Influences of Temperature and Coal Particle Size on the Flash Pyrolysis of Coal in a Fast-entrained Bed

The experiments on the flash pyrolysis of a lignite were carried out in a fast-entrained bed reactor as a basic study on a so-called ＇ coal topping process＇. The investigation focused on the effects of pyrolysis temperature and coal particle size on the product distribution and composition. The experimental results show that an increase in the pyrolysis temperature results in a higher yield of gaseous products while a larger particle size leads to a decrease of the liquid yield. An optimum temperature for the liquid yield was found to be 650℃. A certain amount of phenol groups was found in the liquid products, which may be used to produce high-valued fine chemicals. The FTIR analyses of the coal and chars show that aliphatic structures in the chars are gradually replaced by aromatic structures with the increasing of pyrolysis temperature and coal particle size. The results of this study provide fundamental data and optimal conditions to maximize light oils yields for the coal topping process.

Effect of Temperature on Phase and Alumina Extraction Efficiency of the Product from Sintering Coal Fly Ash with Ammonium Sulfate

A new developed technology for extracting alumina from coal fly ash was studied in this paper. In this technology, coal fly ash is first sintered with ammonium sulfate, forming ammonium aluminum sulfate in the resultant product, where alumina can be easily leached without using any strong acid or alkali. The products obtained under different sintering conditions were characterized by X-ray diffractometry. Alumina extraction efficiency of these products was also investigated. The results show that the sintering temperature and time substantially influence the phase composition and alumina extraction efficiency of sintered products, while the heating rate has little influence. The optimal sintering condition is 400 °C for 3 h in air with a heating rate of 6 °C·min-1.Under the optimal sintering condition, the alumina extraction efficiency from as-sintered coal fly ash can reach 85% or more.

Large-scale laboratory study on the evolution lawof temperature fields in the context of underground coal gasification

This article presents the evolution law of temperature fields in a large-scale laboratory Underground Coal Gasification reactions using Ulanqab lignite under actual conditions.The results show that in the cultivation stage of oxidation zone,the main direction of the temperature field expansion is consistent with the crack direction of the coal seam.In the gasification stabilization stage,the main direction of the temperature field expansion is along the channel.The temperature of the coal seam and the overlying rock mass at its interface with the furnace directly above the gasification channel is equivalent to that of the coal seam temperature,and this temperature is much greater than the temperatures observed near both side walls of the gasification channel at the interface.However,temperatures perpendicular to the axis of the gasification channel are similar at a vertical distance of 40 cm away from the interface.The temperature distributions indicate that the transmission of heat through the overlying rock mass is more rapid in the vertical direction than in the horizontal direction.Moreover,some degree of thermal dispersion is observed in the vertical direction near the outlet.The thermal dispersion coefficient is 0.72 and dispersion angle γ is 78.7°.

Analysis on the Governing Reactions in Coal Oxidation at Temperatures up to 400°C

The present study aims to further understanding of the principal reactions that occur during coal oxidation at moderate temperatures. Mass change and heat evolution of a sample were monitored by thermo-gravimetric analysis coupled with differential thermal analysis (TGA/DTA). Gaseous and solid products were traced using online or in situ Fourier trans- form infrared spectroscopy (FTIR). Measurements were conducted by heating the samples up to 400?C, with the O2 concentration in the reaction medium set at 0, 10, 21, and 40 vol%, respectively. It was observed that the mass increase of a sample between 150?C and ~275oC was a result of the accumulation of C=O containing species in the coal structure, whereas substantial mass loss and heat evolution of a sample at ~400oC can be attributed to the significant involvement of the direct “burn-off” reaction. Enrichment of O2 inthe reaction medium leads to the acceleration in oxygen chemi- sorption, formation and decomposition of the solid oxygenated complexes, as well as the “burn-off” reaction. With the temperature increasing, the oxidation process governed by oxygen chemisorption gradually shifts to that by significant decomposition reactions, and eventually to that by the direct “burn-off” reaction. Temperature boundaries of these stages can be determined using parameters defined based on a set of TG/DTA data. Shift in the governing reactions is essentially due to the diverse requirements of reactants of the reactions and their energy barriers to be overcome. In en- gineering practice, the phenomena of self-heating and spontaneous combustion of coal correspond to chemisorption and the direct “burn-off” reaction, respectively.

The dynamic change of pore structure for low-rank coal under refined upgrading pretreatment temperatures

Pore structure characteristics are significant factor in the evaluation of the physical characteristics of low-rank coal.In this study,three low-rank coal samples were collected from the Xishanyao Formation,Santanghu Basin,and low-temperature liquid-nitrogen adsorption(LP-N2A)measurements were taken under various pretreatment temperatures.Owing to the continuous loss of water and volatile matter in low-rank coal,the total pore volume assumes a three-step profile with knee temperatures of 150°C and 240°C.However,the ash in the coal can protect the coal skeleton.Pore collapse mainly occurs for mesopores with aperture smaller than 20 nm.Mesopores with apertures smaller than 5 nm exhibit a continuous decrease in pore volume,whereas the pore volume of mesopores with apertures ranging from 5 to 10 nm increases at lower pretreatment temperatures(<150°C)followed by a faint decrease.As for mesopores with apertures larger than 10 nm,the pore volume increases significantly when the pretreatment temperature reaches 300°C.The pore structure of low-rank coal features a significant heating effect,the pretreatment temperature should not exceed 150°C when the LP-N2A is used to evaluate the pore structure of low-rank coal to effectively evaluate the reservoir characteristics of low-rank coal.

STUDY ON THE METHOD FOR FORECASTING DANGEROUSNESS OF COAL FACE AND HEADING FACE OUTBURST BY TWO TEMPERATURE INDEXES

In line with the sensitivity of coal drillings temperature and coalbed temperature to the dangerous zone of coal and gas outburst, two temperature sensitive indexes (△Tm, △tm) for forecasting dangerousness of coal face and heading face outburst are defined, and deal with the foundation on drillings and coalbed temperatures used as sensitive indexes and the principle and method of determining drillings and coalbed temperatures. On the basis of this, we put forward the method for forecasting dangerousness of coal face and heading face outburst by two temperature sensitive indexes and determine the critical values of two temperature sensitive indexes (△Tm= 5.5℃, △tm = 4.5℃) by in-situ observation and requirement for determining sensitive index.

A back analysis of the temperature field in the combustion volume space during underground coal gasification

The exact shape and size of the gasification channel during underground coal gasification(UGC) are of vital importance for the safety and stability of the upper parts of the geological formation.In practice existing geological measurements are insufficient to obtain such information because the coal seam is typically deeply buried and the geological conditions are often complex.This paper introduces a cylindrical model for the gasification channel.The rock and soil masses are assumed to be homogeneous and isotropic and the effect of seepage on the temperature field was neglected.The theory of heat conduction was used to write the equation predicting the temperature field around the gasification channel.The idea of an excess temperature was introduced to solve the equations.Applying this model to UCG in the field for an influence radius,r,of 70 m gave the model parameters,u1,2,3...,of 2.4,5.5,8.7...By adjusting the radius(2,4,or 6 m) reasonable temperatures of the gasification channel were found for 4 m.The temperature distribution in the vertical direction,and the combustion volume,were also calculated.Comparison to field measurements shows that the results obtained from the proposed model are very close to practice.

Experimental study on the variation law of coal temperature during excavation in coal mines

By testing the temperature of the coal and the stress of the working surface, we got the variation law of coal temperature and coal stress during the excavation. The result shows that the activities of mining affect the coal temperature, the fluctuation of coal temperature and the coal stress is synchronous. During the smooth change of crustal stress, the coal temperature basically keeps unchanged, when the dynamic phenomenon appears, the coal temperature changes, as well the coal stress. Therefore, we can use the online coal temperature monitoring system to test the coal temperature of the working surface continuously, and it can provide basic information for forecasting coal mine power disaster before it happens.

Effect of Temperature on the Molecular Weight Distribution in the Different Ranks of Coal during the On-Line Investigation of Coal Pyrolysis Gas Using Direct Photoionization Mass Spectroscopy

Coal pyrolysis gas from different ranks of coal was monitored on real time basis using photoionization mass spectroscopy. The molecular weight distribution of different products as a function of temperature from various coal ranks studied was observed. It was noted that the release of different classes of compounds like phenols, alkenes, alkylated aromatics and aromatic skeletons was temperature dependent. For all the coal ranks at lower temperatures phenols were the main component, with alkenes and alkylated aromatics at slight higher temperatures and aromatic skeletons were released at the highest temperatures studied.

Effects of high temperature on the microstructure and mechanical behavior of hard coal

Coal is a common porous sedimentary rock whose microstructure and mechanical behavior are often affected by high temperature.In order to deeply investigate the effect of high temperature on the structure and mechanical properties of coal,six groups of coal samples with different heating temperatures were prepared.Various testing methods,including ultrasonic test,scanning electron microscopy,nuclear magnetic resonance and uniaxial compression test,were used in this study.The results showed that the physical and chemical change processes of coal samples under high temperature can be divided into two stages:the stage of drying and degassing and the stage of pyrolysis of the coal matrix.With the increase of heating temperature,the total porosity of coal samples increases,while the integrity and the deformation resistance of coal samples decrease.In addition,the elastic modulus and uniaxial compressive strength of the coal sample decrease with the increase of heating temperature.The Poisson’s ratio decreases firstly and then increases with the increase of heating temperature.

The relationship between the microstructures and catalytic behaviors of iron–oxygen precursors during direct coal liquefaction

A series of both unsupported and coal‐supported iron–oxygen compounds with gradual changes in microstructure were synthesized by a precipitation‐oxidation process at 20 to 70°C.The relationship between the microstructures and catalytic activities of these precursors during direct coal liquefaction was studied.The results show that the microstructure could be controlled through adjusting the synthesis temperature during the precipitation‐oxidation procedure,and that compounds synthesized at lower temperatures exhibit higher catalytic activity.As a result of their higher proportions ofγ‐FeOOH orα‐FeOOH crystalline phases,the unsupported iron–oxygen compounds synthesized at 20–30°C,which also had high specific surface areas and moisture levels,generate oil yields 4.5%–4.6%higher than those obtained with precursors synthesized at 70°C.It was also determined that higher oil yields were obtained when the catalytically‐active phase formed by the precursors during liquefaction(pyrrhotite,Fe1-xS)had smaller crystallites.Feed coal added as a carrier was found to efficiently disperse the active precursors,which in turn significantly improved the catalytic activity during coal liquefaction.

An experimental study of the effect of ionic liquids on the low temperature oxidation of coal

Fourier transform infrared spectroscopy(FTIR) and constant heating rate experiments were performed to study the low temperature oxidation of coal treated by an ionic liquid,1-allyl-3-methylimidazolium chloride.The inerting effect of the ionic liquid toward the low temperature oxidation process is discussed.The results show that:(1) The hydroxyl content associated with hydrogen bonds,the aliphatic methyl content,the methylene group content,and the ether oxygen bond content are reduced in the treated coal.At the same time the content of aromatic C@C bonds is constant but these chemical bonds weaken and some substituted aromatic hydrocarbon content increases while other types decrease.This demonstrates that(AMIm)Cl dissolves and destroys the coal surface microstructure;(2) The oxygen consumption of the treated coal is less than what is seen in raw coal.The CO,CO 2,C 2 H 4,and C 2 H 6 content from the treated coal is reduced compared to the untreated coal;(3) The apparent activation energy for the oxidizing reaction is different in the treated and raw coals.Micro-structural changes and macroscopic gas production allow us to conclude that(AMIm)Cl can effectively inhibit low temperature oxidation of coal.

Prediction of oxygen concentration and temperature distribution in loose coal based on BP neural network

An effective method for preventing spontaneous combustion of coal stockpiles on the ground is to control the air-flow in loose coal. In order to determine and predict accurately oxygen concentrations and temperatures within coal stockpiles, it is vital to obtain information of self-heating conditions and tendencies of spontaneous coal combustion. For laboratory conditions, we designed our own experimental equipment composed of a control-heating system, a coal column and an oxygen concentration and temperature monitoring system, for simulation of spontaneous combustion of block coal （13-25 mm） covered with fine coal （0-3 mm）. A BP artificial neural network （ANN） with 150 training samples was gradually established over the course of our experiment. Heating time, relative position of measuring points, the ratio of fine coal thickness, artificial density, voidage and activation energy were selected as input variables and oxygen concentration and temperature of coal column as output variables. Then our trained network was applied to predict the trend on the untried experimental data. The results show that the oxygen concentration in the coal column could be reduced below the minimum still able to induce spontaneous combustion of coal - 6% by covering the coal pile with fine coal, which would meet the requirement to prevent spontaneous combustion of coal stockpiles. Based on the prediction of this ANN, the average errors of oxygen concentration and temperature were respectively 0.5% and 7 ℃, which meet actual tolerances. The implementation of the method would provide a practical guide in understanding the course of self-heating and spontaneous combustion of coal stockpiles.

Effects of coal rank, Fe_3O_4 amounts and activation temperature on the preparation and characteristics of magnetic activated carbon

Coal-based Magnetic Activated Carbons （CMAC＇s） were prepared from three representative coal samples of various ranks： Baorigele lignite from Inner Mongolia; Datong bitumite from Shanxi province; and Taixi anthracite from Ningxia Hui Auto- nomous Region. Fe3O4 was used as a magnetic additive. A nitrogen-adsorption analyzer was used to determine the specific surface area and pore structure of the resulting activated carbons. The adsorption capacity was assessed by the adsorption of iodine and methylene blue. X-ray diffraction was used to measure the evolution behavior of Fe304 during the preparation process. Magnetic properties were characterized with a vibrating-sample magnetometer. The effect of the activation temperature on the performance of CMAC＇s was also studied. The results show that, compared to Baorigele lignite and Taixi anthracite, the Datong bitumite is more appropriate for the preparation of CMAC＇s with a high specific surface area, an advanced pore structure and suitable magnetic properties. Fe304 can effectively enhance the magnetic properties and control the pore structure by increasing the ratio of meso- pores. An addition of 6.0% Fe304 and an activation temperature of 880 ℃ produced a CMAC having a specific surface area, an iodine adsorption, a methylene blue adsorption and a specific saturation magnetization of 1152.0 m2/g, 1216.7 mg/g, 229.5 mg/g and 4.623 emu/g, respectively. The coal used to prepare this specimen was Datong bitumite.

Influence of coal blending on mineral transformation at high temperatures

Transformation of mineral matter is important for coal utilization at high temperatures.This is especially true for blended coal.XRD and FTIR were employed together to study the transformation of mineral matter at high temperature in blended coals.It was found that the concentration of catalytic minerals, namely iron oxides, increases with an increasing ratio of Shenfu coal, which could improve coal gasification.The transformation characteristics of the minerals in blended coals are not exactly predictable from the blend ratio.This was proved by comparing the iron oxide content to the blending ratio.The results from FTIR are comparable with those from XRD.FTIR is an effective method for examining variation in mineral matter.

Retrieval and Analysis of Coal Fire Temperature in Wuda Coalfield, Inner Mongolia, China

Coal fire burning around the world is an environmental catastrophe characterized by the emission of noxious gases, particulate matter, and condensation by-products. In this study, coal fire temperature is retrieved based on Landsat 5 TM images and Generalized Single-Channel Algorithm (GSCA), in Wuda coalfield, Inner Mongolia, China. Then coal fire zones are extracted by Jenks′ natural breaks and threshold methods based on temperature images. Changes of coal fire zones are analyzed from 1989 to 2008. The results are summarized as follows: 1) The coal fire temperature retrieval method based on Landsat 5 TM and the GSCA model is effective and feasible, because the temperature error is relatively small (from –2.9℃ to +2.6℃) between the measured temperature and the retrieved temperature. 2) The accuracy is relatively high to extract coal fire zones through the Jenks′ natural breaks and threshold methods, because 83.56% of surveyed area is located in the coal fire zones extracted in 2005. 3) The coal fire area increased 9.81 × 10 5 m 2 from 1989 to 2005, and the annual growth is about 6.1 × 10 4 m 2 , with an annual increasing rate of 2.48%. The area of coal fire decreased by 8.1 × 10 5 m 2 from 2005 to 2008.

Crossing point temperature of coal

A further understanding of the self-heating of coal was obtained by investigating the crossing point temperature（CPT） of different ranks of coal.The tests were carried out using a self-designed experimental system for coal self-heating.50 g（±0.01 g） of coal particles ranging from 0.18 mm to 0.38 mm in size were put into a pure copper reaction vessel attached to the center of a temperature programmed enclosure.The temperature program increased the temperature at a rate of 0.8℃/min.Dry air was permitted to flow into the coal reaction vessel at different rates.The surrounding temperature and the coal temperature were monitored by a temperature logger.The results indicate that CPT is affected by coal rank,moisture,sulfur, and the experimental conditions.Higher ranked coals show higher CPT values.A high moisture content causes a delay phenomenon during the self-heating of the coal.Drying at 40℃decreases the effects of moisture.The reactivity of sulfur components in the coal is low under dry and low-temperature conditions. These components form a film that covers the coal surface and slightly inhibits the self-heating of the coal. The flow rate of dry air,and the heating rate of the surroundings,also affect the self-heating of the coal.The most appropriate experimental conditions for coal samples of a given weight and particle size were determined through contrastive analysis.Based on this analysis we propose that CPTs be determined under the same,or nearly the same conditions,for evaluation of the spontaneous combustion of coal.

Spatio-temporal variation and propagation direction of coal fire in Jharia Coalfield,India by satellite-based multi-temporal night-time land surface temperature imaging

In this paper,the spatio-temporal variation and propagation direction of coal fire were studied in the Jharia Coalfield(JCF),India during 2006–2015 through satellite-based night-time land surface temperature(LST)imaging.The LST was retrieved from Advanced Spaceborne Thermal Emission and Reflection Radiometer(ASTER)night-time thermal-infrared data by a robust split-window algorithm based on scene-specific regression coefficients,band-specific hybrid emissivity,and night-time atmospheric transmittance.The LST-profile-based coal fire detection algorithm was formulated through statistical analysis of the LST values along multiple transects across diverse coal fire locations in the JCF in order to compute date-specific threshold temperatures for separating thermally-anomalous and background pixels.This algorithm efficiently separates surface fire,subsurface fire,and thermally-anomalous transitional pixels.During the observation period,it was noticed that the coal fire area increased significantly,which resulted from new coal fire at many places owing to extensive opencast-mining operations.It was observed that the fire propagation occurred primarily along the dip direction of the coal seams.At places,lateral-propagation of limited spatial extent was also observed along the strike direction possibly due to spatial continuity of the coal seams along strike.Moreover,the opencast-mining activities carried out during 2009–2015 and the structurally weak planes facilitated the fire propagation.

Calculation of Apparent Activation Energy of Coal Oxidation at Low Temperatures by Measuring CO Yield

By analyzing previous studies on activation energy of coal oxidation at low temperatures, a theoretical calculation model of apparent activation energy is established. Yield of CO is measured by using the characteristic detector of coal oxidation at 30-90 ℃. The impact of parameters, such as airflow and particle size, on activation energies is analyzed. Finally, agreement was obtained between activation energies and the dynamic oxygen absorbed in order to test the accuracy of the model. The results show that： 1） a positive exponential relation between concentration of CO and temperature in the process of the experiment is obtained： increases are almost identical and the initial CO is low; 2） the apparent activation energies increase gradually with the sizes of particle at the same airflow, but the gradients increase at a decreasing rate; 3） the apparent activation energies increase linearly with airflow. For the five coal particles, the differences among the energies are relatively high when the airflow was low, but the differences were low when the airflow was high; 4） the optimum sizes of particle, 0.125-0.25 ram, and the optimum volume of airflow, 100 mL/min, are determined from the model; 5） the apparent activation energies decrease with an increase in oxygen absorbed. A negative exponential relation between the two is obtained,

Experimental study on the infrared precursor characteristics of gas-bearing coal failure under loading

The stress and gas pressure in deep coal seams are very high,and instability and failure rapidly and intensely occur.It is important to study the infrared precursor characteristics of gas-bearing coal instability and failure.In this paper,a self-developed stress-gas coupling failure infrared experimental system was used to analyse the infrared radiation temperature(IRT)and infrared thermal image precursor characteristics of gas-free coal and gas-bearing coal.The changes in the areas of the infrared temperature anomalous precursor regions and the effect of the gas on the infrared precursors were examined.The results show that high-temperature anomalous precursors arise mainly when the gas-free coal fails under loading,whereas the gas-bearing coal has high-temperature and low-temperature anomalous precursors.The area of the high-temperature anomalous precursor is approximately 30%–40%under gasbearing coal unstable failure,which is lower than the 60%–70%of the gas-free coal.The area of the low-temperature abnormal precursor is approximately 3%–6%,which is higher than the 1%–2%of the gas-free coal.With increasing gas pressure,the area of the high-temperature anomalous precursor gradually decreases,and the area of the low-temperature anomalous precursor gradually increases.The highand low-temperature anomalous precursors of gas-bearing coal are mainly caused by gas desorption,volume expansion,and thermal friction.The presence of gas inhibits the increase in IRT on the coal surface and increases the difficulty of infrared radiation(IR)monitoring and early warning for gas-bearing coal.