Cathodoluminescence and Trace Element Composition of Scheelite from the Middle-Lower Yangtze River Metallogenic Belt(MLYB): Implications for Mineralization and Exploration

The Middle-Lower Yangtze River Metallogenic Belt(MLYB)is known to contain abundant copper and iron porphyry-skarn deposits,with an increasing number of tungsten deposits and scheelite in Fe-Cu deposits being discovered in the MLYB during recent decades.The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood.We investigate four sets of scheelite samples from tungsten,iron and copper deposits,using CL imaging and LA-ICP-MS techniques to reveal internal zonation patterns and trace element compositions.The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies.The oxygen fugacity of ore-forming fluid increased in Donggushan,while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan,Guilinzheng and Gaojiabang.The scheelites from the Donggushan,Ruanjiawan,Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE,with Nb/La ratios ranging from 1.217 to 52.455,indicating that the four tungsten deposits are enriched in the volatile fluorine.A plot of(La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type,porphyry and skarn tungsten deposits.This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.

Tectonodynamic Adjustment of Crustal Materials in the Middle-Lower Reaches of the Yangtze River

Under the tectonodynamic process, crustal materials tend to experience two modes of adjustment: (1) structural (physical) adjustment, manifested by folding, faulting, uplifting, downwarping, etc.: (2) compositional adjustment, represented by element migration, concentration and dispersion, crystalline and dynamic differentiation of crystals, metamorphism, etc. (Yang Kaiqing. 1986; Yang Kaiqing et al., 1986). The dynamic adjustment of crustal materials in the middle-lower reaches of the Yangtze mainly occurred in the Mesozoic under the conditions of intense collision between the North China (Dabie) massif and the Yangtze massif. The structural adjustment refers to various types of deformation within the two massifs and the intensive shortening of the stratigraphic coyer of the Yangtze massif, whereas the compositional adjustment implies the structural remelting of the basement and the ore. and rock- forming processes in the two massifs.

In Situ Analyses of Trace Elements, U–Pb and Lu–Hf Isotopes in Zircons from the Tongshankou Granodiorite Porphyry in Southeast Hubei Province, Middle-Lower Yangtze River Metallogenic Belt, China

The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.

Basement Characteristics and Crustal Evolution of the Copper-Gold Metallogenic Belt in the Middle and Lower Reaches of the Yangtze River:Some Isotope Constraints

Studies of the Pb, Sr and Nd isotopic composition of Mesozoic intrusive rocks indicate that the basement of the copper-gold metallogenic belt of the middle and lower reaches of the Yangtze River has “two-layer structure” and partly has “multi-layered structure”, and is inhomogeneous and shows the distinct feature of E-W provincialism. The calculated model lead ages (t1) are mostly greater than 2600 Ma, and the model neodymium ages (TDM) vary from 953 to 2276 Ma and concentrate in two time intervals: 1800–2000 Ma and 1200–1600 Ma. It is concluded that the basement of the MBYR is composed of the Late Archaeozoic to Middle Proterozoic metamorphic series and that the crust was initiated in the Archaean and continued to grow in the Early and Middle Proterozoic, and the proportion of new crust formed by mantle differentiation during the Late Proterozoic is low.

Three-dimensional P-wave Velocity Structure Modelling of the Middle and Lower Reaches of the Yangtze River Metallogenic Belt: Crustal Architecture and Metallogenic Implications

In this study,we compiled and analyzed 69310 P-wave travel-time data from 6639 earthquake events.These events(M≥2.0)occurred from 1980 s to June 2019 and were recorded at 319 seismic stations(Chinese Earthquake Networks Center)in the study area.We adopted the double-difference seismic tomographic method(tomo DD)to invert the 3-D P-wave velocity structure and constrain the crust-upper mantle architecture of the Middle and Lower Reaches of the Yangtze River Metallogenic Belt(MLYB).A 1-D initial model extracted from wide-angle seismic profiles was used in the seismic tomography,which greatly reduced the inversion residual.Our results indicate that reliable velocity structure of th e uppermost mantle can be obtained when Pn is involved in the tomography.Our results show that:(1)the pattern of the uppermost mantle velocity structure corresponds well with the geological partitioning:a nearly E-W-trending low-velocity zone is present beneath the Dabie Orogen,in contrast to the mainly NE-trending low-velocity anomalies beneath the Jiangnan Orogen.They suggest the presence of thickened lower crust beneath the orogens in the study area.In contrast,the Yangtze and Cathaysia blocks are characterized by relatively high-velocity anomalies;(2)both the ultra-high-pressure(UHP)metamorphic rocks in the Dabie Orogen and the low-pressure metamorphic rocks in the Zhangbaling dome are characterized by high-velocity anomalies.The upper crust in the Dabie Orogen is characterized by a low-velocity belt,sandwiched between two high velocity zones in a horizontal direction,with discontinuous low-velocity layers in the middle crust.The keel of the Dabie Orogen is mainly preserved beneath its northern section.We infer that the lower crustal delamination may have mainly occurred in the southern Dabie Orogen,which caused the mantle upwelling responsible for the formation of the granitic magmas emplaced in the middle crust as the low-velocity layers observed there.Continuous deep-level compression likely squeezed the granitic magma upward to intrude the upper crustal UHP metamorphic rocks,forming the'sandwich'velocity structure there;(3)high-velocity updoming is widespread in the crust-mantle transition zone beneath the MLYB.From the Anqing-Guichi ore field northeastward to the Luzong,Tongling,Ningwu and Ningzhen orefields,high-velocity anomalies in the crust-mantle transition zone increase rapidly in size and are widely distributed.The updoming also exists in the crust-mantle transition zone beneath the Jiurui and Edongnan orefields,but the high-velocity anomalies are mainly stellate distributed.The updoming high-velocity zone beneath the MLYB generally extends from the crust-mantle transition zone to the middle crust,different from the velocity structure in the upper crust.The upper crust beneath the Early Cretaceous extension-related Luzong and Ningwu volcanic basins is characterized by high velocity zones,in contrast to the low velocity anomalies beneath the Late Jurassic to Early Cretaceous compression-related Tongling ore field.The MLYB may have undergone a compressive-to-extensional transition during the Yanshanian(Jurassic-Cretaceous)period,during which extensive magmatism occurred.The near mantle-crustal boundary updoming was likely caused by asthenospheric underplating at the base of the lower crust.The magmas may have ascended through major crustal faults,undergoing AFC(assimilation and fractional crystallization)processes,became emplaced in the fault-bounded basins or Paleozoic sequences,eventually forming the many Cu-Fe polymetallic deposits there.

Molybdenite Re-Os,titanite and garnet U-Pb dating of the Magushan skarn Cu-Mo deposit,Xuancheng district,Middle-Lower Yangtze River Metallogenic Belt

The Magushan skarn Cu-Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle-Lower Yangtze River Metallogenic Belt of eastern China.The precise age of an ore deposit is important for understanding the timing of mineralization relative to other geological events in a region and to fully place the formation of a mineral deposit within the geological context of other processes that occur within the study area.Here,we present new molybdenite Re-Os and titanite and andradite garnet U-Pb ages for the Magushan deposit and use these data to outline possible approaches for identifying genetic relationships in geologically complex areas.The spatial and paragenetic relationships between the intrusions,alteration,and mineralization within the study area indicates that the formation of the Magushan deposit is genetically associated with the porphyritic granodiorite.However,this is not always the case,as some areas contain complexly zoned plutons with multiple phases of intrusion or mineralization may be distal from or may not have any clear spatial relationship to a pluton.This means that it may not be possible to determine whether the mineralization formed as a result of single or multiple magmatic/hydrothermal events.As such,the approaches presented in this study provide an approach that allows the identification of any geochronological relationships between mineralization and intrusive events in areas more complex than the study area.Previously published zircon U-Pb data for the mineralization-related porphyritic granodiorite in this area yielded an age of 134.2±1.2 Ma(MSWD=1.4)whereas the Re-Os dating of molybdenite from the study area yielded an isochron age of 137.7±2.5 Ma(MSWD=0.43).The timing of the mineralizing event in the study area was further examined by the dating of magmatic accessory titanite and skarn-related andradite garnet,yielding U-Pb ages of 136.3±2.5 Ma(MSWD=3.2)and 135.9±2.7 Ma(MSWD=2.5),respectively.The dating of magmatic and hydrothermal activity within the Magushan area yields ages around 136 Ma,strongly suggesting that the mineralization in this area formed as a result of the emplacement of the intrusion.The dates presented in this study also provide the first indication of the timing of mineralization within the Xuancheng district.providing evidence of a close genetic relationship between the formation of the mineralization within the Xuancheng district and the Early Cretaceous magmatism that occurred in this area.This in turn suggests that other Early Cretaceous intrusive rocks within this region are likely to be associated with mineralization and should be considered highly prospective for future mineral exploration.This study also indicates that the dating of garnet and titanite can also provide reliable geochronological data and evidence of the timing of mineralization and magmatism,respectively,in areas lacking other dateable minerals(e.g.,molybdenite)or where the relationship between mineralization and magmatism is unclear,for example in areas with multiple stages of magmatism,with complexly zoned plutons,and with distal skarn mineralization.

Flood and Waterlogging Disaster Damage Evaluation in Middle-Lower Yangtze River by 3S technology

The evaluation method, model and process for the flood and waterlogging disaster condition by GIS,RS and GPS technology and the method for setting up disaster condition database, dyke database and historical disaster damage database are presented. An index of flood damage degree(FDD) used to evaluate the relative degree of disaster loss and divide flood and waterlogging area is suggested. The value of flood damage degree can be calculated as follows :taking the various disaster losses of sample area in a base year as standard value and computing the ratios of various disaster loss values in different areas and years to the standard flood disaster loss values, then summing up the weighted ratios. The computed results are the value of flood damage degree in the every year. The macroscopic flood disaster distribution can be evaluated by the values of flood loss degree.

A 3D Investigation of Geological Structure and Its Relationship to Mineralization in the Nanling-Xuancheng Ore District,Middle-Lower Yangtze River Metallogenic Belt,China

The Nanling-Xuancheng ore region of Anhui Province is located in the Middle-Lower Yangtze River metallogenic belt.Insufficient exploration and research have been carried out in this newly defined ore district,although the Chating large porphyry Cu-Au deposit and a few middle-sized skarntype Cu polymetallic deposits have been discovered.In this study,we carried out high-resolution seismic reflection,magnetotelluric,gravity,and magnetic investigations,and constructed the 3 D geological structure of the uppermost crust in a depth range of 0-5 km using a comprehensive inversion of the new data constrained by previous deep-drilling data.We hence proposed some new insights to understand the mineralization processes of this district.A system of alternating ridges and valleys is suggested as the major structure pattern,composed of“two-layer structure”of the basins and“three-layer structure”of anticlines.Moreover,a conjugated fault system and its distribution features are revealed in our models,including the Jiangnan fault,Zhouwang fault,and Kunshan thrust nappe.The Jiangnan and Kunshan faults are suggested to have controlled the diagenesis and metallogenesis.Two deep concealed plutons located in Chating and Magushan are found,forming the Mesozoic diorite-felsic intrusions.These intrusions are believed to be the causes of hydrothermal deposits such as the Chating deposit and the Magushan deposit.

Observational and Modeling Studies of Impacts of the South China Sea Monsoon on the Monsoon Rainfall in the Middle-Lower Reaches of the Yangtze River During Summer

Based on the ERA-40 and NCEP/NCAR reanalysis data,the NOAA Climate Prediction Center＇s merged analysis of precipitation（CMAP）,and the fifth-generation PSU/NCAR Mesoscale Model version 3（MM5v3）,we defined a monsoon intensity index over the East Asian tropical region and analyzed the impacts of summer（June-July） South China Sea（SCS） monsoon anomaly on monsoon precipitation over the middle-lower reaches of the Yangtze River（MLRYR） using both observational data analysis and numerical simulation methods.The results from the data analysis show that the interannual variations of the tropical monsoon over the SCS are negatively correlated with the southwesterly winds and precipitation over the MLRYR during June-July.Corresponding to stronger（weaker） tropical monsoon and precipitation,the southwesterly winds are weaker（stronger） over the MLRYR,with less（more） local precipitation.The simulation results further exhibit that when changing the SCS monsoon intensity,there are significant variations of monsoon and precipitation over the MLRYR.The simulated anomalies generally consist with the observations,which verifies the impact of the tropical monsoon on the monsoon precipitation over the MLRYR.This impact might be supported by certain physical processes.Moreover,when the tropical summer monsoon is stronger,the tropical anomalous westerly winds and positive precipitation anomalies usually maintain in the tropics and do not move northward into the MLRYR,hence the transport of water vapor toward southern China is weakened and the southwest flow and precipitation over southern China are also attenuated.On the other hand,the strengthened tropical monsoon may result in the weakening and southward shift of the western Pacific subtropical high through self-adjustment of the atmospheric circulation,leading to the weakening of the monsoon flows and precipitation over the MLRYR.

长江中下游斑岩-矽卡岩铜多金属矿床共伴生碲、硒资源现状和成矿规律浅析

斑岩-矽卡岩铜多金属矿床常伴生大量的碲、硒资源,提供了全球目前几乎所有的碲、硒产量,但碲、硒在这些矿床中的成矿规律还不清楚。长江中下游成矿带多处铜多金属矿床都伴生有硒和/或碲资源,但其资源现状、赋存状态和成矿规律的研究还较为薄弱。本文基于已有的研究资料,对长江中下游伴生碲、硒资源量进行了估算,对碲、硒的赋存状态和分布规律以及成矿规律进行了探讨。目前长江中下游已探明的伴生碲、硒资源量分别为9061 t和10574 t,相当于18个大型碲矿床、21个大型硒矿床,这些矿产资源已部分回收利用。其中九瑞矿集区的资源量最大。碲、硒主要以独立矿物形式存在,发育4种产状碲的独立矿物和2种产状硒的独立矿物,它们均形成于硫化物阶段,后者主要形成于晚硫化物阶段。根据资源量相对规模,该成矿带上的矿床类型可分为硒矿床、碲硒和硒碲矿床三种。以岩体为中心向外,碲、硒含量由低到高依次为斑岩型矿体、矽卡岩型矿体和层间交代型矿体。本文初步揭示了长江中下游成矿带碲、硒矿化的成矿规律,可为资源评价和找矿勘查提供科学依据。今后应加强对斑岩-矽卡岩铜金成矿系统中碲、硒富集机制的研究。

长江经济带矿产——经济——生态环境系统耦合协调发展研究

为贯彻落实“共抓大保护,不搞大开发”的建设思想理念,实现长江经济带绿色可持续发展,基于2001—2019年长江经济带11省市的相关数据,构建了矿产资源—区域经济—生态环境评价体系。通过设定三大子系统的优先发展级,运用熵权法、耦合协调度模型定量分析不同优先级下的矿产资源—区域经济—生态环境系统耦合协调发展水平,并从中选取最优发展模式。结果表明:长江经济带三系统耦合协调发展特征显著,整体上由轻度失调区间上升至中级协调区间,且耦合协调度值上游<中游<下游。分省来看,耦合协调程度由低到高依次为云南、江西、贵州、安徽、湖南、上海、重庆、江苏、四川、浙江、湖北。除了湖北、浙江、四川三省位于良好协调区间外,其余8省市均位于中级协调区间。同时,“经济优先”仅适用于短期发展,“环境优先”更适合长期发展。故为促进长江经济带协调可持续发展,整体上应坚持以环境保护为重心的发展战略,个体上要进一步针对不同省市采取差异化的措施。

基于GNSS的长江下游带状区域高程拟合方法研究——二次多项式与BP神经网络的对比分析

该文旨在研究沿长江大范围带状区域中,GNSS点高程拟合方法的问题,列举二次多项式、BP神经网络拟合2种高程拟合方法,对2种拟合方法在长江下游同一个大范围带状区域的高程拟合结果进行对比分析。结果表明,针对该文大范围带状区域,在均匀布设的GNSS点位下,2种拟合方式计算结果误差基本一致,且BP神经网络拟合进行高程拟合获得较高的内外符合精度,方法具有较好的可塑性和更强的泛化能力。该文研究成果可为相关领域提供参考。

“流域-人-歌”三重互联:对长江中下游流域民歌的考察

基于对长江中下游民歌的沿江调查及研究,从“流域-人-歌”三者关系出发,可以发现作为自然区域、作为文化“通道”和“界限”以及作为经济带三种视域下,流域-人-歌三者之间存在互联。随着现代社会经济的发展,传统民歌的存承方式也在发生改变。在国家大力建设长江经济带背景下,应立足于新兴的流域(水域)音乐文化研究,加强对长江流域民歌文化带的保护,进而打造良好的长江经济带文化生态。

High-resolution 3D crustal S-wave velocity structure of the MiddleLower Yangtze River Metallogenic Belt and implications for its deep geodynamic setting

The Middle-Lower Yangtze River Metallogenic Belt(MLYMB) is an important mineral resource region in China.High-resolution crustal models can provide crucial constraints to understand the ore-forming processes and geodynamic setting in this region. Using ambient seismic noise from 107 permanent and 82 portable stations in the MLYMB and the adjacent area,we present a new high-resolution 3D S-wave velocity model of this region. We first extract 5–50 s Rayleigh wave phase velocity dispersion data by calculating ambient noise cross-correlation functions(CFs) and then use the surface wave direct inversion method to invert the mixed path travel times for the 3D S-wave velocity structure. Checkerboard tests show that the horizontal resolution of the 3D S-wave velocity model is approximately 0.5°–1.0° and that the vertical resolution decreases with increasing noise and depth. Our high-resolution 3D S-wave velocity model reveals:(1) AV-shaped high-velocity zone(HVZ) is located in the lower crust and the uppermost mantle in the study region. The western branch of the HVZ passes through the Jianghan Basin,the Qinling-Dabie orogenic belt and the Nanxiang Basin. The eastern branch, which almost completely covers the main body of the MLYMB, is located near the Tanlu Fault. The low-velocity anomalies between the western and eastern branches are located in the area of the Qinling-Dabie orogenic belt.(2) High-velocity uplifts(HVUs) are common in the crust of the MLYMB,especially in the areas near the Tanlu Fault, the Changjiang Fault and the Yangxin-Changzhou Fault. The intensities of the HVUs gradually weaken from west to east. The V-shaped HVZ in the lower crust and uppermost mantle and the HVUs in the middle and lower crust likely represent cooled mantle intrusive rocks. During the Yanshanian period, fault systems formed in the MLYMB due to the convergence between the South China Plate and the North China Plate, the multiple-direction drifting of the PaleoPacific Plate and its subduction beneath the Eurasian Plate. The dehydration of the cold oceanic crust led to partial melting in the upper mantle. Temperature differences caused strong convection of the upper mantle material that underplated the lower crust and rose to near the surface along the deep fault systems. After mixing with the crustal materials, mineralization processes, such as assimilation and fractional crystallization, occurred in the MLYMB.

Mineral Deposit Model of Cu-Fe-Au Skarn System in the Edongnan Region, Eastern China

Cu and Fe skarns are the world's most abundant and largest skarn type deposits,especially in China,and Au-rich skarn deposits have received much attention in the past two decades and yet there are few papers focused on schematic mineral deposit models of Cu-Fe-Au skarn systems.Three types of Au-rich deposits are recognized in the Edongnan region,Middle-Lower Yangtze River metallogenic belt:~140 Ma Cu-Au and Au-Cu skarn deposits and distal Au-Tl deposits.137-148 Ma Cu-Fe and 130-133 Ma Fe skarn deposits are recognized in the Edongnan region.The Cu-Fe skarn deposits have a greater contribution of mantle components than the Fe skarn deposits,and the hydrothermal fluids responsible for formation of the Fe skarn deposits involved a greater contribution from evaporitic sedimentary rocks compared to Cu-Fe skarn deposits.The carbonate-hosted Au-Tl deposits in the Edongnan region are interpreted as distal products of Cu-Au skarn mineralization.A new schematic mineral deposit model of the Cu-Fe-Au skarn system is proposed to illustrate the relationship between the Cu-Fe-Au skarn mineralization,the evaporitic sedimentary rocks,and distal Au-Tl deposits.This model has important implications for the exploration for carbonate-hosted Au-Tl deposits in the more distal parts of Cu-Au skarn systems,and Fe skarn deposits with the occurrence of gypsum-bearing host sedimentary rocks in the MLYRB,and possibly elsewhere.

皖江城市带饮用天然矿泉水资源开发利用现状与对策建议

基于实际地质调查资料,对照现行饮用天然矿泉水国家标准,对皖江城市带已勘查评价的饮用天然矿泉水资源及开发利用现状进行复核统计。结合矿泉水的资源禀赋、经济社会发展及生态环境保护需求,分析矿泉水开发利用中存在的主要问题并提出对策建议。皖江城市带现存矿泉水井(泉)允许开采量为17540.45 m^(3)/d,实际开采量为1306.39 m^(3)/d,仅占现存井(泉)允许开采量的7.45%。矿泉水开发利用中除了存在资源闲置和资源不足并存、优质低用、保护不力等问题外,还普遍忽视了矿泉水化学成分来源和作用机制认识不深入、资源可持续利用条件不清楚、资源储量评价方法不合理等制约因素。今后矿泉水勘查评价时,应高度重视水化学和环境同位素综合分析,深入研究水-岩作用和资源可持续利用条件,根据水文地质条件正确选择资源储量评价方法,为其开发利用提供坚实基础。同时,应科学规划矿泉水勘查开发布局,重点开展天长地区碳酸偏硅酸锶型矿泉水和大别山区矿泉水的勘查开发,助力产业结构调整和乡村振兴。

江西九瑞矿集区武山铜矿床硒碲钴等关键金属的分布规律、赋存状态和富集机制

武山铜矿床是长江中下游成矿带九瑞矿集区内典型的层控-接触带矽卡岩型铜多金属矿床,铜资源量达到大型,此外还共生硒、碲、钴、镓、铊等关键金属矿产,具备良好的矿产资源综合利用前景,但矿床中关键金属的分布规律、赋存状态和富集机制等研究尚未开展。本文以武山铜矿床为研究对象,系统采集了矿床南矿带接触带矽卡岩型矿体3条勘探线(W3-2、S4-2、N6-1)、北矿带层控硫化物型矿体3条勘探线(E9-2、E2-1、W4-1)和层控矽卡岩型矿体1条勘探线(E7-3)代表性岩矿石样品。通过光学显微镜和扫描电镜的观察,结合全岩地球化学和矿物原位LA-ICP-MS分析,查明了矿床中硒、碲、钴等关键金属的空间分布规律与赋存状态,初步探讨了硒、碲、钴的迁移沉淀机制。研究结果表明矿床中伴生硒、碲、钴的估算资源量分别为5513t、611t和9597t,均达到大-中型规模;武山矿床是成矿带内硒含量最高、潜在资源量最大的矿床。北矿带矿体中Se、Te、Co含量明显高于南矿带,北矿带中部成矿中心向东西远端,矿体中Se、Te、Co含量规律性增高。矿石中Se、Te、Co含量与S含量具有较强的正相关性,矿石中硫化物的含量是关键金属含量主要控制指标;Se和Co富集于含铜黄铁矿矿石、含铜白云岩矿石、含铜矽卡岩矿石(高硫)中;Te富集于含铜黄铁矿矿石和含铜白云岩矿石中。矿床中硒、碲主要以独立矿物和硫化物中类质同象替换两种赋存形式,钴则主要以Co^(2+)类质同象形式进入黄铁矿矿物晶格。矿床中硒、碲随着成矿流体温度降低、硫逸度升高、氧逸度降低、pH值升高逐渐沉淀富集;钴主要随着硫化物的沉淀富集在黄铁矿中。

基于GWR的矿产资源开采时空特征及影响因素探究

文章基于2011—2017年矿产资源开采数据,分析长江经济带矿产资源开采时空演变特征,并利用地理加权回归(geographically weighted regression,GWR)模型探究矿产资源开采的影响因素及其作用程度。研究结果表明:2011年以来长江经济带矿产资源开采数量呈增长趋势,且开采以非金属矿产为主;长江经济带矿产资源开采空间差异逐渐增大,主要集聚区分布在上、中游地区,形成以贵州和江西为主要密度核心的连绵状空间分布;研究期内矿产资源开采活动主要在上、中游地区开展,开采重心位于贵州;矿产资源开采受到海拔高度、路网密度、地区生产总值等因素的影响显著,其效应具有明显空间异质性。研究结果可为矿产资源管理与利用提供参考。

长江中下游转换构造结与区域成矿背景分析

中国东部中生代以来的地壳运动频繁,构造演化复杂,岩浆活动剧烈,成矿作用多样,是不同体制构造转换的重要地区。长江中下游地区是中生代特提斯构造体制与太平洋构造体制转换的经典地区,是两大构造体制交汇和转换的焦点部位,具有岩石圈物质重组、结构重建的时-空演化关系。长江中下游转换构造结由是中国东部中生代特提斯构造体制与太平洋构造体制转换的产物,大别造山带、郯庐断裂带和长江中下游成矿带直接记录了两大构造体制转换的过程、沉积-构造-岩浆-成矿的时空关系和动力学背景。长江中下游转换构造结内构造叠加强烈,规律明显,以长江复合构造带和铜陵-杭州构造带为代表的NE-SW向构造带和NW-SE向构造带,严格控制着区内燕山期岩浆活动和长江中下游成矿带的展布;长江中下游转换构造结内具有结点成矿的规律,不同规模的NE-SW向构造带与NW-SE向构造带的交切处正是区内矿集区和重要矿床的分布位置。

论长江中下游成矿动力学

长江中下游是我国东中部著名的中生代金属成矿带,更是长江工业走廊的矿物供应基地,素称工业摇篮。从地质演化和成矿动力学角度,长江中下游成矿带在我国、甚至世界上具有鲜明的特色。首先,成矿大地构造背景和过程经历了由板缘到板内的环境,成矿作用发生在挤压向伸展的转换过程;其次,成岩成矿受基底构造和深部作用控制、与特有的基底有关;最后,长江中下游成矿作用贯穿于"燕山运动"的始终,深刻地记录了太平洋板块作用的影响。本文对上述重大问题提出粗浅的见解,供讨论。