Life cycle assessment of high concentration organic wastewater treatment by catalytic wet air oxidation

There have been many studies on life cycle assessment in sewage treatment,but there are scarce few studies on the treatment of industrial wastewater in combination with advanced oxidation technology,especially in catalytic wet air oxidation(CWAO).There are no cases of using actual industrialized data onto life cycle assessment.This paper uses Simapro 9.0 software to establish a life cycle assessment model for the treatment of high-concentration organic wastewater by CWAO,and comprehensively explains the impact on the environment from three aspects:the construction phase,the operation phase and the demolition phase.In addition,sensitivity analysis and uncertainty analysis were performed.The results showed that the key factors affecting the environment were marine ecotoxicity,mineral resource consumption and global warming,the operation stage had the greatest impact on the environment,which was related to high power consumption during operation and emissions from the treatment process.Sensitivity analysis showed that electricity consumption has the greatest impact on abiotic depletion and freshwater aquatic ecotoxicity,and it also proved that global warming is mainly caused by pollutant emissions during operation phase.Monte Carlo simulations found slightly higher uncertainty for abiotic depletion and toxicity-related impact categories.

The Effect of Mass Ratio and Air Damper Characteristics on the Resonant Response of an Air Damped Dynamic Vibration Absorber

In this paper, it is shown that, a road vehicle 2DOF air damped quartercar suspension system can conveniently be transformed into a 2DOF air damped vibrating system representing an air damped dynamic vibration absorber (DVA) with an appropriate change in the ratio μ of the main mass and the absorber mass i.e. when mass ratio μ >> 1. Also the effect of variation of the mass ratio, air damping ratio and air spring rate ratio, on the motion transmissibility at the resonant frequency of the main mass of the DVA has been dis- cussed. It is shown that, as the air damping ratio in the absorber system increases, there is a substantial decrease in the motion transmissibility of the main mass system where the air damper has been modeled as a Maxwell type. Optimal value of the air damping ratio for the minimum motion transmissibility of the main mass of the system has been determined. An experimental setup has been designed and developed with a control system to vary air pressure in the damper in the absorber system. The motion transmissibility characteristics of the main mass system have been obtained, and the optimal value of the air damping ratio has been determined for minimum motion transmissibility of the main mass of the

Effects of Free-air CO2 Enrichment on Root Characteristics and C:N Ratio of Rice at the Heading Stage

A hydroponics experiment was conducted to investigate the rice root growth in FACE （free-air carbon dioxide enrichment）. The root biomass, root volume, ratio of root/shoot, number of adventitious roots and root diameter significantly increased under FACE conditions, while the CO2 enrichment decreased the N concentration in rice roots without any change in the C content, leading to an increase in root C：N ratio. Moreover, the elevated CO2 resulted in a remarkable decrease of root activity, expressed as per unit root dry weight, which might be responsible for decreased N concentration in roots.

Development and experimental validation of a one-dimensional dynamic hygrothermal modeling based on air humidity ratio

A modified one-dimensional transient hygrothermal model for multilayer wall was proposed using air humidity ratio and temperature as the driving potentials.The solution for the governing equations was obtained numerically by implementing the finite-difference scheme.To evaluate the accuracy of the model,a test system was built up to measure relative humidity and temperature within a porous wall and compare with the prediction of the model.The prediction results have good agreement with the experimental results.For the interface close to indoor side,the maximum deviation of temperature between calculated and test data is 1.87 K,and the average deviation is 0.95 K;the maximum deviation of relative humidity is 11.4%,and the average deviation is 5.7%.For the interface close to outdoor side,the maximum deviation of temperature between prediction and measurement is 1.78 K,and the average deviation is 1.1 K;the maximum deviation of relative humidity is 9.9%,and the average deviation is 4.2%.

Artificial neural network techniques to predict the moisture ratio content during hot air drying and vacuum drying of Radix isatidis extract

Background:To predict the moisture ratio of Radix isatidis extract during drying.Methods:Artificial neural networks were designed using the MATLAB neural network toolbox to produce a moisture ratio prediction model of Radix isatidis extract during hot air drying and vacuum drying,where regression values and mean squared error were used as evaluation indexes to optimize the number of hidden layer nodes and determine the topological structure of artificial neural networks model.In addition,the drying curves for the different drying parameters were analyzed.Results:The optimal topological structure of the moisture ratio prediction model for hot air drying and vacuum drying of Radix isatidis extract were“4-9-1”and“5-9-1”respectively,and the regression values between the predicted value and the experimental value is close to 1.This indicates that it has a high prediction accuracy.The moisture ratio gradually decreases with an increase in the drying time,reducing the loading,initial moisture content,increasing the temperature,and pressure can shorten the drying time and improve the drying efficiency.Conclusion:Artificial neural networks technology has the advantages of rapid and accurate prediction,and can provide a theoretical basis and technical support for online prediction during the drying process of the extract.

Potential risk of soil irrigation with treated wastewater over 40 years:a field experiment under semi-arid conditions in northeastern Tunisia

In Tunisia,water scarcity is only adding pressure on water demand in agriculture.In the context of sustainable development goals,Tunisia has been reusing treated wastewater(TWW)as a renewable and inexpensive source for soil fertigation and groundwater(GW)recharge.However,major risks can be expected when the irrigation water is of poor quality.This study aims for evaluating the potential risk of TWW and GW irrigation on soil parameters.Accordingly,we evaluated the suitability of water quality through the analysis of major and minor cations and anions,metallic trace elements(MTEs),and the sodium hazard by using the sodium adsorption ratio(SAR)and the soluble sodium percentage(SSP).The risk of soil sodicity was further assessed by SAR and the exchangeable sodium percentage(ESP).The degree of soil pollution caused by MTEs accumulation was evaluated using geoaccumulation index(Igeo)and pollution load index(PLI).Soil maps were generated using inverse spline interpolation in ArcGIS software.The results show that both water samples(i.e.,TWW and GW)are suitable for soil irrigation in terms of salinity(electrical conductivity<7000μS/cm)and sodicity(SAR<10.00;SSP<60.00%).However,the contents of PO_(4)^(3-),Cu^(2+),and Cd^(2+)exceed the maximum threshold values set by the national and other standards.Concerning the soil samples,the average levels of SAR and ESP are within the standards(SAR<13.00;ESP<15.00%).On the other hand,PLI results reveal moderate pollution in the plot irrigated with TWW and no to moderate pollution in the plot irrigated with GW.Igeo results indicate that Cu^(2+)is the metallic trace element(MTE)with the highest risk of soil pollution in both plots(Igeo>5.00),followed by Ni^(2+)and Pb^(2+).Nevertheless,Cd^(2+)presents the lowest risk of soil pollution(Igeo<0.00).Statistical data indicates that Ca^(2+),Na+,Ni^(2+),and Pb^(2+)are highly distributed in both plots(coefficient of variation>50.0%).This study shows that the use of imagery tools,such as ArcGIS,can provide important information for evaluating the current status of soil fertility or pollution and for better managing soil irrigation with TWW.

Investigation of the Effects of a Large Percentage of Dried Sludge on the Operation of a Coal-Fired Boiler

A 600 MW coal-fired boiler with a four-corner tangential combustion mode is considered here to study the combustion features and pollutant emissions at different loads for large-percentages of blending dried sludges.The influence of the over-fired air(OFA)coefficient is examined and the impact of the blending ratio on the boiler operation is explored.The results show that for low blending ratios,a slight increase in the blending ratio can improve the combustion of bituminite,whereas a further increase leads to the deterioration of the combustion of blended fuels and thus reduces the boiler efficiency.Enhancing the supporting capability of the secondary air effectively reduces the slagging degree in the bottom ash hopper and improves the burnout rate of coals.For a large-percentage blending case at full load,it is found that the OFA coefficient must be reduced appropriately,otherwise,a secondary high-temperature combustion zone can be generated in the vicinity of the furnace arches,causing high temperature slagging and superheater tube bursting.Considering the influences of combustion and pollutant emissions,the recommended OFA coefficient is 0.2.Blending dried sludge under low loads increases the flue gas temperature at the furnace exit.While reducing the flue gas temperature in the main combustion region,which is beneficial to the safe operation of the denitrification system.Increasing the blending ratio and reducing load lead to an increase in NOx concentration at the furnace exit Sludges with low nitrogen content are suggested for the practical operation of boilers.

Effect of Air Injector on the Performance of an Air-lift for Conveying River Sand

An air-lift has been more recently applied in the dredging, deep-seated beach placer mining and underground mining engineering. However, the influence and mechanism of various parameters on the air-lift performance are not quite clear, especially the influence of flow pattern on lifting efficiency. Focusing on the problems mentioned above, the key part of the air-lift （namely, the air injector） was proposed aimed to reduce friction loss in the inner pipe according to improving flow field performance, thus increase the lifting efficiency. The study of relative factors of the performance of an air-lift is performed and the river sand is used as simulation of underground ore bed. The total lifting height of the experimental system is 3 m, the water flux, mass flow of solid particles, concentration of particles and lifting efficiency are measured under the same submergence ratios by changing the air injector, which is divided into nine specifications of air injection in this research. The experimental results indicate that the optimal air flow rate corresponding to excellent performance of the air-lift can be obtained in the range of 35-40 m3/h. The air injection method has a great effect on the performance of the air-lift, the air injector with three nozzles is better than that in the case of one or two nozzles. Further more, the air injection angle and arrangement of air injection pipes also have great effect on the performance of an air-lift. The proposed research results have guiding significance for engineering application.

Effects of total pressures and equivalence ratios on kerosene/air rotating detonation engines using a paralleling CE/SE method

In this paper,the kerosene/air rotating detonation engines(RDE)are numerically investigated,and the emphasis is laid on the effects of total pressures and equivalence ratios on the operation characteristics of RDE including the initiation,instabilities,and propulsive performance.A hybrid MPI t OpenMP parallel computing model is applied and it is proved to be able to obtain a more effective parallel performance on high performance computing(HPC)systems.A series of cases with the total pressure of 1 MPa,1.5 MPa,2 MPa,and the equivalence ratio of 0.9,1,1.4 are simulated.On one hand,the total pressure shows a significant impact on the instabilities of rotating detonation waves.The instability phenomenon is observed in cases with low total pressure(1 MPa)and weakened with the increase of the total pressure.The total pressure has a small impact on the detonation wave velocity and the specific impulse.On the other hand,the equivalence ratio shows a negligible influence on the instabilities,while it affects the ignition process and accounts for the detonation velocity deficit.It is more difficult to initiate rotating detonation waves directly in the lean fuel operation condition.Little difference was observed in the thrust with different equivalence ratios of 0.9,1,and 1.4.The highest specific impulse was obtained in the lean fuel cases,which is around 2700 s.The findings could provide insights into the understanding of the operation characteristics of kerosene/air RDE.

Design, Development and Testing of an Air Damper to Control the Resonant Response of a SDOF Quarter-Car Suspension System

An air damper possesses the advantages that there are no long term changes in the damping properties, there is no dependence on working temperature and additionally, it has less manufacturing and maintenance costs. As such, an air damper has been designed and developed based on the Maxwell type model concept in the approach of Nishihara and Asami [1]. The cylinder-piston and air-tank type damper characteristics such as air damping ratio and air spring rate have been studied by changing the length and diameter of the capillary pipe between the air cylinder and the air tank, operating air pressure and the air tank volume. A SDOF quarter-car vehicle suspension system using the developed air enclosed cylinder-piston and air-tank type damper has been analyzed for its motion transmissibility characteristics. Optimal values of the air damping ratio at various values of air spring rate have been determined for minimum motion transmissibility of the sprung mass. An experimental setup has been developed for SDOF quarter-car suspension system model using the developed air enclosed cylinder-piston and air-tank type damper to determine the motion transmissibility characteristics of the sprung mass. An attendant air pressure control system has been designed to vary air damping in the developed air damper. The results of the theoretical analysis have been compared with the experimental analysis.

The influence of nitrified supernate’s recycle ratio on the removal of coking wastewater

The influence of the recycle ratio on the removal of coking wastewater has been researched using the anaerobicanoxic-aerobic （A/A/O） biofilm process. The research indicates that the concentrations of chemical oxygen demand （COD） and NO3 -N in the water are the lowest when the recycle ratio is 3：1 ,but the removal efficiency of total cyanide （TCN） is the highest when the recycle ratio is 1： 1. The removal efficiency of NH4^＋ -N is more than 99% at all three different recycle ratios. Compared with Grade A of the National Discharge Standard （GB 8978--1996）, the effluent NH4 -N is standard,but COD and TCN can not meet the requirements and further treatment processes are needed.

Liquid penetration of freeze-drying and air-drying wood of plantation Chinese fir

比较研究在 freeze-dryingand air-drying 边材和赤木质的液体穿入上被进行种植园汉语冷杉木(Cunninghamia lanceolata ) 伐木。由毛状的上升方法染答案举起的 Themaximum 数量被用来评估对待的木头的液体穿入性质。坑渴望比率是坚定的 bysemithin 切片法。在木头微观结构的变化用扫描电子显微镜学被调查。结果证明与弄干的空气相比，弄干的 freeze 在边材的液体穿入和中国冷杉木的赤木质上有重要效果。边材的液体穿入比为两个都弄干处理的赤木质的显著地高。某具缘纹孔的坑膜的低坑渴望比率和裂缝是为增加液体穿入在以后的主要原因结冰弄干处理。

Catalytic wet air oxidation for the treatment of emulsifying wastewater

The wet air oxidation(WAO) and catalytic WAO(CWAO) of the high strength emulsifying wastewater containing nonionic surfactants have been investigated in terms of COD and TOC removal. The WAO and homogeneous CWAO processes were carried out at the temperature from 433 K to 513 K, with initial oxygen pressure 1 2 MPa. It was found that homogeneous catalyst copper(Cu(NO_3)_2) had an fairly good catalytic activity for the WAO process, and the oxidation was catalyzed when the temperature was higher than 473 K. Moreover, several heterogeneous catalysts were proved to be effective for the WAO process. At the temperature 473 K, after 2 h reaction, WAO process could achieve about 75% COD removal and 66% TOC removal, while catalysts Cu/Al_2O_3 and Mn-Ce/Al_2O_3 elevated the COD removal up to 86%—89% and that of TOC up to 82%. However, complete elimination of COD and TOC was proved to be difficult even the best non-noble catalyst was used. Therefore, the effluent from WAO or CWAO process need to be further disposed. The bioassay proved that the effluent from WAO process was amenable to the biochemical method.

Treatment of desizing wastewater from the textile industry by wet air oxidation

This paper describes the application of wet air oxidation to the treatment of desizing wastewater from two textile companies. A two\|liter high temperature, high pressure autoclave reactor was used in the study. The range of operating temperatures examined was between 150 and 290℃, and the partial pressure of oxygen ranged from 0.375 to 2.25 MPa. Variations in pH, COD Cr and TOD content were monitored during each experiment and used to assess the extent of conversion of the process. The effects of temperature, pressure and reaction time were explored extensively. More than 90% COD Cr reduction and 80% TOC removal have been obtained. The results have also been demonstrated that WAO is a suitable pre\|treatment methods due to improvement of the BOD\-5/COD\-\{Cr\} ratio of desizing wastewater. The reaction kinetics of wet air oxidation of desizing wastewater has been proved to be two steps, a fast reaction followed by a slow reaction stage.

STUDY OF THE HEAT AND HUMIDITY TRANSFER PROCESSES BETWEEN AIR AND WATER IN THE AIR WASHER

The processes of heat and humidity transfer between air and water are what to be studied mainly in the paper, we put forward some main factors which influence the processes of heat and humidity transfer in the air washer. We come to the conclusion that we can change these main factors to achieve different heat and humidity transfer processes and decide processes of heat and humidity transfer of air and water with the initial temperature of spraying water in the air washer. All these results can make things convenient for the air conditioning management.

Study on the Environmental Quality Guarantee Ratio on the Basis of Total Air Pollutant Emission Amount Control

The hourly and daily air quality concentration in the total air pollutant emission amount control zone is not sure to be continuously up to national ambient air quality standard, even though the total annual air pollutant emission is permitted under the total air pollutant emission amount control (TAPEAC) on the basis of A-value method. So the concept of the environmental quality guarantee ratio (EQGR) for TAPEAC is advanced in this paper and its quantitative formula is figured out for both hourly and daily EQGR. It is concluded that the EQGR is related with the yearly arrangement of A-value besides the pollutant type. According to the meteorological data in a lower area along Yangtze River in 2000, the yearly A-value trend is analyzed. Based on the data, the hourly EQGR of SO 2 and NO 2 is respectively 97.4% and 90.2%, and daily EQGR respectively 90.2% and 79.5%.

Influence of thermal flow field of cooling tower on recirculation ratio of a direct air-cooled system for a power plant

In order to get thermal flow field of direct air-cooled system,the hot water was supplied to the model of direct air-cooled condenser(ACC). The particle image velocimetery (PIV) experiments were carried out to get thermal flow field of a ACC under different conditions in low velocity wind tunnel,at the same time,the recirculation ratio at cooling tower was measured,so the relationship between flow field characteristics and recirculation ratio of cooling tower can be discussed. From the results we can see that the flow field configuration around cooling tower has great effects on average recirculation ratio under cooling tower. The eddy formed around cooling tower is a key reason that recirculation produces. The eddy intensity relates to velocity magnitude and direction angle,and the configuration of eddy lies on the geometry size of cooling tower. So changing the flow field configuration around cooling tower reasonably can decrease recirculation ratio under cooling tower,and heat dispel effect of ACC can also be improved.

Pretreatment of apramycin wastewater by catalytic wet air oxidation

The pretreatment technology of wet air oxidation(WAO) and coagulation and acidic hydrolysis for apramycin wastewater was investigated in this paper. The COD, apramycin, NH^+_4 concentration, and the ratio of BOD_5/COD were analyzed, and the color and odor of the effluent were observed. WAO of apramycin wastewater, without catalyst and with RuO_2/Al_2O_3 and RuO_2-CeO_2/Al_2O_3 catalysts, was carried out at degradation temperature of 200℃ and the total pressure of 4 MPa in a 1 L batch reactor. The result showed that the apramycin removals were respectively 50 2% and 55 0%, COD removals were 40 0% and 46 0%, and the ratio of BOD_5/COD was increased to 0 49 and 0 54 with RuO_2/Al_2O_3 and RuO_2-CeO_2/Al_2O_3 catalysts in catylytic wet air oxidation(CWAO) after the reaction of 150 min. With the pretreatment of coagulation and acidic hydrolysis, COD and apramycin removals were slight decreased, and the ratio of BOD_5/COD was increased to 0 45, and the effluents was not suitable to biological treatment. The color and odor of the wastewater were effectively controlled and the reaction time was obviously shortened with WAO. HO_2· may promote organic compounds oxidized in WAO of the apramycin wastewater. The addition of CeO_2 could promote the activity and stability of RuO_2/Al_2O_3 in WAO of apramycin wastewater.

Late Holocene glacier variations indicated by theδ18O of ice core enclosed gaseous oxygen in the central Tibetan Plateau

Theδ18O of ice core enclosed gaseous oxygen(δ18Obub)has been widely used for climate reconstruction in polar regions.Yet,less is known about its climatic implication in the mountainous glaciers as the lack of continuous record.Here,we present a long-term,continuousδ18Obub record from the Tanggula glacier in the central Tibetan Plateau(TP).Based on comparisons of its variation with regional climate and glacier changes,we found that there was a good correlation between the variation of theδ18Obub in this alpine ice core and the accumulation and melting of this glacier.The more developed the firn layer on glacier surface,the more positive theδ18Obub.Conversely,the more intense the glacier melting,the more negative theδ18Obub.Combined with the chronology of ice core enclosed gases,the glacier variations since the late Holocene in the central TP were reconstructed.The result showed that there were four accumulation and three deficit periods of glaciers in this region.The strongest glacier accumulation period was 1610-300 B.C.,which corresponds to the Neoglaciation.The most significant melting period was the last 100 years,which corresponds to the recent global warming.The Medieval Warm Period was relatively significant in the central TP.However,during the Little Ice Age,there was no significant glacier accumulation in the central TP,and even short deficit events occurred.Comparisons of the late Holocene glacier variation in the central TP with glacier and climate variations in the TP and the Northern Hemisphere showed that it was closely related to the North Atlantic Oscillation.

Effect of C/N Ratio on Nitrogen Removal of A/O-MBBR Process for Treating Mariculture Wastewater

In order to explore the effect of carbon and nitrogen(C/N)ratio on the performance of anoxic/aerobic-moving bed bio-film reactor(A/O-MBBR)process for treating mariculture wastewater,a laboratory-scale A/O-MBBR was conducted.The results showed that the reduction of C/N ratio was conducive to improving the removal efficiency of chemical oxygen demand(COD)and ammonia nitrogen(NH_(4)^(+)-N),while inhibiting that of nitrite nitrogen(NO_(2)^(−)-N)and nitrate nitrogen(NO_(3)^(−)-N).The extracellular polymeric substances(EPS)in anoxic zone were significantly higher in concentration than that in aerobic zone although they both declined with decrease of C/N ratio.The result provides solid support for better controlling the pollution of mariculture wastewater.