Combination of Nitrogen-Rich Skeleton and Coordination Group:Synthesis of a High-Energy Primary Explosive Based on 1H-Tetrazole-5-Carbohydrazide

The high energy coordination compounds Cu(TZCA)_(2)(ClO_(4))_(2)(ECCs-1) was prepared by 1H-tetrazole-5-carbohydrazide(TZCA) with a high energy skeleton and a strong coordination ability group.At the same time,the reaction activity of the ligand was explored,and the single crystal structure of it and intermediate were obtained.The structures of all substances were characterized by IR and EA.And the structure and composition of ECCs-1 are confirmed by ESP,AC,SEM and ICP-OES.Physical and chemical properties tests show that ECCs-1 has an acceptable thermal stability(T_(d)=177℃) and extremely sensitive mechanical stimulation(IS=1 J,FS=5 N).The comprehensive performance test results show that ECCs-1 has excellent initiation ability.In addition,the decomposition mechanism of ECCs-1 is explored from two aspects of experiment and theoretical calculation.

Regarding the Regulatory Sandbox Route and Mechanism for Governance of Artificial Intelligence

The main challenge in AI governance today is striking a balance between controlling AI dangers and fostering AI innovation.Regulators in a number of nations have progressively extended the regulatory sandbox,which was first implemented in the banking sector,to AI governance in an effort to reduce the conflict between regulation and innovation.The AI regulatory sandbox is a new and feasible route for AI governance in China that not only helps to manage the risks of technology application but also prevents inhibiting AI innovation.It keeps inventors'trial-and-error tolerance space inside the regulatory purview while offering a controlled setting for the development and testing of novel AI that hasn't yet been put on the market.By providing full-cycle governance of AI with the principles of agility and inclusive prudence,the regulatory sandbox offers an alternative to the conventional top-down hard regulation,expost regulation,and tight regulation.However,the current system also has inherent limitations and practical obstacles that need to be overcome by a more rational and effective approach.To achieve its positive impact on AI governance,the AI regulatory sandbox system should build and improve the access and exit mechanism,the coordination mechanism between the sandbox and personal information protection,and the mechanisms of exemption,disclosure,and communication.

Study on the Coordination Mechanism Between Higher Vocational Students’Career Development Planning and School Management

The coordination mechanism between the career development planning of vocational students and the management of vocational colleges is an important means to improve the quality of education and students’vocational competitiveness.The application of synergy theory in the field of education emphasizes the interaction and coordination of various elements in the system and pursues the optimization of overall efficiency.Based on the theory of coordination and its relevance to the management of higher vocational colleges,this paper analyzes the current development status and problems of the coordination mechanism and puts forward the strategy of building an efficient coordination mechanism designed to enhance the students’employment competitiveness,promote the all-round development,and provide theoretical and practical support for the reform and development of higher vocational education.

On Incentive and Coordination Mechanism of Service Outsourcing Based on Principal-Agent Theory and Blockchain Technology

To address the issue of information asymmetry between the two parties and moral hazard among service providers in the process of service outsourcing,this paper builds the Stackelberg game model based on the principal-agent framework,examines the dynamic game situation before the contract being signed,and develops four information models.The analysis reveals a Pareto improvement in the game’s Nash equilibrium when comparing the four models from the standpoint of the supply chain.In the complete information scenario,the service level of the service provider,the customer company’s incentive effectiveness,and the supply chain system’s ultimate profit are all maximized.Furthermore,a coordinating mechanism for disposable profit is built in this study.The paper then suggests a blockchain-based architecture for the service outsourcing process supervision and a distributed incentive mechanism under the coordination mechanism in response to the inadequacy of the principal-agent theory to address the information asymmetry problem and the moral hazard problem.The experiment’s end findings demonstrate that both parties can benefit from the coordination mechanism,and the application of blockchain technology can resolve these issues and effectively encourage service providers.

Solution for Output Coordination Equations of Several Typical Parallel Six-Dimensional Acceleration Sensing Mechanisms

Aiming at the problem that it is difficult to generate the dynamic decoupling equation of the parallel six-dimensional acceleration sensing mechanism,two typical parallel six-dimensional acceleration sensing mechanisms are taken as examples.By analyzing the scale constraint relationship between the hinge points on the mass block and the hinge points on the base of the sensing mechanism,a new method for establishing the dynamic equation of the sensing mechanism is proposed.Firstly,based on the scale constraint relationship between the hinge points on the mass block and the hinge points on the base of the sensing mechanism,the expression of the branch rod length is obtained.The inherent constraint relationship between the branches is excavated and the branch coordination closed chain of the“12-6”configuration is constructed.The output coordination equation of the sensing mechanism is successfully derived.Secondly,the dynamic equations of“12-4”and“12-6”configurations are constructed by the Newton-Euler method,and the forward decoupling equations of the two configurations are solved by combining the dynamic equations and the output coordination equations.Finally,the virtual prototype experiment is carried out,and the maximum reference errors of the forward decoupling equations of the two configuration sensing mechanisms are 4.23%and 6.53%,respectively.The results show that the proposed method is effective and feasible,and meets the real-time requirements.

Study on the Influence of the Coordinated Development of Resident Income and GDP on Local Economic Development:Take Shandong Province as an Example

With the rapid development of China’s economy,the coordinated development of resident income and GDP has become an important indicator to measure local economic development.How to realize the synergistic growth of the two in the new era is of great significance for promoting the sustainable development of the local economy.Based on the theory of the coordinated development of resident income and GDP,this paper will take Shandong Province as an example to analyze the interaction between resident income growth and GDP,find out the influencing factors that restrict the coordinated development of resident income and GDP,and explore the impact of the coordinated development of resident income and GDP on local economic development.Finally,relevant policies will be studied.How to effectively increase residents’income,promote the sustainable and healthy development of the local economy,and put forward relevant suggestions to promote the coordinated development of residents’income and GDP.

A Comprehensive Evaluation Framework of Water-Energy-Food System Coupling Coordination in the Yellow River Basin,China

For mankind’s survival and development,water,energy,and food(WEF)are essential material guarantees.In China,however,the spatial distribution of WEF is seriously unbalanced and mismatched.Here,a collaborative governance mechanism that aims at nexus security needs to be urgently established.In this paper,the Yellow River Basin in China with a representative WEF system,was selected as a case.Firstly,a comprehensive framework for WEF coupling coordination was constructed,and the relationship and mechanism between them were analyzed theoretically.Then,we investigated the spatiotemporal characteristics and driving mechanisms of the coupling coordination degree(CCD)with a composite evaluation method,coupling coordination degree model,spatial statistical analysis,and multiscale geographic weighted regression.Finally,policy implications were discussed to promote the coordinated development of the WEF system.The results showed that:1)WEF subsystems showed a significant imbalance of spatial pattern and diversity in temporal changes;2)the CCD for the WEF system varied little and remained at moderate coordination.Areas with moderate coordination have increased,while areas with superior coordination and mild disorder have decreased.In addition,the spatial clustering phenomenon of the CCD was significant and showed obvious characteristics of polarization;and 3)the action of each factor is self-differentiated and regionally variable.For different factors,GDP per capita was of particular importance,which contributed most to the regional development’s coupling coordination.For different regions,GDP per capita,average yearly precipitation,population density,and urbanization rate exhibited differences in geographical gradients in an east-west direction.The conclusion can provide references for regional resource allocation and sustainable development by enhancing WEF system utilization efficiency.

Hydrothermal in situ Ligand Synthesis from 1,10-Phenanthroline-5,6-dione and Characterization of 1D Coordination Polymers [Co(bpdc)(H_2O)_3]·H_2O and [Cu(bpy)V_2O_6]

Hydrothermal treatment of MCl2 （ M = Co or Cu ） , NH4 VO3, and 1,10-phenanthroline-5,6-dione （pdon） resulted in the formation of a duplex coordination polymer [ Co （ bpdc ） （ H2O ） 3 ] · H2O （ bpdc = 2,2＇-bipyridine-3,3＇-dicarboxylate） and a chain-like coordination polymer [ Cu （bpy） V2O6 ] （ bpy = 2,2＇-bipyridine ）. X-ray single-crystal structural analysis shows that under hydrothermal conditions and in the presence of different transition metals, the organic reagent pdon was transformed in situ into bpdc and bpy, respectively. Mechanism of the in situ ligand synthesis reaction has been discussed.

SIMULTANEOUS POLYMERIZATION AND FORMATION OF POLYPHENYLACETYLENE FILMS BY RARE-EARTH COORDINATION CATALYSIS Ⅳ.KINETICS AND MECHANISM OF POLYMERIZATION

The CO_2 quenching method has been used for the first time to determine the active complex concen- tration in Nd(naph)_3-Al(i-Bu)_3 catalyst system for polymerization of phenylacetylene into polyphenylacetylene(PPA)films.The kinetics and mechanism of this polymerization have been investigated by CO_2 quenching and IR,UV analytical methods.The kinetic equation can be expressed as Rp=k[M][Cp],and the apparent activation energy is about 13.6 kJ/mol.There is self-termination of chain propagating.Models for formation of the active complex and polymerization mechanism are proposed.

The homogenous growth of Co-based coordination compound on graphene nanosheet for high-performance K-organic battery and its reaction mechanism

Metal coordination compounds(MCCs)are gaining popularity for potassium-ion batteries(PIBs)owing to their tuneable structure,multiple reaction sites,low cost and unique morphology.However,they are generally subjected to intrinsic features of the sluggish ionic diffusion coefficient,low electronic conductivity and slow kinetics.Herein,a new MCC material of cobalt-1,3,5-trioxy-2,4,6-triamino-benzo(Co-TB)coordination compound was synthesized and homogenously grown on the surface of graphene nanosheets(GNS),forming a Co-TB@GNS composite with enhanced electronic conductivity and flexible capability.Benefiting from the overall enhanced conductivity,high surface area and abundant activated K-storage sites,Co-TB@GNS electrodes have exhibited superior cycling performance with high reversible capacities(312 mAh·g^(-1)after 100 cycles at 100 mA·g^(-1),224 mAh·g^(-1)after 500 cycles at 1 A·g^(-1))and better rate performances compared with the pure Co-TB compound when served as PIB's anodes.Furthermore,multiple in-situ measurement techniques have jointly confirmed that the organic functional groups(C=O,C=N and C=C of benzene rings)and Co^(2+)in Co-TB are the main reversible K-storage sites,including in-situ Fourier transform infrared spectroscopy(FTIR)and X-ray diffraction(XRD),and partial capacity contribution is originated from GNS by the apparent K-storage behavior in the in-situ XRD pattern,proving the possibility of K-storage for metal-organic materials.

Agricultural Mechanism of Spreading Catastrophe Risk in China and Legislation Conception

This paper introduces agricultural catastrophe and its characteristics,and conducts comparative analysis on existing mechanism of spreading agricultural catastrophe risk,indicating that the mechanism of administrative remedy has the greatest efficiency and highest cost;the mechanism of social assistance has the lowest cost,but its efficiency is lowest and there are unstable factors;market mechanism,namely the insurance of agricultural catastrophe,is the rational choice of agricultural department in mechanism of risk spreading.This paper analyzes the status quo of China's insurance of agricultural catastrophe,indicating that the main body of management in China's insurance of agricultural catastrophe is missing.In addition,the market demand is critically scanty,and insurance of agricultural catastrophe lacks external development environment.The gap of China's insurance law of agricultural catastrophe has become the greatest obstacle to the development of insurance of agricultural catastrophe.From legislative purpose,basic principle,nature,main body of legal relations,management range,policy support,supervision and management and so on,the legislation conception of China's insurance of agricultural catastrophe is put forward.

Effect of fluoride ions on coordination structure of titanium in molten NaCl–KCl

The effects of fluoride ions(F^(-)) on the electrochemical behavior and coordination properties of titanium ions(Ti^(n+)) were studied in this work,by combining electrochemical and mathematical analysis as well as spectral techniques.The α was taken as a factor to indicate the molar concentration ratio of F^(-) and Ti^(n+).Cyclic voltammetry(CV),square wave voltammetry(SWV),and open circuit potential method(OCP)were used to study the electrochemical behavior of titanium ions under conditions of various α,and in-situ sampler was used to prepare molten salt samples when α equal to 0.0,1.0,2.0,3.0,4.0,5.0,6.0,and 8.0.And then,samples were analyzed by X-ray photoelectron spectroscopy(XPS) and Raman spectroscopy.The results showed that F^(-) in molten salt can reduce the reduction steps of titanium ions and greatly affects the proportion of valence titanium ions which making the high-valence titanium content increased and more stable.Ti^(2+) cannot be detected in the molten salt when α is higher than 3.0 and finally transferred to titanium ions with higher valence state.Investigation revealed that the mechanism behind those phenomenon is the coordination compounds(TiCl_(j) F_(i)^(m-)) forming.

Supersymmetry and Shape Invariance of Hartmann Potential and Ring-Shaped Oscillator Potential in the γ and θ Dimensions of Spherical Polar Coordinates

This article shows that in spherical polar coordinates, some noncentral separable potentials have super-symmetry and shape invariance in the r and θ dimensions, we choose Hartmann potential and ring-shaped oscillator astwo important examples, thus in principle the energy eigenvalues and energy eigenfunctions of such the potentials in ther and θ dimensions can be obtained by the method of supersymmetric quantum mechanics. Here we use an alternativemethod to get the required results.

Evaluating the Relationship between National Park Management and Local Communities’ Perceptions Based on Survey, a Case of Nyungwe National Park, Rwanda

A sustainable management of national park requires collaboration between park staff, NGOs, local organizations and stakeholders, and government intervention. This collaboration promotes community-based welfare and inspires a sense of responsibility, thus promoting more benefits than conflicts. A survey administered to residents surrounding Nyungwe National Park was used to evaluate the relationship between Nyungwe National Park management and local communities. The residents acknowledged a positive attitude towards participating in conservation organizations where there was involvement, while a negative response revealed weak community mobilization. The community’s opinions about protection and tourism progression noted weak conflict resolution, but a positive attitude towards tourism activities in the area since they believed employment was likely as a result. In addition, the residents asked for support from government investments and stakeholders to develop the local private sector, and asked to be involved during the planning process. Approaches including the design of coordination mechanisms and integrated conservation and developments projects are suggested to promote a management structure leading to community involvement in conservation and tourism activities. This will increase visitor numbers and contribute to economic development not only in the region but also in the whole country. Empirical studies along with the factors shaping tourism and conservation activities should be considered as the basis for sustainable decision and policy making for sustainable management, and will contribute to government, stakeholders and park manager collaborations at Nyungwe national park.

Three-dimensional stability calculation method for high and large composite slopes formed by mining stope and inner dump in adjacent open pits

The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope engineering.Using the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding mass.By integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is proposed.Subsequently,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is examined.The analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear failure.The spatial form equation of the sliding mass comprises an ellipsoid and weak plane equation.The analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite slopes.Furthermore,the3D stability coefficient of the composite slope exhibits an exponential correlation with the coordinated development distance,with the coefficient gradually decreasing as the coordinated development distance increases.These findings provide a theoretical guideline for designing similar slope shape parameters and conducting stability analysis.

Determination of the workspace of a new coordinate-measuring machine using parallel-link mechanism

Presents the detailed algorithm established for determination of workspace for a 3-DOF coordinate measuring machine using parallel link mechanism by constructing the inverse kinematic model first and then reviewing the physical and kinematical constraints from the structural characteristics of the parallel link mechanism, and discusses the actual geometries of workspace and the factors having effect on workspace through computer simulation thereby providing necessary theoretical basis for the research and development of coordinate measuring machines using parallel link mechanism.

Coordination mechanism of developing unification of urban agglomeration: A case study of south Sichuan urban agglomerations

With the expansion of the urbanization, the urban agglomeration is forming in the region and showing a unification trend. The development of urban agglomeration and its unification depends on the coordination of the division of labor. It is significant to the further development of urban agglomeration that the coordination mechanism was constructed. Taking the south Sichuan urban agglomerations(SSUA) as an example, the research analyzes the current situation and problems of cities' unification, studies the industrial distribution layout and designs the framework of the regionally coordinated development. Then the author constructs the coordination mechanism of urban agglomeration development and presents strategies for the coordinated development of urban agglomeration and its unification.

G20 AND EVOLUTION OF THE GLOBAL ENERGY GOVERNANCE SYSTEM

Global energy governance refers to actions taken by countries and relevant stakeholders around the world to coordinate and solve cross-border energy issues.Energy issues matter to security and development.However,the current global energy governance system is still decentralized and fragmentary,and lacks a widely representative,coordinated and effective energy governance mechanism.

The coordination of regional interest in developing river basin

River basin is a special region with the characteristics of entireO, and relation, regionality and dlversity, gradation and network, openness and dissipation etc. It is an important unit that organizes and governs national economy as well as a natural re, on. In river basin, all natural essential factors relate closely each other, and there is remarkable influence between inter-regions. In the process of developing river basin, the multiplex main interest body, the diverse interest demand and the multi-ways of interest realization constitute a complicated interest network, and result in various contradictions and conflicts. Therefore, egective regional interest coordination mechanism should be estabfished to coordinate various regional interest relations. They are the public interest realization mechanism, the fair interest assignment mechanism, the effective interest integration mechanism, the expedited interest expression mechanism and the reasonable interest compensative mechanism.

MECHANISM FOR THE INITIATION OF ACRYLONITRILE POLYMERIZATION BY POLYPROPYLENE-BASED POLYAMIDOXIME-THIOUREA COMBINATION

Polymerization of acrylonitrile (AN) in aqueous nitric acid initiated by polypropylene-based polyamidoxime (PPAO)-thiourea (TU) combination has been investigated. The overall rate of polymerization (R_p) under the conditions of [TU]/[PPAO]<0.5 molar ratio isThe molecular weights of the polymers were found to be inversely proportional to 3/2-power of nitric acid concentration and 1-power of thiourea concentration. In addition, it is independent with the concentrations of monomer and PPAO, and decreases with increasing temperature.On the basis of these experimental results, a coordination-proton transfer mechanism for the initiation was proposed and discussed.