于密度的情形,并且把θ的范围扩展到θ>0.

Acoustic Polaron in Free-Standing Slabs

The ground-state energy and its derivate of the acoustic polaron in free-standing slab are calculated by using the Huybrechts-like variational approach. The criteria for presence of the selftrapping transition of the acoustic polaron in free-standing slabs are determined qualitatively. The critical coupling constant for the discontinuous transition from a quasi-free state to a trapped state of the acoustic polaron in free-standing slabs tends to shift toward the weaker electronphonon coupling with the increasing cutoff wave-vector. Detailed numerical results confirm that the self-trapping transition of holes is expected to occur in the free-standing slabs of wide-bandgap semi-conductors.

Associated or Concomitant Diseases Influence Significantly the Health-Sickness Concept in Celiacs

It is well-known that feeling to be a healthy or sick person most probably results from the mind than from the body. We all know healthy people who feel sick and vice versa. We were interested in the health and sickness feeling of celiac people, their autorating of these feelings and its conditioning factors as well as their expectations. In this paper we present the results of an inquiry to evaluate these situations. We performed a descriptive, transversal and prospective study for 2 years to groups of celiacs and their families. They received a closed inquiry to be completed before the beginning of the talk. The inquiry included personal data and the co-existence of associated or concomitant (AoC) diseases. Most of the sample’s patients felt to be a healthy person (86.8%). Mothers see their children as healthy and the auto rated criteria is significantly better than the adult celiac person (“t”= -6.024 (p = 0.000)). AoC diseases influenced negatively in the feeling of being healthy and strongly decreased the autorating. Longer time passed on treatment reflects an increase feeling of health and of the autorating. In people with AoC diseases and who feel sick, the increased time of treatment did not show significant differences. People with “gluten sensitivity” felt sicker and auto rated themselves with a lower number than celiacs. Many pediatric gastroenterologists notice that the newly agreed definition of celiac disease, referring it as “autoimmune, chronic, incurable, and multisystemic”, results in a very negative character of the condition which might compromise the future labour of this people as well as their admittance to different health insurance systems.