A particular non-stromatolitic carbonate succession making up the third member of the Mesoproterozoic Gaoyuzhuang (高于庄) Formation might demonstrate that a stromatolite decline of the Mesoproterozoic occurring at ...A particular non-stromatolitic carbonate succession making up the third member of the Mesoproterozoic Gaoyuzhuang (高于庄) Formation might demonstrate that a stromatolite decline of the Mesoproterozoic occurring at ca. 1 450 Ma besides other three events of the Proterozoic, respectively, occurred at ca. 2 000 Ma, ca. 1 000 Ma, and ca. 675 Ma. The forming duration of this non-stromatolitic carbonate succession can be generally correlative to that of a similar depositional succession in North America, i.e. a non-stromatolitic carbonate succession made up by the Helena Formation of the Belt Supergroup, which suggests that the stromatolite decline occurring at ca. 1 450 Ma may be a global event. This information endows the non-stromatolitic carbonate succession making up the third member of the Gaoyuzhuang Formation in the Yanshan (燕山) area with important significance for the further understanding of Precambrian sedimentology. The Mesoproterozoic Gaoyuzhuang Formation in Yanshan area is a set of more than 1 000 m thick carbonate strata that can be divided into four members (or subformations). The first member (or the Guandi (官地) subformation) is marked by a set of stromatolitic dolomites overlying a set of transgressive sandstones; the second member (or the Sangshu'an (桑树鞍) subformation) is a set of manganese dolomites with a few stromatolites; the third member (or the Zhangjiayu (张家峪) subformation) is chiefly made up of leiolite and laminite limestones and is characterized by the development of molar-tooth structures in leiolite limestone; the fourth member (or the Huanxiusi (环秀寺) subformation) is composed of a set of dolomites of stromatolitic reefs or lithoherms. Sequence-stratigraphic divisions at two sections, i.e. the Jixian (蓟县) Section in Tianjin (天津) and the Qiangou (千沟) Section of Yanqing (延庆) County in Beijing (北京), demonstrate that a particularly non-stromatolitic succession making up the third member of the Mesoproterozoic Gaoyuzhuang Formation is developed in the Yanshan area of North China, in which lots of grotesque matground structures (wrinkle structures and palimpsest ripples) are developed in beds of leiolite limestone at the Qiangou Section and lots,of molar-tooth structures are developed in beds of leiolite limestone at the Jixian Section. The time scale of the Gaoyuzhuang Formation is deduced as 200 Ma (from 1 600 Ma to 1 400 Ma). The duration of an obvious hiatus between the Gaoyuzhuang Formation and the underlying Dahongyu (大红) Formation is deduced as 50 Ma to 100 Ma, thus the forming duration of the Gaoyuzhuang Formation is thought as 100 Ma (1 500 Ma to 1 400 Ma). Furthermore, the age of the subface of the third member of the Gaoyuzhuang Formation that is just in the mid position of the Gaoyuzhuang Formation can be deduced as about 1 450 Ma, which is the basis to infer a stromatolite decline of the Mesoproterozoic occurring at ca. 1 450 Ma. Importantly, several features of both the molar-tooth structure and the stromatolite, such as the particular forming environment, the important facies-indicative meaning, and the episodic distribution in the earth history, might express the evolutionary periodicity of the surface environment of the earth and can provide meaningful clues for the understanding of the Precambrian world, although their origin and forming mechanism is highly contentious. Therefore, like other three stromatolitic declines, respectively, occurring at ca. 675 Ma, ca. 1 000 Ma, and ca. 2 000 Ma, the identification of the stromatolite decline occurring at ca. 1 450 Ma during the Golden Age of stromatolites (2 800 Ma to 1 000 Ma) has important meaning for the further understanding of the evolving carbonate world of the Precambrian.展开更多
In the long Precambrian period, stromatolitic carbonate successions were very common. However, the non-stromatolitic carbonate succession that is marked by subtidal deposits shows a sharp contrast to the stromatolitic...In the long Precambrian period, stromatolitic carbonate successions were very common. However, the non-stromatolitic carbonate succession that is marked by subtidal deposits shows a sharp contrast to the stromatolitic carbonate succession. Both the non-stromatolitic and the stromatolitic carbonate successions are important clues for the further understanding of the evolving carbonate world of the Precambrian. The Mesoproterozoic Gaoyuzhuang Formation at the Qiangou section in northwestern suburb of Beijing is a set of more than 1000 m-thick carbonate strata that can be divided into four members (or subformations), in which a non-stromatolitic carbonate succession marked by the scarcity of stromatolites makes up the third member of the formation. This non-stromatolitic carbonate succession can further be subdivided into three third-order sequences that are marked by the regular succession of sedimentary facies. In third-order sequences, a lot of subtidal carbonate meter-scale cycles made up of medium-bedded leiolite limestones and thin-bedded marls constitute their transgressive system tracts (TSTs) and the early high-stand system tracts (EHSTs), a lot of meter- scale cycles made up by thin-bedded limestones and marls constitute their condensed sections (CSs), and thick-bedded to massive dolomitic limestones or lime dolomites make up the late high-stand system tracts (LHSTs). The particularly non-stromatolitic carbonate succession making up the third member of the Mesoproterozoic Gaoyuzhuang Formation at the Qiangou section might be the representative of the non-stromatolitic carbonate succession of the Precambrian because of its special lithological features and particular sedimentary structures, and its general sedimentary features are helpful and meaningful for the further understanding of the evolution rules of the sophisticate and evolving carbonate world of the Precambrian. The time scale of the Gaoyuzhuang Formation is deduced as that from 1600 Ma to 1400 Ma; thus, the non-stromatolitic sedimentary succession making up the third member of the Gaoyuzhuang Formation may demonstrate a stromatolite decline event occurring at ca. 1450 Ma of the Proterozoic besides other three events that occurred respectively at ca. 2000 Ma, ca. 1000 Ma and ca. 675 Ma. The forming duration of this non-stromatolitic sedimentary succession of the third member of the Gaoyuzhuang Formation can be generally correlated with a similar sedimentary succession in North America, i.e. a non-stromatolitic sedimentary succession of the Helena Formation of the Belt Supergroup, which suggests that the stromatolite decline occurring at ca. 1450 Ma might be a global event. Therefore, the non-stromatolitic sedimentary succession discussed in the paper provides an important example for further understanding of carbonate sedimentology in the Precambrian.展开更多
Geothermometer is one of the most useful methods to reconstruct the thermal history of sedimentary basins. This paper introduces the application of free radicals concentration of organic matter as a thermal indicator ...Geothermometer is one of the most useful methods to reconstruct the thermal history of sedimentary basins. This paper introduces the application of free radicals concentration of organic matter as a thermal indicator in the thermal history reconstruction of carbonate succession, based on anhydrous thermal simulation results of type I and H1 kerogen. A series of free radicals data are obtained under thermal simulation of different heating temperatures and times, and quantitative modds between free radical concentration (Ng) of organic matter and time-temperature index (TTI) for types I and type H1 kerogen are also obtained. This Ng.TTI relation was used to model the Ordovician thermal gradients of Well TZ12 in the Tarim Basin. The modeling result is corresponding to the results obtained by apatite fission track data and published data. This new method of thermal history reconstruction will be benefit to the hydrocarbon generation and accumulation study and resource assessment of carbonate succession.展开更多
Wetland is an important carbon pool,and the degradation of wetlands causes the loss of organic carbon and total nitrogen.This study aims to explore how wetland degradation succession affects soil organic carbon(SOC)an...Wetland is an important carbon pool,and the degradation of wetlands causes the loss of organic carbon and total nitrogen.This study aims to explore how wetland degradation succession affects soil organic carbon(SOC)and total nitrogen(TN)contents in alpine wetland.A field survey of 180 soilsampling profiles was conducted in an alpine wetland that has been classified into three degradation succession stages.The SOC and TN contents of soil layers from 0 to 200 cm depth were studied,including their distribution characteristics and the relationship between microtopography.The results showed that SOC and TN of different degradation succession gradients followed the ranked order of Non Degradation(ND)>Light Degradation(LD)>Heavy Degradation(HD).SWC was positively correlated with SOC and TN(p<0.05).As the degree of degradation succession worsened,SOC and TN became more sensitive to the SWC.Microtopography was closely related to the degree of wetland degradation succession,SWC,SOC and TN,especially in the topsoil(0-30 cm).This result showed that SWC was an important indicator of SOC/TN in alpine wetland.It is highly recommended to strengthen water injection into the wetland as a means of effective restoration to reverse alpine meadow back to marsh alpine wetland.展开更多
Background: Tropical forests play an important role in the global carbon(C) cycle.However, tropical montane forests have been studied less than tropical lowland forests, and their role in carbon storage is not well...Background: Tropical forests play an important role in the global carbon(C) cycle.However, tropical montane forests have been studied less than tropical lowland forests, and their role in carbon storage is not well understood.Montane forests are highly endangered due to logging, land-use and climate change.Our objective was to analyse how the carbon balance changes during forest succession.Methods: In this study, we used a method to estimate local carbon balances that combined forest inventory data with process-based forest models.We utilised such a forest model to study the carbon balance of a tropical montane forest in South Ecuador, comparing two topographical slope positions(ravines and lower slopes vs upper slopes and ridges).Results: The simulation results showed that the forest acts as a carbon sink with a maximum net ecosystem exchange(NEE) of 9.3 Mg C?(ha?yr)-1during its early successional stage(0–100 years).In the late successional stage, the simulated NEE fluctuated around zero and had a variation of 0.77 Mg C?(ha?yr)–1.The simulated variability of the NEE was within the range of the field data.We discovered several forest attributes(e.g., basal area or the relative amount of pioneer trees) that can serve as predictors for NEE for young forest stands(0–100 years) but not for those in the late successional stage(500–1,000 years).In case of young forest stands these correlations are high, especially between stand basal area and NEE.Conclusion: In this study, we used an Ecuadorian study site as an example of how to successfully link a forest model with forest inventory data, for estimating stem-diameter distributions, biomass and aboveground net primary productivity.To conclude, this study shows that process-based forest models can be used to investigate the carbon balance of tropical montane forests.With this model it is possible to find hidden relationships between forest attributes and forest carbon fluxes.These relationships promote a better understanding of the role of tropical montane forests in the context of global carbon cycle, which in future will become more relevant to a society under global change.展开更多
The Liaoyang Petrochemical Company has successfullydeveloped a novel ionic liquid catalyst for carbonylationof ethylene oxide with carbon dioxide to form ethylenecarbonate (EC). This catalyst can achieve an 100 % co...The Liaoyang Petrochemical Company has successfullydeveloped a novel ionic liquid catalyst for carbonylationof ethylene oxide with carbon dioxide to form ethylenecarbonate (EC). This catalyst can achieve an 100 % conversionand a 98% selectivity at low temperature andunder low pressure, featuring high catalytic activity, goodstability, good adaptability to feedstocks and low productioncost.展开更多
Revegetation is a traditional practice widely used for soil protection. We evaluated the effect of natural revegetation succession on soil chemical properties and carbon fractions (particulate organic carbon (POC),...Revegetation is a traditional practice widely used for soil protection. We evaluated the effect of natural revegetation succession on soil chemical properties and carbon fractions (particulate organic carbon (POC), humus carbon (HS-C), humic acid carbon (HA-C) and fulvic acid carbon (FA-C)) on the Loess Plateau of China. The vegetation types, in order from the shortest to the longest enclosure duration, were: (a) abandoned overgrazed grassland (AbG3; 3 years); (b) Hierochloe odorata Beauv. (HiO7; 7 years); (c) Thymus mongoficus Ronnm (ThM15; 15 years); (d) Artemisia sacrorum Ledeb (AtS25; 25 years); (e) Stipa bungeana Trin Ledeb (StB36; 36 years) and (f) Stipa grandis P. Smirn (StG56; 56 years). The results showed that the concentrations of soil organic carbon, total nitrogen and available phosphorus increased with the increase of restoration time except for ThM15. The concen- tration of NH4-N increased in the medium stage (for ThM15 and AtS25) and decreased in the later stage (for StB36 and StG56) of vegetation restoration. However, NO3-N concentration significantly increased in the later stage (for StB36 and StG56). Carbon fractions had a similar increasing trend during natural vegetation restoration. The con- centrations of POC, HS-C, FA-C and HA-C accounted for 24.5%-49.1%, 10.6%-15.2%, 5.8%-9.1% and 4.6%-6.1% of total carbon, respectively. For AbG3, the relative changes of POC, HS-C and FA-C were significantly higher than that of total carbon during the process of revegetation restoration. The higher relative increases in POC, HS-C and FA-C confirmed that soil carbon induced by vegetation restoration was sequestrated by higher physical and chemical protection. The increases of soil C fractions could also result in higher ecological function in semiarid grassland ecosystems.展开更多
The 23-year-old T. flousiana plantation and successive rotation plantation of C. lanceolata at Shankou Forest Farm of Nandan County, Guangxi were tested by the method of plot investigation combining with biomass m...The 23-year-old T. flousiana plantation and successive rotation plantation of C. lanceolata at Shankou Forest Farm of Nandan County, Guangxi were tested by the method of plot investigation combining with biomass measurement. Carbon storage and spatial distribution of different components in the two forests were analyzed. The results indicated that carbon content in different organs of T. flousiana ranged from 426.0 to 503.9 g/kg, and the order was bark 〉stem 〉 root 〉 branch 〉 leaf. The carbon contents in shrub, herb and litter layers were452.9 , 408.0 and 428.9 g/kg, respectively. Carbon content in the soil (0 -80 cm)was 16.59 g/kg. The carbon content in different organs of C. lanceolata ranged from 464.5 to 508.9 g/kg, and the order was bark 〉 stem 〉 branch 〉 root 〉 leaf. The carbon contents in shrub, herb and litter layers were 456.2, 416.3 and 468.1 g/kg, respectively. Carbon content in the soil (0 -80 cm)was 15.77 g/kg. Total carbon storage amounts of T. flousiana plantation and successive rotation plantation of C. lanceolata were 245.83 and 213.52 t/hm^2, respectively. The carbon storage order of different structure layers from T. flousiana plantation and successive rotation plantation of C. lanceolata was soil layer (0 -8 0 cm) 〉 vegetation layer 〉 litter layer. Annual net productivity in the arbor layers of T. flousiana plantation and successive rotation plantation of C. lanceolata plantations was 10.75 and 17.13 t/(hm^2 · a) ; annual net carbon fixation amounts were estimated as 5.05 and 3.47 t /(hm^2 · a) ; annual net absorption C02 amounts were 18.53 and 12.73 t/(hm^2 · a) respectively.展开更多
Since nearly 200 parties to the United Nations Framework Convention on Climate Change reached the Paris Agreement at the UN Climate Change Conference in Paris in 2015,the parties have successively established goals to...Since nearly 200 parties to the United Nations Framework Convention on Climate Change reached the Paris Agreement at the UN Climate Change Conference in Paris in 2015,the parties have successively established goals to achieve carbon neutrality by the middle of the 21st century.Therefore,transforming from high-carbon-emitting fossil fuels to low-carbon or even zero-carbon-emitting renewable energy sources has become a crucial pathway for reducing carbon emissions and achieving carbon peak and neutrality.展开更多
To probe the processes and mechanisms of soil organic carbon (SOC) changes during forest recovery, a 150-yearchronosequence study on SOC was conducted for various vegetation succession stages at the Ziwuling area, in ...To probe the processes and mechanisms of soil organic carbon (SOC) changes during forest recovery, a 150-yearchronosequence study on SOC was conducted for various vegetation succession stages at the Ziwuling area, in the centralpart of the Loess Plateau, China. Results showed that during the 150 years of local vegetation rehabilitation SOC increasedsignificantly (P < 0.05) over time in the initial period of 55-59 years, but slightly decreased afterwards. Average SOCdensities for the 0-100 cm layer of farmland, grassland, shrubland and forest were 4.46, 5.05, 9.95, and 7.49 kg C m-3,respectively. The decrease in SOC from 60 to 150 years of abandonment implied that the soil carbon pool was a sink forCO2 before the shrubland stage and became a source in the later period. This change resulted from the spatially variedcomposition and structure of the vegetation. Vegetation recovery had a maximum effect on the surface (0-20 cm) SOCpool. It. was concluded that vegetation recovery on the Loess Plateau could result in significantly increased sequestrationof atmospheric CO2 in soil and vegetation, which was ecologically important for mitigating the increase of atmosphericconcentration of CO2 and for ameliorating the local eco-environment.展开更多
Background:Old-growth forests are irreplaceable with respect to climate change mitigation and have considerable carbon(C)sink potential in soils.However,the relationship between the soil organic carbon(SOC)turnover ra...Background:Old-growth forests are irreplaceable with respect to climate change mitigation and have considerable carbon(C)sink potential in soils.However,the relationship between the soil organic carbon(SOC)turnover rate and forest development is poorly understood,which hinders our ability to assess the C sequestration capacity of soil in old-growth forests.Methods:In this study,we evaluated the SOC turnover rate by calculating the isotopic enrichment factor β(defined as the slope of the regression between ^(13)C natural abundance and log-transformed C concentrations)along 0-30 cm soil profiles in three successional forests in subtropical China.A lower β(steeper slope)is associated with a higher turnover rate.The three forests were a 60-year-old P.massoniana forest(PF),a 100-year-old coniferous and broadleaved mixed forest(MF),and a 400-year-old monsoon evergreen broadleaved forest(BF).We also analyzed the soil physicochemical properties in these forests to examine the dynamics of SOC turnover during forest succession and the main regulators.Results:The β value for the upper 30-cm soils in the BF was significantly(p<0.05)higher than that in the PF,in addition to the SOC stock,although there were nonsignificant differences between the BF and MF.The β value was significantly(p<0.05)positively correlated with the soil recalcitrance index,total nitrogen,and available nitrogen contents but was significantly(p<0.01)negatively correlated with soil pH.Conclusions:Our results demonstrate that SOC has lower turnover rates in old-growth forests,accompanied by higher soil chemical recalcitrance,nitrogen status,and lower soil pH.This finding helps to elucidate the mechanism underlying C sequestration in old-growth forest soils,and emphasizes the important value of old-growth forests among global C sinks.展开更多
Can soil nitrate: ammonium ratios influence plant carbon: nitrogen ratios of the early succession plant? Can plant carbon: nitrogen ratios limit the plant growth in early succession? To address these two question...Can soil nitrate: ammonium ratios influence plant carbon: nitrogen ratios of the early succession plant? Can plant carbon: nitrogen ratios limit the plant growth in early succession? To address these two questions, we performed a two-factor (soil nitrate: ammonium ratio and plant density) randomized block design and a uniform-precision rotatable central composite design pot experiments to examine the relationships between soil nitrate: ammonium ratios, the carbon: nitrogen ratios and growth rate of Artemisia sphaerocephala seedlings. Under adequate nutrient status, both soil nitrate: ammonium ratios and plant density influenced the carbon: nitrogen ratios and growth rate of A. sphaerocephala seedlings. Under the lower soil nitrate: ammonium ratios, with the increase of soil nitrate: ammonium ratios, the growth rates of plant height and shoot biomass of A. sphaerocephala seedlings decreased significantly; with the increase of plant carbon: nitrogen ratios, the growth rates of shoot biomass of A. sphaerocephala seedlings decreased significantly. Soil nitrate: ammonium ratios affected the carbon: nitrogen ratios of A. sphaerocephala seedlings by plant nitrogen but not by plant carbon. Thus, soil nitrate: ammonium ratios influenced the carbon: nitrogen ratios of A. sphaerocephala seedlings, and hence influenced its growth rates. Our results suggest that under adequate nutrient environment, soil nitrate: ammonium ratios can be a limiting factor for the growth of the early succession plant.展开更多
基金This paper is financially supported by the National Natural Science Foundation of China (Nos.49802012,40472065)the China Petrochemical Corporation (No.C0800-07-ZS-164).
文摘A particular non-stromatolitic carbonate succession making up the third member of the Mesoproterozoic Gaoyuzhuang (高于庄) Formation might demonstrate that a stromatolite decline of the Mesoproterozoic occurring at ca. 1 450 Ma besides other three events of the Proterozoic, respectively, occurred at ca. 2 000 Ma, ca. 1 000 Ma, and ca. 675 Ma. The forming duration of this non-stromatolitic carbonate succession can be generally correlative to that of a similar depositional succession in North America, i.e. a non-stromatolitic carbonate succession made up by the Helena Formation of the Belt Supergroup, which suggests that the stromatolite decline occurring at ca. 1 450 Ma may be a global event. This information endows the non-stromatolitic carbonate succession making up the third member of the Gaoyuzhuang Formation in the Yanshan (燕山) area with important significance for the further understanding of Precambrian sedimentology. The Mesoproterozoic Gaoyuzhuang Formation in Yanshan area is a set of more than 1 000 m thick carbonate strata that can be divided into four members (or subformations). The first member (or the Guandi (官地) subformation) is marked by a set of stromatolitic dolomites overlying a set of transgressive sandstones; the second member (or the Sangshu'an (桑树鞍) subformation) is a set of manganese dolomites with a few stromatolites; the third member (or the Zhangjiayu (张家峪) subformation) is chiefly made up of leiolite and laminite limestones and is characterized by the development of molar-tooth structures in leiolite limestone; the fourth member (or the Huanxiusi (环秀寺) subformation) is composed of a set of dolomites of stromatolitic reefs or lithoherms. Sequence-stratigraphic divisions at two sections, i.e. the Jixian (蓟县) Section in Tianjin (天津) and the Qiangou (千沟) Section of Yanqing (延庆) County in Beijing (北京), demonstrate that a particularly non-stromatolitic succession making up the third member of the Mesoproterozoic Gaoyuzhuang Formation is developed in the Yanshan area of North China, in which lots of grotesque matground structures (wrinkle structures and palimpsest ripples) are developed in beds of leiolite limestone at the Qiangou Section and lots,of molar-tooth structures are developed in beds of leiolite limestone at the Jixian Section. The time scale of the Gaoyuzhuang Formation is deduced as 200 Ma (from 1 600 Ma to 1 400 Ma). The duration of an obvious hiatus between the Gaoyuzhuang Formation and the underlying Dahongyu (大红) Formation is deduced as 50 Ma to 100 Ma, thus the forming duration of the Gaoyuzhuang Formation is thought as 100 Ma (1 500 Ma to 1 400 Ma). Furthermore, the age of the subface of the third member of the Gaoyuzhuang Formation that is just in the mid position of the Gaoyuzhuang Formation can be deduced as about 1 450 Ma, which is the basis to infer a stromatolite decline of the Mesoproterozoic occurring at ca. 1 450 Ma. Importantly, several features of both the molar-tooth structure and the stromatolite, such as the particular forming environment, the important facies-indicative meaning, and the episodic distribution in the earth history, might express the evolutionary periodicity of the surface environment of the earth and can provide meaningful clues for the understanding of the Precambrian world, although their origin and forming mechanism is highly contentious. Therefore, like other three stromatolitic declines, respectively, occurring at ca. 675 Ma, ca. 1 000 Ma, and ca. 2 000 Ma, the identification of the stromatolite decline occurring at ca. 1 450 Ma during the Golden Age of stromatolites (2 800 Ma to 1 000 Ma) has important meaning for the further understanding of the evolving carbonate world of the Precambrian.
文摘In the long Precambrian period, stromatolitic carbonate successions were very common. However, the non-stromatolitic carbonate succession that is marked by subtidal deposits shows a sharp contrast to the stromatolitic carbonate succession. Both the non-stromatolitic and the stromatolitic carbonate successions are important clues for the further understanding of the evolving carbonate world of the Precambrian. The Mesoproterozoic Gaoyuzhuang Formation at the Qiangou section in northwestern suburb of Beijing is a set of more than 1000 m-thick carbonate strata that can be divided into four members (or subformations), in which a non-stromatolitic carbonate succession marked by the scarcity of stromatolites makes up the third member of the formation. This non-stromatolitic carbonate succession can further be subdivided into three third-order sequences that are marked by the regular succession of sedimentary facies. In third-order sequences, a lot of subtidal carbonate meter-scale cycles made up of medium-bedded leiolite limestones and thin-bedded marls constitute their transgressive system tracts (TSTs) and the early high-stand system tracts (EHSTs), a lot of meter- scale cycles made up by thin-bedded limestones and marls constitute their condensed sections (CSs), and thick-bedded to massive dolomitic limestones or lime dolomites make up the late high-stand system tracts (LHSTs). The particularly non-stromatolitic carbonate succession making up the third member of the Mesoproterozoic Gaoyuzhuang Formation at the Qiangou section might be the representative of the non-stromatolitic carbonate succession of the Precambrian because of its special lithological features and particular sedimentary structures, and its general sedimentary features are helpful and meaningful for the further understanding of the evolution rules of the sophisticate and evolving carbonate world of the Precambrian. The time scale of the Gaoyuzhuang Formation is deduced as that from 1600 Ma to 1400 Ma; thus, the non-stromatolitic sedimentary succession making up the third member of the Gaoyuzhuang Formation may demonstrate a stromatolite decline event occurring at ca. 1450 Ma of the Proterozoic besides other three events that occurred respectively at ca. 2000 Ma, ca. 1000 Ma and ca. 675 Ma. The forming duration of this non-stromatolitic sedimentary succession of the third member of the Gaoyuzhuang Formation can be generally correlated with a similar sedimentary succession in North America, i.e. a non-stromatolitic sedimentary succession of the Helena Formation of the Belt Supergroup, which suggests that the stromatolite decline occurring at ca. 1450 Ma might be a global event. Therefore, the non-stromatolitic sedimentary succession discussed in the paper provides an important example for further understanding of carbonate sedimentology in the Precambrian.
基金This work is funded by the National Natural Science Foundation of China (Grant 40472066)the National Major Fundamental Research and Development Project (Nos. 2005CB422102 and 1999043302).
文摘Geothermometer is one of the most useful methods to reconstruct the thermal history of sedimentary basins. This paper introduces the application of free radicals concentration of organic matter as a thermal indicator in the thermal history reconstruction of carbonate succession, based on anhydrous thermal simulation results of type I and H1 kerogen. A series of free radicals data are obtained under thermal simulation of different heating temperatures and times, and quantitative modds between free radical concentration (Ng) of organic matter and time-temperature index (TTI) for types I and type H1 kerogen are also obtained. This Ng.TTI relation was used to model the Ordovician thermal gradients of Well TZ12 in the Tarim Basin. The modeling result is corresponding to the results obtained by apatite fission track data and published data. This new method of thermal history reconstruction will be benefit to the hydrocarbon generation and accumulation study and resource assessment of carbonate succession.
基金funded by the Qinghai Science and Technology Department(Grant No.2017-ZJ-799)the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(Grant No.2019QZKK1002)received form Program for the National Natural Sciences Foundation of China(Grant No.41665008,31872999,41565008,41861049)。
文摘Wetland is an important carbon pool,and the degradation of wetlands causes the loss of organic carbon and total nitrogen.This study aims to explore how wetland degradation succession affects soil organic carbon(SOC)and total nitrogen(TN)contents in alpine wetland.A field survey of 180 soilsampling profiles was conducted in an alpine wetland that has been classified into three degradation succession stages.The SOC and TN contents of soil layers from 0 to 200 cm depth were studied,including their distribution characteristics and the relationship between microtopography.The results showed that SOC and TN of different degradation succession gradients followed the ranked order of Non Degradation(ND)>Light Degradation(LD)>Heavy Degradation(HD).SWC was positively correlated with SOC and TN(p<0.05).As the degree of degradation succession worsened,SOC and TN became more sensitive to the SWC.Microtopography was closely related to the degree of wetland degradation succession,SWC,SOC and TN,especially in the topsoil(0-30 cm).This result showed that SWC was an important indicator of SOC/TN in alpine wetland.It is highly recommended to strengthen water injection into the wetland as a means of effective restoration to reverse alpine meadow back to marsh alpine wetland.
基金financial support of the German Research Foundation(DFG,Research Unit 816)for initializing the forest plots and the plot census as well as a first model parameterisationthe Helmholtz Alliance:Remote Sensing and Earth System Dynamics for financing the work on the further parameterisation of the model and analysis of the data
文摘Background: Tropical forests play an important role in the global carbon(C) cycle.However, tropical montane forests have been studied less than tropical lowland forests, and their role in carbon storage is not well understood.Montane forests are highly endangered due to logging, land-use and climate change.Our objective was to analyse how the carbon balance changes during forest succession.Methods: In this study, we used a method to estimate local carbon balances that combined forest inventory data with process-based forest models.We utilised such a forest model to study the carbon balance of a tropical montane forest in South Ecuador, comparing two topographical slope positions(ravines and lower slopes vs upper slopes and ridges).Results: The simulation results showed that the forest acts as a carbon sink with a maximum net ecosystem exchange(NEE) of 9.3 Mg C?(ha?yr)-1during its early successional stage(0–100 years).In the late successional stage, the simulated NEE fluctuated around zero and had a variation of 0.77 Mg C?(ha?yr)–1.The simulated variability of the NEE was within the range of the field data.We discovered several forest attributes(e.g., basal area or the relative amount of pioneer trees) that can serve as predictors for NEE for young forest stands(0–100 years) but not for those in the late successional stage(500–1,000 years).In case of young forest stands these correlations are high, especially between stand basal area and NEE.Conclusion: In this study, we used an Ecuadorian study site as an example of how to successfully link a forest model with forest inventory data, for estimating stem-diameter distributions, biomass and aboveground net primary productivity.To conclude, this study shows that process-based forest models can be used to investigate the carbon balance of tropical montane forests.With this model it is possible to find hidden relationships between forest attributes and forest carbon fluxes.These relationships promote a better understanding of the role of tropical montane forests in the context of global carbon cycle, which in future will become more relevant to a society under global change.
文摘The Liaoyang Petrochemical Company has successfullydeveloped a novel ionic liquid catalyst for carbonylationof ethylene oxide with carbon dioxide to form ethylenecarbonate (EC). This catalyst can achieve an 100 % conversionand a 98% selectivity at low temperature andunder low pressure, featuring high catalytic activity, goodstability, good adaptability to feedstocks and low productioncost.
基金supported by the National Natural Science Foundation of China (41171226)the Program for New Century Excellent Talents in University (NCET-12-0479)the Foundation for Youths Teacher by Northwest A&F University
文摘Revegetation is a traditional practice widely used for soil protection. We evaluated the effect of natural revegetation succession on soil chemical properties and carbon fractions (particulate organic carbon (POC), humus carbon (HS-C), humic acid carbon (HA-C) and fulvic acid carbon (FA-C)) on the Loess Plateau of China. The vegetation types, in order from the shortest to the longest enclosure duration, were: (a) abandoned overgrazed grassland (AbG3; 3 years); (b) Hierochloe odorata Beauv. (HiO7; 7 years); (c) Thymus mongoficus Ronnm (ThM15; 15 years); (d) Artemisia sacrorum Ledeb (AtS25; 25 years); (e) Stipa bungeana Trin Ledeb (StB36; 36 years) and (f) Stipa grandis P. Smirn (StG56; 56 years). The results showed that the concentrations of soil organic carbon, total nitrogen and available phosphorus increased with the increase of restoration time except for ThM15. The concen- tration of NH4-N increased in the medium stage (for ThM15 and AtS25) and decreased in the later stage (for StB36 and StG56) of vegetation restoration. However, NO3-N concentration significantly increased in the later stage (for StB36 and StG56). Carbon fractions had a similar increasing trend during natural vegetation restoration. The con- centrations of POC, HS-C, FA-C and HA-C accounted for 24.5%-49.1%, 10.6%-15.2%, 5.8%-9.1% and 4.6%-6.1% of total carbon, respectively. For AbG3, the relative changes of POC, HS-C and FA-C were significantly higher than that of total carbon during the process of revegetation restoration. The higher relative increases in POC, HS-C and FA-C confirmed that soil carbon induced by vegetation restoration was sequestrated by higher physical and chemical protection. The increases of soil C fractions could also result in higher ecological function in semiarid grassland ecosystems.
基金Supported by Guangxi Key R&D Plan Project(Guike AB17292008)Guangxi Science Research and Technology Development Plan Program(Guikeneng 1598025-38)Major Science and Technology Project of Guangxi Forestry(Guilin Science Word[2010]No.7)
文摘The 23-year-old T. flousiana plantation and successive rotation plantation of C. lanceolata at Shankou Forest Farm of Nandan County, Guangxi were tested by the method of plot investigation combining with biomass measurement. Carbon storage and spatial distribution of different components in the two forests were analyzed. The results indicated that carbon content in different organs of T. flousiana ranged from 426.0 to 503.9 g/kg, and the order was bark 〉stem 〉 root 〉 branch 〉 leaf. The carbon contents in shrub, herb and litter layers were452.9 , 408.0 and 428.9 g/kg, respectively. Carbon content in the soil (0 -80 cm)was 16.59 g/kg. The carbon content in different organs of C. lanceolata ranged from 464.5 to 508.9 g/kg, and the order was bark 〉 stem 〉 branch 〉 root 〉 leaf. The carbon contents in shrub, herb and litter layers were 456.2, 416.3 and 468.1 g/kg, respectively. Carbon content in the soil (0 -80 cm)was 15.77 g/kg. Total carbon storage amounts of T. flousiana plantation and successive rotation plantation of C. lanceolata were 245.83 and 213.52 t/hm^2, respectively. The carbon storage order of different structure layers from T. flousiana plantation and successive rotation plantation of C. lanceolata was soil layer (0 -8 0 cm) 〉 vegetation layer 〉 litter layer. Annual net productivity in the arbor layers of T. flousiana plantation and successive rotation plantation of C. lanceolata plantations was 10.75 and 17.13 t/(hm^2 · a) ; annual net carbon fixation amounts were estimated as 5.05 and 3.47 t /(hm^2 · a) ; annual net absorption C02 amounts were 18.53 and 12.73 t/(hm^2 · a) respectively.
文摘Since nearly 200 parties to the United Nations Framework Convention on Climate Change reached the Paris Agreement at the UN Climate Change Conference in Paris in 2015,the parties have successively established goals to achieve carbon neutrality by the middle of the 21st century.Therefore,transforming from high-carbon-emitting fossil fuels to low-carbon or even zero-carbon-emitting renewable energy sources has become a crucial pathway for reducing carbon emissions and achieving carbon peak and neutrality.
基金the National Key Basic Research Support Foundation of China (No. 2002CB111502), the NationalNatural Science Foundation of China (Nos. 40371074 and 40025106) and the China Postdoctoral Science Foundation(No. 2003033023).
文摘To probe the processes and mechanisms of soil organic carbon (SOC) changes during forest recovery, a 150-yearchronosequence study on SOC was conducted for various vegetation succession stages at the Ziwuling area, in the centralpart of the Loess Plateau, China. Results showed that during the 150 years of local vegetation rehabilitation SOC increasedsignificantly (P < 0.05) over time in the initial period of 55-59 years, but slightly decreased afterwards. Average SOCdensities for the 0-100 cm layer of farmland, grassland, shrubland and forest were 4.46, 5.05, 9.95, and 7.49 kg C m-3,respectively. The decrease in SOC from 60 to 150 years of abandonment implied that the soil carbon pool was a sink forCO2 before the shrubland stage and became a source in the later period. This change resulted from the spatially variedcomposition and structure of the vegetation. Vegetation recovery had a maximum effect on the surface (0-20 cm) SOCpool. It. was concluded that vegetation recovery on the Loess Plateau could result in significantly increased sequestrationof atmospheric CO2 in soil and vegetation, which was ecologically important for mitigating the increase of atmosphericconcentration of CO2 and for ameliorating the local eco-environment.
基金jointly supported by the China Postdoctoral Science Foundation(No.2020 M682951)the National Natural Science Foundation of China(No.NSFC41773088)the Key Research Program of the Chinese Academy of Sciences(No.QYZDJ-SSW-DQC003).
文摘Background:Old-growth forests are irreplaceable with respect to climate change mitigation and have considerable carbon(C)sink potential in soils.However,the relationship between the soil organic carbon(SOC)turnover rate and forest development is poorly understood,which hinders our ability to assess the C sequestration capacity of soil in old-growth forests.Methods:In this study,we evaluated the SOC turnover rate by calculating the isotopic enrichment factor β(defined as the slope of the regression between ^(13)C natural abundance and log-transformed C concentrations)along 0-30 cm soil profiles in three successional forests in subtropical China.A lower β(steeper slope)is associated with a higher turnover rate.The three forests were a 60-year-old P.massoniana forest(PF),a 100-year-old coniferous and broadleaved mixed forest(MF),and a 400-year-old monsoon evergreen broadleaved forest(BF).We also analyzed the soil physicochemical properties in these forests to examine the dynamics of SOC turnover during forest succession and the main regulators.Results:The β value for the upper 30-cm soils in the BF was significantly(p<0.05)higher than that in the PF,in addition to the SOC stock,although there were nonsignificant differences between the BF and MF.The β value was significantly(p<0.05)positively correlated with the soil recalcitrance index,total nitrogen,and available nitrogen contents but was significantly(p<0.01)negatively correlated with soil pH.Conclusions:Our results demonstrate that SOC has lower turnover rates in old-growth forests,accompanied by higher soil chemical recalcitrance,nitrogen status,and lower soil pH.This finding helps to elucidate the mechanism underlying C sequestration in old-growth forest soils,and emphasizes the important value of old-growth forests among global C sinks.
基金supported in part by the National Basic Research Program of China (2009CB421303)supported by National Natural Science Foundation of China (30970546)
文摘Can soil nitrate: ammonium ratios influence plant carbon: nitrogen ratios of the early succession plant? Can plant carbon: nitrogen ratios limit the plant growth in early succession? To address these two questions, we performed a two-factor (soil nitrate: ammonium ratio and plant density) randomized block design and a uniform-precision rotatable central composite design pot experiments to examine the relationships between soil nitrate: ammonium ratios, the carbon: nitrogen ratios and growth rate of Artemisia sphaerocephala seedlings. Under adequate nutrient status, both soil nitrate: ammonium ratios and plant density influenced the carbon: nitrogen ratios and growth rate of A. sphaerocephala seedlings. Under the lower soil nitrate: ammonium ratios, with the increase of soil nitrate: ammonium ratios, the growth rates of plant height and shoot biomass of A. sphaerocephala seedlings decreased significantly; with the increase of plant carbon: nitrogen ratios, the growth rates of shoot biomass of A. sphaerocephala seedlings decreased significantly. Soil nitrate: ammonium ratios affected the carbon: nitrogen ratios of A. sphaerocephala seedlings by plant nitrogen but not by plant carbon. Thus, soil nitrate: ammonium ratios influenced the carbon: nitrogen ratios of A. sphaerocephala seedlings, and hence influenced its growth rates. Our results suggest that under adequate nutrient environment, soil nitrate: ammonium ratios can be a limiting factor for the growth of the early succession plant.