期刊文献+
共找到192篇文章
< 1 2 10 >
每页显示 20 50 100
Revisiting the Electron Radius in Light of Length Contraction
1
作者 Julie Marty 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2024年第4期1743-1748,共6页
In previous work, the electron radius was identified as the “actual electron radius.” However, this is more accurately described as the electron radius at rest. This study reexamines the electron with an emphasis on... In previous work, the electron radius was identified as the “actual electron radius.” However, this is more accurately described as the electron radius at rest. This study reexamines the electron with an emphasis on the electron radius under motion, incorporating the effects of length contraction. The findings suggest that the radius is subject to Lorentz contraction, which has interesting implications for relativistic effects at the subatomic level. 展开更多
关键词 Electron Radius Length Contraction Lorentz Factor relativistic effects Subatomic Particles Compton Scattering
下载PDF
Optical spectroscopy of CrO and electronic states of the Cr group metal monoxides
2
作者 张磊 于尧 +1 位作者 马新文 杨杰 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第5期63-75,共13页
All of the experimentally known electronic states of the Cr group metal monoxides(Cr O,Mo O,and WO)have been presented in the paper.The optical spectra of the Cr O molecule have been investigated in the gas phase thro... All of the experimentally known electronic states of the Cr group metal monoxides(Cr O,Mo O,and WO)have been presented in the paper.The optical spectra of the Cr O molecule have been investigated in the gas phase through a combination of the laser-induced fluorescence(LIF)excitation and single-vibronic-level(SVL)emission spectroscopy in the supersonic expansion.The rotational constants of the vibronic electronic states,including X^(5)Π_(-1)(v=0–3),B^(5)Π_(-1)(v=0–10),and B~5Π_1(v=1,5),and the vibrational constants of the spin–orbit components X^(5)Π_(-1,0,1)have been obtained.The molecular constants of the Mo O and WO molecules have been summarized by reviewing the previous spectroscopic studies,and a comprehensive energy level diagram of the Cr group metal monoxides has been constructed.By comparing the electronic configurations,bond lengths,and vibrational frequencies of all the transition metal monoxides in the ground electronic state,the significance of the relativistic effect in the bonding of the 5d transition metal monoxides has been discussed.The related spectroscopic data of the Cr O molecule are available at https://doi.org/10.57760/sciencedb.j00113.00085. 展开更多
关键词 laser-induced fluorescence(LIF) transition metal monoxide electronic state molecular constant relativistic effect
下载PDF
A Precise Description of the Electronic Structures and Spin-Allowed Transition Properties of PF and Its Cation:All-Electron Configuration-Interaction Investigations Including Relativistic Effect 被引量:1
3
作者 李奇楠 赵书涛 +3 位作者 张晓美 罗旺 李瑞 闫冰 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第7期42-46,共5页
The electronic structures of PF and PF+ are calculated with the high-level configuration interaction method. To improve the precision of calculations, the spin-orbit coupling effect, the scalar relativistic effect, a... The electronic structures of PF and PF+ are calculated with the high-level configuration interaction method. To improve the precision of calculations, the spin-orbit coupling effect, the scalar relativistic effect, and the Davidson correction(q-Q) are also considered. The spectroscopic parameters of bound states are derived by the electronic structures of PF and PF+, which are in good accordance with the measurements. The transition dipole moments of spin-allowed transitions are evaluated, and the radiative lifetimes of several A S states of PF and PF+ are obtained. 展开更多
关键词 A Precise Description of the electronic Structures and Spin-Allowed Transition Properties of PF and Its Cation:All-Electron Configuration-Interaction Investigations Including relativistic Effect PF TDM
下载PDF
The effects of relativistic broadening and frequency down-shift on electron-cyclotron emission measurements in EAST
4
作者 刘永 韩翔 +4 位作者 提昂 王嵎民 凌必利 胡立群 高翔 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第4期396-400,共5页
This paper presents a theoretical calculation of the effects of relativistic broadening and frequency down-shift on the electron cyclotron emission measurements for a wide range of plasma parameters in the Experimenta... This paper presents a theoretical calculation of the effects of relativistic broadening and frequency down-shift on the electron cyclotron emission measurements for a wide range of plasma parameters in the Experimental Advanced Superconducting Tokamak (EAST). The calculation is based on the radiation transfer equation, with the reabsorption and reemission processes taken into account. The broadening effect contributes to the radial resolution of the measurement, and the calculation results indicate that it is -2 cm in the case of the central electron temperature 10 keV. A pseudo radial displacement of the obtained electron temperature profile occurs if the relativistic frequency down-shift effect is not taken into account in the determination of the emission layer position. The shift could be a few centimeters as the electron temperature increases, and this effect should be taken into account. 展开更多
关键词 electron cyclotron emission relativistic effect experimental advanced superconducting tokamak
下载PDF
Influence of two-stream relativistic electron beam parameters on the space-charge wave with broad frequency spectrum formation
5
作者 Alexander LYSENKO Iurii VOLK 《Plasma Science and Technology》 SCIE EI CAS CSCD 2018年第3期10-18,共9页
We developed a cubic non-linear theory describing the dynamics of the multiharmonic spacecharge wave(SCW), with harmonics frequencies smaller than the two-stream instability critical frequency, with different relati... We developed a cubic non-linear theory describing the dynamics of the multiharmonic spacecharge wave(SCW), with harmonics frequencies smaller than the two-stream instability critical frequency, with different relativistic electron beam(REB) parameters. The self-consistent differential equation system for multiharmonic SCW harmonic amplitudes was elaborated in a cubic non-linear approximation. This system considers plural three-wave parametric resonant interactions between wave harmonics and the two-stream instability effect. Different REB parameters such as the input angle with respect to focusing magnetic field, the average relativistic factor value, difference of partial relativistic factors, and plasma frequency of partial beams were investigated regarding their influence on the frequency spectrum width and multiharmonic SCW saturation levels. We suggested ways in which the multiharmonic SCW frequency spectrum widths could be increased in order to use them in multiharmonic two-stream superheterodyne free-electron lasers, with the main purpose of forming a powerful multiharmonic electromagnetic wave. 展开更多
关键词 space-charge wave relativistic electron beam two-stream instability PARAMETRIC
下载PDF
Electron beam modeling and analyses of the electric field distribution and space charge effect 被引量:1
6
作者 Yueling Jiang Quanlin Dong 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第5期288-293,共6页
In electron beam technology, one of the critical focuses of research and development efforts is on improving the measurement of electron beam parameters. The parameters are closely related to the generation, emission,... In electron beam technology, one of the critical focuses of research and development efforts is on improving the measurement of electron beam parameters. The parameters are closely related to the generation, emission, operation environment, and role of the electron beam and the corresponding medium. In this study, a field calculation method is proposed, and the electric field intensity distribution on the electron beam’s cross-section is analyzed. The characteristics of beam diffusion caused by the space charge effect are investigated in simulation, and the obtained data are compared with the experiment. The simulation demonstrated that the cross-sectional electric field distribution is primarily affected by the electron beam current, current density distribution, and electron beam propagation speed. 展开更多
关键词 electron beam electric field distribution space charge effect
下载PDF
Forming of Space Charge Wave with Broad Frequency Spectrum in Helical Relativistic Two-Stream Electron Beams 被引量:1
7
作者 A.Lysenko I.Volk +1 位作者 A.Serozhko O.Rybalko 《Chinese Physics Letters》 SCIE CAS CSCD 2017年第7期150-154,共5页
We elaborate a quadratic nonlinear theory of plural interactions of growing space charge wave (SCW) harmonics during the development of the two-stream instability in helical relativistic electron beams. It is found ... We elaborate a quadratic nonlinear theory of plural interactions of growing space charge wave (SCW) harmonics during the development of the two-stream instability in helical relativistic electron beams. It is found that in helical two-stream electron beams the growth rate of the two-stream instability increases with the beam entrance angle. An SCW with the broad frequency spectrum, in which higher harmonics have higher amplitudes, forms when the frequency of the first SCW harmonic is much less than the critical frequency of the two-stream instability. For helical electron beams the spectrum expands with the increase of the beam entrance angle. Moreover, we obtain that utilizing helical electron beams in multiharmonic two-stream superheterodyne free-electron lasers leads to the improvement of their amplification characteristics, the frequency spectrum broadening in multiharmonic signal generation mode, and the reduction of the overall system dimensions. 展开更多
关键词 SCW Forming of Space charge Wave with Broad Frequency Spectrum in Helical relativistic Two-Stream Electron Beams
下载PDF
Investigation of Electronic, Elastic and Dynamic Properties of AgNbO3 and AgTaO3 under Pressure: Ab Initio Calculation
8
作者 Sevket Simsek 《World Journal of Condensed Matter Physics》 2023年第2期57-77,共21页
Based on the density functional theory within the local density approximation (LDA), we studied the electronic, elastic, and dynamic properties of AgNbO<sub>3</sub> and AgTaO<sub>3</sub> compou... Based on the density functional theory within the local density approximation (LDA), we studied the electronic, elastic, and dynamic properties of AgNbO<sub>3</sub> and AgTaO<sub>3</sub> compounds under pressure. The elastic constants, optic and static dielectric constants, born effective charges, and dynamic properties of AgNbO<sub>3</sub> and AgTaO<sub>3</sub> in cubic phase were studied as pressure dependences with the ab initio method. For these compounds, we have also calculated the bulk modulus, Young’s modulus, shear modulus, Vickers hardness, Poisson’s ratio, anisotropy factor, sound velocities, and Debye temperature from the obtained elastic constants. In addition, the brittleness and ductility properties of these compounds were estimated from Poisson’s ratio and Pugh’s rule (G/B). Our calculated values also show that AgNbO<sub>3</sub> (0.37) and AgTaO<sub>3</sub> (0.39) behave as ductile materials and steer away from brittleness by increasing pressure. The calculated values of Vicker hardness for both compounds indicate that they are soft materials. The results show that band gaps, elastic constants, elastic modules, and dynamic properties for both compounds are sensitive to pressure changes. We have also made some comparisons with related experimental and theoretical data that is available in the literature. 展开更多
关键词 electronic Structure Elastic Constants Born Effective charges Dynamic Properties AgNbO3 AgTaO3
下载PDF
Measurement and analyses of the mean effective ion charge in the centre of tokamak discharges
9
作者 郑永真 丁玄同 周艳 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第4期1084-1088,共5页
There are two different definitions for specifying the mean effective ion charge Zeff in plasmas: a) from the Spizer electrical resistivity of the plasma and b) from bremsstrahlung radiation losses of the plasma. I... There are two different definitions for specifying the mean effective ion charge Zeff in plasmas: a) from the Spizer electrical resistivity of the plasma and b) from bremsstrahlung radiation losses of the plasma. In this paper Zeff in the centre of tokamak ohmic discharges has been determined from information on sawtooth-relaxations of the steady state plasma, based on the analysis for the power balance of the plasma electrons in the plasma centre during the period of recovery after the sawtooth crashes. This method is found to supply reliable results for tokamak parameters. While its application requires some efforts in data analysis, it can provide a reliable determination of Zeff, independent of the information from bremsstrahlung radiation losses of the plasma. 展开更多
关键词 mean effective ion charge sawtooth relaxation oower balance of plasma electrons
下载PDF
Ion-focused propagation of a relativistic electron beam in the self-generated plasma in atmosphere
10
作者 Jian-Hong Hao Bi-Xi Xue +3 位作者 Qiang Zhao Fang Zhang Jie-Qing Fan Zhi-Wei Dong 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第6期334-341,共8页
It is known that ion-focused regime(IFR)can effectively suppress expansion of a relativistic electron beam(REB).Using the particle-in-cell Monte Carlo collision(PIC-MCC)method,we numerically investigate the propagatio... It is known that ion-focused regime(IFR)can effectively suppress expansion of a relativistic electron beam(REB).Using the particle-in-cell Monte Carlo collision(PIC-MCC)method,we numerically investigate the propagation of an REB in neutral gas.The results demonstrate that the beam body is charge neutralization and a stable IFR can be established.As a result,the beam transverse dimensions and longitudinal velocities keep close to the initial parameters.We also calculate the charge and current neutralization factors of the REB.Combined with envelope equations,we obtain the variations of beam envelopes,which agree well with the PIC simulations.However,both the energy loss and instabilities of the REB may lead to a low transport efficiency during long-range propagation.It is proved that decreasing the initial pulse length of the REB can avoid the influence of electron avalanche.Using parts of REB pulses to build a long-distance IFR in advance can improve the beam quality of subsequent pulses.Further,a long-distance IFR may contribute to the implementation of long-range propagation of the REB in space environment. 展开更多
关键词 ion-focused regime(IFR) charge neutralization electron avalanche relativistic electron beam(REB) particle-in-cell Monte Carlo collision(PIC-MCC)
下载PDF
Theoretical Study of the Nuclear Charge Distributions of Tin Isotopes
11
作者 刘健 褚衍运 任中洲 《Plasma Science and Technology》 SCIE EI CAS CSCD 2012年第7期614-618,共5页
Nuclear binding energies, charge radii and the charge distributions of even-even tin (Sn) isotopes are calculated using relativistic mean field theory, and the theoretical results are found to be in accordance with ... Nuclear binding energies, charge radii and the charge distributions of even-even tin (Sn) isotopes are calculated using relativistic mean field theory, and the theoretical results are found to be in accordance with the experimental data. The nuclear charge form factors for Sn isotopes are calculated using the phase-shift analysis method. It is shown that the minima of the charge form factors shift upward and inward with an increase in the neutron number of the Sn isotopes. 展开更多
关键词 elastic electron-nucleus scattering relativistic mean-field theory phase-shift analysis method nuclear charge form factor
下载PDF
Semi-quantitative study on the Staebler-Wronski effect of hydrogenated amorphous silicon films prepared with HW-ECR-CVD system 被引量:2
12
作者 丁毅 刘国汉 +5 位作者 陈光华 贺德衍 朱秀红 张文理 田凌 马占杰 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第4期813-817,共5页
The method of numerical simulation is used to fit the relationship between the photoconductivity in films and the illumination time. The generation and process rule of kinds of different charged defect states during i... The method of numerical simulation is used to fit the relationship between the photoconductivity in films and the illumination time. The generation and process rule of kinds of different charged defect states during illumination are revealed. It is found surprisingly that the initial photoconductivity determines directly the total account of photoconductivity degradation of sample. 展开更多
关键词 hydrogenated amorphous silicon Staebler-Wronski effect microwave electron cyclotronresonant chemical vapour deposition charged defects
下载PDF
Axial effect analysis of relativistic electron beam propagation in vacuum 被引量:1
13
作者 Xi WANG Jianhong HAO +6 位作者 Fang ZHANG Qiang ZHAO Jieqing FAN Bixi XUE Lei GAO Chenrui CHAI Zhiwei DONG 《Plasma Science and Technology》 SCIE EI CAS CSCD 2022年第6期116-123,共8页
In geostationary orbits and other quasi-vacuum environments,relativistic electron beams are affected by the initial emittance and space charge effects during the propagation process,resulting in beam quality degradati... In geostationary orbits and other quasi-vacuum environments,relativistic electron beams are affected by the initial emittance and space charge effects during the propagation process,resulting in beam quality degradation.Furthermore,axial energy distribution change in the beam and the axial transient electromagnetic effect caused by current changes in the head and tail regions of the beam also cause the beam to expand and affect its quality.In this study,the particle-in-cell method was used to construct a long-range propagation model of a relativistic electron beam in a vacuum environment.By calculating and simulating the axial energy distribution of the beam and the changes in the transient electromagnetic field,the axial effect during the propagation process was analyzed,and the parameter change law of the effective propagation of the beam was explored.This provided a theoretical reference for a more accurate assessment of the beam quality during propagation. 展开更多
关键词 relativistic electron beam axial energy distribution transient electromagnetic effect particle simulation
下载PDF
Effect of Bohm quantum potential in the propagation of ion–acoustic waves in degenerate plasmas
14
作者 M M Hasan M A Hossen +1 位作者 A Rafat A A Mamun 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第10期222-229,共8页
A theoretical investigation has been carried out on the propagation of the ion–acoustic(IA) waves in a relativistic degenerate plasma containing relativistic degenerate electron and positron fluids in the presence of... A theoretical investigation has been carried out on the propagation of the ion–acoustic(IA) waves in a relativistic degenerate plasma containing relativistic degenerate electron and positron fluids in the presence of inertial non-relativistic light ion fluid. The Korteweg-de Vries(K-dV), modified K-dV(m K-dV), and mixed m K-dV(mm K-dV) equations are derived by adopting the reductive perturbation method. In order to analyze the basic features(phase speed, amplitude, width,etc.) of the IA solitary waves(SWs), the SWs solutions of the K-dV, m K-dV, and mm K-d V are numerically analyzed. It is found that the degenerate pressure, inclusion of the new phenomena like the Fermi temperatures and quantum mechanical effects(arising due to the quantum diffraction) of both electrons and positrons, number densities, etc., of the plasma species remarkably change the basic characteristics of the IA SWs which are found to be formed either with positive or negative potential. The implication of our results in explaining different nonlinear phenomena in astrophysical compact objects, e.g.,white dwarfs, neutron stars, etc., and laboratory plasmas like intense laser–solid matter interaction experiments, etc., are mentioned. 展开更多
关键词 Bohm quantum potential degenerate relativistic plasma electron and positron quantum effect
下载PDF
Relativistic effect on synergy of electron cyclotron and lower hybrid waves on EAST
15
作者 Longhao MA Nong XIANG +2 位作者 Yueheng HUANG Yemin HU Xuemei ZHAI 《Plasma Science and Technology》 SCIE EI CAS CSCD 2021年第12期32-41,共10页
In recent experiments on EAST,the electron temperature at the center can be raised to 9.7 ke V by injecting electron cyclotron(EC)and lower hybrid(LH)waves simultaneously.With such strong core electron heating,the rel... In recent experiments on EAST,the electron temperature at the center can be raised to 9.7 ke V by injecting electron cyclotron(EC)and lower hybrid(LH)waves simultaneously.With such strong core electron heating,the relativistic effect could play an important role in the interactions between the plasma and waves.In order to explore the relativistic effect on synergy between the EC and LH waves on EAST,ray-tracing/Fokker-Planck simulations are conducted to investigate electron heating for a typical discharge with a center electron temperature of 9.7 ke V.It is found that the relativistic effect can cause the EC wave to deposit its power deeper in the plasma core,where the synergy between the EC and LH waves occurs and enhances the absorption of the LH waves.As a result,a high center electron temperature can be achieved. 展开更多
关键词 electron cyclotron waves lower hybrid waves synergy effect relativistic effect
下载PDF
Relativistic and distorted wave effects on Xe 4d electron momentum distributions
16
作者 赵敏福 单旭 +1 位作者 牛姗姗 陈向军 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第9期133-136,共4页
The relativistic and distorted wave effects are investigated for the electron momentum distributions of Xe 4d electrons.The theoretical results show good agreements with the experimental data measured previously with ... The relativistic and distorted wave effects are investigated for the electron momentum distributions of Xe 4d electrons.The theoretical results show good agreements with the experimental data measured previously with electron momentum spectroscopy. The distorted wave effect and the relativistic effect are found to play important roles in the low and high momentum regions, respectively. 展开更多
关键词 relativistic effect distorted wave effect electron momentum distributions
下载PDF
Interpretation of the"Catastrophe"of Quasars on the Basis of New Decisions of the Problem of the Reverse Compton-Effect
17
作者 Nikolay I.Perov Artem Eltsov 《Journal of Physical Science and Application》 2018年第1期55-58,共4页
In a model based on a search with increased accuracy of calculations-four times-of all the roots of the equations for the velocities of electrons in the inverse Compton effect,it is established that for new values of ... In a model based on a search with increased accuracy of calculations-four times-of all the roots of the equations for the velocities of electrons in the inverse Compton effect,it is established that for new values of the roots of the equations(corresponding to the laws of conservation of momentum and energy),the recoil electrons remain ultra-relativistic,according to the authors,allows to eliminate the reverse Compton catastrophe of quasars.The maximum value of the scattering angle of the formed particles was found to explain the thin quasar jets. 展开更多
关键词 QUASAR 3C273 critical temperature inverse COMPTON EFFECT ultra relativistic ELECTRONS limiting angle of expansion
下载PDF
Application of Electrodynamic Theory on Quantum Hall Effect
18
作者 Saleem Iqbal Muhammad Zafar +2 位作者 Farhana Sarwar Syed Mohsin Raza Muhammad Afzal Rana 《World Journal of Condensed Matter Physics》 CAS 2016年第2期87-94,共8页
The quantum electrodynamic (QED) behaviour is studied for quantum Hall effect (QHE). Quantum theory with conjecture of fractional charge quantization (quantum dipole moment), eigenfunctions for fractional charge quant... The quantum electrodynamic (QED) behaviour is studied for quantum Hall effect (QHE). Quantum theory with conjecture of fractional charge quantization (quantum dipole moment), eigenfunctions for fractional charge quantization at the surface of a twisted and twigged electron quanta and above its surface, fractional Fourier transform and Hermite function for fractional charge quantization is developed. With energy eigen value equation for QHE and with energy operator on an eigenfunction of a twisted and twigged electron quanta, the corresponding eigenfunctions are normalized with Schrodinger’s quantum wave mechanical equation for electric scalar and magnetic potentials, respectively (QED behavior). The fractional electric and magnetic fields with their corresponding potentials for the quantized fractional states in semiconducting hereto structures are theoretically calculated. Such mathematical expressions are in good agreement with experimental results of Nobel Prize winning scientists Klitzing, Haroche, Peter and Gruebber. Our results can also explain the hybridized states of orbits with emphasis on sigma and pi bonding and their corresponding antibonding orbitals as a manifestation of electrophilic and nucleophilic chemical reactions. 展开更多
关键词 Fractional charge Quantization Fractional Fourier Transform Quantum Hall Effect Quantum Electrodynamics Electron Quanta String Twisted and Twigged Electron Quanta
下载PDF
ZnIn_(2)S_(4)/MOF-808微球结构S型异质结光催化剂的制备及其光还原CO_(2)性能研究
19
作者 宋明明 宋相海 +2 位作者 刘鑫 周伟强 霍鹏伟 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2023年第8期180-192,共13页
近年来,能源过度消耗导致的温室效应引起人们广泛关注.通过不同半导体材料间能带交错排列构建异质结,用于将CO_(2)转化为高附加值产品是解决该问题的可行方法之一.其中, S型异质结的还原型光催化剂与氧化型光催化剂具有交错带结构,使各... 近年来,能源过度消耗导致的温室效应引起人们广泛关注.通过不同半导体材料间能带交错排列构建异质结,用于将CO_(2)转化为高附加值产品是解决该问题的可行方法之一.其中, S型异质结的还原型光催化剂与氧化型光催化剂具有交错带结构,使各自存在的弱空穴与弱电子复合,极大提高光生载流子的透过率和电荷利用率,有效实现强电子-空穴对分离.在半导体中,ZnIn_(2)S_(4)由于能带结构适当、可见光响应范围广和化学性质稳定等优点,在CO_(2)减排领域表现出较好的性能.但其光吸收能力低、光生载流子分离效率低和光生电子的迁移过程缓慢,这些缺点导致单一ZnIn_(2)S_(4)在光催化领域的应用受限.在S前半导体研究中,MOF-808制备方法简单、比表面积大以及框架结构稳定,是一种理想的催化材料.因此,本文利用MOF-808与ZnIn_(2)S_(4)偶联形成合适的交错带结构,构建S型异质结以提高光催化CO_(2)还原活性.本文采用原位合成法设计由三维花球ZnIn_(2)S_(4)和八面体MOF-808组成的阶跃式异质结(S型异质结).通过调控反应温度与时间设计不同尺寸的ZnIn_(2)S_(4)微球,并探索制备条件对光催化CO_(2)还原活性的影响.结果表明,当ZnIn_(2)S_(4)微球直径为6μm时,与MOF-808偶联所构建的复合光催化剂的CO_(2)还原活性最高.并且通过调控MOF-808比例,制备的S型异质结ZM6-15%光催化剂的CO产率在辐照4 h后达到8.21μmol g^(-1)h^(-1),分为别MOF-808 (1.03μmol g^(-1)h^(-1))和ZnIn_(2)S_(4)(0.84μmol g-1h-1)的8倍和10倍左右,明显提高了光催化CO_(2)还原性能.X射线衍射、扫描电镜、透射电镜和X射线光电子能谱(XPS)等研究结果表明,ZnIn_(2)S_(4)微球表面被MOF-808八面体粘附,这种紧密粘附的结构有利于ZnIn_(2)S_(4)与MOF-808之间载流子的转移和分离,从而提高光催化CO_(2)的还原效果.此外,电子顺磁共振和紫外光电子能谱等测试结果表明ZnIn_(2)S_(4)中存在弱空穴,MOF-808中存在弱电子.在光照下,光生电子通过界面接触快速从MOF-808导带中迁移到ZnIn_(2)S_(4)价带中并被消耗,为光生电子提供快速传输途径,提高了电子利用率.最终,MOF-808中存在光生空穴具有最高的氧化能力,ZnIn_(2)S_(4)中存在光生电子具有最高的还原能力.原位XPS测试与密度泛函理论计算结果进一步证明了ZnIn_(2)S_(4)与MOF-808之间的S型电荷转移机制.原位红外技术分析结果表明,S型异质结ZnIn_(2)S_(4)/MOF-808光催化剂通过Carbene途径将CO_(2)光催化还原为CO (CO—→CO_(2)*→COOH*→CO*→CO).综上,本文为合理设计S型异质结光催化剂,以实现高效光催化CO_(2)还原活性提供了新思路. 展开更多
关键词 S型异质结 形态作用 光催化CO_(2)还原 光生电子与空穴 电荷转移机制
下载PDF
Regularly Tuning Quantum Interference in Single-Molecule Junctions through Systematic Substitution of Side Groups with Varied Electron Effects
20
作者 Xianjing Xie Yirong Zhang +3 位作者 Junrui Zhang Xingyuan Cui Wei Liu Xunshan Liu 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2024年第11期1217-1222,共6页
Investigating the quantum interference effect in single molecules is essential to comprehensively understand the underlying mechanism of single-molecule charge transport.In this study,we employed the mother molecule m... Investigating the quantum interference effect in single molecules is essential to comprehensively understand the underlying mechanism of single-molecule charge transport.In this study,we employed the mother molecule m-OPE and introduced a series of side groups with various electronic effects at the 2-position of the central phenyl ring,creating four daughter m-OPE derivatives.The single molecular conductivities of these molecule wires were measured using the scanning tunneling microscope breaking junction technique.Our findings demonstrate that the substitutions regularly modulate the destructive quantum interference occurring within the m-OPE molecules.By combining optical and electrochemical investigations,along with density functional theory computations,we discover that the conductivity of the molecules corresponds to the electron-donating/withdrawing ability of the substituents.Specifically,by adjusting the electron structures of the molecular backbone,we can systematically tailor the destructive quantum interference in the m-OPE molecules. 展开更多
关键词 Quantum interference Single-molecule junctions Electron effect substituents charge transport Molecular devices
原文传递
上一页 1 2 10 下一页 到第
使用帮助 返回顶部