Long-term permeability experiments have indicated that sorption-induced swelling can switch from internal to bulk depending on the evolutive sorption status.However,this sorption swelling switch mechanism has not been...Long-term permeability experiments have indicated that sorption-induced swelling can switch from internal to bulk depending on the evolutive sorption status.However,this sorption swelling switch mechanism has not been considered in current analytical permeability models.This study introduces a normalized sorption non-equilibrium index(SNEI)to characterize the sorption status,quantify the dynamical variations of matrix swelling accumulation and internal swelling partition,and formulate the sorption swelling switch model.The incorporation of this index into the extended total effective stress concept leads to an analytical transient coal permeability model.Model results show that the sorption swelling switch itself results in the permeability switch under stress-constrained conditions,while the confined bulk swelling suppresses the permeability recovery to the continuous reduction under displacement-constrained conditions.Model verifications show that current experimental observations correspond to the early stages of the transient process,and they could be extended to the whole process with these models.This study demonstrates the importance of the sorption swelling switch in determining permeability evolution using simple boundary conditions.It provides new insights into experimentally revealing the sorption swelling switch in the future,and underscores the requirement of a rigorous model for complex coupled processes in large-scale coal seams.展开更多
The co-liquefaction of lignite coal and used tire was performed in a 250-ml batch reactor, in supercritical water under a nitrogen atmosphere to investigate the effects of temperature (380-440℃), water/feedstock rati...The co-liquefaction of lignite coal and used tire was performed in a 250-ml batch reactor, in supercritical water under a nitrogen atmosphere to investigate the effects of temperature (380-440℃), water/feedstock ratio (4/1-10/1 (wt./wt.)) and the % used tire content in the feedstock (0-100 wt.%) on the conversion efficiency, liquid yield and oil composition attained. The maximum conversion and oil yield were 67 and 50%, respectively, obtained at 400℃ at 1 min, with water/feedstock ratio of 10/1 and 80% used tire content. The distillation characteristics of the oil products, analyzed by simulated distillation gas chromatography, revealed that the oil composition depended significantly on the reaction temperature. The co-liquefaction of coal and used tire yielded a synergistically increased level of oil production. Moreover, the total conversion level obtained with co-liquefaction alone was almost equal to those obtained in the presence of either Fe2O3 or NiMo as catalysts, under the same conditions. Therefore, supercritical water is a good medium for the dissolution of the volatile matter from a coal and used tire matrix.展开更多
Based on the two temporal TM images of 1995 and 2001 of one coal mining area,analyzed the variety information of the coal mining area.Relative registration were done with the two images firstly,then cut out the study ...Based on the two temporal TM images of 1995 and 2001 of one coal mining area,analyzed the variety information of the coal mining area.Relative registration were done with the two images firstly,then cut out the study area for experimental data,classi- fied the coal mining area using supervised classification in ERDAS,the coal mining area will be divided into five categories as water body,agricultural land,construction land,coal mining area and other land.Make land use change matrix,the result shows that in the six years of 1995 to 2001,the change of the utilize of the land is greatly,the main represent is showed as follows: the area of water body,agricultural land and coal mining land had con- tinually increased,on the contrary,construction area and other decreased.The percen- tage speed of the construction land is the biggest,the value reach-1.08%.The main rea- sons is that with the exploitation of the coal mine and the reclaim of the land,the exploita- tion of the coal mining land make the agricultural land and construction area convert into coal mining land,on the other hand with the backfill of the subsided waterlogged land and the reclaim of the subsided land make the coal mining land convert into agricultural land.展开更多
Coal cities are the main part of the resource-based cities in China, and the benign development of coal cities' spatial structure has a direct impact on these cities' future economic and social development, as...Coal cities are the main part of the resource-based cities in China, and the benign development of coal cities' spatial structure has a direct impact on these cities' future economic and social development, as well as the urban residents' welfare. Land use fragmentation is the most typical morphological characteristic of the coal city's spatial structure development. In this paper, Pingdingshan City of Henan Province in China is taken as an example. Through empirical analysis, the urban spatial structure development processes of a typical coal resource-based city in its mature period are illustrated, and the formation reasons and potential mechanism behind coal city land use fragmentation are explored, and the measurement method of land use fragmentation degree of the coal city is put forward. On the above basis, the appropriate adjustment strategies and methods aimed at the coal city spatial structure are found out and given. This study is a good guideline and reference for the spatial structure planning and land use planning of the coal city during the mature and declining period, which is of great help to the sustainable development and industrial structure transformation of the coal city. It also has certain reference significance for the coal city in the growth period.展开更多
In this paper, the authors point out that the Creativity is an inevitable request in solving engineering and technological problems and that the coal beneficiation technology with air dense medium fluidized bed is a r...In this paper, the authors point out that the Creativity is an inevitable request in solving engineering and technological problems and that the coal beneficiation technology with air dense medium fluidized bed is a result of reversal thinking, and its forming mechanism is the use of other things for reference and the transplantation.展开更多
Reclamations of dumps in the Most Basin that is located in the North Bohemia consist of restoration of extremely unfavourable properties of rocks that are poured down onto the dump body. These rocks come from the surf...Reclamations of dumps in the Most Basin that is located in the North Bohemia consist of restoration of extremely unfavourable properties of rocks that are poured down onto the dump body. These rocks come from the surface layer and the layer where coal bed is present. Sands, clay sands and kaolin (illitic clays) are the main components that occur in the material. Other components are predominantly organic (coal) mass, siderite and pyrite. This report briefly summarizes the history and present of ore, non-metallic and coal mining in the region and addresses in detail the issue of moderating the consequences of mining, which is one of the principal activities of the Research Institute for Brown Coal, j.s.c. in Most. The concept of landscape reclamation in the largest dumps after mining ends, the technical reclamation methodology and the well considered use of fertilizable soil are main results presented in this article.展开更多
This paper is based on the existing status and development prediction of Fujian power industry, and describes that the structure of energy sources for generating power which will mainly use coal, will not be changed i...This paper is based on the existing status and development prediction of Fujian power industry, and describes that the structure of energy sources for generating power which will mainly use coal, will not be changed in the 2010s and 2020s in Fujian Province. In order to meet the requirements of high efficiency and envirofimental protection, the usage of clean coal technologies for power generating will be an inevitable option and the technologies will occupy the important position in Fujian power industry. This paper puts forward the staged targets and measures of developing and utilizing clean coal technologies, suggests that all government depotments related should give support and guarantee in policies and conditions, and welcome technical and economic cooperation at home and abroad, which is good for co-development of both parties.展开更多
The Internet is believed to bring more technological dividends to vulnerable farmers during the green agriculture transformation.However,this is different from the theory of skill-biased technological change,which emp...The Internet is believed to bring more technological dividends to vulnerable farmers during the green agriculture transformation.However,this is different from the theory of skill-biased technological change,which emphasizes that individuals with higher levels of human capital and more technological endowments benefit more.This study investigates the effects of Internet use on farmers'adoption of integrated pest management(IPM),theoretically and empirically,based on a dataset containing 1015 farmers in China's Shandong Province.By exploring the perspective of rational inattention,the reasons for the heterogeneity of the effects across farmers with different endowments,i.e.,education and land size,are analyzed.The potential endogeneity issues are addressed using the endogenous switching probit model.The results reveal that:(1)although Internet use significantly positively affects farmers'adoption of IPM,vulnerable farmers do not benefit more from it.Considerable selection bias leads to an overestimation of technological dividends for vulnerable farmers;(2)different sources of technology information lead to the difference in the degree of farmers'rational inattention toward Internet information,which plays a crucial role in the heterogeneous effect of Internet use;and(3)excessive dependence on strong-tie social network information sources entraps vulnerable farmers in information cocoons,hindering their ability to reap the benefits of Internet use fully.Therefore,it is essential to promote services geared towards elderly-oriented Internet agricultural technology information and encourage farmers with strong Internet utilization skills to share technology information with other farmers actively.展开更多
Condition assessment is one of the most significant techniques of the equipment’s health management.Also,in PHM methodology cycle,which is a developed form of CBM,condition assessment is the most important step of th...Condition assessment is one of the most significant techniques of the equipment’s health management.Also,in PHM methodology cycle,which is a developed form of CBM,condition assessment is the most important step of this cycle.In this paper,the remaining useful life of the equipment is calculated using the combination of sensor information,determination of degradation state and forecasting the proposed health index.The combination of sensor information has been carried out using a new approach to determining the probabilities in the Dempster-Shafer combination rules and fuzzy c-means clustering method.Using the simulation and forecasting of extracted vibration-based health index by autoregressive Markov regime switching(ARMRS)method,final health state is determined and the remaining useful life(RUL)is estimated.In order to evaluate the model,sensor data provided by FEMTO-ST Institute have been used.展开更多
DNA is an attractive biomaterial for constructing nanomachines and nanomaterials owing to their self-recognition and self-assembly properties.In addition to the well-known double helical structures,DNA molecules can a...DNA is an attractive biomaterial for constructing nanomachines and nanomaterials owing to their self-recognition and self-assembly properties.In addition to the well-known double helical structures,DNA molecules can also form a variety of unusual structures like hairpins,triplexes and quadruplexes.These unusual DNAs sometimes have advantages over double helical DNAs in constructing nanomachines such as enhanced thermodynamic stability and higher sensitivity to external stimuli,which made them as promising motifs in recenttwo decades.Regardless of how complicated DNA-based nanomachines are,the fundamental concept in these nanomachines is based on a proper design and usage of DNA molecular switch.Among the reported DNA molecular switches,pH-controlled systems show great potentials in drug delivery and cellular pH sensing.Up to now,most of the reported pH-controlled molecular switches used i-motif or triplex DNAs.However,owing to the relatively long sequence requirement for the formation of i-motif and triplex DNAs,an invading DNA strand needs to be added to activate the molecular switch,and thus DNA wastes will be generated into the system and a full structural conversion will usually take a relatively long time of minutes to hours.To overcome the disadvantages of DNA waste generation and slow kinetics,molecular switches using smaller-size,thermodynamically stable and pH-sensible unusual DNA structures will have the advantages of easier manipulation and faster kinetics.Recently,we discovered a new type of unusual DNA structure called the minidumbbell(MDB)which is formed by a single-strand 8-nucleotide sequence.The MDB is composed of two type II tetraloops in which the first and fourth loop residues form loop-closing base pairs,the second loop residues fold into the minor groove to form base-base stacking or mispairing interactions,and the third loop residues stack on their nearby loop-closing base pairs.In particular,the MDB formed by a sequence containing two CCTG repeats has a relatively low melting temperature(Tm)of^22℃at pH 7.0,whereas its Tm can be significantly increased to^46℃at pH 5.0 due to the formation of a three hydrogen bond hemiprotonated C+·C mispair in the minor groove.This MDB,when combined with its complementary sequence,shows instant and complete structural conversions when the pH switches between 5.0 and 7.0 without using an invading DNA strand,serving as a simple and efficient pH-controlled molecular switch.In order to allow the incorporation of fluorophores to the two termini of the MDB,we aim to design a thermodynamically more stable MDB structure in this study.Through a rational design by introducing hydrophobic interactions to the MDB formed by the sequence containing two CCTG repeats at pH 5.0,we obtained an MDB structure with a record-high Tm of^62℃.Furthermore,this MDB was found to exist stably in the presence of 5’and 3’-overhanging residues,revealing its capability of being attached with fluorophores or other functional groups,and thus making it potentially a versatile pH-controlled molecular switch for designing nanomachines and nanomaterials.展开更多
Broad-band all-optical wavelength conversion of differential phase-shift keyed (DPSK) signal is experimentally demonstrated. This scheme is composed of a one-bit delay interferometer demodulation stage followed by a...Broad-band all-optical wavelength conversion of differential phase-shift keyed (DPSK) signal is experimentally demonstrated. This scheme is composed of a one-bit delay interferometer demodulation stage followed by a semiconductor optical amplifier (SOA) based nonlinear polarization switch. A wavelength converter for the 10 G b/s DPSK signal is presented, which has a wide wavelength range of more than 30 nm. The converted signals experience small power penalties less than 1.4 dB compared with the original signal, at a bit error rate of 10-9. Additionally, the optical spectra, the measured waveforms and the open eye diagrams of the converted signals show a high quality wavelength conversion performance.展开更多
We propose and fabricate a vertically integrated thermo-optic waveguide switch. It controls the optical path between two vertically stacked waveguides using the thermo-optic effect of optical polymer. The measured cro...We propose and fabricate a vertically integrated thermo-optic waveguide switch. It controls the optical path between two vertically stacked waveguides using the thermo-optic effect of optical polymer. The measured crosstalk is less than -10 dB.展开更多
基金supported by the Australian Research Council(Grant No.DP200101293)the National Natural Science Foundation of China(Grant No.42202286)the Zhejiang Collaborative Innovation Center for Prevention and Control of Mountain Geological Hazards(Grant No.PCMGH-2017-Z-02).
文摘Long-term permeability experiments have indicated that sorption-induced swelling can switch from internal to bulk depending on the evolutive sorption status.However,this sorption swelling switch mechanism has not been considered in current analytical permeability models.This study introduces a normalized sorption non-equilibrium index(SNEI)to characterize the sorption status,quantify the dynamical variations of matrix swelling accumulation and internal swelling partition,and formulate the sorption swelling switch model.The incorporation of this index into the extended total effective stress concept leads to an analytical transient coal permeability model.Model results show that the sorption swelling switch itself results in the permeability switch under stress-constrained conditions,while the confined bulk swelling suppresses the permeability recovery to the continuous reduction under displacement-constrained conditions.Model verifications show that current experimental observations correspond to the early stages of the transient process,and they could be extended to the whole process with these models.This study demonstrates the importance of the sorption swelling switch in determining permeability evolution using simple boundary conditions.It provides new insights into experimentally revealing the sorption swelling switch in the future,and underscores the requirement of a rigorous model for complex coupled processes in large-scale coal seams.
文摘The co-liquefaction of lignite coal and used tire was performed in a 250-ml batch reactor, in supercritical water under a nitrogen atmosphere to investigate the effects of temperature (380-440℃), water/feedstock ratio (4/1-10/1 (wt./wt.)) and the % used tire content in the feedstock (0-100 wt.%) on the conversion efficiency, liquid yield and oil composition attained. The maximum conversion and oil yield were 67 and 50%, respectively, obtained at 400℃ at 1 min, with water/feedstock ratio of 10/1 and 80% used tire content. The distillation characteristics of the oil products, analyzed by simulated distillation gas chromatography, revealed that the oil composition depended significantly on the reaction temperature. The co-liquefaction of coal and used tire yielded a synergistically increased level of oil production. Moreover, the total conversion level obtained with co-liquefaction alone was almost equal to those obtained in the presence of either Fe2O3 or NiMo as catalysts, under the same conditions. Therefore, supercritical water is a good medium for the dissolution of the volatile matter from a coal and used tire matrix.
基金the Ministry of Education of Doctor Spot Foundation(20050147002)College of Liaoning Province Emphasis Laboratory Item(20060370)
文摘Based on the two temporal TM images of 1995 and 2001 of one coal mining area,analyzed the variety information of the coal mining area.Relative registration were done with the two images firstly,then cut out the study area for experimental data,classi- fied the coal mining area using supervised classification in ERDAS,the coal mining area will be divided into five categories as water body,agricultural land,construction land,coal mining area and other land.Make land use change matrix,the result shows that in the six years of 1995 to 2001,the change of the utilize of the land is greatly,the main represent is showed as follows: the area of water body,agricultural land and coal mining land had con- tinually increased,on the contrary,construction area and other decreased.The percen- tage speed of the construction land is the biggest,the value reach-1.08%.The main rea- sons is that with the exploitation of the coal mine and the reclaim of the land,the exploita- tion of the coal mining land make the agricultural land and construction area convert into coal mining land,on the other hand with the backfill of the subsided waterlogged land and the reclaim of the subsided land make the coal mining land convert into agricultural land.
基金Sponsored by National Natural Science Foundation of China(51478389)
文摘Coal cities are the main part of the resource-based cities in China, and the benign development of coal cities' spatial structure has a direct impact on these cities' future economic and social development, as well as the urban residents' welfare. Land use fragmentation is the most typical morphological characteristic of the coal city's spatial structure development. In this paper, Pingdingshan City of Henan Province in China is taken as an example. Through empirical analysis, the urban spatial structure development processes of a typical coal resource-based city in its mature period are illustrated, and the formation reasons and potential mechanism behind coal city land use fragmentation are explored, and the measurement method of land use fragmentation degree of the coal city is put forward. On the above basis, the appropriate adjustment strategies and methods aimed at the coal city spatial structure are found out and given. This study is a good guideline and reference for the spatial structure planning and land use planning of the coal city during the mature and declining period, which is of great help to the sustainable development and industrial structure transformation of the coal city. It also has certain reference significance for the coal city in the growth period.
文摘In this paper, the authors point out that the Creativity is an inevitable request in solving engineering and technological problems and that the coal beneficiation technology with air dense medium fluidized bed is a result of reversal thinking, and its forming mechanism is the use of other things for reference and the transplantation.
基金supported by project QJ1520307 entitled“Sustainable Forms of Management in an Anthropogenically Burdened Region.”financial support from state budget resources through the KUS program,Ministry of Agriculture of the Czech Republic.
文摘Reclamations of dumps in the Most Basin that is located in the North Bohemia consist of restoration of extremely unfavourable properties of rocks that are poured down onto the dump body. These rocks come from the surface layer and the layer where coal bed is present. Sands, clay sands and kaolin (illitic clays) are the main components that occur in the material. Other components are predominantly organic (coal) mass, siderite and pyrite. This report briefly summarizes the history and present of ore, non-metallic and coal mining in the region and addresses in detail the issue of moderating the consequences of mining, which is one of the principal activities of the Research Institute for Brown Coal, j.s.c. in Most. The concept of landscape reclamation in the largest dumps after mining ends, the technical reclamation methodology and the well considered use of fertilizable soil are main results presented in this article.
文摘This paper is based on the existing status and development prediction of Fujian power industry, and describes that the structure of energy sources for generating power which will mainly use coal, will not be changed in the 2010s and 2020s in Fujian Province. In order to meet the requirements of high efficiency and envirofimental protection, the usage of clean coal technologies for power generating will be an inevitable option and the technologies will occupy the important position in Fujian power industry. This paper puts forward the staged targets and measures of developing and utilizing clean coal technologies, suggests that all government depotments related should give support and guarantee in policies and conditions, and welcome technical and economic cooperation at home and abroad, which is good for co-development of both parties.
基金the National Social Science Fund of China(20CGL027)。
文摘The Internet is believed to bring more technological dividends to vulnerable farmers during the green agriculture transformation.However,this is different from the theory of skill-biased technological change,which emphasizes that individuals with higher levels of human capital and more technological endowments benefit more.This study investigates the effects of Internet use on farmers'adoption of integrated pest management(IPM),theoretically and empirically,based on a dataset containing 1015 farmers in China's Shandong Province.By exploring the perspective of rational inattention,the reasons for the heterogeneity of the effects across farmers with different endowments,i.e.,education and land size,are analyzed.The potential endogeneity issues are addressed using the endogenous switching probit model.The results reveal that:(1)although Internet use significantly positively affects farmers'adoption of IPM,vulnerable farmers do not benefit more from it.Considerable selection bias leads to an overestimation of technological dividends for vulnerable farmers;(2)different sources of technology information lead to the difference in the degree of farmers'rational inattention toward Internet information,which plays a crucial role in the heterogeneous effect of Internet use;and(3)excessive dependence on strong-tie social network information sources entraps vulnerable farmers in information cocoons,hindering their ability to reap the benefits of Internet use fully.Therefore,it is essential to promote services geared towards elderly-oriented Internet agricultural technology information and encourage farmers with strong Internet utilization skills to share technology information with other farmers actively.
文摘Condition assessment is one of the most significant techniques of the equipment’s health management.Also,in PHM methodology cycle,which is a developed form of CBM,condition assessment is the most important step of this cycle.In this paper,the remaining useful life of the equipment is calculated using the combination of sensor information,determination of degradation state and forecasting the proposed health index.The combination of sensor information has been carried out using a new approach to determining the probabilities in the Dempster-Shafer combination rules and fuzzy c-means clustering method.Using the simulation and forecasting of extracted vibration-based health index by autoregressive Markov regime switching(ARMRS)method,final health state is determined and the remaining useful life(RUL)is estimated.In order to evaluate the model,sensor data provided by FEMTO-ST Institute have been used.
基金supported by General Research Fund ( CUHK14302915) from the Research Grants Council of the Hong Kong Special Administrative RegionDirect Grant ( 4053270) from the Faculty of Science of The Chinese University of Hong Kong
文摘DNA is an attractive biomaterial for constructing nanomachines and nanomaterials owing to their self-recognition and self-assembly properties.In addition to the well-known double helical structures,DNA molecules can also form a variety of unusual structures like hairpins,triplexes and quadruplexes.These unusual DNAs sometimes have advantages over double helical DNAs in constructing nanomachines such as enhanced thermodynamic stability and higher sensitivity to external stimuli,which made them as promising motifs in recenttwo decades.Regardless of how complicated DNA-based nanomachines are,the fundamental concept in these nanomachines is based on a proper design and usage of DNA molecular switch.Among the reported DNA molecular switches,pH-controlled systems show great potentials in drug delivery and cellular pH sensing.Up to now,most of the reported pH-controlled molecular switches used i-motif or triplex DNAs.However,owing to the relatively long sequence requirement for the formation of i-motif and triplex DNAs,an invading DNA strand needs to be added to activate the molecular switch,and thus DNA wastes will be generated into the system and a full structural conversion will usually take a relatively long time of minutes to hours.To overcome the disadvantages of DNA waste generation and slow kinetics,molecular switches using smaller-size,thermodynamically stable and pH-sensible unusual DNA structures will have the advantages of easier manipulation and faster kinetics.Recently,we discovered a new type of unusual DNA structure called the minidumbbell(MDB)which is formed by a single-strand 8-nucleotide sequence.The MDB is composed of two type II tetraloops in which the first and fourth loop residues form loop-closing base pairs,the second loop residues fold into the minor groove to form base-base stacking or mispairing interactions,and the third loop residues stack on their nearby loop-closing base pairs.In particular,the MDB formed by a sequence containing two CCTG repeats has a relatively low melting temperature(Tm)of^22℃at pH 7.0,whereas its Tm can be significantly increased to^46℃at pH 5.0 due to the formation of a three hydrogen bond hemiprotonated C+·C mispair in the minor groove.This MDB,when combined with its complementary sequence,shows instant and complete structural conversions when the pH switches between 5.0 and 7.0 without using an invading DNA strand,serving as a simple and efficient pH-controlled molecular switch.In order to allow the incorporation of fluorophores to the two termini of the MDB,we aim to design a thermodynamically more stable MDB structure in this study.Through a rational design by introducing hydrophobic interactions to the MDB formed by the sequence containing two CCTG repeats at pH 5.0,we obtained an MDB structure with a record-high Tm of^62℃.Furthermore,this MDB was found to exist stably in the presence of 5’and 3’-overhanging residues,revealing its capability of being attached with fluorophores or other functional groups,and thus making it potentially a versatile pH-controlled molecular switch for designing nanomachines and nanomaterials.
文摘Broad-band all-optical wavelength conversion of differential phase-shift keyed (DPSK) signal is experimentally demonstrated. This scheme is composed of a one-bit delay interferometer demodulation stage followed by a semiconductor optical amplifier (SOA) based nonlinear polarization switch. A wavelength converter for the 10 G b/s DPSK signal is presented, which has a wide wavelength range of more than 30 nm. The converted signals experience small power penalties less than 1.4 dB compared with the original signal, at a bit error rate of 10-9. Additionally, the optical spectra, the measured waveforms and the open eye diagrams of the converted signals show a high quality wavelength conversion performance.
文摘We propose and fabricate a vertically integrated thermo-optic waveguide switch. It controls the optical path between two vertically stacked waveguides using the thermo-optic effect of optical polymer. The measured crosstalk is less than -10 dB.