An approach of stochastically statistical mechanics and a unified molecular theory of nonlinear viscoelasticity with constraints of Nagai chain entanglement for polymer melts have been proposed. A multimode model stru...An approach of stochastically statistical mechanics and a unified molecular theory of nonlinear viscoelasticity with constraints of Nagai chain entanglement for polymer melts have been proposed. A multimode model structure for a single polymer chain with n tail segments and N reversible entanglement sites on the test polymer chain is developed. Based on the above model structure and the mechanism of molecular flow by the dynamical reorganization of entanglement sites, the probability distribution function of the end-to-end vectr for a single polymer chain at entangled state and the viscoelastic free energy of deformation for polymer melts are calculated by using the method of the stochastically statistical mechanics. The four types of stress-strain relation and the memory function are derived from this thery. The above theoretical relations are verified by the experimentaf data for various polymer melts. These relations are found to be in good agreement with the experimental results展开更多
The nonlinearity has significant effect on the ultrasonic therapy using phased ar- rays. A numerical approach is developed to calculate the nonlinear sound field generated from a phased array based on the Gaussian sup...The nonlinearity has significant effect on the ultrasonic therapy using phased ar- rays. A numerical approach is developed to calculate the nonlinear sound field generated from a phased array based on the Gaussian superposition technique. The parameters of the phased array elements are first estimated from the focal parameters using the inverse matrix algorithm; Then the elements are expressed as a set of Gaussian functions; Finally, the nonlinear sound field can be calculated using the Gaussian superposition technique. In the numerical simulation, a 64~ 1 phased array is used as the transmitter. In the linear case, the difference between the results of the Gaussian superposition technique and the Fresnel integral is less than 0.5%, which verifies the feasibility of the approach. In the nonlinear case, the nonlinear fields of single-focus modes and double-focus modes are calculated. The results reveal that the nonlinear effects can improve the focusing performance, and the nonlinear effects are related with the source pressures and the excitation frequencies.展开更多
文摘An approach of stochastically statistical mechanics and a unified molecular theory of nonlinear viscoelasticity with constraints of Nagai chain entanglement for polymer melts have been proposed. A multimode model structure for a single polymer chain with n tail segments and N reversible entanglement sites on the test polymer chain is developed. Based on the above model structure and the mechanism of molecular flow by the dynamical reorganization of entanglement sites, the probability distribution function of the end-to-end vectr for a single polymer chain at entangled state and the viscoelastic free energy of deformation for polymer melts are calculated by using the method of the stochastically statistical mechanics. The four types of stress-strain relation and the memory function are derived from this thery. The above theoretical relations are verified by the experimentaf data for various polymer melts. These relations are found to be in good agreement with the experimental results
基金supported by the National Basic Research Program 973(2011CB707900)National Natural Science Foundation of China(81127901,81227004,11174141,11274170 and 11161120324)+2 种基金the Natural Science Foundation of Jiangsu Province of China(BK2011543 and BE2011110)the National High Technology Research and Development Program 863(2012AA022700)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘The nonlinearity has significant effect on the ultrasonic therapy using phased ar- rays. A numerical approach is developed to calculate the nonlinear sound field generated from a phased array based on the Gaussian superposition technique. The parameters of the phased array elements are first estimated from the focal parameters using the inverse matrix algorithm; Then the elements are expressed as a set of Gaussian functions; Finally, the nonlinear sound field can be calculated using the Gaussian superposition technique. In the numerical simulation, a 64~ 1 phased array is used as the transmitter. In the linear case, the difference between the results of the Gaussian superposition technique and the Fresnel integral is less than 0.5%, which verifies the feasibility of the approach. In the nonlinear case, the nonlinear fields of single-focus modes and double-focus modes are calculated. The results reveal that the nonlinear effects can improve the focusing performance, and the nonlinear effects are related with the source pressures and the excitation frequencies.
