The tectonic development of the Tarim block has experienced four stages, i. e. Earth's core accretion and block formation in the Precambrian, margin splitting, opening-closing and piecing up in the Early Palaeozoi...The tectonic development of the Tarim block has experienced four stages, i. e. Earth's core accretion and block formation in the Precambrian, margin splitting, opening-closing and piecing up in the Early Palaeozoic, rift formation and plate unification in the Late Palaeozoic, and basin-mountain coupling and landform shaping in the Meso-Cenozoic, forming six ore-bearing formations and ore deposits of various genetic types in the Tianshan Mountains, Kunlun Mountains and Altun Mountains. In the peripheral areas of Tarim there are four giant intercontinental metallogenic belts passing through, the Central Tianshan and southwestern Tianshan belts in the former USSR and the Qinling-Qilian-Kunlun and Palaeo-Tethys belts in China. According to the macro-analysis on the nearly one thousand known deposits (occurrences) and geophysical-geochemical anomalies, and the information from reconnaissance in some areas, the region has very good prospects for mineral resources. Some of the metallogenic belts may well become the reserve bases for exploration of mineral resources in China.展开更多
In the Precambrian System of the Yangtze and Cathaysian plates six ore-bearing formations can be identified: the Cu-Pb-Zn-bearing formations in volcanic rocks of marine facies of the Neoarchean-Paleoproterozoic, Cu-Au...In the Precambrian System of the Yangtze and Cathaysian plates six ore-bearing formations can be identified: the Cu-Pb-Zn-bearing formations in volcanic rocks of marine facies of the Neoarchean-Paleoproterozoic, Cu-Au-bearing formations and Pb-Zn-bearing formations in volcanic rocks of marine facies of the Mesoproterozoic, Pb-Zn-bearing formations in volcaniclastic rock and carbonate rock of the Neoproterozoic, Fe-Mn-bearing formations in the volcaniclastic rock of the Neoproterozoic, and Ni-Cr-serpentine-bearing formations in ophiolite and ultrabasic rock of the Meso- and Neoproterozoic. They were mostly formed in the marginal rift valleys of the Yangtze and Cathaysian plates, where occur stratabound and stratiform ore deposits, thermal deposits and porphyry polymetallic deposits. The six regions with ore-bearing formations have good prospects for ore deposits.展开更多
A molecular [Ru(bda)]-type(bda = 2,2’-bipyridine-6,6’-dicarboxylate) water oxidation catalyst with 4-vinylpyridine as the axial ligand(Complex 1) was immobilized or co-immobilized with 1-(trifluoromethyl)-4-vinylben...A molecular [Ru(bda)]-type(bda = 2,2’-bipyridine-6,6’-dicarboxylate) water oxidation catalyst with 4-vinylpyridine as the axial ligand(Complex 1) was immobilized or co-immobilized with 1-(trifluoromethyl)-4-vinylbenzene(3 F) or styrene(St) blocking units on the surface of glassy carbon(GC) electrodes by electrochemical polymerization, in order to prepare the corresponding poly-1@GC, poly-1+P3 F@GC, and poly-1+PSt@GC functional electrodes. Kinetic measurements of the electrode surface reaction revealed that [Ru(bda)] triggers the O–O bond formation via(1) the radical coupling interaction between the two metallo-oxyl radicals(I2 M) in the homo-coupling polymer(poly-1), and(2) the water nucleophilic attack(WNA) pathway in poly-1+P3 F and poly-1+PSt copolymers. The comparison of the three electrodes revealed that the second coordination sphere of the water oxidation catalysts plays vital roles in stabilizing their reaction intermediates, tuning the O–O bond formation pathways and improving the water oxidation reaction kinetics without changing the first coordination structures.展开更多
The Dongfang1-1 gas field(DF1-1)in the Yinggehai Basin is currently the largest offshore self-developed gas field in China and is rich in oil and gas resources.The second member of the Pliocene Yinggehai Formation(YGH...The Dongfang1-1 gas field(DF1-1)in the Yinggehai Basin is currently the largest offshore self-developed gas field in China and is rich in oil and gas resources.The second member of the Pliocene Yinggehai Formation(YGHF)is the main gas-producing formation and is composed of various sedimentary types;however,a clear understanding of the sedimentary types and development patterns is lacking.Here,typical lithofacies,logging facies and seismic facies types and characteristics of the YGHF are identified based on high-precision 3D seismic data combined with drilling,logging,analysis and testing data.Based on 3D seismic interpretation and attribute analysis,the origin of high-amplitude reflections is clarified,and the main types and evolution characteristics of sedimentary facies are identified.Taking gas formation upper II(IIU)as an example,the plane distribution of the delta front and bottom current channel is determined;finally,a comprehensive sedimentary model of the YGHF second member is established.This second member is a shallowly buried“bright spot”gas reservoir with weak compaction.The velocity of sandstone is slightly lower than that of mudstone,and the reflection has medium amplitude when there is no gas.The velocity of sandstone decreases considerably after gas accumulation,resulting in an increase in the wave impedance difference and high-amplitude(bright spot)reflection between sandstone and mudstone;the range of high amplitudes is consistent with that of gas-bearing traps.The distribution of gas reservoirs is obviously controlled by dome-shaped diapir structural traps,and diapir faults are channels through which natural gas from underlying Miocene source rocks can enter traps.The study area is a delta front deposit developed on a shallow sea shelf.The lithologies of the reservoir are mainly composed of very fine sand and coarse silt,and a variety of sedimentary structural types reflect a shallow sea delta environment;upward thickening funnel type,strong toothed bell type and toothed funnel type logging facies are developed.In total,4 stages of delta front sand bodies(corresponding to progradational reflection seismic facies)derived from the Red River and Blue River in Vietnam have developed in the second member of the YGHF;these sand bodies are dated to 1.5 Ma and correspond to four gas formations.During sedimentation,many bottom current channels(corresponding to channel fill seismic facies)formed,which interacted with the superposed progradational reflections.When the provenance supply was strong in the northwest,the area was dominated by a large set of delta front deposits.In the period of relative sea level rise,surface bottom currents parallel to the coastline were dominant,and undercutting erosion was obvious,forming multistage superimposed erosion troughs.Three large bottom current channels that developed in the late sedimentary period of gas formation IIU are the most typical.展开更多
文摘The tectonic development of the Tarim block has experienced four stages, i. e. Earth's core accretion and block formation in the Precambrian, margin splitting, opening-closing and piecing up in the Early Palaeozoic, rift formation and plate unification in the Late Palaeozoic, and basin-mountain coupling and landform shaping in the Meso-Cenozoic, forming six ore-bearing formations and ore deposits of various genetic types in the Tianshan Mountains, Kunlun Mountains and Altun Mountains. In the peripheral areas of Tarim there are four giant intercontinental metallogenic belts passing through, the Central Tianshan and southwestern Tianshan belts in the former USSR and the Qinling-Qilian-Kunlun and Palaeo-Tethys belts in China. According to the macro-analysis on the nearly one thousand known deposits (occurrences) and geophysical-geochemical anomalies, and the information from reconnaissance in some areas, the region has very good prospects for mineral resources. Some of the metallogenic belts may well become the reserve bases for exploration of mineral resources in China.
文摘In the Precambrian System of the Yangtze and Cathaysian plates six ore-bearing formations can be identified: the Cu-Pb-Zn-bearing formations in volcanic rocks of marine facies of the Neoarchean-Paleoproterozoic, Cu-Au-bearing formations and Pb-Zn-bearing formations in volcanic rocks of marine facies of the Mesoproterozoic, Pb-Zn-bearing formations in volcaniclastic rock and carbonate rock of the Neoproterozoic, Fe-Mn-bearing formations in the volcaniclastic rock of the Neoproterozoic, and Ni-Cr-serpentine-bearing formations in ophiolite and ultrabasic rock of the Meso- and Neoproterozoic. They were mostly formed in the marginal rift valleys of the Yangtze and Cathaysian plates, where occur stratabound and stratiform ore deposits, thermal deposits and porphyry polymetallic deposits. The six regions with ore-bearing formations have good prospects for ore deposits.
文摘A molecular [Ru(bda)]-type(bda = 2,2’-bipyridine-6,6’-dicarboxylate) water oxidation catalyst with 4-vinylpyridine as the axial ligand(Complex 1) was immobilized or co-immobilized with 1-(trifluoromethyl)-4-vinylbenzene(3 F) or styrene(St) blocking units on the surface of glassy carbon(GC) electrodes by electrochemical polymerization, in order to prepare the corresponding poly-1@GC, poly-1+P3 F@GC, and poly-1+PSt@GC functional electrodes. Kinetic measurements of the electrode surface reaction revealed that [Ru(bda)] triggers the O–O bond formation via(1) the radical coupling interaction between the two metallo-oxyl radicals(I2 M) in the homo-coupling polymer(poly-1), and(2) the water nucleophilic attack(WNA) pathway in poly-1+P3 F and poly-1+PSt copolymers. The comparison of the three electrodes revealed that the second coordination sphere of the water oxidation catalysts plays vital roles in stabilizing their reaction intermediates, tuning the O–O bond formation pathways and improving the water oxidation reaction kinetics without changing the first coordination structures.
基金The National Natural Science Foundation of China’s Major Project“Research on Geophysical Theories and Methods of Unconventional Oil and Gas Exploration and Development”,Task I:“China’s Tight Oil and Gas Reservoir Geological Characteristics,Classification and Typical Geological Model Establishment”under contract No.41390451。
文摘The Dongfang1-1 gas field(DF1-1)in the Yinggehai Basin is currently the largest offshore self-developed gas field in China and is rich in oil and gas resources.The second member of the Pliocene Yinggehai Formation(YGHF)is the main gas-producing formation and is composed of various sedimentary types;however,a clear understanding of the sedimentary types and development patterns is lacking.Here,typical lithofacies,logging facies and seismic facies types and characteristics of the YGHF are identified based on high-precision 3D seismic data combined with drilling,logging,analysis and testing data.Based on 3D seismic interpretation and attribute analysis,the origin of high-amplitude reflections is clarified,and the main types and evolution characteristics of sedimentary facies are identified.Taking gas formation upper II(IIU)as an example,the plane distribution of the delta front and bottom current channel is determined;finally,a comprehensive sedimentary model of the YGHF second member is established.This second member is a shallowly buried“bright spot”gas reservoir with weak compaction.The velocity of sandstone is slightly lower than that of mudstone,and the reflection has medium amplitude when there is no gas.The velocity of sandstone decreases considerably after gas accumulation,resulting in an increase in the wave impedance difference and high-amplitude(bright spot)reflection between sandstone and mudstone;the range of high amplitudes is consistent with that of gas-bearing traps.The distribution of gas reservoirs is obviously controlled by dome-shaped diapir structural traps,and diapir faults are channels through which natural gas from underlying Miocene source rocks can enter traps.The study area is a delta front deposit developed on a shallow sea shelf.The lithologies of the reservoir are mainly composed of very fine sand and coarse silt,and a variety of sedimentary structural types reflect a shallow sea delta environment;upward thickening funnel type,strong toothed bell type and toothed funnel type logging facies are developed.In total,4 stages of delta front sand bodies(corresponding to progradational reflection seismic facies)derived from the Red River and Blue River in Vietnam have developed in the second member of the YGHF;these sand bodies are dated to 1.5 Ma and correspond to four gas formations.During sedimentation,many bottom current channels(corresponding to channel fill seismic facies)formed,which interacted with the superposed progradational reflections.When the provenance supply was strong in the northwest,the area was dominated by a large set of delta front deposits.In the period of relative sea level rise,surface bottom currents parallel to the coastline were dominant,and undercutting erosion was obvious,forming multistage superimposed erosion troughs.Three large bottom current channels that developed in the late sedimentary period of gas formation IIU are the most typical.
